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1.
We investigated the inventory of presolar silicate, oxide, and silicon carbide (SiC) grains of fine‐grained chondrule rims in six Mighei‐type (CM) carbonaceous chondrites (Banten, Jbilet Winselwan, Maribo, Murchison, Murray and Yamato 791198), and the CM‐related carbonaceous chondrite Sutter's Mill. Sixteen O‐anomalous grains (nine silicates, six oxides) were detected, corresponding to a combined matrix‐normalized abundance of ~18 ppm, together with 21 presolar SiC grains (~42 ppm). Twelve of the O‐rich grains are enriched in 17O, and could originate from low‐mass asymptotic giant branch stars. One grain is enriched in 17O and significantly depleted in 18O, indicative of additional cool bottom processing or hot bottom burning in its stellar parent, and three grains are of likely core‐collapse supernova origin showing enhanced 18O/16O ratios relative to the solar system ratio. We find a presolar silicate/oxide ratio of 1.5, significantly lower than the ratios typically observed for chondritic meteorites. This may indicate a higher degree of aqueous alteration in the studied meteorites, or hint at a heterogeneous distribution of presolar silicates and oxides in the solar nebula. Nevertheless, the low O‐anomalous grain abundance is consistent with aqueous alteration occurring in the protosolar nebula and/or on the respective parent bodies. Six O‐rich presolar grains were studied by Auger Electron Spectroscopy, revealing two Fe‐rich silicates, one forsterite‐like Mg‐rich silicate, two Al‐oxides with spinel‐like compositions, and one Fe‐(Mg‐)oxide. Scanning electron and transmission electron microscopic investigation of a relatively large silicate grain (490 nm × 735 nm) revealed that it was crystalline åkermanite (Ca2Mg[Si2O7]) or a an åkermanite‐diopside (MgCaSi2O6) intergrowth.  相似文献   

2.
Abstract— The fine-grained matrix of the Semarkona unequilibrated ordinary chondrite contains an assemblage of Fe carbides that are associated with oxides, sulfides, carbonates, and hydrated silicates. The carbides consist of fine-scale epitactic intergrowths of cohenite (Fe3C) and Hägg carbide (Fe5C2) that formed as by-products of gas-solid reactions on the Semarkona parent body. The carbide intergrowths resulted from prograde reactions at moderate temperatures in the presence of a highly reducing carbon-bearing gas. The carburization occurred prior to the aqueous alteration episode that produced the Fe-rich phyllosilicates throughout the interchondrule matrix and the thin magnetite rims surrounding the carbide grains. The occurrence of the carbide intergrowths places an upper limit of <500 °C on the maximum postaccretional thermal processing that occurred on the Semarkona parent body.  相似文献   

3.
Abstract— We report the results of our petrological and mineralogical study of Fe‐Ni metal in type 3 ordinary and CO chondrites, and the ungrouped carbonaceous chondrite Acfer 094. Fe‐Ni metal in ordinary and CO chondrites occurs in chondrule interiors, on chondrule surfaces, and as isolated grains in the matrix. Isolated Ni‐rich metal in chondrites of petrologic type lower than type 3.10 is enriched in Co relative to the kamacite in chondrules. However, Ni‐rich metal in type 3.15–3.9 chondrites always contains less Co than does kamacite. Fe‐Ni metal grains in chondrules in Semarkona typically show plessitic intergrowths consisting of submicrometer kamacite and Ni‐rich regions. Metal in other type 3 chondrites is composed of fine‐ to coarse‐grained aggregates of kamacite and Ni‐rich metal, resulting from metamorphism in the parent body. We found that the number density of Ni‐rich grains in metal (number of Ni‐rich grains per unit area of metal) in chondrules systematically decreases with increasing petrologic type. Thus, Fe‐Ni metal is a highly sensitive recorder of metamorphism in ordinary and carbonaceous chondrites, and can be used to distinguish petrologic type and identify the least thermally metamorphosed chondrites. Among the known ordinary and CO chondrites, Semarkona is the most primitive. The range of metamorphic temperatures were similar for type 3 ordinary and CO chondrites, despite them having different parent bodies. Most Fe‐Ni metal in Acfer 094 is martensite, and it preserves primary features. The degree of metamorphism is lower in Acfer 094, a true type 3.00 chondrite, than in Semarkona, which should be reclassified as type 3.01.  相似文献   

