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1.
Vicente G. Ruiz de Argandoa Lope Calleja ngel Rodríguez-Rey Luis Miguel Surez del Río Carmen Celorio 《Engineering Geology》2009,103(3-4):69-75
X-ray Computed Tomography (X-ray CT) has been used to study the petrophysical characteristics of a Jurassic sandstone from Asturias (Northern Spain) used as building stone in several monuments in the region. CT monitoring of water capillarity tests has made it possible to visualize the movement of water inside the samples, to relate this movement with texture characteristics, and to measure the height reached in successive images, thereby determining the capillary penetration coefficient; based on this coefficient, the effective capillary pore radius has also been estimated. An advantage of the use of CT is that, as the information comes from the sample interior, border effects that can be generated in the external faces can be avoided.The CT was also used to visualize how a commercial organosilicon consolidant penetrates inside the rock by means of capillarity, a usual way of consolidant application in stone restoration processes. The coefficient of capillary penetration of the product, determined on the basis of the measurements made on the tomographic images, is 53% less than that of water. The influence of rock texture characteristics on the capillarity both of the consolidant and the water was also observed.The samples underwent CT water capillarity studies before and after the consolidant application, proving that the treatment improves the rock's hydric properties. The coefficient of capillary penetration decreased by 24% following the application of the consolidant, whereas the effective pore radius decreased by more than 40%. 相似文献
2.
钙基液态水硬性加固剂用于潮湿土遗址的加固保护 总被引：2，自引：0，他引：2
通过对钙基液态水硬性加固剂的研制,对潮湿环境土遗址的加固保护进行了探索性研究。X射线衍射（XRD）和扫描电镜（SEM）分析结果表明,已成功制出了潮湿土样水硬性加固所需的纳米材料。同时,研究发现,氢氧化钙在650 ℃下用马弗炉煅烧1.5 h后,可得到直径约50 nm、长度约200 nm的针状二次生石灰;这种二次生石灰经水消化后,会成为粒径在200～300 nm左右、大小十分均匀的扁平椭圆状纳米氢氧化钙颗粒;氧化钙在密封陈化一段时间后,也可使氢氧化钙的粒径达到纳米级。土样加固试验的结果显示,纳米石灰的乙醇分散液的渗透性优于分析纯氢氧化钙,钙基水硬性加固剂对潮湿土样的加固效果较为明显,有望成为一种适合于潮湿环境土遗址加固的新型材料。 相似文献
3.
It is often necessary to locate the original quarry which supplied the stone for a particular historical building. This stones could be used for future restoration work and for testing in the laboratory (artificial aging tests, physical properties determination, control of the efficacy of conservation treatments, etc.). Generally, reviewing historical documentation gives information about the geographical setting of quarries and location of the stones in the monument, but this information needs to be proved by field and laboratory studies. The comparative study of stone from quarries and monuments should basically include the following: (1) mineralogical and petrographical studies; (2) the chemical analysis of major, minor and trace elements; (3)stable isotopes determinations; (4) physical properties of quarry materials and unweathered building stone (water absorption, ultrasound transmission velocity, porosity and porous system, density, bulk density, compressive strength, etc.). This methodology was applied to Málaga Cathedral stones represented in the main façade, towers, and the western zone of the terrace, which, according to historical literature, came from Almayate (Miocene–Pliocene limestones) and Cerro Coronado (Permotriassic sandstone) in Málaga. The conclusion of the comparative study carried out on quarries and building stones was consistent with the information available from the historical documentation. 相似文献
4.
Wanja Wedekind Christian J. Gross Andreas Hoffmann Siegfried Siegesmund 《Environmental Earth Sciences》2018,77(21):735
Sandstones, clay in the form of bricks and laterite are the building materials used by the Khmer to construct the imposing and magnificent temples in Southeast Asia. Many of these monuments suffer from fracturing, sanding, contour scaling, crust formation and salt weathering. The affinity to weathering is closely connected to the type of material. Two sandstone types classified as feldspathic arenite and quartz arenite of Angkor as well as two arkosic sandstones from Thailand are described and investigated in this study. Important petrophysical properties determined for the different sandstones consist of hydric expansion, thermal expansion, pore radii distribution and ultrasonic velocity. Different investigations such as capillary water uptake, surface hardness, hygroscopic water sorption, and salt resistance tests were undertaken in the laboratory to characterize the various rock types. Observations and quantified damage mapping were done onsite at the Phnom Bakheng Temple. Contour scaling in the form of weathering crusts is one of the main deterioration features observable at the Angkor monuments. Comparisons are made between the building stone, the crust material from the Phnom Bakheng Temple and fresh stone material used for restoration. Significant differences in hydric and especially in thermal expansion of the crust and sandstone have been determined. The results seem to indicate that extensional processes occur, which can be considered a force for detachment (i.e., contour scaling, flaking). In an experimental trial, the hydric and thermal expansion of the weathering crust and the building stone was significantly reduced by using a weak acid for the crust and a swelling inhibitor for the original building stone. 相似文献
5.
