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1.
《中国海洋湖沼学报》1986,(1)
This article deals with a new type of isotherm discovered in sea water systems. The characteristics of this type of isotherm are the non-linear exponential relationship in the low concentration region and the isotherm composed of two or three "S" curves with one or two plateaus in the middle. This isotherm cannot be expressed by the isotherm equation used in marine chemistry at present. Besides, there has been no report in literature about this type of isotherm in so far as the reaction of minor elements on hydrous oxides is concerned. In order to explain theoretically this type of isotherm, this article suggests the use of the theory of interfacial stepwise ion/coordination particle exchange (for simplicity, ion exchange is used herein-after) of suspended particles to deduce a corresponding isotherm equation. Proceeding from the isotherm of this article, we made theoretical analyses of these two characteristics as well as experiments in verification thereof. Twenty-four systems of experiments on this n 相似文献
2.
《中国海洋湖沼学报》1985,(2)
In the present paper, determination of isotherms of the exchange reaction between Cu(II) and clays is presented, verifying again the "cation exchange-surface precipitation" isotherm worked out formerly in our laboratory. A modified BET equation was applied to treating the experimental data and describing the new isotherm. In addition, the mechanism of the effects of organics are further discussed and verified. Based on the isotherm equations and the estimates of the average area occupied by a single molecule on the surface, we put forward a new hypothesis which differs from the current one of "organic film". 相似文献
3.
Regional Summer Temperature Decrease against Global Warming in China, Landform Effect？ 总被引：1，自引：1，他引：0
The data of 160 national meteorological observatory(NMO)stations with long-term monthly temperature data for China were analyzed in this study to show the basin-centered summer temperature decrease against global warming in the past half century. The summer and winter isotherm structures of 1950s and 1990s worked out by interpolation show the isotherm structure variations: the isotherm structure generally moves northward in winter, but in summer it is characterized with separate high-temperature and low-temperature centers and the isotherm structure moves inward the centers with global warming, indicating that the temperature in the highland areas increases but that in the lowland areas decreases in the summer of the duration. The possible mechanism of the basin-centered temperature decrease in summer is discussed in this paper. 相似文献
4.
Summarized results of studies on the physical and interfacial chemistry of the Huanghe estuary are presented as follows: 1. The relationship between the exchange ratio (%) and pH for the Cu (II)-Sedi.ments of the Huanghe Estuary and that of the Cu (II)-illite system were observed to be very similar. 2. A stepwise ion/coordination particle exchange isotherm of trace metal in Huanghe estuary sediment was derived. 3. The ion/coordination particle exchange between trace metal and Huanghe Estuary sediment is analogous to the interfacial chemical characteristic of illite. 相似文献
5.
A study on the curves of the exchange ratio E(%)-pH on the liquid-solid interface of the systems Zn(II) with clay minerals (Kaolinite , illite and montmorillonite), Zn(II) with hydrous ferric oxides (amorphous ferric oxide, goethite and hematite). Zn(II) with hydrous manganese oxide (y-MnOOH, manganite and 5-MnO2) etc . in seawater resulted in the discovery of new plateau type exchange ratio ?%)-pH curves not yet reported in literature. The two factors that decide the growth , decline and the change of the " plateau type " curve are : (1) the inherent characteristics of systems , which can be explained by the exchange constants i(i=1 ,2 , 3 . etc .) of interfacial stepwise ion / coordination particle exchange between liquid and solid ; and (2)The theory of interfacial stepwise ion/coordination(the amount of solid exchange reagent)particle exchange in seawater was applied to explain the experimental results of the above study and a general formula was derived for the plateau type exchange ratio E(%)-pH c 相似文献
6.
The stepwise exchange action and steric hindrance effect of organic phenols on clays in seawater 总被引：4，自引：0，他引：4
The exchange action of six types of organic phenols on clay surfaces in seawater is systematically studied in this work. The following significant conclusions are drawn from the experiments. (1) The interaction of organic phenols with montmorillonite, illite and kaolinite in seawater is monovalent anion exchage.(2) Their isotherms of stepwise exchage on clay surfaces belong to the Langmuir type or stepwise type.(3) The discovery of the"steric hindrance effects of stepwise exchange of organic phenols on clays surfaces", and revelation of an exchange mechanisrn diffeient from that in references are the greatest achieverments in this work. 相似文献
7.
