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1.
Experimental study on supercritical phenomena of WO<Subscript>3</Subscript> solubility in NaCl-H<Subscript>2</Subscript>O system 总被引：1，自引：0，他引：1
The solubility measurements of WO3 in NaCl-H2O system with 4.0% by weight salt were carried out to study the supercritical phenomena of solubility. These experiments were
carried out using rapid-quench pressure vessels, with quantitative Na2WO4-2H2O, HCl, NaCl and H2O in Pt capsule to determine the solubility of WO3 from supersaturated solution. The pressure was kept at 34 MPa, which was near the critical pressure 31.4 MPa and the temperatures
varied from 250°C to 550°C. The experimental results indicate that the solubility of WO3 has the features of supercritical phenomenon in critical region and is sensitive to the change of system temperature and
solvent density. The temperature and pressure in this experiment are close to those of ore-forming fluids in many tungsten
deposits, so the features of supercritical geofluids can be helpful to investigating the ore-forming mechanism of tungsten
deposit. 相似文献
2.
为了探讨大陆地壳断层深部的力学性质,我们选择了采自红河断裂带的糜棱岩作为实验样品,进行热水条件下的高温高压摩擦滑动实验.实验在一个以气体为介质的高温高压三轴实验系统中进行.实验条件是：有效正应力为200 MPa;孔隙水压为30 MPa（在400 ℃到600 ℃之间为超临界水条件）;温度为100 ℃到600 ℃;轴向加载的速率范围从0.04 μm/s到0.2 μm/s再到1 μm/s.实验结果表明：（1）当温度小于300 ℃时,糜棱岩的摩擦强度随着温度的上升而增大;当温度大于300 ℃时,糜棱岩的摩擦强度随着温度的上升而减小.这种趋势和以往花岗岩的摩擦滑动数据基本一致;（2）糜棱岩在200 ℃和400 ℃时表现为速度弱化,其余温度下为速度强化;（3）糜棱岩与已有花岗岩的摩擦滑动数据并不完全一致;（4）花岗质糜棱岩速度弱化向速度强化转变的温度在430 ℃附近,以此我们可以推测：在变形机制为摩擦滑动的深部条件下,地震成核的深度范围可以比以往的估计更深. 相似文献
3.
为探索断层岩石摩擦特性对于断层力学性质的影响,我们采集了龙门山汶茂断裂韧性剪切带中的富含层状硅酸盐矿物的糜棱岩样品进行了水热条件下摩擦滑动实验研究.实验在三轴压机之上完成,实验温度为100~600℃,有效正压力100MPa,孔隙水压分别为30MPa和130MPa.为获得摩擦滑动的稳定性参数(a-b),剪切滑移速率在1.22μm·s-1,0.244μm·s-1和0.0488μm·s-1之间切换.实验发现在200~500℃的温度范围内,摩擦系数随着温度的增加而显著增大(约0.56~0.72).在200~300℃范围内,随温度的升高糜棱岩的摩擦滑动表现出由稳定的速度强化向不稳定速度弱化转变的趋势.在有效正压力不变的情况下,孔隙水压的增大会促进糜棱岩的摩擦滑动在500~600℃温度范围内由不稳定的速度弱化向稳定的速度强化的转变.实验给出的断层在原地深度处的脆性和塑性变形机制的转变,有助于理解断层深部的地震成核机制以及成核的温压条件. 相似文献
4.
温度和压力是沉积盆地两个重要的物理场,温度影响着超压的形成和分布.本文根据钻孔实测温度和压力数据分析了川中古隆起现今压力与温度的关系;在实验室对封闭流体进行了多组温-压关系实验;利用等效镜质体反射率和包裹体测温数据恢复了川中古隆起不同井区在白垩纪抬升之前的最大古地温,并在此基础上分析了温度降低对研究区超压的影响;最后探讨了生烃增压和欠压实超压形成过程中温度的作用.研究结果表明,川中古隆起现今超压层的压力系数与温度呈正相关关系;在绝对密封的条件下,当压力大于15 MPa时,温度每变化1℃,压力变化1.076 MPa.川中地区不同井区自晚白垩世以来的差异性降温是现今同一超压层系超压强度不同的主要因素,此外超压层还应发生了流体的横向压力传递和泄漏.下古生界原油裂解形成超压的时间是180~110 Ma;气态烃伴生的盐水包裹体均一温度暗示了在90 Ma超压发生调整.盆地模拟结果显示温度对上三叠统须家河组的欠压实增压影响微弱. 相似文献
5.
