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1.
Scottish Dinantian transitional to mildly alkaline volcanism is represented by abundant outcrops in the Midland Valley, Southern Uplands and Highlands provinces. Dinantian volcanic rocks from Kintyre in the Scottish Highlands range in composition from basalt through basaltic hawaiite, hawaiite, mugearite and benmoreite to trachyte, the compositions of the evolved types being largely due to differentiation from the basaltic parents.Recent geochemical investigations of Scottish Caledonian granitoids, Siluro-Devonian Old Red Sandstone (ORS) lavas and xenolith suites from numerous vents and dykes of Permo-Carboniferous to Tertiary age have revealed that the Scottish crust and upper mantle both increase in age and are increasingly enriched in incompatible elements towards the north and northwest. The upper mantle and lower crust below the Highlands province are therefore largely considered to be more enriched and in parts older than those below the Midland Valley and Southern Uplands. Dinantian alkali basalts from these latter two provinces have Nd values predominantly in the range +3 to +6, initial 87Sr/86Sr values of 0.7029–0.7041 and 207Pb/ 204Pb values of 15.48–15.60. However, similar basalts from Kintyre and Arran in the Highlands have lower Nd (+0.1 to +3.4) and 207Pb/204Pb (for given 206Pb/204Pb ratios; 15.49–15.51) and slightly higher 87Sr/86Sr (0.7033–0.7046). This regional variation correlates well with the differences seen between Midland Valley and Highland magmas in the ORS calc-alkaline suite (Thirlwall 1986) and it is suggested that both the ORS and Dinantian basic rocks are derived from similar types of mantle, although no lithospheric slab component is present in the later Dinantian suites. Isotopically-distinct portions of mantle therefore appear to have been present below the Highland and Midland Valley-Southern Upland provinces from at least Caledonian to Carboniferous times. The combined incompatible element and Sr-Nd-Pd isotopic evidence from Kintyre and Arran basaltic rocks does not allow unequivocal distinction between a lithospheric mantle and a sublithospheric mantle source. The observed correlation between isotopic composition of Dinantian basalts and the chemical composition of the lithosphere, together with the apparent involvement of long-term separated source reservoirs suggests that Kintyre and Arran lavas were derived largely from a lithospheric mantle source. On the other hand, the isotopic enrichment of Kintyre basaltic rocks is not extreme; trace element and isotopic compositions are still comparable to modem OIB. Sublithospheric mantle could therefore also be a viable source for Kintyre and Arran Dinantian volcanism.  相似文献   

2.
The 19 November 1923 earthquake in the Aran Valley (Central Pyrenees), with observed maximum intensityI max = VIII (MSK), has been studied through the compiling and reviewing of macroseismic information and collecting and processing early seismograms. Analysis of macroseismic data gives a focal depth ofh = 5 km and an anelastic attenuation coefficient 10–3 km–1. Analysis of early instrumental records allows the computation of estimate of magnitude (M L = 5.6) and seismic moment (M o = 1.1 × 1017 N × m) which are consistent with the values ofI o andh obtained from macroseismic data.  相似文献   

3.
Previous interdisciplinary paleoenvironmental and archaeological research along the Río Verde Valley of Oaxaca, Mexico, showed that Holocene erosion in the highland valleys of the upper drainage basin triggered geomorphic changes in the river's coastal floodplain. This article uses stratigraphic data from sediment cores extracted from Laguna Pastoría, an estuary in the lower Río Verde Valley, to examine changes in coastal geomorphology potentially triggered by highland erosion. Coastal lagoon sediments contain a stratigraphically and chronologically distinct record of major hurricane strikes during late Holocene times. Three distinct storm facies are identified from sediment cores obtained from Laguna Pastoría, which indicate that profound coastal environmental changes occurred within the region and are correlated with increased sediment supplied from highland erosion. The Chione/Laevicardium facies was deposited in an open bay while the Mytella/barnacle facies and sand facies were deposited in an enclosed lagoon following bay barrier formation. We argue that highland erosion triggered major geomorphic changes in the lowlands including bay barrier formation by 2500 cal yr B.P. These environmental changes may have had significant effects on human populations in the region. The lagoon stratigraphy further indicates an increase in mid–late Holocene hurricane activity, possibly caused by increased El Niño frequencies.  相似文献   

