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大兴安岭北部诺敏河地幔金云母及钾质地幔熔体研究 总被引：2，自引：1，他引：1
在大兴安岭北部诺敏河第四纪钾质火山岩携带的地幔捕虏体中,发现少量金云母矿物和富钾地幔熔体。金云母颗粒大小1~5mm,呈网脉状充填在橄榄石和辉石、石榴子石等地幔矿物间隙。电子探针研究表明地幔橄榄石、单斜辉石、斜方辉石和石榴石等矿物几乎不含钾质成分(K2O0.01%),而金云母矿物成分具有高钾(K2O~10%)、高钛(Ti O25.41%~7.74%)的特点,暗示区域地幔钾的富集与金云母矿物有密切关系。地幔金云母的成因往往与富钾地幔流体/熔体的交代作用有关,在地幔捕虏体矿物反应边的硅酸盐熔体(囊体)中,发现富硅、富钾的熔体,K2O 4%~8%。结合前人地幔熔体研究,认为区域地幔经历了多期、不同成分地幔熔体的富集作用,其中富钾熔体对地幔钾质成分的富集起到重要作用。诺敏钾质火山正是富钾地幔部分熔融的产物,钾质熔体成分的来源可能与俯冲再循环的壳源物质有关。 相似文献
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数年前,我们在湖北某地的石英-正长岩中采到一种黑色矿物,经初步研究,可按成分命名为铁硅钛铈矿(Ferchevkinite)。现将结果报道如下。 一、铁硅钛铈矿产出的地质特征 含铁硅钛铈矿的石英-正长岩产于太古界厚层大理岩中,该大理岩为白色,具中粒变晶结构,块状构造,矿物成分以方解石为主,其次有少量辉石、透闪石、白云母、黑云母、金云母、蛇纹石、石榴石、磷灰石、黄铜矿、黄铁矿以及粒径达1—5毫米的石墨颗粒等。在构 相似文献
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周口店岩体由三次侵入的中酸性岩石组成, 本次测得石英闪长岩锆石U-Pb年龄为131.6±2.1 Ma, 闪长玢岩锆石U-Pb年龄为128.1±1.4 Ma.周口店岩体各种类型岩石属高钾钙碱性系列、偏铝质, Mg#较高, 重稀土元素和Ta、Nb、P以及Ti明显亏损, 轻稀土元素和Ba、K以及Sr相对富集, Eu没有异常, Yb元素含量小于2×10-6, (La/Yb)N和Sr/Y比值较高.斜长石复杂环带能谱线扫描表明, 花岗闪长岩中的斜长石核部牌号高, 完整的幔部由内向外由反环带和正环带组成, 微粒包体中的斜长石核部牌号低, 幔部以尘状环带开始, 然后演变为正环带, 这揭示存在多期基性岩浆的注入作用, 结合暗色微粒包体的形态、大小、数量、反向脉、矿物含量统计、矿物成分、地球化学和各类环带包体、岩墙状包体群等特征, 说明暗色微粒包体是在花岗闪长岩浆冷凝过程的不同阶段, 多期幔源基性岩浆注入并与酸性岩浆在围绕包体周缘的局部范围内发生不均一机械混合作用的结果.周口店中酸性岩石体现埃达克质岩的地球化学特征, 岩浆成分主要受源区控制, 形成于加厚下地壳环境.由石英闪长岩-花岗闪长岩至中酸性岩脉, 岩石(Er/Lu)N和Nb/Ta比值升高, 说明源区残留相矿物组合由角闪石+石榴石向石榴石+金红石变化, 岩浆源区不断变深. 相似文献
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贵州麻江金云火山岩（钾镁煌斑岩）的地质特征 总被引：1，自引：0，他引：1
1992年我队在麻江地区发现一批金云火山岩(钾镁煌斑岩)岩体,其中岩管5个。产出的大地构造部位在江南台隆与黔南坳陷的交接部位偏向坳陷一侧,围岩为下、中寒武统。岩石具斑状结构、交代结构、环边结构及块状构造。组成矿物有云母、橄榄石、辉石、铬铁矿、钛铁矿、锐钛矿、碳硅石、磷灰石、钙钛矿、刚玉、金红石、紫苏辉石、石榴石、锆石、独居石、电气石等。岩石化学分析显示偏碱性超基性特征,稀土元素含量特高。新发现岩石命名为橄榄金云火山岩及(过渡型)金云火山岩。其含金刚石性待定。 相似文献
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浙江次坞地区晋宁晚期双峰式岩浆杂岩带的地球化学特征：Rodinia超大陆裂解的岩石学记录 总被引：2，自引：0，他引：2
次坞地区晋宁晚期火山岩与侵入岩由基性岩（上墅组下段基性火山岩与次坞辉绿岩体）和酸性岩（上墅组上段酸性火山岩与道林山碱长花岗岩体）组成,它们在时空上紧密伴生,成因上密切相关,SiO2 含量集中分布在两个区间,缺乏SiO2为57％~68％的中性及中酸性成分,构成一套双峰式岩浆杂岩组合。酸性岩在化学组成上富硅碱而贫钙镁,准铝-过铝质,富含Zr、Nb和稀土元素,FeO*/MgO、Rb/Sr比值大,显示出A型花岗质岩石的成分特征;基性岩具有富铝、钠、钛和偏碱性的特征,形成于陆内至陆缘张裂环境。基性岩与酸性岩由不同的源区熔融形成,基性岩起源于亏损程度较低的地幔或来源于亏损地幔的岩浆受到陆壳物质的混染,酸性岩可能起源于地壳中既含有基性地壳组分和又含有酸性地壳组分的源区的部分熔融。双峰式岩浆杂岩的形成,是华南Rodinia超大陆裂解事件的岩石学记录,揭示了华南Rodinia超大陆裂解始于青白口纪。 相似文献
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X射线粉晶衍射仪在山东蒙阴金伯利岩蚀变矿物鉴定中的应用 总被引：5，自引：4，他引：1
山东蒙阴金伯利岩组成矿物以蚀变矿物为主,X射线粉晶衍射仪鉴定结果显示无矿金伯利岩矿物组分为方解石、白云石、石英、钙锆钛矿,标志性矿物为白云石和钙锆钛矿;贫矿金伯利岩矿物组分为蛇纹石、方解石、钙铝榴石、磁铁矿和金云母,标志性矿物为钙铝榴石;富矿金伯利岩矿物组分为蛇纹石、方解石、绿泥石、磷灰石、磁铁矿和金云母,标志性矿物为绿泥石和磷灰石。采用X射线粉晶衍射仪鉴定金伯利岩蚀变矿物组合,寻找蚀变矿物组分变化与金伯利岩含矿性的关系,利用标志性的蚀变矿物判断金伯利岩无矿、贫矿还是富矿,是非常有意义的。 相似文献
