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1.
针对石墨炉原子吸收法测定土壤中痕量金的测定过程,建立了数学模型,分析了其不确定度的来源,对不确定度的各分量进行量化,计算得出合成标准不确定度和扩展不确定度,并以不确定度的形式表达了测定结果。 相似文献
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电感耦合等离子体发射光谱法测定矿石中7种元素的结果不确定度评价 总被引：1，自引：0，他引：1
对电感耦合等离子体发射光谱法测定矿石中铜、铅、锌、钾、钠、钛、钒7种元素的整个实验过程可能引入的各种不确定度来源进行分析,并对各种不确定度分量进行量化计算,最后得出合成标准不确定度和扩展不确定度,给出测试结果。 相似文献
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按照测量不确定度评定方法,对氢化物发生-原子荧光光谱法测定地球化学样品中铋结果进行不确定度评定。研究发现原子荧光光谱法测定地球化学样品中铋含量的不确定度主要来源于样品制备过程、标准溶液配制过程、校准曲线拟合过程、重复性测量以及分析仪器的不确定度等。通过对各分量的不确定度进行量化,得出合成标准不确定度和扩展不确定度。结果表明最大的不确定度来源于样品制备过程。当样品中铋含量为24.76μg/g时,其扩展不确定度(k=2)为1.40μg/g。 相似文献
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为建立非分散红外吸收法测定岩溶区流域水体中溶解性无机碳(DIC)分析结果不确定度的评定方法,采用不确定度连续传递模式,对两个岩溶地下水样的DIC测定结果的不确定度进行了评定。其主要做法是:先采用双误差回归方式对校准曲线进行拟合,对评定过程中各个不确定度分量进行量化,然后合成得到DIC测定结果的不确定度评定模型。通过实验结果计算表明:(1)测定结果的不确定度主要来源于标准溶液引入的不确定度、曲线拟合产生的不确定度和测定过程产生的不确定度。(2)样品的DIC含量越低,其相对不确定度越大,且校准曲线在拟合过程中所引入的不确定度对其测定结果的总不确定度具有较大的贡献率。 相似文献
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采用《测量不确定度评定与表示指南》，以等离子体发射光谱法测定土壤中的稀土元素铈为例，对测定结果进行不确定度评定。分析了不确定度的重要来源，包括溶液制备过程中引入的不确定度、样品称量引入的不确定度、标准物质外标法测量不确定度及仪器重复测定的不确定度。提供了引入不确定度各参数的采集和计算方法，对各不确定度分量进行分析计算，最后合成标准不确定度，通过乘以95％概率下的扩展因子2，获得测量结果的扩展不确定度。 相似文献
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对743型大孔阳离子交换树脂分离偶氮胂Ⅲ分光光度法测定样品中钍的不确定度进行了评定。根据其测定方法和测定程序,通过对各不确定度的来源分析,计算了相对不确定度分量、合成相对不确定度和扩展不确定度,详细介绍了不确定度的评定过程,分析结果显示出整个测定过程中易带来误差的步骤,为分析人员获得更为准确的结果提供很好的指导作用。 相似文献
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本文以火焰原子吸收光谱法对化探样品中铜的含量测定为对象,分析了测定不确定度的主要来源,包括样品称量过程、标准溶液配制、标准曲线拟合过程以及样品溶液定容过程,对各不确定度分量进行了分类与计算,评估了某化探样品的合成不确定度以及扩展不确定度.实验结果显示不确定度主要来自样品重复测量过程和标准溶液的配制过程.对于含量为35.05μg/g的土壤样品,其扩展不确定度为0.9744μg/g. 相似文献
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采用电感耦合等离子体发射光谱法(ICP-OES)法测定氧化钕中杂质氧化镍的含量,得到氧化镍含量为0.002 7%,分析了检测过程中的各个影响因素,并对测量结果的可靠性以相对扩展不确定度表示(Urel=12%,k=2)。相对不确定度分量计算结果表明,标准曲线拟合时引入的相对不确定度分量最大,urel(c2)=5.639%,其次为标准溶液配制过程中引入的相对不确定度分量urel(c1)=0.879%。本文可为相关检测人员的结果不确定度分析提供参考。 相似文献
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Fuzzy logic mineral prospectivity modelling was performed to identify camp-scale areas in western Victoria with an elevated potential for hydrothermal-remobilised nickel mineralisation. This prospectivity analysis was based on a conceptual mineral system model defined for a group of hydrothermal nickel deposits geologically similar to the Avebury deposit in Tasmania. The critical components of the conceptual model were translated into regional spatial predictor maps combined using a fuzzy inference system. Applying additional criteria of land use restrictions and depth of post-mineralisation cover, downgrading the exploration potential of the areas within national parks or with thick barren cover, allowed the identification of just a few potentially viable exploration targets, in the south of the Grampians-Stavely and Glenelg zones. Uncertainties of geological interpretations and parameters of the conceptual mineral system model were explicitly defined and propagated to the final prospectivity model by applying Monte Carlo simulations to the fuzzy inference system. Modelling uncertainty provides additional information which can assist in a further risk analysis for exploration decision making. 相似文献