This article focuses on two issues. The first concerns definitions of the Northern Sea Route （NSR） in old and new Russian legislation, and the second relates to Russian rules on icebreaker guiding. Based on a comprehensive comparative analysis of relevant Russian legal provisions enacted in 2013 and previous laws in this area, we offer the following conclusions. （1） Our legal analysis indicates that Russia＇s view of the NSR as a historical national transportation route has not changed. However, the new law redefines the scope and coverage of the NSR, which now comprises the internal waters, territorial sea, adjacent zone, and the exclusive economic zone of the Russian Federation. In fact, the new law resolves previous ambiguity regarding extension of the NSR boundary to the high seas. （2） Based on an analysis of the new rules on icebreaker guiding, the article concludes that NSR is transitioning from a mandatory icebreaker guiding regime into a permit regime. This is particularly evident in its provision of a concrete, practical, and predictable clause on permissible or impermissible conditions relating to independent navigation. According to the new rules, it is possible for foreign ships to undertake independent navigation in the NSR. The Russian NSR policy, therefore, appears to have changed significantly, and has future potential for opening the NSR up to the international community. 相似文献
8.
Administrative urbanization and city-making in post-reform China: a case study of Ordos City,Inner Mongolia 总被引：1，自引：0，他引：1
In post-reform China, local governments, instead of the central state, have become major promoters of urbanization. Differing from the existing literature based on Western theories, this article argues that a localized perspective, ‘administrative urbanization', can provide a contextual explanation for the mechanism of urbanization in the reform era. The case study of Ordos indicates that new town construction, especially in the inland area, has become the main strategy for investment attraction and economic development. The local government has played a dominant role in this construction through a series of administrative measures, including avoidance of central state regulations, land leasing, high standard infrastructure construction, relocation policies and industrial attraction. This article also explores the issue of unsustainability in the new town, and identifies that underdeveloped industrialization, slow population agglomeration and real estate bubbles are primary threats to the sustainability of administrative urbanization. 相似文献
9.
10.
《中国海洋湖沼学报》1985,(1)
By the study of the effects of pH on the exchange ratio ( %) of Cu (II) with clay (illite) in the presence of different concentrations of amino acids and fulvic acid, a new model of the mechanism of the effect of organics has been presented in this paper. 相似文献
11.
A highly sensitive and selective catalytic kinetic spectrophotometric method for the determination of Cu(Ⅱ) is proposed. It is based on the catalytic effect of Cu(Ⅱ) on the oxidation of glutathione(GSH) by potassium hexacyanoferrate(Ⅲ) in acidic medium at 25.0℃. The reaction is monitored spectrophotometrically by measuring the decrease in absorbance of oxidant at 420 nm using the fix-time method. Under the optimum conditions, the proposed method allows the determination of Cu(Ⅱ) in a range of 0-35.0 ng m L-1 with good precision and accuracy and the limit of detection is down to 0.04 ng m L-1. The relative standard deviation(RSD) is 1.02%. The reaction orders with respect to each reagent are found to be 1, 1/2, and 1/2 for potassium hexacyanoferrate(Ⅲ), glutathione and Cu(Ⅱ) respectively. On the basis of these values, the rate equation is obtained and the possible mechanism is established. Moreover, few anions and cations can interfere with the determination of Cu(Ⅱ). The new proposed method can be successfully used to the determination of Cu(Ⅱ) in fresh water samples and seawater samples. It is found that the proposed method has fairly good selectivity, high sensitivity, good repeatability, simplicity and rapidity. 相似文献
12.
The relationship between urbanization and economic development has become a hot topic in the scientific community due to its great practical significance,and economic and social value.However,this relationship continues to change dynamically.In the new stage of urbanization,it is urgent to reveal the causal relationship quantitatively and diagnose the future direction systematically.Based on this,this paper calculates the contribution rate of China’s urbanization to economic development from 1978 to 2019 and uses the panel data cointegration test method to explore the causal relationship between urbanization and economic development in China.The study has three principal results.First,the contribution rate of urbanization to economic growth has maintained the overall growth trend from1978 to 2019,but the growth rate of urbanization’s contribution to economic growth has been relatively low since 2012.It is an important reason that the real estate sector has moved into a new stage of transformation.Second,the cointegration test shows that economic development is a significant factor in advancing urbanization and the urbanization is the product of economic development.Urbanization has a positive feedback effect on economic development,but this effect does not pass the 5%significance level test.The impulse response function shows that the impact of urbanization on economic development is relatively small and stable,indicating that it is limited that the boost of economic development by land-centered urbanization.Third,China’s urbanization and economic development have both shown rapid growth for some time,but their relationship is still the low level of coordination,which has also led to a downward trend in the contribution of new-type,people-oriented urbanization to economic growth in recent years.In the future,China’s urbanization and economy need to maintain relatively medium-low speed growth in the medium-long term,and we should boost the coordinated development of urbanization and economy from low level to high level. 相似文献
13.
