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1.
This paper applies the density functional theory method to optimise the structure for X 3Δ state of TiO molecule with the basis sets 6-31G, 6-31++G and 6-311G**. Comparing the attained results with the experiments, it obtains the conclusion that the basis set 6-31++G is most suitable for the optimal structure calculations of X 3Δ state of TiO molecule. The whole potential energy curve for the electronic state is further scanned by using B3P86/6-31++G method for the ground state, then it uses a least square fitted to Murrell--Sorbie functions, at last it calculates the spectroscopic constants and force constants, which are in better agreement with the experimental data.  相似文献   

2.
This paper employs the highly accurate valence internally contracted multireference configuration interaction method to investigate the potential energy curves (PECs) for the ground state (X1Σ+) and two low-lying excited states (A1Π and D1Δ of phosphorus nitride (PN) radical with the correlation-consistent basis set, aug-cc-pV6Z, in the valence range. Relativistic effects are considered in these calculations. The spectroscopic constants of the X1Σ+ and A1Π states are calculated based on the PECs, and the results are in good accord with the available experimental data. The first 30 vibrational states for the A1Π state and the first 40 vibrational states for the A1Π state are determined when J=0. For each vibrational state, molecular constants G(υ), B(υ) and D(υ) are also attained.  相似文献   

3.
A theory of (1+1)-dimensional gravity is constructed on the basis of the teleparallel equivalent of general relativity. The fundamental field variables are the tetrad fields eiμ and the gravity is attributed to the torsion. A dilatonic spherically symmetric exact solution of the gravitational field equations characterized by two parameters M and Q is derived. The energy associated with this solution is calculated using the two-dimensional gravitational energy--momentum formula.  相似文献   

4.
In this paper,on the basis of the heat conduction equation without consideration of the advection and turbulence effects,one-dimensional model for describing surface sea temperature (Ts),bottom sea temperature (Th) and the thickness of the upper homogeneous layer (h) is developed in terms of the dimensionless temperature θT and depth η and self-simulation function θT-f(η) of vertical temperature profile by means of historical temperature data.The results of trial prediction with our one-dimensional model on Ts,Th,h,the thickness and gradient of thermocline are satisfactory to some extent.  相似文献   

5.
Mangrove ecosystems are sites with high biodiversity of benthic fauna, and fiddler crabs (genus Uca) are common benthic fauna in mangroves. The North Sulawesi in Indonesia has a good condition of mangrove while the information of the fiddler crabs is still limited. Manual samplings were conducted in wet, dry and transient seasons at a mangrove in Kema, North Sulawesi to investigate the species composition, density and distribution pattern of fiddler crabs. A total of 168 individuals, subjected to eight species of genus Uca crabs were collected at the mangrove, with U. triangularis having the highest abundance and U. annulipes having the lowest abundance. The densities of fiddle crabs were 27.56 ind./m2, 32.89 ind./m2 and 14.22 ind./m2 at the seaward, middle and landward zones, respectively, and the density was higher in dry and wet seasons than in transient season.  相似文献   

6.
A multispecies model for shellfish polyculture in the Sanggou Bay in China used for large-scale long-line cultivation of the Chinese scallop Chlamys farreri, the Pacific oyster Crassostrea gigas and the kelp Laminaria japonica is presented. The model includes key physical processes which are the transports of matter at the system boundary, and the main biological process that is the primary production and nutrients release from the bottom. By the model, the seasonal fluctuations of phytoplankton biomass and dissolved inorganic nitrogen(DIN) in 1994 are simulated. Furthermore, if the kelp culture scale is kept constant and the Chinese scallop and the Pacific oyster culture scales are adjusted, virtual shellfish farms are funded and responses of phytoplankton to the large-scale shellfish culture are simulated. According to these simulated results, the room limitation, and the hypothesis that shellfish will not grow well if the phytoplankton biomass is less than 8.2 mg/m3, the expandable multiple of scallop culture k and that of oyster culture y are determined as k=-0.276 5y+4.690 5 and 0.133 3k+0.006 6y ≤ 0.667 5, where, k (or y) is equal to 1, the culture scale of scallop (or oyster) is 8.8×109 individuals (or 66 ha, with a density of 59 ind./m2), and the kelp culture scale is 3 300 ha with a density of 12 ind./m2.  相似文献   