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元江镍矿区硫化镍矿床找矿思路探讨 总被引：2，自引：0，他引：2
总结了墨江-元江红土镍矿床的地质特征，并根据该区已发现超基性岩体接触带中岩浆热液改造型硫化镍矿的事实，对今后在区内寻找硫化型镍矿床的可能性及其有利地段进行了探讨。 相似文献
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菲律宾AREA矿区红土镍矿为硫化镍矿岩体风化-淋滤-沉积形成的地表风化壳型矿床,矿体赋存在含矿风化基岩中。为圈定该矿区红土镍矿有利地段,依据岩(矿)石物性特征、矿体地质特征,采用对称四极电阻率剖面法(简称对称四极法)面积性测量,发现低阻异常;利用高密度电阻率测深法(简称高密度电法)剖面,对成矿有利地段进行评价并确定含矿层厚度和产状,圈定镍矿富集部位。工程验证结果表明,见矿较好位置与电法结果吻合较好。研究结果表明,红土镍矿勘探在前期工作中,采用电阻率法可圈定含矿层范围和延伸产状,有效缩小勘探范围,指导工程勘探布置,节约勘探成本。 相似文献
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Hans PitterssonHenri Rotschi 《Geochimica et cosmochimica acta》1952,2(2):81-90
Determinations of the nickel, manganese and iron present in sediment cores from the Central Pacific Ocean have been made by microchemical methods. The results show (a) that the nickel content is high relative to that of continental rocks and sediments and, (b) that there are considerable variations in the nickel contents with depth below the sediment surface. No correlation with the manganese and iron contents is evident except in cases where a change in the rate of sedimentation appears to have affected all three elements in the same manner. 相似文献
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T. V. M. Sreekanth P. C. Nagajyothi K. D. Lee T. N. V. K. V. Prasad 《International Journal of Environmental Science and Technology》2013,10(5):1129-1140
The focus of the review is on the specific aspects of nickel’s effects on growth, morphology, photosynthesis, mineral nutrition and enzyme activity of plants. The mobility of nickel in the environment and the consequent contamination in soil and water is of great concern. Also, the detrimental effects of excessive nickel on plant growth have been well known for many years. Toxic effects of nickel on plants include alterations in the germination process as well as in the growth of roots, stems and leaves. Total dry matter production and yield was significantly affected by nickel and also causes deleterious effects on plant physiological processes, such as photosynthesis, water relations and mineral nutrition. Nickel strongly influences metabolic reactions in plants and has the ability to generate reactive oxygen species which may cause oxidative stress. More recent evidence indicates that nickel is required in small amounts for normal plant growth and development. Hence, with the increasing level of nickel pollution in the environment, it is essential to understand the functional roles and toxic effects of nickel in plants. 相似文献
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Many nickel deposits are known in Brazil, accounting for about 350 · 106 tons of ore with an average of 1.5% Ni. All are of the lateritic type. These deposits are scattered throughout the country, being rarer in the Northeastern Region and in the South, below 25 °S latitude. They are mainly associated with mafic-ultramafic massifs of large dimensions and ultramafic alkaline complexes, and occur in climatic regions of contrasting seasons. The weathering profile developed over the fresh rock consists, from bottom to top, of the following horizons: altered rock, coarse saprolite, argillaceous saprolite, ferruginous saprolite and lateritic overburden. The thickness of