4.
Primary 18O values for tonalitic rocks from the San Jacinto Intrusive Complex range from +9.0 to +10.6; initial87Sr/86Sr for the same samples varies from 0.7058 to 0.7076. Rocks with low 18O tend to have higher initial87Sr/86Sr. The majority of samples have a limited range of 18O values (+10.0–+10.4) that is anticorrelated with colour index; this variation is compatible with crystallization of rocks with varying mineral abundances from an homogeneous (for oxygen) reservoir. More mafic rocks show a large range of 18O values, reflecting original variations in source material compositions. The combined Sr-O isotope data demonstrate that three or more distinct components were involved in the genesis of these rocks; these three components are also seen in batholithic rocks from the Mojave Block and Sierra Nevada to the north. These data are interpreted as indicating a 0–35% (oxygen atom basis) contribution to the San Jacinto rocks from an old continental lithosphere source.Division Contribution No. 4064  相似文献   

5.
Transmissivity (T) is one of the most important parameters in groundwater studies, and is generally estimated from pumping tests. T can also be deduced from abundantly available specific-capacity (Q/s) data by using analytical and/or empirical approaches, further upscaled by geostatistical methods. A different, remote sensing based, hydrogeomorphological approach is proposed, to upscale T from point- or well-scale to aquifer-scale, and it is applied to the piedmont alluvial aquifer system of Doon Valley in India. In the first step, Q/s and T data-pairs available from aquifer tests were used to establish an empirical, logarithmic relation. Subsequently, satellite imagery along with available data from published and unpublished maps, literature sources and ground surveys were used to divide the aquifer system into major hydrogeomorphological domains that control the groundwater occurrence and flow. Then, the T data derived from Q/s (using the empirical relation) and that available from pumping tests at well-scale were upscaled to aquifer-scale by averaging the T values within each hydrogeomorphological domain. Such a stratification approach is especially useful in areas where availability of only a few data-pairs of known Q/s and T limit the use of geostatistical techniques. A comparative study of the published empirical relations between Q/s and T in various hydrogeologic settings revealed that the relation obtained for Doon Valley aquifer system is close to that found for a similar alluvial aquifer system in Morocco.  相似文献   

6.
Nd, Sr and O isotopic data were obtained from silicic ash-flow tuffs and lavas at the Tertiary age (16–9 Ma) Timber (Mountain/Oasis Valley volcanic center (TMOV) in southern Nevada, to assess models for the origin and evolution of the large-volume silicic magma bodies generated in this region. The large-volume (>900 km3), chemically-zoned, Topopah Spring (TS) and Tiva Canyon (TC) members of the Paintbrush Tuff, and the Rainier Mesa (RM) and Ammonia Tanks (AT) members of the younger Timber Mountain Tuff all have internal Nd and Sr isotopic zonations. In each tuff, high-silica rhyolites have lower initial Nd values (1 Nd unit), higher87Sr/86Sr, and lower Nd and Sr contents, than cocrupted trachytes. The TS, TC, and RM members have similar Nd values for high-silica rhyolites (-11.7 to -11.2) and trachytes (-10.5 to -10.7), but the younger AT member has a higher Nd for both compositional types (-10.3 and -9.4). Oxygen isotope data confirm that the TC and AT members were derived from low Nd magmas. The internal Sr and Nd isotopic variations in each tuff are interpreted to be the result of the incorporation of 20–40% (by mass) wall-rock into magmas that were injected into the upper crust. The low Nd magmas most likely formed via the incorporation of low 18O, hydrothermally-altered, wall-rock. Small-volume rhyolite lavas and ash-flow tuffs have similar isotopic characteristics to the large-volume ash-flow tuffs, but lavas erupted from extracaldera vents may have interacted with higher 18O crustal rocks peripheral to the main magma chamber(s). Andesitic lavas from the 13–14 Ma Wahmonie/Salyer volcanic center southeast of the TMOV have low Nd (-13.2 to -13.8) and are considered on the basis of textural evidence to be mixtures of basaltic composition magmas and large proportions (70–80%) of anatectic crustal melts. A similar process may have occurred early in the magmatic history of the TMOV. The large-volume rhyolites may represent a mature stage of magmatism after repeated injection of basaltic magmas, crustal melting, and volcanism cleared sufficient space in the upper crust for large magma bodies to accumulate and differentiate. The TMOV rhyolites and 0–10 Ma old basalts that erupted in southern Nevada all have similar Nd and Sr isotopic compositions, which suggests that silicic and mafic magmatism at the TMOV were genetically related. The distinctive isotopic compositions of the AT member may reflect temporal changes in the isotopic compositions of basaltic magmas entering the upper crust, possibly as a result of increasing basification of a lower crustal magma source by repeated injection of mantle-derived mafic magmas.  相似文献   