4.
We report in situ O isotope and chemical compositions of magnetite and olivine in chondrules of the carbonaceous chondrites Watson‐002 (anomalous CK3) and Asuka (A)‐881595 (ungrouped C3). Magnetite in Watson‐002 occurs as inclusion‐free subhedral grains and rounded inclusion‐bearing porous grains replacing Fe,Ni‐metal. In A‐881595, magnetite is almost entirely inclusion‐free and coexists with Ni‐rich sulfide and less abundant Ni‐poor metal. Oxygen isotope compositions of chondrule olivine in both meteorites plot along carbonaceous chondrite anhydrous mineral (CCAM) line with a slope of approximately 1 and show a range of Δ17O values (from approximately ?3 to ?6‰). One chondrule from each sample was found to contain O isotopically heterogeneous olivine, probably relict grains. Oxygen isotope compositions of magnetite in A‐881595 plot along a mass‐dependent fractionation line with a slope of 0.5 and show a range of Δ17O values from ?2.4‰ to ?1.1‰. Oxygen isotope compositions of magnetite in Watson‐002 cluster near the CCAM line and a Δ17O value of ?4.0‰ to ?2.9‰. These observations indicate that magnetite and chondrule olivine are in O isotope disequilibrium, and, therefore, not cogenetic. We infer that magnetite in CK chondrites formed by the oxidation of pre‐existing metal grains by an aqueous fluid during parent body alteration, in agreement with previous studies. The differences in Δ17O values of magnetite between Watson‐002 and A‐881595 can be attributed to their different thermal histories: the former experienced a higher degree of thermal metamorphism that led to the O isotope exchange between magnetite and adjacent silicates.  相似文献   

5.
We have carried out a systematic study involving SEM, EPMA, and TEM analyses to determine the textures and compositions of sulfides and sulfide–metal assemblages in a suite of minimally to weakly altered CM and CR carbonaceous chondrites. We have attempted to constrain the distribution and origin of primary sulfides that formed in the solar nebula, rather than by secondary asteroidal alteration processes. Our study focused primarily on sulfide assemblages associated with chondrules, but also examined some occurrences of sulfides within the matrices of these meteorites. Although sulfides are a minor phase in carbonaceous chondrites, we have determined that primary sulfide grains are actually a major proportion of the sulfide grains in weakly altered CM chondrites and have survived aqueous alteration relatively unscathed. In minimally altered CR chondrites, we have determined that essentially all of the sulfides are of primary origin, confirming the observations of Schrader et al. ( 2015 ). The pyrrhotite–pentlandite intergrowth (PPI) grains formed from crystallization of monosulfide solid solution (mss) melts, while sulfide-rimmed metal (SRM) grains formed from sulfidization of Fe,Ni metal. Micron-sized metal inclusions in some PPI grains may have formed by co-crystallization of metal and sulfide from a sulfide melt that experienced S volatilization during the chondrule formation event, or alternatively, may be a remnant of sulfidization of Fe,Ni metal that also occurred during chondrule formation. Sulfur fugacity for SRM grains ranged from −18 to −10 (log units) largely in agreement with predicted solar nebular values. Our observations show that understanding the formation mechanisms of primary sulfide grains provides clues to solar nebular conditions, such as the sulfur fugacity during chondrule formation.  相似文献   

6.
Our detailed mineralogical, elemental, and isotopic study of the Miller Range (MIL) 07687 meteorite showed that, although this meteorite has affinities to CO chondrites, it also exhibits sufficient differences to warrant classification as an ungrouped carbonaceous chondrite. The most notable feature of MIL 07687 is the presence of two distinct matrix lithologies that result from highly localized aqueous alteration. One of these lithologies is Fe‐rich and exhibits evidence for interaction with water, including the presence of fibrous (dendritic) ferrihydrite. The other lithology, which is Fe‐poor, appears to represent relatively unaltered protolith material. MIL 07687 has presolar grain abundances consistent with those observed in other modestly altered carbonaceous chondrites: the overall abundance of O‐rich presolar grains is 137 ± 3 ppm and the overall abundance of SiC grains is 71 ± 11 ppm. However, there is a large difference in the observed O‐rich and SiC grain number densities between altered and unaltered areas, reflecting partial destruction of presolar grains (both O‐ and C‐rich grains) due to the aqueous alteration experienced by MIL 07687 under highly oxidizing conditions. Detailed coordinated NanoSIMS‐TEM analysis of a large hotspot composed of an isotopically normal core surrounded by a rim composed of 17O‐rich grains is consistent with either original condensation of the core and surrounding grains in the same parent AGB star, or with grain accretion in the ISM or solar nebula.  相似文献   