Abstract Hydrothermal experiments of dissolution of granite and quartz with pure water up to 600°C and 60 MPa were carried out in order to evaluate chemical reaction under sub- and supercritical conditions. The supercritical region beyond the critical point for water has been inferred to be a homogeneous state, which does not correspond to either a true liquid phase, or a true vapor phase. Results of dissolution experiments of granite and quartz in a supercritical state (artificially defined as higher pressures and temperatures than the critical point), show this fluid can be subdivided into two apparent phases comprising a 'liquid-like' region and a 'vapor-like' region. Chemical phenomena with respect to dissolution reactions in the 'liquid-like' region are more similar to those of subcritical water, whilst those reactions in the 'vapor-like' region even in the supercritical state are considered to be weak. The critical point of various kinds of geofluids, composed of solutions in the H2 O-CO2 -NaCl system was experimentally determined using a visible type autoclave. Chemical reaction diversity, depending on location of the critical point for a given solution and apparent phase boundary in terms of chemical reaction within the supercritical state, was recognized by hydrothermal experiments. 相似文献
6.
FRICTIONAL SLIDING OF PLAGIOCLASE GOUGE UNDER LOWER-CRUST TEMPERATURE AND RELATIVELY LOW EFFECTIVE NORMAL STRESS 
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下载免费PDF全文 The discovery of tremors on the lower crust portion of the San Andreas Fault has attracted more attention on the mechanical properties of the lower crust in recent years, and some experimental studies have been carried out to understand the mechanical behavior. Previous experiments under effective normal stresses of 200MPa have shown that pyroxene and plagioclase mineral separated from the gabbro and their mixtures all show velocity weakening in the lower-crust temperature range, which results in unstable slip when frictional sliding is the dominant deformation mechanism. This work is to examine whether the velocity-weakening behavior of plagioclase gouge also applies to relatively lower effective normal stress. Our experiments were performed under effective normal stress of about 100MPa, with a constant confining pressure control, with pore pressure of 30MPa and temperature of 100℃ to 600℃. We found that the frictional sliding of plagioclase are basically the same with the previous results obtained under effective normal stress of 200MPa, both of which show velocity weakening over the entire temperature range. The only difference is the out-of-trend drop of constitutive parameter a at 600℃ for the lower effective normal stress of 100MPa. It is thus concluded that reducing the effective normal stress has little effect on the sliding stability of plagioclase, and the previous conclusion made for mechanical behavior of the lower crust that unstable slips are possible therein also applies to the lower effective normal stress of 100MPa. 相似文献
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《中国科学:地球科学(英文版)》2021,(9)
The solubility of Au in silicate melts and fluids governs the enrichment and migration of Au during the formation of magmatic-hydrothermal Au deposits. Large Au deposits require vast amounts of Au to migrate from the upper mantle-lower crust to the shallow crust, and high Au solubility in magma and hydrothermal fluid facilitates the formation of Au-rich magma and fluid in the crust and mantle source and efficient transport. This paper reviews recent high-pressure and high-temperature experimental studies on Au species in magmas and hydrothermal fluids, the partitioning behavior of Au between silicate melts and fluids, and the effects of temperature, pressure, oxygen fugacity, sulfur fugacity, silicate melt composition, and volatiles(H_2O, CO_2, chlorine, and sulfur) on the solubility of Au in magma. We show that the solubility of Au in magma is largely controlled by the volatiles in the magma: the higher the content of reduced sulfur(S~(2-) and HS~-) in the magma, the higher the solubility of Au. Under high-temperature, high-pressure, H_2O-rich, and intermediate oxygen fugacity conditions, magma can dissolve more reduced sulfur species, thus enhancing the ability of the magma to transport Au. If the ore-forming elements of the Au deposits in the North China Craton originate from mantle-derived magmas and fluids, we can conclude, in terms of massive Au migration, that these deep Au-rich magmas might have been generated under H2 O-rich and moderately oxidized conditions(S~(2-) coexists with S~(6+)). The big mantle wedge beneath East Asia was metasomatized by melts and fluids from the dehydration of the Early Cretaceous paleo-Pacific stagnant slab, which not only caused thinning of the North China Craton, but also created physicochemical conditions favorable for massive Au migration. 相似文献