The behaviour of consolidated volcanic tuffs: weathering mechanisms under simulated laboratory conditions 总被引：1，自引：0，他引：1
Five volcanic tuffs ranging from dacitic tuffs of Hungary to rhyolite, phonolite and basaltic tuffs of Germany were consolidated under laboratory conditions. Prior to consolidation an anti-hygro, a hydrous consolidant, which reduces the swelling ability of clay minerals, was applied. The three consolidants, a silicic acid ester (SAE), an elastic silicic acid ester (eSAE) and an acrylate resin (PMMA) were applied on test specimens under vacuum. Petrographic characterisation (polarizing microscopy, XRD, SEM) provided data for fabric analyses and the mineral composition of the tuffs. Changes in fabric, effective porosity, density, tensile strength, ultrasonic wave velocity were evaluated after the treatment. Weathering simulation tests such as hygric dilatation and thermal dilatation aimed to prove the effectiveness of consolidation and the durability of consolidated tuff samples. More than 500 samples were analysed. The tests showed that SAE caused the highest increase in indirect tensile strength. The water absorption and the pore size distribution of the tuffs were modified by consolidation. The PMMA reduced the water absorption the most, whereas SAE modified it the least. All the tested consolidants increased the thermal dilatation of the tuffs. The changes in hygric dilatation were not uniform: for most tuffs SAE increased and PMMA decreased the hygric dilatation, although the clay-rich Habichtswald tuff showed the opposite trend. The changes in hygric and thermal behaviour of consolidated tuff require special care when specific consolidants are chosen. These products modify the physical properties of consolidated tuffs and change the behaviour of weathering. 相似文献
6.
Giuseppe Montana Luciana Randazzo Paolo Mazzoleni 《Environmental Earth Sciences》2012,67(4):1097-1110
Blackening and disaggregation of exposed surfaces of stone monuments are well-known effects of stone decay taking place in polluted urban environments all over the world. This paper aims to assess the contribution of natural and anthropogenic sources of total suspended particulate (TSP) causing permanent damage (black crusts) to the stone monuments of Catania (Sicily), one of the most popular ??cities of art?? of southern Italy. Atmospheric pollution of Catania, a typical Mediterranean coastal town, is mainly contributed by vehicle exhaust emissions rather than industrial ones. Episodically, the city also suffers gaseous and ash emissions (plumes) from the nearby Mount Etna volcano. Thus, to discriminate between natural and anthropogenic contributions to stone decay on Catania monuments, black crusts and TSP were sampled within the urban area and subjected to specific analytical procedures (optical microscopy, X-ray powder diffraction, Fourier transformed infrared spectroscopy, scanning electron microscopy equipped with energy dispersive spectrometry, ionic chromatography and dual inlet mass spectrometry). Mineralogical, chemical and isotopic characterization of black crusts and TSP provided new insights concerning the partition of sulfate sources in this particular urban context. The influence of Mount Etna emissions on both TSP and black crusts compositions was shown. Nevertheless, the key role of anthropogenic sources in the total sulfate budget was confirmed, while sea spray and volcanic emissions were found to make subordinate contributions. Quantitative data useful for the identification of the threshold pollution levels for preventive conservation of Catania monuments were obtained. 相似文献
7.
The extant remains of the Roman monuments of Tarragona, Spain are made of different types of Miocenic rocks from the quarries surrounding the city, which vary from calcarenite to bioclastic limestones, showing different degrees of dolomitization, depending on their diagenetic evolution. The decay of these monuments is highly dependent on the mineralogy and the fabric of the stone as well as on the environmental conditions to which the monument subjected. As a consequence, different forms of decay are observed on these monuments, namely, granular disintegration, differential erosion between sparitic and micritic areas of the rock, and development of black crust and orange patinas, some of them attributed to a sulfation process. A number of processes have been established as being responsible for the decay forms observed: sulfation on sheltered areas of the building in the urban environment; differential dilatation because of the NaCl of the marine spray that crystallizes inside the porosity; hydric and thermal expansion of the stone, both related to the amount and crystallinity of the clay minerals forming the rock matrix; and biocolonization on the stone surface. An empirical model is proposed to explain the decay forms studied in relation to these factors (rock and environment). 相似文献
8.