7.
The texture of digital rock images, as recorded, for instance, with borehole imaging devices, is shown to reflect different bedding types. Textural segmentation of borehole images, therefore, subdivides the recorded sequence into bedding units. We show that a textural segmentation algorithm based on the concept of texture energy achieves good results when compared with synthetic as well as real data in which petroleum geologists have performed zonations on cores. Texture energy involves filtering of the original image with a set of texture sensitive masks. The filtering is done as a finite convolution over the size of the masks. On the resulting images the variance is computed over a relatively large sliding window, which, in its practical implementation, covers the full width of the image. The resulting nine one-dimensional curves are then clustered hierarchically into a user-determined number of image texture or lithological bedding classes. Principal component analysis previous to clustering can be used to reduce redundancy in the data. A recurring and relatively ill-defined problem in this field are macro-textures, i.e., the cyclic interbedding of two or more bedding types. We show that sliding Fourier transforms and variable mask scale can successfully address the zonation of macro-textures. In general, the method gives best results with mask sizes equivalent to 2–4 centimeters, reflecting the length scale at which the investigated geological bedding seems to have its highest variation.  相似文献   

8.
Rb-Sr isotopic analyses of whole-rocks and biotite and U-Th-Pb analyses of zircon and monazite reveal regional metamorphic events for the Ordovician (Caledonian metamorphism) and the Carboniferous (Variscan=Hercynian orogeny), both accompanied by anatexis. The extent of the Caledonian and Variscan anatexis, however, cannot be evaluated, so far, because the field petrographic criteria are not sufficient to distinguish clearly between early and late Paleozoic anatexites. Evidence for a Precambrian metamorphism has not been found. Rb-Sr whole-rock isochrons obtained on leucosomes and melanosomes of partially molten paragneisses are interpreted as a minimum age of the second, early Variscan anatexis. The alternative explanation of the isochrons as a result of local Sr isotopic redistribution without a melt involved is considered less likely. Concordant and nearly concordant zircon ages (318–335 m.y.) of a coarse-grained granite and of diatexites are regarded as evidence for an intensive early Variscan granitization and palingenesis. Concordant zircon ages of diorite dykes, crosscutting the anatexites, establish a lower time limit of 309–312 m.y. for the Variscan anatexis. Rb-Sr ages of biotite (310-290 m.y.) indicate the end of the Variscan metamorphism. Estimates of the time of sedimentation or diagenesis based on Rb-Sr whole-rock analyses for some metasediment series in the north of the area yield maximum ages of 550 m.y., provided that Rb and Sr migration did not exceed substantially the extent of the outcrops (30–500 m) between the time of diagenesis and the Ordovician metamorphism. Otherwise, an upper limit of 2000–2300 m.y., which is the primary age of detrital zircon populations, can be established. Zircon populations of paragneisses and their anatectic derivatives were separated into size and shape fractions. From morphologic studies and U-Pb isotopic analyses, they were found to be composites of young concordant (318–325 m.y.) and old, highly discordant zircon components, with more than fifty per cent of young crystals in some anatexites. The apparent ages of the composites are 320–750 m.y. The U concentrations of the newly formed crystals can be higher, equal, or lower than those of the inherited zircon component. Some peculiarities in the concordia plot of the zircon data of paragneisses and migmatites (curved pattern; inversion of the generally observed systematics with respect to U concentration, grain size, degree of discordance) are interpreted as the result of polyepisodic disturbances of the inherited crystals in connection with new zircon growth. In the concordia diagram, the data points of the individual zircon grains containing inherited components appear to plot in band or wedgelike areas, and not on lines as the patterns of size fractions of the same zircon populations could pretend. Consequently, ages obtained by extrapolation of the regression curves to the concordia are not necessarily meaningful and require verification by other methods.  相似文献   