7.
Abstract— Isheyevo is a metal‐rich carbonaceous chondrite that contains several lithologies with different abundances of Fe,Ni metal (7–90 vol%). The metal‐rich lithologies with 50–60 vol% of Fe,Ni metal are dominant. The metal‐rich and metal‐poor lithologies are most similar to the CBb and CH carbonaceous chondrites, respectively, providing a potential link between these chondrite groups. All lithologies experienced shock metamorphism of shock stage S4. All consist of similar components—Fe,Ni metal, chondrules, refractory inclusions (Ca, Al‐rich inclusions [CAIs] and amoeboid olivine aggregates [AOAs]), and heavily hydrated lithic clasts—but show differences in their modal abundances, chondrule sizes, and proportions of porphyritic versus non‐porphyritic chondrules. Bulk chemical and oxygen isotopic compositions are in the range of CH and CB chondrites. Bulk nitrogen isotopic composition is highly enriched in 15N (δ15N = 1122‰). The magnetic fraction is very similar to the bulk sample in terms of both nitrogen release pattern and isotopic profile; the non‐magnetic fraction contains significantly less heavy N. Carbon released at high temperatures shows a relatively heavy isotope signature. Similarly to CBb chondrites, ～20% of Fe,Ni‐metal grains in Isheyevo are chemically zoned. Similarly to CH chondrites, some metal grains are Ni‐rich (>20 wt% Ni). In contrast to CBb and CH chondrites, most metal grains are thermally decomposed into Ni‐rich and Ni‐poor phases. Similar to CH chondrites, chondrules have porphyritic and non‐porphyritic textures and ferromagnesian (type I and II), silica‐rich, and aluminum‐rich bulk compositions. Some of the layered ferromagnesian chondrules are surrounded by ferrous olivine or phyllosilicate rims. Phyllosilicates in chondrule rims are compositionally distinct from those in the hydrated lithic clasts. Similarly to CH chondrites, CAIs are dominated by the hibonite‐, grossite‐, and melilite‐rich types; AOAs are very rare. We infer that Isheyevo is a complex mixture of materials formed by different processes and under different physico‐chemical conditions. Chondrules and refractory inclusions of two populations, metal grains, and heavily hydrated clasts accreted together into the Isheyevo parent asteroid in a region of the protoplanetary disk depleted in fine‐grained dust. Such a scenario is consistent with the presence of solar wind—implanted noble gases in Isheyevo and with its comparatively old K‐Ar age. We cannot exclude that the K‐Ar system was affected by a later collisional event. The cosmic‐ray exposure (CRE) age of Isheyevo determined by cosmogenic 38Ar is ～34 Ma, similar to that of the Bencubbin (CBa) meteorite.  相似文献   

8.
The CM carbonaceous chondrite meteorites experienced aqueous alteration in the early solar system. They range from mildly altered type 2 to almost completely hydrated type 1 chondrites, and offer a record of geochemical conditions on water‐rich asteroids. We show that CM1 chondrites contain abundant (84–91 vol%) phyllosilicate, plus olivine (4–8 vol%), magnetite (2–3 vol%), Fe‐sulfide (<5 vol%), and calcite (<2 vol%). The CM1/2 chondrites contain phyllosilicate (71–88 vol%), olivine (4–20 vol%), enstatite (2–6 vol%), magnetite (2–3 vol%), Fe‐sulfides (1–2 vol%), and calcite (~1 vol%). As aqueous alteration progressed, the abundance of Mg‐serpentine and magnetite in the CM chondrites increased. In contrast, calcite abundances in the CM1/2 and CM1 chondrites are often depleted relative to the CM2s. The modal data support the model, whereby metal and Fe‐rich matrix were the first components to be altered on the CM parent body(ies), before further hydration attacked the coarser Mg‐rich silicates found in chondrules and fragments. Based on the absence of tochilinite, we suggest that CM1 chondrites experienced increased alteration due to elevated temperatures (>120 °C), although higher water/rock ratios may also have played a role. The modal data provide constraints for interpreting the composition of asteroids and the mineralogy of samples returned from these bodies. We predict that “CM1‐like” asteroids, as has been proposed for Bennu—target for the OSIRIS‐REx mission—will have a high abundance of Mg‐rich phyllosilicates and Fe‐oxides, but be depleted in calcite.  相似文献   