I˙stanbul, the capital of the east Roman, Byzantine and Ottoman Empires embraces two continents, one arm reaching out to
Asia, the other to Europe. It is therefore, a rich city in terms of monuments and historical cites. Shell limestones of Upper
Miocene age are used as building stone in the majority of the monuments in I˙stanbul because of their attractiveness, availability
and workability. The durability characteristics of the limestones are examined, and those factors that are responsible for
atmospheric weathering are discussed, in a humid and marine environment with important problems of urban pollution, specifically
due to traffic. In the present study weathering of the building stones were first examined in situ by macroscopic observations.
The weathering that developed as a result of environmental effects since this limestone was first used in historical monuments
has been affected 0.1–1.5 cm deep from the surface. The weathered facing stone of Şehzade Mehmed Mosque in I˙stanbul is undergoing
a program of progressive replacement. During this study, samples were taken from this monument where the shell limestone was
used. The stone surface was principally examined by means of Scanning Electron Microscopy (SEM). Petrographical and mineralogical
analyses were made by using optical microscopy and X-ray diffraction method. The physico-chemical properties of these rocks
control their weathering behaviour and reactivity. Major and trace element analyses and the effect of deterioration on the
physical properties of the limestones (unit weight, porosity and water absorption) have also been investigated. Studies on
the samples implies that weathering on the stone surface caused important variations on the physical characteristics of the
rock.
Received: 11 February 1998 · Accepted: 18 August 1998 相似文献
9.
Rosalda Punturo Laura G. Russo Antonino Lo Giudice Paolo Mazzoleni Antonino Pezzino 《Environmental Geology》2006,50(2):156-169
An archaeometric study of the stone materials employed in the Late Baroque historical monuments of the ancient city centre of Catania was carried out. Lithological maps of a selection of monuments, transferred to a digital format, revealed that the stone materials are both magmatic and sedimentary rocks, the colours of which are matched in a peculiar type of bichromy. Particular attention focused on sedimentary rocks, which consist of various types of limestone quarried near the city of Syracuse (Hyblean Plateau, south-eastern Sicily). Carbonate rocks were characterised in terms of mineralogy, petrography and geochemistry, by studying rock samples from both monuments and historical extraction sites. Results showed that, although only one name was historically attributed to the above lithotypes (i.e. “Pietra di Siracusa‘’), they were quarried from many locations and, as they belong to various geological formations, they therefore exhibit great variety. In order to examine the durability of Hyblean limestones employed in works of cultural heritage interest, salt crystallisation tests were carried out according to standard procedure norms (UNI EN 12370 (1999) Determination of resistance to crystallisation of salts, 6p). Results are consistent with the forms of deterioration observed in the monuments, and highlight the close relationship between textural characteristics and damage. Our purpose is to provide a basic tool, which may be useful both for conserving monuments of cultural heritage and for their restoration. 相似文献
10.
Wissem Frikha Mounir Bouassida Jean Canou 《Geotechnical and Geological Engineering》2013,31(2):739-752
The paper describes the behavior of remolded kaolin clay reinforced by stone column as investigated in laboratory. The installation of stone column was simulated by performing lateral expansion at different rates within hollow cylindrical remolded kaolin specimens initially subjected to K0 consolidation path. These specimens were, then, subjected to classical consolidated undrained triaxial tests while recording excess pore pressure values. The objective of the experimental programme was to quantify the effects of consolidation stress and stone column on the undrained Young’s modulus and shear strength of kaolin clay. Obtained results showed a significant improvement in Young’s modulus when the cavity expansion ratio and the consolidation stress increase. It was also found that the increase in undrained shear strength of improved kaolin clay mainly occurred at lower consolidation stress. Another important finding of this study is that the ratio of undrained Young’s modulus to undrained shear stress increases when the consolidation stress decreases. Finally, the paper presents a model developed for the design of stone columns. 相似文献
11.
E. Omdal M. V. Madland T. G. Kristiansen N. B. Nagel R. I. Korsnes A. Hiorth 《Rock Mechanics and Rock Engineering》2010,43(5):557-580
A laboratory test program, which simulated reservoir conditions of pressure and temperature, was conducted on outcrop and
reservoir chalk samples of various porosities. All the samples experienced a stress path following uniaxial strain condition
K
0 that led to compaction failure, i.e. pore collapse. The experiments were loaded by depletion of pore pressure conducted under
load controlled conditions. This depletion phase was followed by a creep period, where time-dependent deformation was monitored.