9.
The 29Si and 27Al nuclear magnetic resonance (NMR) analysis of synthetic trioctahedral phyllosilicates 2:1, with tetrahedral ratios Al T/(Si + Al T) ranging from 0 to 0.5, has shown that the ditrigonal distortion of tetrahedral rings (angle ) is the main factor controlling chemical shift values of tetrahedral components in both signals. The increase of ditrigonal rotation angle shifts these components towards more positive values. For each sample, the composition of tetrahedral and octahedral sheets determine the value of , and from this parameter, the mean tetrahedral Tot angle and the chemical shift values of components are deduced. For a given environment, variations on ditrigonal angle are responsibles for the observed evolution of chemical shift values with bulk composition. The comparative analysis of micas and saponite samples has demonstrated that the location of compensating charge (interlayer and octahedral sheet) does not affect chemical shift values.  相似文献   

10.
The 50 km-long West Valley segment of the northern Juan de Fuca Ridge is a young, extension-dominated spreading centre, with volcanic activity concentrated in its southern half. A suite of basalts dredged from the West Valley floor, the adjacent Heck Seamount chain, and a small near-axis cone here named Southwest Seamount, includes a spectrum of geochemical compositions ranging from highly depleted normal (N-) MORB to enriched (E-) MORB. Heck Seamount lavas have chondrite-normalized La/Smcn0.3, 87Sr/86Sr=0.70235–0.70242, and 206Pb/204Pb=18.22–18.44, requiring a source which is highly depleted in trace elements both at the time of melt generation and over geologic time. The E-MORB from Southwest Seamount have La/Smcn1.8, 87Sr/86Sr=0.70245–0.70260, and 206Pb/204Pb=18.73–19.15, indicating a more enriched source. Basalts from the West Valley floor have chemical compositions intermediate between these two end-members. As a group, West Valley basalts from a two-component mixing array in element-element and element-isotope plots which is best explained by magma mixing. Evidence for crustal-level magma mixing in some basalts includes mineral-melt chemical and isotopic disequilibrium, but mixing of melts at depth (within the mantle) may also occur. The mantle beneath the northern Juan de Fuca Ridge is modelled as a plum-pudding, with plums of enriched, amphibole-bearing peridotite floating in a depleted matrix (DM). Low degrees of melting preferentially melt the plums, initially removing only the amphibole component and producing alkaline to transitional E-MORB. Higher degrees of melting tap both the plums and the depleted matrix to yield N-MORB. The subtly different isotopic compositions of the E-MORBs compared to the N-MORBs require that any enriched component in the upper mantle was derived from a depleted source. If the enriched component crystallized from fluids with a DM source, the plums could evolve to their more evolved isotopic composition after a period of 1.5–2.0 Ga. Alternatively, the enriched component could have formed recently from fluids with a less-depleted source than DM, such as subducted oceanic crust. A third possibility is that enriched material might be dispersed as plums throughout the upper mantle, transported from depth by mantle plumes.  相似文献   

11.
This paper presents the results of processing and analysis of acoustic waves in the surface layer of the atmosphere, registered at the Mikhnevo Geophysical Observatory, Institute of Geosphere Dynamics, Russian Academy of Sciences (IGD RAS). Using the autoregression model of digital series, the spectrum of acoustic oscillations was evaluated and the tidal waves in the envelopes of acoustic oscillations were distinguished. The tidal components with similar periods were separated using the method of extraction of harmonic components by using adaptive notch filters. The observed features of the spectrum of acoustic oscillations open up new opportunities for instrumental control over meteorological conditions and the establishment of general regularities controlling the regimes of energy-exchange processes in the Earth’s atmosphere.  相似文献   

