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1.
This paper employs the highly accurate valence internally contracted multireference configuration interaction method to investigate the potential energy curves (PECs) for the ground state (X1Σ+) and two low-lying excited states (A1Π and D1Δ of phosphorus nitride (PN) radical with the correlation-consistent basis set, aug-cc-pV6Z, in the valence range. Relativistic effects are considered in these calculations. The spectroscopic constants of the X1Σ+ and A1Π states are calculated based on the PECs, and the results are in good accord with the available experimental data. The first 30 vibrational states for the A1Π state and the first 40 vibrational states for the A1Π state are determined when J=0. For each vibrational state, molecular constants G(υ), B(υ) and D(υ) are also attained.  相似文献   

2.
Interaction potentials for LiCl(X1Σ+) are constructed by the highly accurate valence internally contracted multireference configuration interaction in combination with a number of large correlation-consistent basis sets, which are used to determine the spectroscopic parameters (D0, De, Re, ωe, eχe, Be and αe. The potentials obtained at the basis sets, i.e., aug-cc-pV5Z-JKFI for Cl and cc-pV5Z for Li, are selected to study the elastic collision properties of Li and Cl atoms at the impact energies from 1.0×10-12 to 1.0×10-4 a.u. The derived total elastic cross sections are very large and almost constant at ultralow temperatures, and their shapes are mainly dominated by the s-partial wave at very low impact energies. Only one shape resonance can be found in the total elastic cross sections over the present collision energy regime, which is rather strong and obviously broadened by the overlap contributions of the abundant resonances coming from various partial waves. Abundant resonances exist for the elastic partial-wave cross sections until l = 22 partial waves. The vibrational manifolds of the LiCl(X1Σ+) molecule, which are predicted at the present level of theory and the basis sets cc-pV5Z for Li and the aug-cc-pV5Z-JKFI for Cl, should achieve much high accuracy due to the employment of the large correlation-consistent basis sets.  相似文献   

3.
All-vertical-piled wharf is a kind of high-piled wharf, but it is extremely different from the traditional ones in some aspects, such as the structural property, bearing characteristics, failure mechanism, and static or dynamic calculation methods. In this paper, the finite element method (FEM) and theoretical analysis method are combined to analyze the structural property, bearing behavior and failure mode of the all-vertical-piled wharf in offshore deep water, and to establish simplified calculation methods determining the horizontal static ultimate bearing capacity and the dynamic response for the all-vertical-piled wharf. Firstly, the bearing capability and failure mechanism for all-vertical-piled wharf are studied by use of FEM, and the failure criterion is put forward for all-vertical-piled wharf based on the ‘plastic hinge’. According to the failure criterion and P-Y curve method, the simplified calculation method of the horizontal static ultimate bearing capacity for all-vertical-piled wharf is proposed, and it is verified that the simplified method is reasonable by comparison with the FEM. Secondly, the displacement dynamic magnification factor for the all-vertical-piled wharf under wave cyclic loads and ship impact loads is calculated by the FEM and the theory formula based on the single degree of freedom (SDOF) system. The results obtained by the two methods are in good agreement with each other, and the simplified calculation method of the displacement dynamic magnification factor for all-vertical-piled wharf under dynamic loads is proposed. Then the simplified calculation method determining the dynamic response for the all-vertical-piled wharf is proposed in combination with P-Y curve method. That is, the dynamic response of the structure can be obtained through the static calculation results of P-Y curve method multiplied by the displacement dynamic magnification factor. The feasibility of the simplified dynamic response method is verified by comparison with the FEM under different conditions.  相似文献   