9.
Abstract— Scanning electron microscopy and secondary ion mass spectrometry of the unequilibrated CH chondrite Pecora Escarpment (PCA) 91467 revealed four carriers of isotopically heavy N: (1) aggregates of carbonaceous material and silicates, (2) iron‐nickel metal grains with fine Fe‐Cr sulfide inclusions, (3) Si‐rich Fe‐Ni metal associated with Fe‐sulfide and (4) hydrated areas in the matrix. N in carbon‐silicate aggregates is isotopically heavy (δ15N is as high as 2500%0), whereas the other elements are isotopically normal, suggesting interstellar origin of carbonaceous material in the aggregates. Based on isotopic and textural evidence, we suggest that the carriers (2) and (3) were formed by brief heating in the solar nebula, whereas the carrier (4) was formed in a parent‐body asteroid. The carbon‐silicate aggregates are likely to be related to interstellar graphite found in Murchison and may also be the source of heavy N in bencubbinites.  相似文献   

10.
Abstract— Iron‐rich aureoles in CM carbonaceous chondrites are previously unidentified domains of aqueously altered matrix material, whose FeO content may exceed that of the surrounding matrix by up to more than 15 wt%. We describe the petrography and mineralogy of these objects in the CM chondrites Murray, Murchison, and Allan Hills (ALH) 81002. The size of Fe‐rich aureoles ranges from a few hundred microns to several millimeters in diameter and appears to be a function of the degree of alteration of the host chondrite. The origin of Fe‐rich aureoles is related to the alteration of large metal grains that has resulted in the formation of characteristic PCP‐rich reaction products that are frequently observed at the centers of the aureoles. This suggests that Fe‐rich aureoles in CM chondrites are the result of the mobilization of Fe from altering metal grains into the matrix. The fact that Fe‐rich aureoles enclose numerous chondritic components such as chondrules, calcium‐aluminum‐rich inclusions (CAIs), and mineral fragments, as well as their radial symmetric appearance, are strong evidence that they formed in situ and that significant directional fluid flow was not involved in the alteration process. This and additional constraints, such as the distribution of S and other elements, as well as the inferred alteration conditions, are consistent with in situ parent‐body alteration. The observations are, however, entirely incompatible with preaccretionary alteration models in which the individual CM chondrite components have experienced diverse alteration histories. The presence of numerous intact aureoles in the brecciated CM chondrites Murray and Murchison further suggests that the alteration occurred largely after brecciation affected these meteorites. Therefore, the progressive aqueous alteration of CM chondrites may not be necessarily coupled to brecciation as has been previously proposed.  相似文献   

11.
We have carried out a SEM-EPMA-TEM study to determine the textures and compositions of relict primary iron sulfides and their alteration products in a suite of moderately to heavily altered CM1 carbonaceous chondrites. We observed four textural groups of altered primary iron sulfides: (1) pentlandite+phyllosilicate (2P) grains, characterized by pentlandite with submicron lenses of phyllosilicates; (2) pyrrhotite+pentlandite+magnetite (PPM) grains, characterized by pyrrhotite–pentlandite exsolution textures with magnetite veining and secondary pentlandite; (3) pentlandite+serpentine (PS) grains, characterized by relict pentlandite exsolution, serpentine, and secondary pentlandite; and (4) pyrrhotite+pentlandite+magnetite+serpentine (PPMS) grains, characterized by features of both the PPM and PS grains. We have determined that all four groups were initially primary iron sulfides, which formed from crystallization of immiscible sulfide melts within silicate chondrules in the solar nebula. The fact that such different alteration products could result from the same precursor sulfides within even the same meteorite sample further underscores the complexity of the aqueous alteration environment for the CM chondrites. The different alteration reactions for each textural group place constraints on the mechanisms and conditions of alteration with evidence for acidic environments, oxidizing environments, and changing fluid compositions (Ni-bearing and Si-Mg-bearing).  相似文献   