7.
We measured the ammonium excretion, phosphate excretion and respiration rates of the scyphomedusa Aurelia aurita from Ondo Strait, in the central part of the Inland Sea of Japan, at 28 and 20°C. The rates measured at 28°C were converted to those at 20°C using the Q10 values, i.e. 1.56, 1.57 and 2.80, for ammonium excretion, phosphate excretion and respiration rates, respectively. The composite relationships between metabolic rates and wet weight of a medusa (WW, g, range 11–1330 g) at 20°C were expressed by the following allometric equations. For ammonium excretion rate (N, μmoles N medusa−1d−1): N = 0.497WW 1.09, phosphate excretion rate (P, μmoles P medusa−1d−1): P = 0.453WW 0.84, and respiration rate (R, μmoles O2 medusa−1d−1): R = 96.9WW 1.06. Mean O:N ratios (i.e. atomic ratios of 16.9 and 11.0 at 28 and 20°C, respectively) indicated that the metabolism of A. aurita medusae was protein-dominated. These metabolic parameters enabled us to estimate the nitrogen and phosphorus regeneration rates of an A. aurita medusa population typical of early summer in the Ondo Strait (means of water temperature, medusa individual weight and population biomass: 20°C, 200 g WW and 50.8 g WW m−3, respectively). Regenerated nitrogen and phosphorus were equivalent to 10.0 and 21.6% of phytoplankton uptake rates, respectively, nearly twice that estimated for mesozooplankton, demonstrating that A. aurita medusae are key components of the plankton community, influencing the trophic and nutrient dynamics in the Ondo Strait during early summer.  相似文献   

8.
The influences of electron screening (ES) and electron energy correction (EEC) are investigated by superstrong magnetic field (SMF). We also discuss in detail the discrepant factor between our results and those of Fushiki, Gudmundsson and Pethick (FGP) in SMF. The results show that SMF has only a slight effect on ES when B < 109 T on the surfaces of most neutron stars. Whereas for some magnetars, SMF influence ES greatly when B > 109 T . For instance, due to SMF the ES potential may be increased about 23.6% and the EEC may be increased about 4 orders of magnitude at ρ/μe = 1.0×106 mol/cm3 and T9 = 1. On the other hand, the discrepant factor shows that our results are in good agreement with FGP's when B < 109 T . But the difference will be increased with increasing SMF.  相似文献   

9.
Influence of the turbulence intensity and turbulence length scale on the hydrodynamic characteristics and heat transfer of a circular cylinder, streamlined by a viscous fluid flow, is numerically studied. We take the Reynolds number of the oncoming flow equal to 4×104, the turbulence intensity Tuf and the dimensionless turbulence length scale Lf varying from 1.0% to 40% and from 0.25 to 4.0, respectively. We confirmed that the increase of Tuf leads to the suppression of the periodic vortex shedding from the cylinder surface, and as a result the stationary mode of streamlining is formed. Consequently, with the increasing turbulence intensity directly in front of the cylinder Tu*, the amplitude of the lift coefficient decreases monotonically. Nevertheless, the time-averaged drag coefficient of the streamlined cylinder decreases at Tu*<6.0%, and increases at Tu*>9.0%. The dependence of the average Nusselt number on Tu* is near-linear, and with the increasing turbulence intensity, the Nusselt number rises. However, the change of the average Nusselt number depending on Lf is non-monotonic and at Lf=1.0, the value reaches its maximum.  相似文献   

10.
The thermal entanglement of a two-qutrit spin-1 anisotropic Heisenberg XXZ chain in an inhomogeneous magnetic field is studied in detail. The effects of the external magnetic field (B), a parameter b which controls the inhomogeneity of B, and the bilinear interaction parameters Jx=Jy≠Jz on the thermal variation of the negativity are studied in detail. It is found that negativity N decreases when the values of magnetic field, inhomogeneity b and temperature are increasing. In addition, N remains at higher temperatures for higher values of Jz and lower values of B and b.  相似文献   