each horizon varies from one deposit to another, the whole profile generally exceeding 20 m. The saprolitic horizons with inherited minerals (serpentine, chlorite) or neoformed minerals (smectites) constitute the silicated nickel ore and are thicker were climatic conditions are drier; the ferruginous upper horizons made up of iron oxide-hydroxides are more developed in more humid regions. In Brazil, the silicated ore generally prevails over the oxidized ore. The main Ni-bearing minerals are serpentine, smectite, garnierite and goethite. The lateritic nickel deposits of Brazil may be correlated with two erosion surfaces, corresponding to the Sul Americano (Lower Tertiary) and Velhas (Upper Tertiary) levelling cycles. The degree of dismantling of the higher and more ancient surface and the consequent development of the Velhas Surface control the position of the nickel accumulation in the landscape. Thus, the deposits may be found either in the lowlands or in the highlands, where they are always covered by a silcrete layer. The alteration profiles in the Brazilian lateritic nickel deposits are broadly similar to those described elsewhere in the world. However, they present two characteristic features: the silicated ore prevails over the oxidized ore, and a silicified layer covers the profies developed on the highlands. 相似文献
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Specification and prediction of nickel mobilization using artificial intelligence methods 总被引：1，自引：0，他引：1
Raoof Gholami Mansour Ziaii Faramarz Doulati Ardejani Shahoo Maleki 《Central European Journal of Geosciences》2011,3(4):375-384
Groundwater and soil pollution from pyrite oxidation, acid mine drainage generation, and release and transport of toxic metals are common environmental problems associated with the mining industry. Nickel is one toxic metal considered to be a key pollutant in some mining setting; to date, its formation mechanism has not yet been fully evaluated. The goals of this study are 1) to describe the process of nickel mobilization in waste dumps by introducing a novel conceptual model, and 2) to predict nickel concentration using two algorithms, namely the support vector machine (SVM) and the general regression neural network (GRNN). The results obtained from this study have shown that considerable amount of nickel concentration can be arrived into the water flow system during the oxidation of pyrite and subsequent Acid Drainage (AMD) generation. It was concluded that pyrite, water, and oxygen are the most important factors for nickel pollution generation while pH condition, SO4, HCO3, TDS, EC, Mg, Fe, Zn, and Cu are measured quantities playing significant role in nickel mobilization. SVM and GRNN have predicted nickel concentration with a high degree of accuracy. Hence, SVM and GRNN can be considered as appropriate tools for environmental risk assessment. 相似文献
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中国镍资源丰富,同时也是镍资源消费大国。矿床类型相对简单,主要为岩浆型,其次为海相沉积型和风化壳型3种。矿床形成时代从中—新元古代一直延续到新生代,主要集中在新元古代和晚古生代两个高峰期;空间分布较为集中,主要分布在西北、西南和东北地区,往往具有成群分布的特征。大陆边缘裂解、碰撞造山期后伸展以及地幔柱是形成中国镍矿床的3种重要构造背景。在全国Ⅲ级成矿区带的基础上,以镍矿床的空间分布特征为基础,以成矿规律和成矿条件为依据,在全国范围内划分30个成镍带;对东天山、甘—新北山、龙首山、吉中—延边、康滇、扬子南缘等6个成镍带的主要特征进行了简单叙述;从成镍带的角度,探讨了中国镍矿找矿方向,认为深部找矿尤其值得重视。 相似文献