12.
The petrographic and palynologic compositions of coal seams of the acler formation (Upper Carboniferous, Westphalian A) from northwestern and southeastern part of the Lower Silesian Coal Basin (LSCB) were examined. Coals studied are highly volatile bituminous coal, where Ro ranges from 0.91% to 1.09%. Seam 430 from the northwestern part of the basin contains high vitrinite percentage with rather low inertinite and liptinite contents, while percentage of mineral matter is variable. This petrographic composition is associated either with a predominance of Lycospora in miospore assemblage, or with a miospore assemblage of mixed character. The abundance of Lycospora reflects vegetation composed of the arborescent lycopsids while the mixed miospore assemblage is connected with diverse palaeoplant communities, namely, arborescent lycopsids, calamites and ferns. Seams 409 and 412/413 from the southeastern part of the LSCB are rich in inertinite and liptinite, while the vitrinite content is moderate. Their characteristic feature is the occurrence of a diagnostic crassisporinite (densosporinite). Amount of the mineral components in these coals is very low. Densosporites and related crassicingulate genera are main components of these miospore assemblages and were produced by herbaceous and/or sub-arborescent lycopsids. These petrographic and palynologic features were the basis for distinguishing three maceral–miospore associations: an arborescent lycopsid and mixed associations, occurring in the seam 430 and a herbaceous and/or sub-arborescent lycopsid association which was recorded in seams 409 and 412/413. The first two assemblages are interpreted as having been deposited in a planar rheotrophic mire, whereas the herbaceous and/or sub-arborescent lycopsid association is thought to have developed in an ombrotrophic, domed mire.  相似文献   

13.
This study summarizes the final results of magnetostratigraphic and micropalaeontological investigations of the Tithonian/Berriasian boundary (J/K) limestones at the locality of Brodno near ilina, Western Carpathians, West Slovakia. The aim is to prepare the background for correlation of a Late Tithonian and Early Berriasian biostratigraphic zonation with global magnetoevents (manifested in detailed magnetostratigraphic profiles) between the Tethyan realm and other regions, particularly the Boreal and Pacific realms. Suitable physical properties of the limestones studied, a favourable geological setting and rich microfossil assemblages (calpionellids) at Brodno (magnetozones M21r to M18r) allowed a systematic collection of new data on the original synoptic section, which now has the character of a high-resolution profile across the J/K boundary. Two reverse subzones detected within magnetozones M20n and M19n are named ‘Kysuca Subzone’ and ‘Brodno Subzone’, respectively. Both can be correlated with analogous subzones in the M-sequence of marine anomalies. Their existence can also be confirmed in the Bosso Valley section in Umbria, central Italy. A detailed study of the interval between magnetozones M20n and M17r in the Bosso Valley profile is presently in its final stage. Both magnetostratigraphic profiles, from the Brodno and Bosso Valley localities, were thoroughly investigated in the intervals close to the J/K boundary and are still unique among continent-based profiles in the detection and precise definition of both reverse subzones within M20n and M19n. Samples collected from the boundary strata of the reverse Kysuca Subzone at Brodno indicated a transition from N (R) to R (N) polarity of the Earth's palaeomagnetic field within a time interval of c. ±5 ka. Limestone samples (total number N=368) were subjected to progressive thermal demagnetization in 10–12 thermal fields and to subsequent multi-component analysis of remanence. The C-component, as the carrier of palaeomagnetic directions, was determined in the temperature interval of 300° to 540°, or possibly 580°C. Magnetomineralogical analyses of pilot samples and unblocking temperatures determined for all samples showed that magnetite is the carrier of remanent magnetization. The positions of the individual events of calpionellid stratigraphy relative to the global magnetic polarity timescale are precisely defined. The base of the Calpionella Standard Zone, which is considered a provisional J/K boundary indicator in ammonite-free sections in the Tethyan realm, lies within magnetozone M19n at the level of 35% of its local thickness. None of the boundaries in the calpionellid zonation coincides precisely with any of those in the palaeomagnetic zonation, but the first appearance ofCalpionella grandalpina , indicating the base of the Intermedia Subzone, lies in close proximity to the base of magnetozone M19r.  相似文献   