11.
There were two severe coral bleaching events at Ko Khang Khao, the inner Gulf of Thailand, occurred during the prolonged period of the elevated sea surface temperature (SST) in 2010 and low salinity as well as turbidity due to heavy flooding in 2011. The bleaching index (BI) and mortality index (MI) are calculated to compare the susceptibilities of coral species in the two bleaching events. The BI and MI vary significantly among the study sites and bleaching events. The most susceptible corals during both bleaching events are Acropora millepora, Pocillopora damicornis and Pavona decussate, while the most resistant species were Galaxea fascicularis, Fungia fungites, Pavona frondifera, Oulastrea crispate, and Symphyllia recta. The corals Favia favus, Goniopora columna, Platygyra pini, Symphyllia agaricia were relatively more tolerant to high SST but they are relatively more susceptible to low salinity. Coral bleaching is a phenomenon that the dissociation stress of the symbiotic relationship between zooxanthellae and their cnidarian host results in the reduction in photosynthetic pigment concentration. Among stressors, both prolonged exposure of high SST and low salinity, above and below their thresholds, respectively. The long-term resilience of coral communities at Ko Khang Khao and other coral communities close to the mouth of large rivers may depend on the frequency and duration of the exposure on the elevated SST due to atmospheric heating and low salinity due to river flooding.  相似文献   

12.
In the present study, we have investigated the conditions influencing encystment and excystment in the dinoflagellate Gyrodinium instriatum under laboratory conditions. We incubated G. instriatum in modified whole SWM-3 culture medium and in versions of modified SWM-3 from which NO3 −, PO4 3−, NO3 − + PO4 3−, or Si had been omitted and observed encystment. Percentage encystment was high in the media without N and without P, while the percentage encystment in the medium lacking both N and P was highest. Moreover, to investigate N or P concentration which induced the encystment, Gyrodinium instriatum was also incubated in media with different concentrations of inorganic N and P; the concentrations of NO2 − + NO3 − and PO4 3− were measured over time. The precursors of cysts appeared within 2 or 3 days of a decrease in NO2 − + NO3 − or PO4 3− concentration to values lower than 1 μM or 0.2 μM, respectively. When cysts produced in the laboratory were incubated, we observed excystment after 8–37 days, without a mandatory period of darkness or low temperature. We incubated cysts collected from nature at different temperatures or in the dark or light and observed excystments. Natural cysts excysted at temperatures from 10 to 30°C, in both light and dark, but excystment was delayed at low temperatures. These studies indicate that G. instriatum encysts in low N or P concentration and excysts over a wide temperature range, regardless of light conditions, after short dormancy periods.  相似文献   

13.
Using a double resonant KTiOPO4 (KTP) intracavity optical parametric oscillator operating at degenerated point of 2 μm, we demonstrate a unique mid-infrared source based on difference frequency generation in GaSe crystal. The output tuning range is 8.42-19.52 μm, and a peak power of 834 W for type-I phase matching scheme and 730 W for type-II phase matching scheme are achieved. Experimental results show that this oscillator is a good alternative to the generator of a compact and tabletop mid-infrared radiation with a widely tunable range.  相似文献   

14.
The paper presents a new model of electronic-vibrational kinetics of the products of ozone and molecular oxygen photodissociation in the terrestrial middle atmosphere. The model includes 45 excited states of the oxygen molecules O2(b 1, Σ g + ,v= 0−2), O2 (a 1Δ g , v= 0−5), and O2(X 3Σ g − , v= 1−35) and of the metastable atom O (1 D) and over 100 aeronomic reactions. The model takes into account the dependence of quantum yields of the production of O2(a 1Δ g , v= 0−5) in a singlet channel of ozone photolysis in the Hartley band on the wavelength of photolytic emission. Taking account of the electronic-vibrational kinetics is important in retrieval of the vertical profiles of ozone concentration from measured intensities of the Atm and IR Atm emissions of the oxygen bands above 65 km and leads to an increase in the ozone concentration retrieved from the 1.27-μm emission, in contrast to the previous model of pure electronic kinetics. Sensitivity analysis of the new model is made for variations in the concentrations of atmospheric constituents ([O2], [N2], [O(3P)], [O3], [CO2]), the gas temperature, rate constants of the reactions, and quantum yields of the reaction products. A group of reactions that most strongly affect the uncertainty of ozone retrieval from measured intensities of atmospheric emissions of molecular oxygen O2(b 1Σ g + , v) and O2(a 1Δ g , v) has been determined. Original Russian Text ? V.A. Yankovsky, V.A. Kuleshov, R.O. Manuilova, A.O. Semenov, 2007, published in Izvestiya AN. Fizika Atmosfery i Okeana, 2007, Vol. 43, No. 4, pp. 557–569.  相似文献   