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《中国科学:地球科学(英文版)》2021,(9)
The gold deposits in the Jiaodong Peninsula constitute the largest gold mineralized province in China. The mineralization shows common characteristics in their tectonic setting, ore-forming fluid and metallogenic system. Sulfidation and fluid immiscibility are two important mechanisms controlling gold precipitation, both of which consume sulfur in the oreforming fluids. The escape of H_2S from the main ore-forming fluids and the decrease of total sulfur concentration not only lead to the efficient precipitation of gold, but also result in the crystallization of reducing minerals such as pyrrhotite and oxidizing minerals such as magnetite. Quartz solubility shows strong dependence on temperature, pressure, and CO_2 content. The dependence of quartz solubility on pressure is weak at low temperatures, and progressively stronger at higher temperatures.Similarly, the temperature dependence of quartz solubility is relatively low at low pressures, but becomes gradually stronger at high pressures. The results of solubility modeling can constrain the dissolution and reprecipitation behavior of quartz in the oreforming veins and the formation mechanism of different types of quartz veins. The multi-stage mineralization fluid activity resulted in the complex dissolution structure of quartz in the Jiaodong gold veins. Pyrite in the main metallogenic period in the Jiaodong gold deposits shows complex microstructure characteristics at single crystal scale. The trace elements(mainly the coupling of As-and Au-rich belt) and sulfur isotope composition also display a certain regularity. The As-rich fluids might have formed by the initial pulse of ore-forming fluids through As-rich metasedimentary strata, while the As-Au oscillation zone at the margin of pyrite grains is related to the pressure fluctuation caused by fault activity and the local phase separation of fluids. There is a temporal and spatial evolution of gold fineness in the Jiaodong gold deposits. Water/rock reaction(sulfidation) was the main ore-forming mechanism of early gold mineralization, forming relatively high fineness gold, while significant pressure drop in the shallow part accompanied by fluid phase separation promoted the late gold mineralization, forming low fineness gold. Under cratonic destruction setting, dehydration of the amphibolite and granulite facies metamorphic lower-crust resulted in the formation of Au-CO_2-rich ore-forming fluids, which rose along the deep fault and secondary structure, and formed the largescale fault-controlled gold deposits in Jiaodong. 相似文献
10.
黑云母是自然界常见的层状硅酸盐矿物,其摩擦系数不高且化学稳定性好,对其摩擦性质的关注可能会对弱断层的研究有所帮助.本次工作选取的实验温度条件对应于典型地壳强度模型中脆塑性转化带的范围,为300 ℃和400 ℃.有效正应力为200 MPa,孔隙水压包括10 MPa和30 MPa,在此条件下对黑云母模拟断层泥进行摩擦实验研究.实验得出黑云母的摩擦系数平均在0.36左右.速度依赖性随温度升高速度弱化的程度增强,表现为300 ℃为十分微弱的速度弱化,而在400 ℃出现了黏滑行为,代表了更强的速度弱化.显微结构中同时出现了脆性剪切变形和塑性扭折变形,但决定宏观力学性质的显然是脆性剪切变形.在黑云母存在的情况下,本研究的实验结果有助于理解大陆地壳脆塑性转化带中地震的可能性和弱断层深部的变形机制、宏观力学行为以及地震活动. 相似文献
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本文重点报道了高温高压下流体与流体-岩石相互作用实验结果,提供了中地壳条件下流体性质和水岩反应速率数据.这些数据有助于理解中地壳的一些地球物理现象.作者进行了25℃~435℃和22~39 MPa条件下水-岩相互作用反应动力学实验.同时,研究水在近临界区至超临界区的性质.一般地说,中地壳大致位于10(15)至25 km的深度范围.各地的地壳厚度不同,但是中地壳高导-低速层的深度范围十分相似.中地壳的顶界温度处于300℃,底界大致为450℃范围,压力高达200 MPa以上.流体-岩石相互作用实验表明:硅酸盐矿物和岩石的硅最大溶解速率出现在300℃~400℃.此时,硅酸盐矿物格架解体.通常,地壳里普遍存在水、流体.地壳构造活动导致断裂空隙、减压、流体流动.这时,有可能导致中地壳处于300℃~450℃流体的压力减低,由超临界区进入临界态、亚临界态.这会引发强烈流动的水与岩石相互作用.溶解反应导致岩层的硅淋失,硅的强烈淋失又会导致硅酸盐矿物格架解体,岩石崩塌.同时,进一步促进流体的流动.实验表明300℃~400℃下的强烈水岩相互作用促进了岩石破坏,并有可能影响岩层的地球物理性质,如高导层出现.另外,实验和理论研究表明处于300℃~400℃流体具有高电导率性质.这些水岩相互作用会使中地壳出现高导-低速层. 相似文献
