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层控夕卡岩型矿床成矿系统的元素活动性及质量迁移--以铜陵冬瓜山铜矿床为例 总被引:7,自引:0,他引:7
应用改善了的质量平衡方程研究冬瓜山层控夕卡岩型铜矿床成矿系统的元素活动性及质量迁移,结果表明:系统中Zr,Hf,Y和Nb为不活动元素,其余均为活动元素。主量元素中仅CaO为迁出组分,其质量迁移量为84%,其余均为带入组分,带入量最大的SiO2的质量迁移量高达2384%;稀土元素均为带入组分,其中,中稀土较轻稀土和重稀土的活动性更强;其它微量元素中,带入序列由强到弱为:Cr→Ta→Sn→Th,迁出序列由强至弱依次为:U→Sb→Ni—Sr→Ba→Bb→Co→W;成矿元素Cu和Ag为带入组分,其中Cu的带入量最大,质量迁移量高达1200%。本文还得出两点具普适性认识:①稀土元素较其它微量元素对体系条件的变化更为敏感,且往往表现出明显的规律性变化,能更好地示踪地质地球化学过程。②不同元素在不同体系中的行为特征差异极大,仅凭经验判定某一元素为不活动元素往往不可靠。因此,在开展质量平衡研究时,首先采用适当方法确认体系的不活动元素是一项不可或缺的前提工作。 相似文献
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银厂坡银矿床碳酸盐化蚀变作用与银的矿化富集在空间上紧密相伴,这种蚀变作用导致矿石与围岩中组分有明显差异。本文通过定量计算阐明组分之间的迁移方向;计算表明在银的原生富集过程中,常量组分的带入与带出最不明显;而微量组分Ag和Cu、Pb、Zn、As、Sb、Cd、Ge带入围岩明显。在银的次生富集过程表现为Ag和Cu、Pb、Cd、Ga、Ge、REE、AlO3、Fe2O3、MnO、K2O、P2O5的强烈带入,以Al2O3、Fe2O3、K2O、P2O5带入强度最大,这是由于CaO、MgO被淋滤,体积亏损造成强烈带入的假象,而As、Sb、Zn、V、Cr、Co、Ni、CaO、MgO为自围岩中带出组分,以CaO、MgO带出强度最大。REE除原生富集的弱蚀变白岩→矿化白云岩表现为带出外,其余原富集过程均表现为带入围岩。造成组分发生迁 相似文献
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明溪蓝刚中Fe主要以Fe^3 形式存在,Fe^3 的d-d电子跃迁和Fe^2 -Ti^4 /Fe^3 -Ti^3 、O^2-Fe^3 间电荷转移是致色的主要因素;浓度差可以作为扩散动力;氢含量的提高可以促进蓝色致因子的形成。采用高温高压水溶液方法对蓝刚玉进行改色处理,可消除刚玉中的杂色调,使颜色向纯蓝色方向变化。 相似文献
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碳酸盐矿物的阴极发光性主要受其Mn^2+和Fe^2+含量,以及Mn^2+/Fe^2+值的综合控制,但Mn^2+/Fe^2+值的控制作用强一些。研究中充填裂缝的方解石胶结物样品主要采自北京西山寒武系和奥陶系的碳酸盐岩地层中。此外,还从北京石花洞中采集了现代溶洞的石笋样品。样品的阴极发光强度可分为不发光、暗、中等和亮,阴极发光颜色也相应地分为不发光、橙红色、橙黄色和亮黄色。通过对野外露头样品进行电子探针研究,测定其中的Mn^2+和F^2+’的含量,并结合样品的阴极发光颜色和强度,得出Mn^2+含量要在0.01%以上,Fe^2+含量至少在0.8%以下,Mn^2+/Fe^2+在0.05以上,方解石胶结物才能发光。经研究发现,充填裂缝中方解石胶结物的阴极发光性与Mn^2+和Fe^2+含量,以及Mn^2+/Fe^2+值之间存在如下关系:不含Mn^2+,Fe^2+微量,Mn^2+/Fe^2+为0时,不发光;0.05〈Mn^2+Fe^2+〈0.2时,发光强度暗,发光颜色为橙红色;0.2〈Mn^2+/Fe^2+〈2时,发光强度中等,发光颜色为橙黄色;Mn^2+/Fe^2+〉2时,发光强度亮,发光颜色为亮黄色。 相似文献
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蚀变岩中物质迁移的定量计算:以锡矿山锑矿床为例 总被引:6,自引:2,他引:6
本文提出了确定沉积岩蚀变作用过程中的不活动组分的方法,并以锡矿山锑矿床为例,定量计算了蚀变岩中各组分的带入带出量,研究表明:锡矿山锑矿硅化过程中TiO2和Al2O3为不活动组;SiO2,K2O,Na2O及锑,硫,坤,汞,铅和钡为带入组分;而CaO,MgO,Fe2O3,MnO及铜,锌为带出组分,锑,钡,硫,SiO2和CaO有较大的带进或带出量,锡矿山锑矿床矿石矿物为单一辉锑矿可能是由于矿液中缺少其它 相似文献
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Mg-Fe电气石的热膨胀与相变 总被引:5,自引:0,他引:5
对Mg-Fe系列的两种电气石进行了不同温度下的热膨胀与相变研究,发现电气石在900℃以下保持稳定,900-950℃分解,镁电气石分解为堇青石-α与非晶质,黑电气石分解为赤铁矿与Al5(BO3)O6。加热过程中电气石晶胞大小发生变化,是晶体热膨胀与Fe^2 →Fe^3 替代、OH^-→O^2-替代综合作用的结果。在含Fe的电气石中,晶胞收缩幅度取决于电气石中Fe^2 的含量;800℃时,Fe^2 完全氧化,表面赤铁矿晶出,晶胞收缩显著。电气石的热膨胀率为锂电气石>镁电气石>黑电气石;c轴>a轴。 相似文献
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Emily Keeble David I. Whiteside Michael J. Benton 《Proceedings of the Geologists' Association. Geologists' Association》2018,129(2):99-119
Pant-y-ffynnon Quarry in South Wales yielded a rich cache of fossils in the early 1950s, including articulated specimens of new species (the small sauropodomorph dinosaur Pantydraco caducus and the crocodylomorph Terrestrisuchus gracilis), but no substantial study of the wider fauna of the Pant-y-ffynnon fissure systems has been published. Here, our overview of existing specimens, a few described but mostly undescribed, as well as freshly processed material, provides a