4.
A multispecies model for shellfish polyculture in the Sanggou Bay in China used for large-scale long-line cultivation of the Chinese scallop Chlamys farreri, the Pacific oyster Crassostrea gigas and the kelp Laminaria japonica is presented. The model includes key physical processes which are the transports of matter at the system boundary, and the main biological process that is the primary production and nutrients release from the bottom. By the model, the seasonal fluctuations of phytoplankton biomass and dissolved inorganic nitrogen(DIN) in 1994 are simulated. Furthermore, if the kelp culture scale is kept constant and the Chinese scallop and the Pacific oyster culture scales are adjusted, virtual shellfish farms are funded and responses of phytoplankton to the large-scale shellfish culture are simulated. According to these simulated results, the room limitation, and the hypothesis that shellfish will not grow well if the phytoplankton biomass is less than 8.2 mg/m3, the expandable multiple of scallop culture k and that of oyster culture y are determined as k=-0.276 5y+4.690 5 and 0.133 3k+0.006 6y ≤ 0.667 5, where, k (or y) is equal to 1, the culture scale of scallop (or oyster) is 8.8×109 individuals (or 66 ha, with a density of 59 ind./m2), and the kelp culture scale is 3 300 ha with a density of 12 ind./m2.  相似文献   

5.
A theory of (1+1)-dimensional gravity is constructed on the basis of the teleparallel equivalent of general relativity. The fundamental field variables are the tetrad fields eiμ and the gravity is attributed to the torsion. A dilatonic spherically symmetric exact solution of the gravitational field equations characterized by two parameters M and Q is derived. The energy associated with this solution is calculated using the two-dimensional gravitational energy--momentum formula.  相似文献   

6.
A 30-d current numerical simulation is running for the Yangshan Port, the Changjiang Estuary, the Hangzhou Bay and their adjacent seas using a finite volume coastal ocean model (FVCOM), with Changjiang River runoff and wind effect being considered. At the open boundary, this model is driven by the water level obtained from prediction including eight main partial tides. After the harmonic analysis, the cotidal chart and the iso-amplitude line as well as the current ellipse distribution map are displayed to illustrate the propagation property of a tidal wave. Horizontal velocity of both the U and V components coincides with the actual measurement, which shows that the model result is credible to describe the hydrodynamic pattern in this sea area. On this basis, real-time current data from high-frequency radar is assimilated with the implementation of quick ensemble Kalman filter, which takes the variation tendency of the state vector to compute the analysis field, instead of integrating the field for N (the number of ensemble) times as it used to in the standard EnKF, aiming at raising the efficiency of computation, reducing the error of prediction and at the same time, improving the forecast effect.  相似文献   

7.
Vibrio vulnificus is an opportunistic pathogen widely distributed in estuarine and coastal seawaters. In this study, a culture-free method was developed to rapid detection of V. vulnificus in all seasons, based on loop-mediated isothermal amplification (LAMP) targeting virulent-correlated gene (vcg). The new assay method allows differentiation between the virulent and non-virulent strain of V. vulnificus accurately. This method also allows effective detection of the pathogeny in winter when the bacterium lives in the viable but non-culturable (VBNC) state. A total of 30 costal seawater samples collected in all seasons were used for the evaluation of this method. The results show that the method is sensitive, accurate and convenient.  相似文献   

8.
This is a paper dealing mainly with the accumulation and biological cycle of calcium and magnesium elements of the artificial 20-years old Kandelia candel community in the Jiulongjiang River Estuary of Fujian Province, China.The result of measurements is that the quantities of the two elements in the standing crop are (kg·ha-1) 772.91 for Ca and 526.57 for Mg.In the biological cycle of the two elements, the annual uptakes are 174.86 for Ca and 89.30 for Mg (kg·ha-1); the amounts of Ca and Mg returned via litter fall are estimated to be (kg·ha-1·a-1) 103.28 for Ca and 40.42 for Mg; the annual retention are (kg·ha-1·a-1) 71.58 for Ca and 48.88 for Mg, respectively.The turnover periods of Ca and Mg are 8 and 13 years, respectively.  相似文献   