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对华北克拉通新太古代和古元古代的构造模式有多种不同认识,有必要进行深入的变质作用研究。本文选取了辽北清原地区中性麻粒岩、石榴方辉石岩和变质基性岩墙,开展系统的岩相学观察、矿物化学分析、相平衡模拟和锆石-独居定年研究,以阐明其变质演化过程和大地构造意义。中性麻粒岩和石榴方辉石岩均发育两期麻粒岩相组合。中性麻粒岩第一期斜长石发育复杂成份环带,从核到幔部其钙长石含量(XAn)降低,然后再向边部升高;石榴方辉石岩中第一期石榴石与斜方辉石互相包裹。第一期麻粒岩相变质作用P-T轨迹为逆时针型,包含峰期前升压至峰期和峰后降温降压至固相线两个变质阶段。依据两个样品中观测的峰期矿物组合在P-T视剖面图中的稳定范围,并结合斜长石幔部成份,确定峰期温压条件为1.0～1.2GPa/890～1000℃。石榴方辉石岩在峰前升压过程,斜方辉石转变为石榴石,形成石榴石包裹斜方辉石的结构;在峰后降温降压过程中,石榴石又转变为斜方辉石,导斜方辉石包裹石榴石。中性麻粒岩和石榴方辉石岩的第二期组合以形成石榴石+石英和黑云母+石英±单斜辉石±钾长石后成合晶和冠状体为特征。变质基性岩墙只发育第二期矿物组合,... 相似文献
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Potassic syenites from Svidnya, Bulgaria crop out as small isolated bodies as the primary for this intrusion liquid has basic to intermediate composition. The evolution in a closed magma chamber created plutonic rocks ranging from basic (melasyenite) to acid (granite) and from metaluminous to peralkaline. The most mafic varieties show cumulative textures typical for orthocumulates with cumulus phases clinopyroxene, biotite, apatite and potassium feldspar as gravitational settling is a viable process for separation of particles in the bottom parts of magma chamber. In the middle stratigraphic level of biggest body modal igneous layering with development of dark (clinopyroxene?+?amphibole) and light (potassium feldspar) laminas was observed. Oscillatory crystallization around eutectic point resulted in cyclic separation of mafic and felsic phases in repetitive layers. Fractionation of Ca- and Al-rich phases—clinopyroxene, biotie and potassium feldspar created peralkaline residual liquid strongly enriched in HFS elements. 相似文献
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The Nakora Ring Complex(NRC)(732 Ma) occurs as a part of Malani Igneous Suite(MIS) in the West-ern Rajasthan,India.This complex consists of three phases(volcanic,plutonic and dyke).Geochemically,the Na-kora granites are peralkaline,metaluminous and slightly peraluminous.They display geochemical characteristics of A-type granites and distinct variation trends with increasing silica content.The peralkaline granites show higher concentrations of SiO2,total alkalies,TiO2,MgO,Ni,Rb,Sr,Y,Zr,Th,U,La,Ce,Nd,Eu and Yb and lower concen-trations of Al2O3,total iron,Cu and Zn than metaluminous granites.AI content is ≥1 for peralkaline granites and <1 for peraluminous and metaluminous granites.Nakora peralkaline granites are plotted between 4 to 7 kb in pressure and are emplaced at