In this study, the differences in reservoir parameters, such as pore radius, throat radius, and pore-throat ratio, between the east and west subsags of the Lishui Sag are analyzed by using data obtained from a constant-rate mercury injection experiment. Furthermore, the quality of the reservoirs in the two subsags is systematically evaluated. Results show that the throat radius of the Lishui west subsag is larger than that of the east subsag, and this parameter has a positive correlation with reservoir quality. However, the pore-throat ratio of the east subsag is larger than that of the west subsag, which has an inverse relationship with reservoir quality. The main reasons for this reservoir difference can be attributed to sedimentation and diagenesis. The sedimentary facies types of the Lishui east subsag are the fan delta, shore lake, shallow lake, and shore shallow lake;their sandstone composition maturity is low;the clay mineral content is high;and the rock has undergone strong diagenesis. Therefore, the physical conditions of the reservoir are poor. However, the sandstones in the Lishui west subsag have weak cementation and compaction, mainly with an intergranular pore structure type, which leads to good connectivity between pores. Therefore, the storage performance and seepage capacity of the Lishui west subsag are better than those of the east subsag;the west subsag is the main area of oil and gas accumulation, as confirmed in the process of exploration and development. 相似文献
14.
WANG Xiuhai TIAN Zhuangcai ZHANG Yanan SU Xiuting LIU Hongjun LIU Tao 《中国海洋大学学报(英文版)》2022,21(1):124-130
Saline soil is widely distributed in the marine sediments along the coast of the world and the arid-semi-arid areas of the Middle East and Iraq,and calcium sulfate erosion has become one of the important factors affecting the durability of concrete in this area.In order to clarify the mechanism of sulfate ion damage to concrete,this paper mainly takes saline soil with high sulfate content in coastal area as well as arid-semi-arid area as the research object,and uses indoor geotechnical test,field test and numerical simulation to study the influence of different dry-wet cycle times on the unconfined compressive strength of concrete test blocks,and puts forward the relationship between the erosion arrival depth and time of sulfate ion in concrete,so as to predict the long-term erosion depth by using the erosion depth of sulfate ion in concrete in short time.The results show that the shorter the erosion time when the erosion reaches a certain depth,and the larger the erosion reaches when the erosion time is the same,the faster the erosion reaches the depth with the increase of erosion time.Compared with rectangular section concrete,circular section concrete penetrates faster.The results of this study can provide a reference for the durability design of concrete in saline soil sites containing sulfate. 相似文献
15.
LI Yong SU De-chen ZHOU Rong-jun LI Hai-bing Alexander L.DENSMORE YAN Liang YAN Zhao-kun 《山地科学学报》2013,10(1):29-42
Longmen Mountain located at the boundary between the Sichuan Basin and Tibetan Plateau,representing the steepest gradient of any edges of the plateau.Three endmember models of uplift process and mechanism have been proposed,including crustal thickening,crustal flow,and crustal isostatic rebound.Here we use coeval sedimentary sequences in the foreland basin to restraint uplift process and mechanism in the Longmen Mountain.The more than 10,000 m thick Late TriassicQuaternary strata filled in this foreland basin and can be divided into six megasequences that are distinguished as two distinct types.The first type is the wedge-shaped megasequences which are sedimentary response of strong active thrust loading events,characterized by a high rate of subsidence and sediment accumulation,coarsening-upward succession and a dual-sourced sediment supply.This type includes Late Triassic,Late Jurassic to Early Cretaceous and Late Cretaceous to Paleogene megasequences.The second type is the tabular megasequences,characterized by the low rate of subsidence and sediment accumulation,finingupward succession,and a single-sourced sediment supply,which is sedimentary response of isostatic rebound and erosion unloading.This type includes the Early to Middle Jurassic,Middle Cretaceous and Neogene to Quaternary megasequences.Basing on sedimentary,active tectonic,geomorphic evidence,we infer that the direction has been reversed from SSWdirected sinistral strike-slip to NNE-directed dextral strike-slip during 40-3.6 Ma,and since 3.6 Ma,the Longmen Mountain thrust belt belong to times of isostatic rebound and erosional unloading with NNEdirected dextral strike-slip.This suggests that crustal isostatic rebound is a primary driver for uplift and topography of the present Longmen Mountain.The Wenchuan(Ms8.0) earthquake,which ruptured a large thrust fault with NNE-directed dextral strikeslip along the range front,is an active manifestation of this crustal isostatic rebound process with dextral strike-slipping and shortening.This process may be the cause for the Wenchuan Earthquake and the apparent paradox of high relief,little shortening,the relative dearth of historical seismicity in the region. 相似文献
16.