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In this paper, we show that supercritical fluids have a greater significance in the generation of pegmatites,and for ore-forming processes related to granites than is usually assumed. We show that the supercritical melt or fluid is a silicate phase in which volatiles; principally H_2O are completely miscible in all proportions at magmatic temperatures and pressures. This phase evolves from felsic melts and changes into hydrothermal fluids, and its unique properties are particularly important in sequestering and concentrating low abundance elements, such as metals. In our past research, we have focused on processes observed at upper crustal levels, however extensive work by us and other researchers have demonstrated that supercritical melt/fluids should be abundant in melting zones at deep-crustal levels too. We propose that these fluids may provide a connecting link between lower and upper crustal magmas,and a highly efficient transport mechanism for usually melt incompatible elements. In this paper, we explore the unique features of this fluid which allow the partitioning of variouselements and compounds, potentially up to extreme levels,and may explain various features both of mineralization and the magmas that produced them. 相似文献
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Songtao Li Yong Xia Jianzhong Liu Zhuojun Xie Qinping Tan Yimeng Zhao Minghua Meng Lijin Tan Rong Nie Zepeng Wang Guanghong Zhou Haiyan Guo 《Acta Geochimica》2019,(4):587-609
The newly discovered Baogudi gold district is located in the southwestern Guizhou Province,China,where there are numerous Carlin-type gold deposits.To better understand the geological and geochemical characteristics of the Baogudi gold district,we carried out petrographic observations,elemental analyses,and fluid inclusion and isotopic composition studies.We also compared the results with those of typical Carlin-type gold deposits in southwestern Guizhou.Three mineralization stages,namely,the sedimentation diagenesis,hydrothermal(main-ore and late-ore substages),and supergene stages,were identified based on field and petrographic observations.The main-ore and late-ore stages correspond to Au and Sb mineralization,respectively,which are similar to typical Carlin-type mineralization.The mass transfer associated with alteration and mineralization shows that a significant amount of Au,As,Sb,Hg,Tl,Mo,and S were added to mineralized rocks during the main-ore stage.Remarkably,arsenic,Sb,and S were added to the mineralized rocks during the late-ore stage.Element migration indicates that the sulfidation process was responsible for ore formation.Four types of fluid inclusions were identified in ore-related quartz and fluorite.The main-ore stage fluids are characterized by an H2O–NaCl–CO2–CH4±N2system,with medium to low temperatures(180–260℃)and low salinity(0–9.08%NaCl equivalent).The late-ore stage fluids featured H2O–NaCl±CO2±CH4,with low temperature(120–200℃)and low salinity(0–7.48%Na Cl equivalent).The temperature,salinity,and CO2and CH4concentrations of ore-forming fluids decreased from the main-ore stage to the late-ore stage.The calculated δ^13C,d D,and δ^18O values of the ore-forming fluids range from-14.3 to-7.0%,-76 to-55.7%,and 4.5–15.0%,respectively.Late-ore-stage stibnite had δ^34S values ranging from-0.6 to 1.9%.These stable isotopic compositions indicate that the ore-forming fluids originated mainly from deep magmatic hydrothermal fluids,with minor contributions from strata.Collectively,the Baogudi metallogenic district has geological and geochemical characteristics that are typical of Carlin-type gold deposits in southwest Guizhou.It is likely that the Baogudi gold district,together with other Carlin-type gold deposits in southwestern Guizhou,was formed in response to a single widespread metallogenic event. 相似文献
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It has been proved to be a difficult problem to determine directly trapping pressure of fluid inclusions. Recently, PVT simulation softwares have been applied to simulating the trapping pressure of petroleum inclusions in reservoir rocks, but the reported methods have many limitations in practice. In this paper, a method is suggested to calculating the trapping pressure and temperature of fluid inclusions by combining the isochore equations of a gas-bearing aqueous inclusion with its coeval petroleum inclusions. A case study was conducted by this method for fluid inclusions occurring in the Upper-Paleozoic Shanxi Formation reservoir sandstones from the Ordos Basin. The results show that the trapping pressure of these inclusions ranges from 21 to 32 MPa, which is 6-7 MPa higher than their minimum trapping pressure although the trapping temperature is only 2-3℃ higher than the homogenization temperature. The trapping pressure and temperature of the fluid inclusions decrease from southern area to northern area of the basin.The trapping pressure is obviously lower than the state water pressures when the inclusions formed. These data are consistent with the regional geological and geochemical conditions of the basin when the deep basin gas trap formed. 相似文献
15.