greater depths(16-28 km and 480-840℃) as compared to metaluminous granites which indicate the high fluorine content in peralkaline granites.The primitive mantle normalized multi-element profiles suggest that Nakora granites(peralkaline,metaluminous and peraluminous) are characterized by low La,Sr and Eu and relatively less minima of Ba,Nb and Ti which suggests the aspects related to crustal origin for Nakora magma.The Nakora granites are characterized as A-type granites(Whalen et al.,1987) and correspond to the field of "Within Plate Gran-ite"(Pearce et al.,1984).Geochemical,field and petrological data suggest that Nakora granites are the product of partial melting of rocks similar to Banded Gneiss from Kolar Schist Belt of India. 相似文献
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Nature and origin of A-type granites with particular reference to southeastern Australia 总被引：163，自引：1，他引：163
W. J. Collins S. D. Beams A. J. R. White B. W. Chappell 《Contributions to Mineralogy and Petrology》1982,80(2):189-200
In the Lachlan Fold Belt of southeastern Australia, Upper Devonian A-type granite suites were emplaced after the Lower Devonian
I-type granites of the Bega Batholith. Individual plutons of two A-type suites are homogeneous and the granites are characterized
by late interstitial annite. Chemically they are distinguished from I-type granites with similar SiO2 contents of the Bega Batholith, by higher abundances of large highly charged cations such as Nb, Ga, Y, and the REE and lower
Al, Mg and Ca: high Ga/Al is diagnostic. These A-type suites are metaluminous, but peralkaline and peraluminous A-type granites
also occur in Australia and elsewhere.
Partial melting of felsic granulite is the preferred genetic model. This source rock is the residue remaining in the lower
crust after production of a previous granite. High temperature, vapour-absent melting of the granulitic source generates a
low viscosity, relatively anhydrous melt containing F and possibly Cl. The framework structure of this melt is considerably
distorted by the presence of these dissolved halides allowing the large highly charged cations to form stable high co-ordination
structures. The high concentration of Zr and probably other elements such as the REE in peralkaline or near peralkaline A-type
melts is a result of the counter ion effect where excess alkali cations stabilize structures in the melt such as alkali-zircono-silicates.
The melt structure determines the trace element composition of the granite.