14.
The exchange of Ca and Mg between olivine and clinopyroxene has been studied in the CFMS system. Experiments were conducted in a piston-cylinder apparatus in the temperature range of 1,100–1,300° C and the pressure range 10–30 kbar. Results confirm the previous suggestion (Adams and Bishop 1982) that this reaction has a sufficiently large V° to be used as a geobarometer in several basic and ultrabasic systems. Experimental results were corrected for compositional effects using recent activity-composition models for quadrilateral pyroxenes and olivines. The corrected results indicate that the exchange reaction has aH 1 bar of 34,900 J, a S° of -7.25J/deg, and a V° of -0.489 J/bar. Corrected results agree well with calculations based on the thermodynamic properties of the endmembers.Application of the olivine-clinopyroxene geobarometer to many systems will require additional calibration of non CFMS components. Preliminary pressure estimates based on simple assumptions about the activity relations of these components have been made for spinel lherzolites from southwestern United States and coarse and porphyroclastic garnet lherzolites from southern Africa. A geotherm calculated from spinel lherzolites near the Rio Grande rift is consistent with a geophysical geotherm based on near-surface heat-flow measurements of 100 mW/m2 or greater. Results on garnet lherzolites yield a southern African geotherm with no inflection which falls at somewhat higher temperatures than pyroxene geotherms calculated for the same area.  相似文献   

15.
Some important primary structures have been studied and described from the chromities of Sukinda Valley in Orissa, India. The structures include primary layering, Ball and Pillow structures, and cross laminations. From the similarity of the structures and texture of the chromitites with the sedimentary rocks, it is presumed that the chromities were formed by magmatic sedimentation under the influence of gravity.
Zusammenfassung Aus den Chromititen von Sukinda Valley in Orissa, Indien, werden einige wichtige, primäre Gefüge untersucht und beschrieben. Die Gefüge zeigen primäre Bänderung, Ball and Pillow-Lagen und Kreuzschichtung. Aus der Ähnlichkeit der Gefüge der Chromitite mit denen sedimentärer Gesteine wird geschlossen, daß die Chromitite durch gravitative, magmatische Saigerung sedimentiert worden sind.
  相似文献   

16.
基流分割方法在疏勒河上游流域的应用对比分析   总被引：3，自引：1，他引：2  
周嘉欣  丁永建  吴锦奎  王建 《冰川冻土》2019,41(6):1456-1466
基于疏勒河上游昌马堡水文站2007—2016年日径流资料, 运用单参数数字滤波法、 平滑最小值法、 递归数字滤波法和HYSEP法（固定步长法、 滑动步长法、 局部最小值法）对其进行基流分割计算。结果表明： 4种方法均可实现基流的自动分割, 且得到的基流过程线平滑缓慢, 所获得的基流序列稳定, 变异性小。4种方法得到基流指数具有差异性, 最大为0.72, 最小为0.49, 其中递归数字滤波法估算的结果稳定性最高。单参数数字滤波法中, 当滤波参数β取值0.95时为最优参数。平滑最小值法、 HYSEP法中的SI法、 LM法和单参数数字滤波法（β=0.95）具有较高的Nash-Sutcliffe效率系数, 且平均相对误差小于10%, 说明这些方法基流估算结果稳定可靠且精度高, 均适用于疏勒河上游流域。  相似文献   

17.
Near Mesquite Spring on the southern edge of the Soda Lake basin in the Mojave Desert, there is a shoreline of an ancient lake at an elevation of 340 m above sea level. At present, Soda Lake would overflow at 280 m; a lake surface at 340 m would extend 240 km northward, to the northern end of Death Valley. Shorelines and lacustrine deposits near the Salt Spring and Saddle Peak Hills, 75 km north of Mesquite Spring, are at 180 m; a lake surface at this elevation today would also extend to the northern end of Death Valley. The most prominent shoreline of the pluvial lake that occupied Death Valley during the Pleistocene, Lake Manly, is that of the Blackwelder stand which ended 120,000 yr ago. This shoreline is 90 m above sea level. The Mesquite Spring and Salt Spring Hills shorelines were probably formed by the Blackwelder stand and subsequently displaced with respect to one another, tectonically, due to transpression in the northeastern Mojave Desert and NW–SE extension across Death Valley. This tectonic regime would result in subsidence of Death Valley and the Salt Spring Hills relative to Mesquite Spring. A reconstruction suggests that the topography at the time of the Blackwelder stand would have had a sill near the level of the highest lake, and also one 20 m lower, corresponding to the next most prominent shoreline in Death Valley. Expansion of the lake over these sills would have increased evaporation, thus possibly stabilizing the lake level.  相似文献   