The intention of creating such reservoir condition in these laboratory experiments was to gain knowledge of the nature of
chalk compaction. Chalk is an important reservoir rock for the oil and gas industry with unique storage capability with porosities
up toward 50%. However, this rock is also very weak which has resulted in significant reservoir compaction and in turn severe
seabed subsidence and casing failure. Mapping of the mechanical behavior of chalk in terms of deformation is thus decisive
for a proper understanding of these reservoirs. The results of this study show that chalk is indeed a rate-dependent material
under laboratory loading conditions as time effects were revealed as the loading rate was varied. However, the results raise
uncertainty about the importance of rate dependency for chalk under completely drained conditions. Further, such high-porosity
chalk suffers for substantial plastic strains and obvious strain hardening. Indeed, a relation between deformation/porosity
and hardening is proposed by the introduction of real-time modulus values. Time-dependent deformation, also called creep was
influenced by the depletion phase, as consolidation or transient creep influenced the deformation response for as much as
175 h after a change in load. This indicates that transient creep is dependent on the stress history. However, observations
suggest the existence of a universal mechanism for steady state creep, governed by neither the initial porosity nor the stress
history or chalk type, which thus seems to be an independent strain contributor. Finally, time dependence is found on the
K
0 development for chalk tested at typically laboratory rates, which has been discussed as a reflection of the nature of the
grain re-arrangement during failure and plastic deformation. Ultimately, such time dependence of the K
0 may contribute to the understanding of stress path data deduced from field data. 相似文献
12.
在砂井地基固结度计算中,土的固结系数是一个十分重要的参数,土的固结系数通常通过室内试验求得,但室内取得水平向固结系数制样比较困难。利用软基处理过程中孔隙水压力监测资料来推算软土的固结系数,并和室内试验加以对比分析,总结出二者之间的相互关系及变化规律,可供同类工程设计借鉴。 相似文献
13.
潮湿环境下古代土遗址的原位保护加固研究 总被引：3，自引：1，他引：2
古遗址的保护是文物保护工作中最复杂的问题之一,而土质文物是文物保护中最难保护的文物,所以古代土遗址的保护已在国际上被列为专门的保护项目,而处于潮湿环境下的古代土遗址保护的课题在文化遗产实物和遗迹就地保存和展示领域就更为迫切。浙江良渚文化是中国新石器时代长江流域最重要的史前文化, 塘山遗址位于良渚文化遗址的西北部,选择了PS（硅酸钾）、WD－10（十二烷基三甲氧基硅烷）、WD－S（低聚甲氧基硅烷）、RTV（聚有机硅氧烷+硅酸乙酯）4种保护材料对塘山遗址进行了保护加固实验研究。室内实验和现场实验（2个月,6个月,9个月）的结果都表明,RTV和WD-10防水性优于WD-S,WD-10和WD-S材料仅能作为防水材料,PS材料仅能作为加固材料使用,而RTV则具有较好的加固和防水效果,且加样量越大,强度提高越多。 相似文献
14.
H.M. Rendell 《Engineering Geology》1988,25(2-4):229-233
Rendell, H.M., 1988. Comparison between naturally consolidated and laboratory consolidated loess. Eng. Geol., 25: 229–233.
Preliminary results of a comparison between naturally consolidated and laboratory consolidated loess are presented. Mercury intrusion porosimetry was used to compare nominal pore size distributions of loess before and after laboratory consolidation with those for samples that had undergone “natural” compaction. Although changes in density appear to be modelled well by the oedometer tests, the pore size distributions approach, they do not mirror exactly those for naturally consolidated loess. 相似文献
15.
通过某码头工程典型试验区进行的强夯试验，研究了在单点夯试验过程中夯沉量与夯击次数的关系、地基土水平位移和深度的关系、夯击次数与孔隙水压力的关系及孔隙水压力增长与消散和时间的关系；在试验块强夯后，进行了静载试验、静力触探试验和钻孔取土室内土工试验。通过对强夯前后进行对比，得到了强夯法加固吹填砂地基的效果，提出了合理的强夯施工参数和控制工艺，并得出了一些有益的结论。 相似文献
16.
The paper presents a new fully coupled elastoplastic solution for the response of a poroelastic thick-walled soil cylinder around an elastoplastic stone column using Biot’s (J Appl Phys 12:155–164, 1941) consolidation theory. A unit cell concept is adopted for the soil–stone column analysis, and the problem is formulated in cylindrical coordinates. Expressions for excess pore pressure, stresses and displacements in the Laplace domain are derived analytically taking into account elastic or plastic behavior of the column. The inverse of the Laplace transform is evaluated numerically using an efficient scheme to obtain the final elastoplastic solution in time domain. The validity of the new solution has been checked against finite element solution and compared with some previously developed analytical methods for the stone column analysis. The results showing settlements, change in excess pore pressures and stresses with time are presented in terms of time factor. The proposed solution can be used to calculate transient state of settlements, distribution of deformations, stresses and excess pore pressures in soil and column under instantaneous or time-dependent monotonically increasing rigid vertical load. 相似文献
17.