Separation of a fluid phase from an A-type magma results in destabilization of co-ordination complexes and in the formation
of rare-metal deposits commonly associated with fluorite. At this stage the role of Cl in metal transport is considered more
important than F. 相似文献
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Zircon (ZrSiO4) and hafnon (HfSiO4) solubilities in water-saturated granitic melts have been determined as a function of melt composition at 800° and 1035°C at 200 MPa. The solubilities of zircon and hafnon in metaluminous or peraluminous melts are orders of magnitude lower than in strongly peralkaline melt. Moreover, the molar ratio of zircon and hafnon solubility is a function of melt composition. Although the solubilities are nearly identical in peralkaline melts, zircon on a molar basis is up to five times more soluble than hafnon in peraluminous melts. Accordingly, calculated partition coefficients of Zr and Hf between zircon and melt are nearly equal for the peralkaline melts, whereas for metaluminous and peraluminous melts DHf/DZr for zircon is 0.5 to 0.2. Consequently, zircon fractionation will strongly decrease Zr/Hf in some granites, whereas it has little effect on the Zr/Hf ratio in alkaline melts or similar depolymerized melt compositions.The ratio of the molar solubilities of zircon and hafnon for a given melt composition, temperature, and pressure is proportional to the Hf/Zr activity coefficient ratio in the melt. The data imply that this ratio is nearly constant and probably close to unity for a wide range of peralkaline and similar depolymerized melts. However, it changes by a factor of two to five over a relatively small interval of melt compositions when a nearly fully polymerized melt structure is approached. For most ferromagnesian minerals in equilibrium with a depolymerized melt, DHf > DZr. Typical values of DHf/DZr range from 1.5 to 2.5 for clinopyroxene, amphibole, and titanite. Because of the change in the Hf/Zr activity ratio in the melt, the relative fractionation of Zr and Hf by these minerals will disappear or even be reversed when the melt composition approaches that of a metaluminous or peraluminous granite. It is thus not surprising that fractional crystallization of such granitic magmas leads to a decrease in Zr/Hf, whereas fractional crystallization of depolymerized melts tends to increase Zr/Hf. There is no need to invoke fluid metasomatism to explain these effects. Results demonstrate that for ions with identical charge and nearly identical radius, crystal chemistry does not alone determine relative compatibilities. Rather, the effect of changing activity coefficients in the melt may be comparable to or even larger than elastic strain effects in the crystal lattice. 相似文献
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The phase relationships of three peralkaline rhyolites fromthe Kenya Rift have been established at 150 and 50 MPa, at oxygenfugacities of NNO - 1·6 and NNO + 3·6 (log fO2relative to the Ni–NiO solid buffer), between 800 and660°C and for melt H2O contents ranging between saturationand nominally anhydrous. The stability fields of fayalite, sodicamphiboles, chevkinite and fluorite in natural hydrous silicicmagmas are established. Additional phases include quartz, alkalifeldspar, ferrohedenbergite, biotite, aegirine, titanite, montdoriteand oxides. Ferrohedenbergite crystallization is restrictedto the least peralkaline rock, together with fayalite; it isreplaced at low melt water contents by ferrorichterite. Riebeckite–arfvedsoniteappears only in the more peralkaline rocks, at temperaturesbelow 750°C (dry) and below 670°C at H2O saturation.Under oxidizing conditions, it breaks down to aegirine. In themore peralkaline rocks, biotite is restricted to temperaturesbelow 700°C and conditions close to H2O saturation. At 50MPa, the tectosilicate liquidus temperatures are raised by 50–60°C,and that of amphibole by 30°C. Riebeckite–arfvedsonitestability extends down nearly to atmospheric pressure, as aresult of its F-rich character. The solidi of all three rocksare depressed by 40–100°C compared with the solidusof the metaluminous granite system, as a result of the abundanceof F and Cl. Low fO2 lowers solidus temperatures by at least30°C. Comparison with studies of metaluminous and peraluminousfelsic magmas shows that plagioclase crystallization is suppressedas soon as the melt becomes peralkaline, whatever its CaO orvolatile contents. In contrast, at 100 MPa and H2O saturation,the liquidus temperatures of quartz and alkali feldspar arenot significantly affected by changes in rock peralkalinity,showing that the incorporation of water in peralkaline meltsdiminishes the depression of liquidus temperatures in dry peralkalinesilicic melts compared with dry metaluminous or peraluminousvarieties. At 150 MPa, pre-eruptive melt H2O contents rangefrom 4 wt % in the least peralkaline rock to nearly 6 wt % inthe two more peralkaline compositions, in broad agreement withprevious melt inclusion data. The experimental results implymagmatic fO2 at or below the fayalite–quartz–magnetitesolid buffer, temperatures between 740 and 660°C, and meltevolution under near H2O saturation conditions. KEY WORDS: peralkaline; rhyolite; phase equilibria 相似文献