18.
An effect of closure on the structure of principal components   总被引：2，自引：0，他引：2  
The principal components transformation generates, from any data array, a new set of variables—the scores of the components—characterized by a total variance exactly equal to that of the initial set. It is in this sense that the transformed variables are said to contain, preserve, or account for, the variance of the original set. The scores, however, are uncorrelated. In the course of the transformation, what becomes of the strong interdependence of variance and covariance so characteristic of closed arrays? The question seems to have attracted little attention; we are aware of no study of it in the earth sciences. Experimental work reported here shows quite clearly that the overall equivalence of variance and covariance imposed by closure, though absent from the component scores,may emerge in relations between the coefficientsof each of the lower-order components; if the raw data are complete rock analyses, the sum of all the covariances of the coefficients of such a component is negative, and is very nearly equal to the sum of all the variances in absolute value. (In all cases so far examined, the absolute value of the first sum is a little less than that of the second.) The principal components transformation provides an elegant escape from closure correlation if a petrographic problem can be restated entirely in terms of component scores, but not if a physical interpretation of the component vectors is required.  相似文献   

19.
Oxygen-isotope compositions have been measured for whole-rock and mineral samples of host and hydrothermally altered rocks from three massive sulfide deposits, Centennial (CL), Spruce Point (SP), and Anderson Lake (AL), in the Flin Flon — Snow Lake belt, Manitoba. Wholerock 18O values of felsic metavolcanic, host rocks (+8.5 to +16.1) are higher than those of altered rocks from the three deposits. The 18O values of altered rocks are lower in the chlorite zone and muscovite zone-I (CL=+ 5.3; SP=+5.4 to +8.3; AL= +3.7 to +5.9) than in the gradational zone (CL= +9.9 to +11.7; SP= +8.4 to +9.8; AL= + 6.6 to +7.7). Muscovite schist (Muscovite Zone-II) enveloping the Anderson Lake ore body has 18O values of +7.2 to +8.3. Quartz, biotite, muscovite, and chlorite separated from the altered rocks have lower 18O values compared to the same minerals separated from the host rocks. However, isotopic fractionation between mineral-pairs is generally similar in both host and altered rocks.It is interpreted that differences in the oxygen-isotope compositions of the altered and host rocks were produced prior to metamorphism, during hydrothermal alteration related to ore-deposition. Isotopic homogenization during metamorphism occurred on a grain-to-grain scale, over no more than a few meters. The whole-rock 18O values did not change significantly during metamorphism. The generally lower 18O values of altered rocks, the Cu-rich nature of the ore and the occurrence of the muscovite zone-II at Anderson Lake are consistent with the presence of higher temperature hydrothermal fluids at Anderson Lake than at the Centennial and Spruce Point deposits.  相似文献   

20.
An order parameter treatment of the phase transitions in leucite, KAlSi2O6, at approximately 950 and 920 K: (cubic) I41 acd(tetragonal) I41 a(tetragonal) is presented in terms of Landau theory and induced representation theory. The Al-Si order with decreasing temperature is taken as the primary order parameter to which other distortions (K+ ion displacements, strain components, etc.) couple linearly. The expected Al-Si ordering behavior and the associated K+ ion displacements for both transitions are derived and the resulting twin domain orientations are listed. The sequence of phase transitions results from a coupling of 3 + and 4 + representations. The Landau free energy for the five-dimensional reducible representation has been simplified to two components resulting in a linearquadratic coupling of the components. Possible phase diagrams are derived by free energy minimization. The cubic tetragonal transition is first-order, whereas the tetragonal-tetragonal transition may be second order. A tricritical point exists at which the first-order transition changes to second-order.  相似文献   

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