comprehensive picture of the Pant-y-ffynnon palaeo-island of the Late Triassic. This was an island with a relatively impoverished fauna dominated by small clevosaurs (rhynchocephalians), including a new species, Clevosaurus cambrica, described here from a partially articulated specimen and isolated bones. The new species has a dental morphology that is intermediate between the Late Triassic Clevosaurus hudsoni, from Cromhall Quarry to the east, and the younger C. convallis from Pant Quarry to the west, suggesting adaptive radiation of clevosaurs in the palaeo-archipelago. The larger reptiles on the palaeo-island do not exceed 1.5?m in length, including a small carnivorous crocodylomorph, Terrestrisuchus, and a possible example of insular dwarfism in the basal dinosaur Pantydraco. 相似文献
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Gilles Serge Odin 《Comptes Rendus Geoscience》2002,334(6):409-414
Lithostratigraphy, physicochemical stratigraphy, biostratigraphy, and geochronology of the 77–70 Ma old series bracketing the Campanian–Maastrichtian boundary have been investigated by 70 experts. For the first time, direct relationships between macro- and microfossils have been established, as well as direct and indirect relationships between chemo-physical and biostratigraphical tools. A combination of criteria for selecting the boundary level, duration estimates, uncertainties on durations and on the location of biohorizons have been considered; new chronostratigraphic units are proposed. The geological site at Tercis is accepted by the Commission on Stratigraphy as the international reference for the stratigraphy of the studied interval. To cite this article: G.S. Odin, C. R. Geoscience 334 (2002) 409–414. 相似文献
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The effect of water on accessory phase solubility in subaluminous and peralkaline granitic melts 总被引:4,自引:0,他引:4
The solubilities of columbite, tantalite, wolframite, rutile, zircon and hafnon were determined as a function of the water contents in peralkaline and subaluminous granite melts. All experiments were conducted at 1035 °C and 2 kbar and the water contents of the melts ranged from nominally dry to approximately 6 wt.% H2O. Accessory phase solubilities are not affected by the water content of the peralkaline melt. By contrast, solubilities are affected by the water content of the subaluminous melt, where the solubilities of all the accessory phases examined increase with the water content of the melt, up to 2 wt.% H2O. At higher water contents, solubilities are nearly constant. It can be concluded that water is not an important control of accessory phase solubility, although the water content will affect diffusivities of components in the melt, thus whether or not accessory phases will be present as restite material. The solubility behaviour in the subaluminous and peralkaline melts supports previous spectroscopic studies, which have observed differences in the coordination of high field strength elements in dry vs. wet subaluminous granitic glasses, but not for peralkaline granitic glasses. Lastly, the fact that wolframite solubility increases with increasing water content in the subaluminous melt suggests that tungsten dissolved as a hexavalent species. 相似文献