12.
Abstract— We used high‐resolution transmission electron microscopy (HRTEM), electron tomography, electron energy‐loss spectroscopy (EELS), and energy‐dispersive spectroscopy (EDS) to investigate the structure and composition of polyhedral serpentine grains that occur in the matrices and fine‐grained rims of the Murchison, Mighei, and Cold Bokkeveld CM chondrites. The structure of these grains is similar to terrestrial polygonal serpentine, but the data show that some have spherical or subspherical, rather than cylindrical morphologies. We therefore propose that the term polyhedral rather than polygonal be used to describe this material. EDS shows that the polyhedral grains are rich in Mg with up to 8 atom% Fe. EELS indicates that 70% of the Fe occurs as Fe3+. Alteration of cronstedtite on the meteorite parent body under relatively oxidizing conditions is one probable pathway by which the polyhedral material formed. The polyhedral grains are the end‐member serpentine in a mineralogic alteration sequence for the CM chondrites.  相似文献   

13.
The Sutter's Mill (SM) carbonaceous chondrite is a regolith breccia, composed predominantly of CM2 clasts with varying degrees of aqueous alteration and thermal metamorphism. An investigation of presolar grains in four Sutter's Mill sections, SM43, SM51, SM2‐4, and SM18, was carried out using NanoSIMS ion mapping technique. A total of 37 C‐anomalous grains and one O‐anomalous grain have been identified, indicating an abundance of 63 ppm for presolar C‐anomalous grains and 2 ppm for presolar oxides. Thirty‐one silicon carbide (SiC), five carbonaceous grains, and one Al‐oxide (Al2O3) were confirmed based on their elemental compositions determined by C‐N‐Si and O‐Si‐Mg‐Al isotopic measurements. The overall abundance of SiC grains in Sutter's Mill (55 ppm) is consistent with those in other CM chondrites. The absence of presolar silicates in Sutter's Mill suggests that they were destroyed by aqueous alteration on the parent asteroid. Furthermore, SM2‐4 shows heterogeneous distributions of presolar SiC grains (12–54 ppm) in different matrix areas, indicating that the fine‐grained matrix clasts come from different sources, with various thermal histories, in the solar nebula.  相似文献   

14.
Abstract— Fine‐grained, heavily‐hydrated lithic clasts in the metal‐rich (CB) chondrites Queen Alexandra Range (QUE) 94411 and Hammadah al Hamra 237 and CH chondrites, such as Patuxent Range (PAT) 91546 and Allan Hills (ALH) 85085, are mineralogically similar suggesting genetic relationship between these meteorites. These clasts contain no anhydrous silicates and consist of framboidal and platelet magnetite, prismatic sulfides (pentlandite and pyrrhotite), and Fe‐Mn‐Mg‐bearing Ca‐carbonates set in a phyllosilicate‐rich matrix. Two types of phyllosilicates were identified: serpentine, with basal spacing of ?0.73 nm, and saponite, with basal spacings of about 1.1–1.2 nm. Chondrules and FeNi‐metal grains in CB and CH chondrites are believed to have formed at high temperature (>1300 K) by condensation in a solar nebula region that experienced complete vaporization. The absence of aqueous alteration of chondrules and metal grains in CB and CH chondrites indicates that the clasts experienced hydration in an asteroidal setting prior to incorporation into the CH and CB parent bodies. The hydrated clasts were either incorporated during regolith gardening or accreted together with chondrules and FeNi‐metal grains after these high‐temperature components had been transported from their hot formation region to a much colder region of the solar nebula.  相似文献   

15.
One approach to decipher the dynamics of material transport and planetary accretion in the early solar system is to investigate xenolithic fragments in meteorites. In this work, we examined an igneous fragment from the NWA 12651 meteorite—the first igneous fragment found in any CM chondrite—by analyzing its mineralogy, rare earth elements (REEs), and O‐isotopes. The study shows that the exsolution lamellae of the igneous fragment consist of Fe‐rich and Ca‐rich pyroxene. Thus, the fragment was part of a progressive crystallization in a closed system, such as in a depleted magma reservoir or mantle. In this environment, the pyroxene co‐crystallized with plagioclase, resulting in a negative Eu anomaly and enrichment of the heavy REEs compared to the light REEs. The O‐isotopes of the fragment are more 16O‐enriched than the mafic minerals in the matrix or in other bulk CM chondrites; therefore, the fragment was formed in a different region than the NWA 12651 parent body. The iron meteorites Tucson and Deep Springs, the pallasite Milton, and the CB chondrites have similar O‐isotopes as the igneous fragment. However, no direct connection can be drawn and it is questionable if the fragment shares a same parent body with one of these meteorites. The close formation region to the CB chondrites may suggest a formation of the fragment in the carbonaceous chondrite region. Thus, a wide transport through the nebula of the early solar system may not have been necessary to move the fragment to the CM chondrite formation region.  相似文献   