Changkeng Au-Ag deposit is a newly-discovered new type precious metal deposit. N2-Ar-He systematics studies and3He/4He and δD- δ18O composition analyses show that the ore-forming fluid of the deposit is composed mainly of formation water (sedimentary brine)
but not of meteoric water, which was thought to be source of the ore-forming fluid by most previous researchers. The content
of mantle-derived magmatic water in the ore-forming fluid is quite low, usually lower than 10%. According to the source of
the ore-forming fluid, the Changkeng Au-Ag deposit should belong to sedimentary brine transformed deposits. From the Late
Jurassic to the Early Cretaceous Period, with deposition and accumulation of thick sediments in Sanzhou Basin, the formation
water in the sedimentary layers was expelled from the basin because of overburden pressure and increasing temperature. The
expelled fluid moved laterally along sedimentary layers to the margin of the basin, and finally moved upward along a gently-dipping
interlayer fault. Because of a decline in pressure and temperature, ore minerals were deposited in the fault.
Project supported by the National Natural Science Foundation of China (Grant No. 495020291, the Natural Science Foundation
of Zhongshan University, the Research Foundation of National Key Laboratory of Metallogenesis in Nanjing University (Grant
No. 039704) and the Lingnan Foundation. 相似文献
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镁铁质、超镁铁质岩石波速实验测量在高压700-800MPa、高温800-1100℃下进行．波速-温度曲线的斜率以温度系数dVp／dT表示，大体在700℃以内，8个标本的温度系数平均为-1．86×10-4km·S-1／℃，比资料值小得多，即在此温度范围内，波速随温度的降幅不大．在这一温度限以上，大多岩石开始脱水出溶，相组合发生变化，同时波速大幅度下降．曲线发生转折的机制是岩石中液相的产生．角闪岩波速曲线斜率也从700℃开始发生改变，950℃后速度直线下降，到1008℃时，岩石中液量达30％，波速Vp值下降到487km／s．最后，依岩类不同以及岩石出溶和相变对波速的影响划分出5个速度-温度区，讨论了华北断块内构造隆起区和沉降区下地壳可能存在的岩石及其状态． 相似文献
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On the basis of FTIR and Raman spectra studies on hydrous albite glasses, it is found that there exist two water solubility mechanisms in albite melts simultaneously. On the one hand, water interacts with Al -O°-Al to produce the Q3 Al-OH, leading to depolymerization, and this results in the appearance of 4500 cm(1 in FTIR spectra and 900 cm(1 in Raman spectra. On the other hand, the exchange of H+ in water with Na+ in albite melt as charge-balancing cation occurs at the same time. In the initial stage, the production of Al -OH is the dominant solubility mechanism, at the stage of higher water contents, the exchange of H+ with Na+ becomes the important dissolution mechanism. The dissolution of water into albite melt can be expressed as H2O+ 3NaAlSi3O8 = 2NaAl(OH)Si3O7.5 +HAlSi3O8 +NaOH. 相似文献
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利用 Kolsky 扭转棒作为实验装置,笔者在常温常压条件下对干燥的和潮湿的大理岩试样进行了一系列的动态简单剪切的实验变形研究,以期了解在高应变率(373-1-1736-1)时岩石中孔隙水对于岩石抗剪强度的影响.结果表明,孔隙水的存在不但没有降低,反而稍微提高了岩石的抗剪强度.结合前人在静态条件下的实验研究资料,笔者认为水对岩石变形的作用机制随应变率的变化而改变.在低应变率(例如:10-9-1)时,水对岩石变形的影响分别表现为压溶作用、应力侵蚀作用和降低有效应力的效应.压溶作用和应力侵蚀作用导致岩石强度的降低;而有效应力的降低则导致岩石强度的相对提高. 相似文献