9.
This study examines wave interactions with multiple semi-immersed Jarlan-type perforated breakwaters. A numerical model based on linear wave theory and an eigenfunction expansion method has been developed to study the hydrodynamic characteristics of breakwaters. The numerical results show a good agreement with previous analytical results and experimental data for limiting cases of double partially immersed impermeable walls and double and triple Jarlan-type breakwaters. The wave transmission coefficient CT; reflection coefficient CR, and energy dissipation coefficient CE coefficients and the horizontal wave force exerted on the front and rear walls are examined. The results show that CR reaches the maximum value when B/L = 0.46n while it is smallest when B/L=0.46n+0.24 (n=0, 1, 2,...). An economical triple semi-immersed Jarlan-type perforated breakwater can be designed with B/L = 0.25 and CR and CT ranging from 0.25 to 0.32 by choosing a relative draft d/h of 0.35 and a permeability parameter of the perforated front walls being 0.5 for an incident wave number kh nearly equal to 2.0. The triple semi-immersed Jarlan-type perforated breakwaters with significantly reduced CR, will enhance the structure’s wave absorption ability, and lead to smaller wave forces compared with the double one. The proposed model may be used to predict the response of a structure in the preliminary design stage for practical engineering.  相似文献   

10.
This paper presents the results of an experimental investigation on the variation in the tension and the distribution of drag force coefficients along flexible risers under vortex-induced vibration (VIV) in a uniform flow for Reynolds numbers (Re) up to 2.2×105. The results show that the mean tension is proportional to the square of the incoming current speed, and the tension coefficient of a flexible riser undergoing VIV can be up to 12. The mean drag force is uniformly and symmetrically distributed along the axes of the risers undergoing VIV. The corresponding drag coefficient can vary between 1.6 and 2.4 but is not a constant value of 1.2, as it is for a fixed cylinder in the absence of VIV. These experimental results are used to develop a new empirical prediction model to estimate the drag force coefficient for flexible risers undergoing VIV for Reynolds number on the order of 105, which accounts for the effects of the incoming current speed, the VIV dominant modal number and the frequency.  相似文献   

11.
Recently many authors have attepmted to model circulations in East China Sea by numerical means, for example, Xi et al1),2). (henceforth Ref.[1] is referred to as A and[2] as B respectively), Yuan et al. and Chio. We had raised questions in regard to the correctness of the governing equations used in A, as well as their choice of boundary conditions. Comparing numerical solution of A with that of B which employed a correct form of governing equations (but with an incorrect value for the bottom friction coefficient), B asserted that the governing equations used in A were correct. It is, therefore, appropriate to have a discussion on the formulation of proper equations.  相似文献   

12.
This paper studies the viscid and inviscid fluid resonance in gaps of bottom mounted caissons on the basis of the plane wave hypothesis and full wave model. The theoretical analysis and the numerical results demonstrate that the condition for the appearance of fluid resonance in narrow gaps is kh=(2n+1)π (n=0, 1, 2, 3, …), rather than kh=nπ (n=0, 1, 2, 3, …); the transmission peaks in viscid fluid are related to the resonance peaks in the gaps. k and h stand for the wave number and the gap length. The combination of the plane wave hypothesis or the full wave model with the local viscosity model can accurately determine the heights and the locations of the resonance peaks. The upper bound for the appearance of fluid resonance in gaps is 2b/L<1 (2b, grating constant; L, wave length) and the lower bound is h/b≤1. The main reason for the phase shift of the resonance peaks is the inductive factors. The number of resonance peaks in the spectrum curve is dependent on the ratio of the gap length to the grating constant. The heights and the positions of the resonance peaks predicted by the present models agree well with the experimental data.  相似文献   

