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1.
新疆准噶尔地区金矿床成矿流体稀土元素地球化学特征   总被引:11,自引:0,他引:11  
新疆准噶尔地区出现大量不同类型金矿床,为了探讨它们的成因,为金矿床的找矿勘探提供依据。笔者进行了哈图、包谷图、阔尔真阔腊、科克萨依等金矿床包裹体流体中稀土元素及同位素等研究。结果表明,尽管它们成矿形式不同,规模不等,但它们的金均主要来自深源,并有地层物质参与。其中哈图金矿石英脉型矿体与蚀变岩型矿体是两种不同来源的流体叠加成矿,石英脉型矿体主要与哈图岩体岩浆流体关系密切,蚀变岩型矿体与深源流体有关。包谷图、阔尔真阔腊金矿矿、科克萨依金矿成矿流体主要来源于深源,成矿过程中受到浅成流体的综合影响。矿物包裹体流体的稀土元素特征主要反映了原始成矿流体来源,矿物的稀土元素特征可能较多地体现了矿床特有的后期地质作用,这在今后研究中将进一步探讨。  相似文献   

2.
韧性剪切带型金矿床是新疆准噶尔-东天山地区重要金矿类型。本文以科克萨依、康古尔、红石金矿为典型矿床,研究它们的流体包裹体均一温度、爆裂温度、包裹体成分、包裹体水的来源等,并进行了硫、铅同位素及近矿围岩碳同位素、矿体石英包裹体中CO2、CH4气体的碳同位素分析。结果表明,硫、铅为深源,暗示了本区金成矿物质的地幔来源。部分碳为有机碳,反映了本区年轻碳质沉积地层中有机碳参与了金的迁移与成矿作用。综合研究表明,在本区特定的后碰撞地质背景下,在构造挤压与伸展作用中形成的韧性剪切带中的金矿床金成矿物质源于深源,成矿流体主要是变质水。岩浆作用、变质作用、碳质围岩地层有机碳参与成矿,变质流体与岩浆热液及天水等流体的不同程度的混合与叠加,形成本区特征的韧性剪切带型金矿床。  相似文献   

3.
高家店金矿床位于华北克拉通北缘冀东矿集区中部,为典型的蚀变岩型金矿床,少部分为石英脉型,赋存于高家店岩体的花岗岩和闪长岩内,受断裂构造控制。为了探讨高家店金矿床的成因,文章对其开展了详细的矿床地质特征、金及载金黄铁矿化学成分、流体包裹体和氢氧硫同位素研究。结果表明,高家店金矿床热液成矿期包括4个阶段,其中Ⅱ和Ⅲ阶段为金的主要成矿阶段。黄铁矿是金的主要载体矿物,金矿物为自然金和银金矿,以独立的金矿物的形式赋存于黄铁矿中。主成矿阶段黄铁矿Fe和S含量及Fe/S元素比值揭示金矿床具有岩浆热液型的特征。主成矿阶段流体包裹体类型以富液相的两相H2O溶液包裹体为主,其次为含CO2三相包裹体,属中温、中低盐度流体。不同成矿阶段的流体δ18OH2O值为1.82‰~5.60‰,δD值为-83.3‰~-55.3‰,指示流体主要来自岩浆水,并有少量大气降水混入。主成矿阶段黄铁矿δ34S值为2.40‰~5.61‰,显示地幔硫或岩浆硫特征,揭示成矿物质硫主要来自于深部岩浆。综合研究认为,高家店岩体的多期次岩浆侵入活动为金成矿提供了充足的热源及成矿流体,因而高家店金矿床成因类型为岩浆热液型。  相似文献   

4.
新疆北部浅成低温热液型金矿床成矿地球化学特征初探   总被引:6,自引:0,他引:6  
产于晚古生代火山岩中的浅成低温热液型金矿床是新疆北部近期发现的一个重要的金成矿类型。通过对本区部分浅成低温热液型金矿的容矿火山岩岩石化学成分、REE分布模式、硫同位素、氢同位素、氧同位素和锶同位素及流体包裹体成分的分析与对比,讨论了其基本成矿地球化学特征,并揭示了本区浅成低温热液型金矿床与我国东部地区某些产于中生代陆相火山岩中的同类型金矿床在成矿地球化学特征上存在的一些差异。  相似文献   

5.
阔尔真阔腊浅成低温热液金矿床成矿作用与成矿模式初探   总被引:4,自引:0,他引:4  
对阔尔真阔腊金矿床的成矿温度、微量元素与稀土元素含量、流体包裹体成份、硫、氢、氧、铷、锶等同位素资料的分析对比 ,探讨了该金矿床的成矿作用及其主要过程。认为该金矿床是一产于地洼区的浅成低温热液矿床 ,具有一系列多因复成矿床的基本成矿特征 ,其成矿至少经历了海西期地槽阶段的低温热液富集及中亚期地洼阶段的活化改造这两个重要阶段 ,并建立了其新的成矿模式。  相似文献   