The headland-bay beach is one of the most common coastal types in the world.Its morphology reflects the changes that occurred during long-term evolution of the sandy coast.Several headland-bay beach models have been proposed to simulate the coastline’s configuration in equilibrium.In this paper,a new elliptical model is proposed,described,and applied.On the east coast of Laizhou Bay in Shandong Province from Longkou Port to Diaolongzui,four typical headland-bay beaches have developed,and four headland-bay beach models are used in this paper to simulate the morphology of these beaches to assess the applicability of each model.The simulation results of the elliptical model verify that it is applicable to the study area.In addition,the elliptical model is easy to use.Through simulation and field investigations,we concluded that most of the coastal segments in this area will remain in an erosion state,and the human activity has a significant impact on the shoreline’s evolution. 相似文献
17.
ZHANG Shuo FANG Xin ZHANG Junbo YIN Fang ZHANG Hu WU Lizhen KITAZAWA Daisuke 《中国海洋大学学报(英文版)》2020,19(1):232-240
Filter-feeding shellfish are common benthos and significantly affect the biogeochemical cycle in the shallow coastal ecosystems.Ark clam Scapharca subcrenata is one of the widely cultured bivalve species in many coastal areas owing to its tremendous economic value.However,there is little information regarding the effects of the bioturbation of S.subcrenata on the fluxes of nutrient exchange in the sediment-water interface(SWI).In this regard,S.subcrenata was sampled during October 2016 to determine the effects of its bioturbation activity on the nutrient exchange flux of the SWI.The results showed that the biological activity of S.subcrenata could increase the diffusion depth and the rate of the nutrients exchange in the sediments.The bioturbation of S.subcrenata could allow the nutrients to permeate into the surface sediments at 6-10cm and increase the release rate of nutrients at the SWI.The releasing fluxes of DIN and PO43−-P in the culture area were found to be around three times higher than that in the non-cultured region.The culture of S.subcrenata has been proved to be an important contributor to nutrient exchange across the SWI in the farming area of Haizhou Bay.Nutrients exchange in the SWI contributes a part of 86%DIN,71%PO43−-P and 18%SiO32−-Si for the aquaculture farm. 相似文献
18.
In this study, the temporal and spatial variations of observed global oceanic precipitation during 1979–2010 are investigated. It is found that the global trend in precipitation during this period varies at a rate of 1.5%/K of surface warming while the rate is 6.6%/K during 2006–2010. The precipitation is highly correlated with Sea Surface Temperature(SST) in both the temporal and the spatial patterns since the strong 1997–98 El Nino event. Considering the distributions of precipitation and SST, seven oceanic regions are classified and presented using the observed Global Precipitation Climatology Project(GPCP) data and Extended Reconstructed Sea Surface Temperatures, version 3(ERSST.v3) data. Further examining the mechanisms of the classified oceanic precipitation regions is conducted using the Tropical Rainfall Measuring Mission(TRMM) satellite, GFDL-ESM-2G model precipitation and SST data and Hadley Center sea ice and SST version 1(Had ISST1) data. More than 85% of global oceanic precipitations are controlled by either one or both of the warmer-get-wetter mechanism and wet-get-wetter mechanism. It is estimated that a 0.5 SST signal-to-noise ratio, representing the trend of SST time series to the standard deviation, is a criterion to distinguish the mechanism of a region. When the SST ratio is larger than 0.5, the precipitation of this region is controlled by the warmer-get-wetter mechanism. SST, rather than the humidity, is the pivotal factor. On the other hand, when the SST ratio is less than 0.5, the precipitation is controlled by the wet-get-wetter mechanism. The SST variability is a significant factor contributing to the precipitation variation. 相似文献
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20.
Results of a series of experiments(on the adsorption of divalent metal ions by dried alginic acid, Na and Ca alginates of different composition and block structure) conducted in this systematic study of the effects of the composition and structure of alginates on the static adsorption equilibrium of divalent metal ions indicate that the properties of alginate adsorption to divalent metal ions are highly different, depending not only on the cations used, but also on the form and structure of the alginates. There is close correlation between the adsorption properties and the structure of the alginates. The selectivity coefficient of Na alginate for Cd-Sr ion exchange tends to increase with the increase of the M/G ratio in alginate, whereas the adsorption capacity of Ca alginate for Cu~(2+) ion decrease with the increase of the G-block or the average length of the G-block ((?)_G) and the total adsorption capacity of alginic acid is found to vary in the same order as the F_(MM)(diad frequency) in alginate in 相似文献