16.
Ordinary chondrite meteorites contain silicates, Fe,Ni‐metal grains, and troilite (FeS). Conjoined metal‐troilite grains would be the first phase to melt during radiogenic heating in the parent body, if temperatures reached over approximately 910–960 °C (the Fe,Ni‐FeS eutectic). On the basis of two‐pyroxene thermometry of 13 ordinary chondrites, we argue that peak temperatures in some type 6 chondrites exceeded the Fe,Ni‐FeS eutectic and thus conjoined metal‐troilite grains would have begun to melt. Melting reactions consume energy, so thermal models were constructed to investigate the effect of melting on the thermal history of the H, L, and LL parent asteroids. We constrained the models by finding the proportions of conjoined metal‐troilite grains in ordinary chondrites using high‐resolution X‐ray computed tomography. The models show that metal‐troilite melting causes thermal buffering and inhibits the onset of silicate melting. Compared with models that ignore the effect of melting, our models predict longer cooling histories for the asteroids and accretion times that are earlier by 61, 124, or 113 kyr for the H, L, and LL asteroids, respectively. Because the Ni/Fe ratio of the metal and the bulk troilite/metal ratio is higher in L and LL chondrites than H chondrites, thermal buffering has the greatest effect in models for the L and LL chondrite parent bodies, and least effect for the H chondrite parent. Metal‐troilite melting is also relevant to models of primitive achondrite parent bodies, particularly those that underwent only low degrees of silicate partial melting. Thermal models can predict proportions of petrologic types formed within an asteroid, but are systematically different from the statistics of meteorite collections. A sampling bias is interpreted to explain these differences.  相似文献   

17.
We have sampled sulfide grains from one pristine CM2 chondrite (Yamato [Y‐] 791198), one thermally metamorphosed CM2 chondrite (Y‐793321), and two anomalous, metamorphosed CM/CI‐like chondrites (Y‐86720 and Belgica [B‐] 7904) by the focused ion beam (FIB) technique and studied them by analytical transmission electron microscopy (TEM). Our study aims at exploring the potential of sulfide assemblages and microstructures to decipher processes and conditions of chondrite petrogenesis. Complex exsolution textures of pyrrhotite (crystallographic NC‐type with N ≈ 6), troilite, and pentlandite occur in grains of Y‐791198 and Y‐793321. Additionally, polycrystalline 4C‐pyrrhotite‐pentlandite‐magnetite aggregates occur in Y‐791198, pointing to diverse conditions of gas–solid interactions in the solar nebula. Coarser exsolution textures of Y‐793321 grains indicate higher long‐term average temperatures in the <100 °C range compared to Y‐791198 and other CM chondrites. Sulfide mineralogy of Y‐86720 and B‐7904 is dominated by aggregates of pure troilite and metal, indicating metamorphic equilibration at sulfur fugacities (fS2) of the iron‐troilite buffer. Absence of magnetite in equilibrium with sulfide and metal in Y‐86720 indicates higher peak temperatures compared with B‐7904, in which coexistence of troilite, metal, and magnetite constrains metamorphic temperature to less than 570 °C. NC‐pyrrhotite occurs in both meteorites as nm‐wide rims on troilite grains and, together with frequent anhydrite, indicates a retrograde metamorphic stage at higher fS2 slightly above the fayalite‐magnetite‐quartz‐pyrrhotite buffer. Fine‐grained troilite‐olivine intergrowths in both meteorites suggest the pre‐metamorphic presence of tochilinite‐serpentine interlayer phases, pointing to mineralogical CM affinity. Pseudomorphs after euhedral pyrrhotite crystals in Y‐86720 in turn suggest CI affinity as do previously published O isotopic data of both meteorites.  相似文献   