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Muriel Rocher Stéphane Baize Stéphane Jaillet Edward Marc Cushing Yannick Lozach Francis Lemeille 《Comptes Rendus Geoscience》2003,335(8):701-708
Calcite samples were extracted both from the rock matrix and the superficial coating of a karstified fault plane of an underground quarry, located in the eastern border of the Paris basin. The karstification is dated as Quaternary. Analysis of mechanical calcite twinning reveals that only the calcite matrix has also undergone a compression trending WNW that can be attributed to the Mio-Pliocene alpine collision. Both coating and matrix have undergone a strike-slip regime with σ1 roughly trending north–south, that could correspond to the regional present-day state of stress, a strike-slip compression rather trending NNW, modified by local phenomena. To cite this article: M. Rocher et al., C. R. Geoscience 335 (2003). 相似文献
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正20141756 Chen Ruige(Mathematical College,China University of Geosciences,Beijing100083,China);Zhou Xun Numerical Simulation of Groundwater Level Fluctuation in a Coastal Confined Aquifer with Sloping Initial Groundwater Level Induced by the Tide(Geological Bulletin of China,ISSN1671-2552,CN11-4648/P,32(7),2013,p.1099-1104,6 illus.,16 refs.) Key words:confined water,groundwater level 相似文献
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正20141408 Cai Jia(Institute of Geology,Chinese Academy of Geological Sciences,Beijing100037,China);Liu Fulai Petrogenesis and Metamorphic P-T Conditions of Garnet-Spinel-Biotitebearing Paragneiss in Danangou Area,Daqingshan-Wulashan Metamorphic Complex Belt(Acta Petrologica Sinica,ISSN1000-0569,CN11-1922/P,29(7), 相似文献
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正20142386An Guoying(China Aero Geophysical Survey and Remote Sensing Center for Land and Resources,Beijing 100083,China)Application of Satellite Remote Sensing in Regional Hydrogeological Investigation:Taking Cenozoic Strata in Wenquan Sheet(1∶250 000)of Karakoram Range as an Example(Geosci- 相似文献
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正20141016An Chengbang(Key Laboratory of Western China’s Environmental Systems,Ministry of Education,Lanzhou University,Lanzhou 730000,China);Zhao Yongtao Lake Records during the Last Glacial Maximum from Xinjiang,NW China and Their Climatic Impli- 相似文献
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正20141538 Cao Qing(School of Earth Sciences and Engineering,Xi’an Petroleum University,Xi’an 710065,China);Zhao Jingzhou Characteristics and Significance of Fluid Inclusions from Majiagou Formation,Yichuan Huangling Area,Ordos Basin(Advances in Earth Science,ISSN1001-8166,CN62-1091/P,28(7),2013,p.819-828,7 illus.,3 tables,43 refs.) 相似文献