15.
Short-term tidal and diel variations of autumn fish assemblage in a Zostera marina bed were investigated using 3 h interval samplings for 24 h in both spring and neap tide using a small beam trawl. A total of 1 346 fishes belonging to 19 species were collected at spring tide, whereas 1 115 fishes belonging to 17 species were at neap tide. The common fish species were Nuchequula nuchalis, Acanthogobius flavimanus, Takifugu niphobles, Acentrogobius pflaumii, and Pholis nebulosa with the former three species dominating at spring tide, while the latter two species being abundant at neap tide. Diel variation in abundance was significant with higher abundance at night than day, but there were no significant differences between spring and neap tides, and between ebb and flood tides (three-way ANOVAs). Diel variation in the abundance of fishes may be influenced by tidal range and cycle, and day-night differences of food availability and behaviors of fishes indirectly. Non-metric multidimensional scaling (nMDS) ordination and analysis of similarity (ANOSIM) results revealed significant differences in species compositions both between day and night, and between spring and neap tide. Eelgrass beds are highly productive marine ecosystem, and thus, our results will contribute to conservation of seagrass ecosystem in the study area.  相似文献   

16.
This study concerned the accumulation of trace metals in tissues of seagrass (Thalassia hemprichii) exposed to various concentrations of Zn2++, Cd2++, Pb2++ and Cu2++ for 10 d, and the effect of excessive metals on quantum yield (ΔF=Fm'), photosynthetic pigments and antioxidative enzymes like superoxide dismutase (SOD), guaiacol peroxidase (POD) were also examined. Cadmium was the most highly accumulated metal. Meanwhile, high metals levels led to a remarkable breakdown of photosynthetic parameters. Especially, ΔF=Fm', chlorophyll and carotenoid were significantly low during prolonged Cu exposure. Besides, ΔF=Fm' was more severely depressed by Cu and Zn than Pb and Cd. However, T. hemprichii had positive response by increasing the activity of SOD and POD. The results indicate that T. hemprichii is the most sensitive to Cu, and the antioxidative protection mechanisms of T. hemprichii are more efficiently activated to avoid damage of Zn, Cd and Pb stress. Finally, due to the high Cd-accumulation and strong Cd-tolerance capacity, T. hemprichii can be used for phytoremediation in Cd-contaminated areas.  相似文献   

17.
The purpose of this study was to investigate the accumulation behavior of two typical PAHs,phenanthrene(PHE) and fluoranthene(FLA),uptaken by the mangrove Kandelia candel in various treated sandy soils.The experiment lasted for three months.Soil and plant samples were collected after 3,6,9 and 13 weeks of the incubation and the levels of PAHs were analyzed using a GC/MS(HP6890-5975B).The results showed that the root accumulations of PHE and FLA were elevated with the increase of the PAH concentrations in the soil.With prolonged exposure time,PHE and FLA concentrations of the roots increased significantly in comparison with the control.PHE and FLA concentrations of root after 13 weeks of treatment ranged from 0.28 to 4.36 μg·g-1 and 0.79 to 35.76 μg·g-1,respectively.The calculated mean values of the root concentration factors were 0.58 for PHE and 0.71 for FLA.This indicated that root accumulation of FLA was greater than PHE,which would result from the higher octanol-water partition coefficient(Kow) of FLA.These results underline the ability of mangroves to remove PAHs from contaminated marine substrates and hence their potential use in bioremediation and the removal of PAHs from the marine food chain.  相似文献   