Germana Barone Mauro Francesco La Russa Antonino Lo Giudice Paolo Mazzoleni Antonino Pezzino 《Environmental Geology》2008,55(3):499-504
The Cathedral of St. Giorgio in Ragusa Ibla (Sicily) is one of the most important Baroque monuments of eastern Sicily. The restoration of the monument underway has put forward notable questions regarding the stone materials used and their state of degradation. The façade appears to be made mainly of a creamy white calcarenite, and of mortars and plasters. However, detailed analysis has highlighted a more complex use of the raw material. The mortar and plaster have a different composition in regards to their architectural use while the natural stone material is distinguished not only by a creamy-white calcarenite but also by a dark coloured bituminous calcarenite (pitch rock), which now appears whiter because of superficial chromatic alterations. This process was reproduced in the laboratory using an accelerated aging technique on samples of bituminous calcarenite, which allowed the cause of the alternation to be identified as photo-oxidation of the asphaltenes. Following this process of photo-oxidation, other forms of chromatic alterations affected the façade (brown–orange-coloured patinas). FTIR, Scanning Electron Microscope and thin section microscopic observation allowed the characterization of also the products of this process to be carried out, highlighting the complex mechanism which the processes underwent. 相似文献
18.
M. E. Young H.-L. Alakomi I. Fortune A. A. Gorbushina W. E. Krumbein I. Maxwell C. McCullagh P. Robertson M. Saarela J. Valero M. Vendrell 《Environmental Geology》2008,56(3-4):631-641
Existing chemical treatments to prevent biological damage to monuments often involve considerable amounts of potentially dangerous and even poisonous biocides. The scientific approach described in this paper aims at a drastic reduction in the concentration of biocide applications by a polyphasic approach of biocides combined with cell permeabilisers, polysaccharide and pigment inhibitors and a photodynamic treatment. A variety of potential agents were screened to determine the most effective combination. Promising compounds were tested under laboratory conditions with cultures of rock deteriorating bacteria, algae, cyanobacteria and fungi. A subsequent field trial involved two sandstone types with natural biofilms. These were treated with multiple combinations of chemicals and exposed to three different climatic conditions. Although treatments proved successful in the laboratory, field trials were inconclusive and further testing will be required to determine the most effective treatment regime. While the most effective combination of chemicals and their application methodology is still being optimised, results to date indicate that this is a promising and effective treatment for the control of a wide variety of potentially damaging organisms colonising stone substrates. 相似文献
19.
Mauro F. La Russa Germana Barone Cristina M. Belfiore Paolo Mazzoleni Antonino Pezzino 《Environmental Earth Sciences》2011,62(6):1263-1272
Noto is an important Baroque urban center in south-eastern Sicily, which was completely reconstructed after the severe earthquake
of 1693. Most of its monuments and historic buildings were built in Pietra di Noto stone, a pale cream calcarenite, quarried
in outcrops located near the city. This stone, still currently used as building material, is undergoing many forms of alteration
and degradation, which cause significant damage to monuments. In this study, three commercial protective products were tested
on some Noto calcarenite samples from quarries, with the aim of assessing their protective effectiveness. In particular, petrographic
analyses by optical microscopy were carried out for textural characterization of the stone materials. Capillary water absorption,
porosimetric and colorimetric procedures, UV radiation and salt crystallization aging tests were performed to better evaluate
interactions between protective products and substrate. 相似文献
20.
Physical, chemical and biogenic weathering considerably threatens all historic stone monuments. Microorganisms, though inconspicuous, are key players of stone surface colonization and penetration. This study highlights eukaryotic microbial communities on dimension stone surfaces from two representative monuments of the “cultural landscape corridor” in the Saale–Unstrut area. The historical buildings were erected from local Triassic limestone and sandstone and are prone to various deteriorative mechanisms. Generally, trebouxiophyceaen algae and ascomycete fungi dominate among the latter dematiaceous fungi and lichen fungi are abundant. Inside the stone substratum, ascomycetes, mosses and even large soil organisms (tardigrades) are present. This may be taken as a hint for the formation of pores with large radii, which are “risk indicators” for progressive weathering and degradation of the rock matrix. 相似文献