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The occurrence and distribution of Mo and molybdenite in unaltered peralkaline rhyolites from Pantelleria,Italy 总被引：4，自引：0，他引：4
Jacob B. Lowenstern Gail A. Mahood Richard L. Hervig Joel Sparks 《Contributions to Mineralogy and Petrology》1993,114(1):119-129
Small hexagonal and triangular platelets of molybdenite (MoS2), 5 to 25 m in diameter, were identified in phenocrysts and matrix glass of unaltered felsic volcanic rocks from Pantelleria, Italy. The MoS2 occurs commonly in pantellerites (peralkaline rhyolites), rarely in pantelleritic trachytes, and never in trachytes. The occurrence of euhedral MoS2 platelets in all phenocryst phases, in matrix glass, and even in some melt inclusions indicates that MoS2 precipitated directly from the peralkaline melt. Despite MoS2 saturation, the melt (glass) contains greater than 95% of the Mo in Pantellerian rocks: X-ray fluorescence analyses of 20 whole rocks and separated glasses show that whole rocks consistently contain less Mo than corresponding matrix glasses, the differences being in proportion to phenocryst abundances. The Mo contents increase with differentiation from trachytes (2–12 ppm) to pantellerites (15–25 ppm) and correlate positively with incompatible elements such as Th, Y, and Nb. The Mo concentrations, as determined by secondary ion mass spectrometry, are essentially the same in matrix glasses and melt inclusions, showing that Mo did not partition strongly into a volatile fluid phase during outgassing. The high Mo contents of the pantellerites (relative to metaluminous magmas with 1–5 ppm) may be due to several factors: (1) the enhanced stability of highly charged cations (such as Mo6+, U4+, and Zr4+) in peralkaline melts; (2) the rarity of Fe-Ti oxides and litanite into which Mo might normally partition; (3) reduced volatility of Mo in low fO2, H2O-poor (1–2 wt%) peralkaline magmas. Geochemical modeling indicates that the precipitation of MoS2 can be explained simply by the drop in temperature during magmatic differentiation. The occurrence of MoS2 in pantellerites may result from their high Mo concentrations and low redox state (Ni/NiO=-2.5) relative to metaluminous magmas, causing them to reach MoS2 saturation at magmatic temperatures. The apparent absence of MoS2 microphenocrysts in more oxidized, metaluminous rhyolites may indicate that Mo is dissolved primarily as a hexavalent ion in those magmas. 相似文献
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Amphiboles are the main mafic minerals in most metaluminous to peralkaline alkali-feldspar granites and syenites, and they usually preserve an important record of the compositional evolution of the melts from which they crystallize. In the alkaline association of the Serra da Graciosa A-type Granites and Syenites (southern Brazil), amphibole compositions span a large range, including calcic, sodic–calcic, and sodic amphiboles. Calcic amphiboles are typically observed in the metaluminous rocks, while sodic amphiboles are characteristic of the more strongly peralkaline rocks; sodic–calcic amphiboles are found in intermediate varieties. Compositional variations record the differentiation trends within two petrographic series of the alkaline association. The overall evolution of amphibole compositions is similar in both: they reveal a progressive increase in Na and Fe3+ with differentiation (increase in alkalinity of the magmas), a characteristic shared by undersaturated peralkaline (or agpaitic) differentiation trends. In detail, however, the evolutions of the amphibole compositions in the two series are distinct. In Alkaline series 1, the cores of the crystals form a continuum from calcic to sodic compositions, with the exception of a small compositional gap within the sodic–calcic amphiboles. The rims, however, show compositions that diverge from this main trend; this divergence results from increasing amounts of the oxy-amphibole component, and reflects more oxidizing conditions at the final stages of magmatic crystallization. In Alkaline series 2, these oxidation trends are much more subtle and a reverse trend is observed in the sodic amphiboles. Sodic–calcic amphiboles are in several cases replaced by intergrowths of post-magmatic sodic amphibole and Al-poor (“tetrasilicic”) biotite. 相似文献