18.
Seasonal and interannual variations in physicochemical properties were investigated in the neritic area of Sagami Bay, Kanagawa, Japan, from December 2000 to December 2005. Physicochemical properties (i.e. temperature, salinity, density, dissolved oxygen and dissolved inorganic nutrient concentration) revealed clear seasonal variations, which were similar to each other during all 5 years. Temperature, salinity and dissolved inorganic nutrients showed rapid, drastic variations within a few days and/or weeks. These variations are related to sea levels, principally due to the shifting effects of the Kuroshio Current axis: they were strongly affected by the Kuroshio Water and other waters, when sea level difference was greater than ca. 35 cm and lower than ca. 15 cm, respectively. Temperature difference (DF T ) increased with sea level difference, and the difference of salinity and dissolved inorganic nutrients (NH4 +-N, NO3 −+NO2 −-N, NH4 ++NO3 −+NO2 −-N, PO4 3−-P and SiO2-Si) increased and decreased with DF T , respectively. All these correlations are significant. Total dissolved inorganic nitrogen (N), phosphate (P) and silicate (Si) revealed seasonal variations in the ranges of 0.57–16.08, 0.0070–0.91 and 0.22–46.38 μM, respectively. From the regression equations between these elements allowed the following relation to be obtained; Si:N:P = 14.8:13.4:1. Dissolved inorganic nutrients were characterized by Si and/or P deficiency, especially in the upper layer (0–20 m depth) during summer. Single and/or combined elements are discussed on the basis of potential and stoichiometric nutrient limitations, which could restrict phytoplankton (diatom) growth as a limiting factor.  相似文献   

19.
To date no analytical solution of the pile ultimate lateral capacity for the general c-φ soil has been obtained. In the present study, a new dimensionless embedded ratio was proposed and the analytical solutions of ultimate lateral capacity and rotation center of rigid pile in c-φ soils were obtained. The results showed that both the dimensionless ultimate lateral capacity and dimensionless rotation center were the univariate functions of the embedded ratio. Also, the ultimate lateral capacity in the c-φ soil was the combination of the ultimate lateral capacity (fc) in the clay, and the ultimate lateral capacity (fφ) in the sand. Therefore, the Broms chart for clay, solution for clay (φ=0) put forward by Poulos and Davis, solution for sand (c=0) obtained by Petrasovits and Awad, and Kondner''s ultimate bending moment were all proven to be the special cases of the general solution in the present study. A comparison of the field and laboratory tests in 93 cases showed that the average ratios of the theoretical values to the experimental value ranged from 0.85 to 1.15. Also, the theoretical values displayed a good agreement with the test values.  相似文献   

20.
The performance of the “version 2” Global Imager (GLI) standard atmospheric correction algorithm, which includes empirical absorptive aerosol correction and sun glint correction, was evaluated using data collected with handheld above-water SIMBADA radiometers during 23 cruises of opportunity (research vessels, merchant ships), mostly in the North Atlantic and European seas. A number of 100 match-up data sets of GLI-derived and SIMBADA-measured normalized water-leaving radiance (nL W ) and aerosol optical thickness (AOT) were sorted out, using objective selection criteria, and analyzed. The Root-Mean-Square (RMS) difference between GLI and SIMBADA nL W was about 0.32 μW/cm2/nm/sr for the 412 nm band, showing improvement by 30% in RMS difference with respect to the conventional “version 1” GLI atmospheric correction algorithm, and the mean difference (or bias) was reduced significantly. For AOT, the RMS difference was 0.1 between GLI estimates and SIMBADA measurements and the bias was small (a few 0.01), but the ?ngstr?m exponent was systematically underestimated, by 0.4 on average, suggesting a potential GLI calibration offset in the near infrared. The nL W differences were not correlated to AOT, although performance was best in very clear conditions (AOT less than 0.05 in the 865 nm band). Despite the relatively large scatter between estimated and measured nL W , the derived chlorophyll-a concentration estimates, applying the same ratio algorithm (GLI OC4V4) to GLI and SIMBADA, were consistent and highly correlated in the range of 0.05–2 μg/l. The large variability in chlorophyll-a concentration estimate for clear clean water areas (e.g. with the concentration range lower than about 0.05 μg/l) turns out to be due to the nature of the “band ratio” based in-water algorithm.  相似文献   

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