13.
Vertical distributions of phytoplankton biomass, compositions and size structure were investigated during the spring-intermonsoon (April 22 to 30) of 2010 along transact 10°N of the Bay of Bengal, northern Indian Ocean. Surface phytoplankton biomass (Chl a) was (0.065§0.009) μg/L, being greater than 80% of which was contributed by pico-phytoplankton (<3 μm). The Chl a concen- tration vertically increased to the maximal values at deep chlorophyll maximum (DCM) layer that shoaled eastwards from 75 to 40 m. The Chl a biomass at DCM layer generally varied between 0.2 and 0.4 μg/L, reaching the maximum of 0.56 μg/L with micro-phytoplankton cells (>20 μm) accounting for 58% and nano- (3-20 μm) or pico-cells for 15% and 27%, respectively. In particular, the cells concentration coupling well with phosphate level was observed at middle layer (75-100 m) of 87° to 89°E, dominated by micro-cells diatoms (e.g., Chaetoceros atlanticus v. neapolitana, Chaetoceros femur and Pseudonitzschia sp.) and cyanobacteria (i.e., Trichodesmium hildebrandtii), with the cells concentration reached as high as 4.0×104 and 4.3×104 cells/L. At the rest of the trans- act however, dino°agellates (e.g., Amphisdinium carterae and Prorocentrum sp.) were the dominant species, with the cells concentration varying from 0.3×103 to 6.8×103 cells/L. Our results also in- dicate that the regulation of large cells (micro-, nano-) on phytoplankton biomass merely occurred at DCM layer of the Bay.  相似文献   

14.
Combination of a fixed design wave height with various wave periods may exert quite different wave loads on ocean structure. The response of structure induced by mild sea state may be larger than that by severe sea state because the frequency of the spectral peak for mild sea state is near to the natural frequency of structure. Thus it is necessary to investigate the worst combination between wave height and period, and also the critical combination between sea state and response for any design criteria. This paper presents a new combinative mode of wave height and period for equal return period. The selections of original design wave height and the critical combination of sea state with response for equal probability are also discussed.  相似文献   

15.
Influence of the turbulence intensity and turbulence length scale on the hydrodynamic characteristics and heat transfer of a circular cylinder, streamlined by a viscous fluid flow, is numerically studied. We take the Reynolds number of the oncoming flow equal to 4×104, the turbulence intensity Tuf and the dimensionless turbulence length scale Lf varying from 1.0% to 40% and from 0.25 to 4.0, respectively. We confirmed that the increase of Tuf leads to the suppression of the periodic vortex shedding from the cylinder surface, and as a result the stationary mode of streamlining is formed. Consequently, with the increasing turbulence intensity directly in front of the cylinder Tu*, the amplitude of the lift coefficient decreases monotonically. Nevertheless, the time-averaged drag coefficient of the streamlined cylinder decreases at Tu*<6.0%, and increases at Tu*>9.0%. The dependence of the average Nusselt number on Tu* is near-linear, and with the increasing turbulence intensity, the Nusselt number rises. However, the change of the average Nusselt number depending on Lf is non-monotonic and at Lf=1.0, the value reaches its maximum.  相似文献   

16.
The purpose of this study was to investigate the accumulation behavior of two typical PAHs,phenanthrene(PHE) and fluoranthene(FLA),uptaken by the mangrove Kandelia candel in various treated sandy soils.The experiment lasted for three months.Soil and plant samples were collected after 3,6,9 and 13 weeks of the incubation and the levels of PAHs were analyzed using a GC/MS(HP6890-5975B).The results showed that the root accumulations of PHE and FLA were elevated with the increase of the PAH concentrations in the soil.With prolonged exposure time,PHE and FLA concentrations of the roots increased significantly in comparison with the control.PHE and FLA concentrations of root after 13 weeks of treatment ranged from 0.28 to 4.36 μg·g-1 and 0.79 to 35.76 μg·g-1,respectively.The calculated mean values of the root concentration factors were 0.58 for PHE and 0.71 for FLA.This indicated that root accumulation of FLA was greater than PHE,which would result from the higher octanol-water partition coefficient(Kow) of FLA.These results underline the ability of mangroves to remove PAHs from contaminated marine substrates and hence their potential use in bioremediation and the removal of PAHs from the marine food chain.  相似文献   