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Volcanic rocks of the Latir volcanic field evolved in an open system by crystal fractionation, magma mixing, and crustal assimilation. Early high-SiO2 rhyolites (28.5 Ma) fractionated from intermediate compositionmagmas that did not reach the surface. Most precaldera lavas have intermediate-compositions, from olivine basaltic-andesite (53% SiO2) to quartz latite (67% SiO2). The precaldera intermediate-composition lavas have anomalously high Ni and MgO contents and reversely zoned hornblende and augite phenocrysts, indicating mixing between primitive basalts and fractionated magmas. Isotopic data indicate that all of the intermediate-composition rocks studied contain large crustal components, although xenocrysts are found only in one unit. Inception of alkaline magmatism (alkalic dacite to high-SiO2 peralkaline rhyolite) correlates with, initiation of regional extension approximately 26 Ma ago. The Questa caldera formed 26.5 Ma ago upon eruption of the >500 km3 high-SiO2 peralkaline Amalia Tuff. Phenocryst compositions preserved in the cogenetic peralkaline granite suggest that the Amalia Tuff magma initially formed from a trace element-enriched, high-alkali metaluminous magma; isotopic data suggest that the parental magmas contain a large crustal component. Degassing of water- and halogen-rich alkali basalts may have provided sufficient volatile transport of alkalis and other elements into the overlying silicic magma chamber to drive the Amalia Tuff magma to peralkaline compositions. Trace element variations within the Amalia Tuff itself may be explained solely by 75% crystal fractionation of the observed phenocrysts. Crystal settling, however, is inconsistent with mineralogical variations in the tuff, and crystallization is thought to have occurred at a level below that tapped by the eruption. Spatially associated Miocene (15-11 Ma) lavas did not assimilate large amounts of crust or mix with primitive basaltic magmas. Both mixing and crustal assimilation processes appear to require development of relatively large magma chambers in the crust that are sustained by large basalt fluxes from the mantle. The lack of extensive crustal contamination and mixing in the Miocene lavas may be related to a decreased basalt flux or initiation of blockfaulting that prevented pooling of basaltic magma in the crust. 相似文献
19.
Clark M. Johnson Gerald K. Czamanske Peter W. Lipman 《Contributions to Mineralogy and Petrology》1989,103(1):90-109
Plutonic rocks associated with the Latir volcanic field comprise three groups: 1) 25 Ma high-level resurgent plutons composed of monzogranite and silicic metaluminous and peralkaline granite, 2) 23–25 Ma syenogranite, and alkali-feldspar granite intrusions emplaced along the southern caldera margin, and 3) 19–23 Ma granodiorite and granite plutons emplaced south of the caldera. Major-element compositions of both extrusive and intrusive suites in the Latir field are broadly similar; both suites include high-SiO2 rocks with low Ba and Sr, and high Rb, Nb, Th, and U contents. Moreover, both intermediateto siliciccomposition volcanic and plutonic rocks contain abundant accessory sphene and apatite, rich in rare-earth elements (REE), as well as phases in which REE's are essential components. Strong depletion in Y and REE contents, with increasing SiO2 content, in the plutonic rocks indicate a major role for accessory mineral fractionation that is not observed in volcanic rocks of equivalent composition. Considerations of the rheology of granitic magma suggest that accessory-mineral fractionation may occur primarily by filter-pressing evolved magmas from crystal-rich melts. More limited accessory-mineral crystallization and fractionation during evolution of the volcanic magmas may have resulted from markedly lower diffusivities of essential trace elements than major elements. Accessory-mineral fractionation probably becomes most significant at high crystallinities. The contrast in crystallization environments postulated for the extrusive and intrusive rocks may be common to other magmatic systems; the effects are particularly pronounced in highly evolved rocks of the Latir field. High-SiO2 peralkaline porphyry emplaced during resurgence of the Questa caldera represents non-erupted portions of the magma that produced the Amalia Tuff during caldera-forming eruption. The peralkaline porphyry continues compositional and mineralogical trends found in the tuff. Amphibole, mica, and sphene compositions suggest that the peralkaline magma evolved from metaluminous magma. Extensive feldspar fractionation occurred during evolution of the peralkaline magmas, but additional alkali and iron enrichment was likely a result of high halogen fluxes from crystallizing plutons and basaltic magmas at depth. 相似文献
20.
吉林省白头山火山岩的微量元素及其岩石学意义 总被引：2，自引：0，他引：2
白头山火山岩中含有一套粗面岩—钠碱流岩,与下伏的长白山玄武岩组成一个岩石系列。在白头山火山岩中,REE、Zn、Zr等元素十分富集,而过渡元素及Sr、Ba等元素极其贫 化。REE配分具明显的Eu负异常,许多不相容元素在岩石系列中表现出良好的线性关系。依据微量元素行为的数学模式对这些特征进行定性分析和定量模拟,其结果表明白头山火山岩是由长白山玄武岩岩浆经结晶分异形成的。 相似文献