18.
Abstract– The study of aqueous alteration of kamacite in CM chondrites provides insight on the conditions, products, and relative timing of aqueous alteration. We studied unaltered, partially altered, and fully altered kamacite grains from Murray, Murchison, Cold Bokkeveld, and Nogoya using optical microscopy, electron microprobe analysis, scanning electron microscopy, and Raman spectroscopy. From textual evidence and chemical analysis, we established three separate microchemical environments. 1) In a microchemical environment with a high S activity, kamacite alters to form tochilinite, P‐bearing sulfides, eskolaite, and schreibersite. Mass balance calculations show that 81% of the Fe in kamacite is removed from the alteration region, making it available for the formation of other minerals or Fe‐rich aureoles. The release of Fe can alter the mesostasis of type‐I chondrules forming cronstedtite. 2) In a microchemical environment with a high Si activity and a low S activity, kamacite alters to form cronstedtite with small accessory sulfide inclusions. 3) A microchemical environment with limited S and Si activity results in kamacite alteration forming magnetite. The resulting magnetite retains associated Ni that can distinguish it from precipitated magnetite. In addition, the accessory phases of pentlandite and apatite can be formed if S or Ca are present. Finally, we note that small tochilinite grains in the matrix lack typical Ni, P, and Co levels, suggesting that they did not form from kamacite but possibly by sulfidization of magnetite.  相似文献   

19.
Abstract— Redistribution or loss of batches of condensate from a cooling protosolar nebula is generally thought to have led to the formation of the chemical groups of chondrites. This demands a nebula hot enough for silicate vaporization over 1–3 AU, the region where chondrites formed. Alternatively, heating of a protosolar accretion disk may have been confined to an annular zone at its inner edge, ?0.06 AU from the protosun. Most infalling matter was accreted by the protosun, but a proportion was heated and carried outwards by an x‐wind. Shu et al. (1996, 1997) proposed that larger objects such as chondrules and calcium‐aluminum‐rich inclusions (CAIs) were returned to the disk at asteroidal distances by sedimentation from the x‐wind. Fine dust and gas were lost to space. The model implies that solids were not lost from the cold disk. The chemical compositions of the chondrite groups were produced by mixing different proportions of CAIs and chondrules with disk solids of CI composition. Heating at the inner edge of the disk was accompanied by particle irradiation, which synthesized nuclides including 26Al. The x‐wind model can produce CAIs, not chondrules, and allows survival of presolar grains >0.06 AU from the protosun. Normalization to Al and CI indicates that non‐carbonaceous chondrites may be disk material that gained a Si‐ and Mg‐enriched fraction. Carbonaceous chondrites are different; they appear to be CI that lost lithophile elements more volatile than Ca. Five carbonaceous chondrite groups also lost Ni and Fe but the CH group gained siderophiles. Elemental loss from CI is incompatible with the x‐wind model. Silicon and CI normalization confirms that the CM, CO, CK and CV groups may be CI that gained refractories as CAIs. The Si‐, Mg‐rich fraction may have formed by selective vaporization followed by precipitation on grains in the x‐wind. This fractional distillation mechanism can account for lithophile element abundances in non‐carbonaceous chondrite groups, but an additional process is required for the loss of Ca and Mn in the EL group and for fractionated siderophile abundances in the H, L and LL groups. Heated and recycled fractions were not homogenized across the disk so the chondrite groups were established in a single cycle of enhanced protosolar activity in lt;104 years, the time for a millimeter‐sized particle to drift into the Sun from 2 to 3 AU, due to gas‐drag.  相似文献   

20.
Abstract– CM chondrites were subjected to aqueous alteration and, in some cases, to secondary metamorphic heating. The effects of these processes vary widely, and have mainly been documented in silicate phases. Herein, we report the characteristic features of Fe‐Ni metal and sulfide phases in 13 CM and 2 CM‐related chondrites to explore the thermal history of these chondrites. The texture and compositional distribution of the metal in CM are different from those in unequilibrated ordinary and CO chondrites, but most have similarities to those in highly primitive chondrites, such as CH, CR, and Acfer 094. We classified the CM samples into three categories based on metal composition and sulfide texture. Fe‐Ni metal in category A is kamacite to martensite. Category B is characterized by pyrrhotite grains always containing blebs or lamellae of pentlandite. Opaque mineral assemblages of category C are typically kamacite, Ni‐Co‐rich metal, and pyrrhotite. These categories are closely related to the degree of secondary heating and are not related to degree of the aqueous alteration. The characteristic features of the opaque minerals can be explained by secondary heating processes after aqueous alteration. Category A CM chondrites are unheated, whereas those in category B experienced small degrees of secondary heating. CMs in category C were subjected to the most severe secondary heating process. Thus, opaque minerals can provide constraints on the thermal history for CM chondrites.  相似文献   

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