17.
Suspended particulate matter (SPM) has been known as an important variable in the organic matter flow of coastal ecosystem. Half of burial carbon in seagrass meadows is contributed by allochthonous sources that compose the SPM such as phytoplankton, seagrass detritus, marine snow aggregates and terrestrially derived particles. Each composition of the SPM contributes different roles and is important to be identified, for instance, the exact contribution of seagrass detritus will be useful for determination of carbon export through the detritus form in seagrass meadows. Here, the SPM of seagrass meadows is studied in Bintan Island and the Selayar Archipelago. The aim of this research is to determine the source origin of the SPM using a stable isotope signature. In order to fulfill this aim, the objectives are defined as: (1) to specify the stable isotope signature (δ13C and δ15N) of the SPM, and (2) to determine the proportional distribution of the SPM''s prospectus sources. The result shows that the possibility of the source origin of the SPM includes a seagrass fraction (Enhalus acoroides and Thalassia hemprichii), terrestrial C4 plant, macroalgae, and terrestrial C3 plant. The SPM lies between the marine- and terrigenous-end members. However, it seems that the SPM is more to be terrigenous-end and allochthonous. According to a Bayesian mixing model, the terrestrial C4 has the highest contribution of the SPM at all sites except Barugaia and Pasi Island in Selayar (i.e., the highest contribution of the SPM is from the detritus of E. acoroides). The second contribution has been contributed by either seagrass detritus (E. acoroides or Th. hemprichii) or terrestrial C3 plant. The finding of this study indicates that there is a strong influence of the terrigenous sources in the SPM of the seagrass meadows.  相似文献   

18.
Pure Ti plate surfaces are micro-ablated by femtosecond lasers in the ambience of hydroxyapatite suspension. It is found that three-stage hierarchical surface structures are produced with various laser energies. When the laser energy is 150 μJ, a lava-like structure with a distribution of nanoholes is dispersed evenly on the laser ablated surface. While in the case of 300 μ J, the grooves-and-islands micro-patterns covered with nanoparticles are generated on the surface. Remarkably, Ca/P based substances are revealed to firmly deposit on the micro-structured surfaces. More phosphate growth is seen for the higher laser energy. Discussions suggest that the additional elements deposition could be attributed to the chemical reaction of plasma related ions in the suspension and their subsequent crystallisation on the fresh surfaces of Ti plate due to the femtosecond laser ablation.  相似文献   

19.
In order to estimate the deposition rate of extraterrestrial material onto a manganese crust in a search for supernova debris, we analyzed the contents of 10Be, 230Th, 231Pa, and 239,240Pu in a sample of manganese crust collected from the North Pacific Ocean. On the basis of the depth profile of 10Be, the growth rate of the manganese crust was determined to be 2.3 mm Myr−1. The uptake rates of 10Be, 230Th, and 231Pa onto the manganese crust were estimated to be 0.22–0.44%, 0.11–0.73%, and 1.4–4.5%, respectively, as compared to the deposition rates onto the deep-sea sediments near the sampling station, while that for 239,240Pu was 0.14% as compared to the total inventory of seawater and sediment column. Assuming that sinking particles represent 0.11–4.5% of the uptake rates, the deposition rate of extraterrestrial material onto the manganese crust was estimated to be 2–800 μg cm−2Myr−1 according to the uptake of 10Be onto the manganese crust. Further, our estimate is similar to the value of 9–90 μg cm− 2Myr−1 obtained using the integrated global production rate of 10Be and the deposition rate of 10Be onto the manganese crust.  相似文献   

20.
We present the theoretical results of the electronic band structure of wurtzite GaN films under biaxial strains in the (11-22)-plane. The calculations are performed by the κ• p perturbation theory approach through using the effective-mass Hamiltonian for an arbitrary direction. The results show that the transition energies decrease with the biaxial strains changing from -0.5% to 0.5%. For films of (11-22)-plane, the strains are expected to be anisotropic in the growth plane. Such anisotropic strains give rise to valence band mixing which results in dramatic change in optical polarisation property. The strain can also result in optical polarisation switching phenomena. Finally, we discuss the applications of these properties to the (11-22) plane GaN-based light-emitting diode and lase diode.  相似文献   

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