6.
新疆阔尔真阔腊金矿床成矿流体包裹体研究   总被引:16,自引:1,他引:15  
新疆西北部阔尔真阔腊金矿床是产于海西期岛弧型钙碱性火山岩中的火山晚期热液型金矿床。流体包裹体研究表明,成矿阶段(Ⅰ)包裹体为气相包裹体,均一温度为308~396℃,盐度为5.86~8.41wt%NaCl;主成矿阶段(Ⅱ、Ⅲ)为气液包裹体,均一温度分别为209~276℃(Ⅱ)、119~198℃(Ⅲ),盐度分别为5.11~7.86wt%NaCl(Ⅱ)、2.74~6.17wt%NaCl(Ⅲ)。石英流体包裹体成分测定采用分阶段法,有效地排除了不同成矿阶段包裹体成分的影响,准确地测出了成矿阶段(Ⅰ)和主成矿阶段(Ⅱ、Ⅲ)包裹体的成分,结果表明成矿流体具Na^ -H^--Cl^--H2O型中低温、低盐特征,金主要以金硫络合物的形式迁移,金矿化是在还原条件下进行。主成矿阶段包裹体中水的氢同位素组成为-83.97~-89.07‰,氧同位素组成为1.8~3.2‰,成矿流体是岩浆热液与古大气降水混合而成。流体混合及水-岩反应是造成本区金沉淀成矿的主要因素。  相似文献   

7.
粤西罗定盆地南缘金矿地球化学特征及成矿作用   总被引:1,自引:0,他引:1  
研究区矿石及近矿蚀变围岩中黄铁矿的硫、铅同位素组成特征,以及金矿石(含金石英脉)和花岗斑岩的稀土元素特征,显示金矿成矿物质来源于地壳。矿体石英中的流体包裹体氢、氧同位素组成特征,显示成矿热液来源于大气降水。结合气液包裹体均一温度,认为本区金矿的成矿作用发生于低温、浅成-超浅成的环境条件,金矿的成因类型为浅成一超浅成低温热液型。  相似文献   

8.
河北小石门银金矿床位于小寺沟斑岩铜钼矿床的南西侧.矿体呈脉状、透镜状,银金矿化受NNE向断裂控制,成矿与杂岩体及二长斑岩有关;矿物组合主要为中低温矿物组合,成矿温度240~365℃;流体包裹体研究表明成矿流体富硫,有较高的K ,NH4 ,Ca2 和Na ,成矿热液为岩浆热液;硫同位素分析显示,硫来源于岩浆;稀土元素分析亦表明成矿物质来自于二长斑岩及小寺沟岩体,而铅锌矿可能部分来源于地层.推断小石门银金矿床为中低温热液矿床.  相似文献   

9.
以位于西准噶尔的阔尔真阔腊、布尔克斯岱、哈图、包古图金矿;东准噶尔的科克萨依、野马泉金矿;东天山的康古尔,石英滩,红石金矿为研究重点,着重探讨了S、Pb、C同位素在本区特定构造地质条件下对金成矿作用的示踪。结果表明。主成矿期矿化剂元素硫来源于深部,有少量地壳物质混染,金属元素铅主要来源于地幔及下地壳,少量浅部铅混染。反映了本区金的来源以深源为主的特征,各类金矿矿化剂元素碳为无机碳与有机碳不同程度的混合,表明地层有机质不同程度地参与了金的运移与卸载成矿,这是本区金成矿的重要特色。本区年轻的基底、深大断裂、火山活动及地层中有机质的参与等地质条件成就了本区不同类型金矿床的成矿。  相似文献   

10.
水晶屯金矿区金矿化主要与黄铁矿化、硅化、绢云母化和钾长石化有关,矿体严格受断裂构造控制。通过对矿体硫同位素、氢氧同位素、矿物包裹体及控矿因素等方面的分析,推测其成矿物质来源于桑干群老变质地层及深源岩浆热液,成矿流体主要来自岩浆水,岩浆活动为矿体提供热动力;阐明了该矿的成因类型,认为水晶屯金矿是一个中—高温中浅成热液充填...  相似文献   

11.
F, Cl, S and P were determined, using electron microprobe, in magmatic inclusions trapped within minerals and glass mesostasis from Wudalianchi volcanic rocks. The initial volcanic magma from Wudalianchi corresponds to the basanitic magma crystallized near the surface ( pressure < 91 Mpa ). The potential H2O content of this magma is in the range 2 — 4 wt. %. The initial composition of volcanic magmas varies regularly from early to late volcanic events. From the Middle Pleistocene to the recent eruptions (1719 – 1721 yr.), the basicity of volcanic magma tends to increase, as reflected by an increase in MgO and CaO contents and by a progressive decrease in SiO2 and K2O contents. Meanwhile. from early (Q2 ) to late (Q3) episodic eruptions of the Middle Pleistocene, the initial concentrations of chlorine in volcanic magmas range from 1430 – 1930 ppm to 1700 ppm and decrease to 700 — 970 ppm for the first episodic eruption during the Holocene (Q 4 1 ). The chlorine concentrations of volcanic magmas of recent eruption (Q 4 2 ) are increased again to 2600 – 2870 ppm. A parallel evolution trend for phosphorus and chlorine concentrations in magmas has been certified: 1500 – 5970 ppm (Q2)→ 3500 – 4210 ppm (Q3)→ 1100– 3500 ppm (Q 4 1 )→ 6800– 7900 ppm (Q 4 2 ). The fluorine contents of volcanic magmas, from early to late volcanic events, show the same trend: 770 – 2470 ppm → 200–700 ppm → 700 – 800 ppm. During the crystallization-evolution of volcanic magmas, fluorine and phosphorus tend to be enriched in residual magmas as a result of crystal-melt differentiation. for example. the fluorine contents reach 5000– 6800 ppm and the phosphorus contents, 2.93wt.% in residual magmas. An appreciable amount of chlorine may be lost from water rich volcanic magmas prior to eruption as a result of degassing. Apparently, water serves as a gas carrier for the chlorine. The chlorine contents of residual magmas may decrease to 100 – 300 ppm. The volcanic magmas from Wudalianchi are poor in sulfur, normally ranging from 200 to 400ppm. On account of the behavior of sulfur in magmas and the strontium and oxygen isotopic analyses ((87Sr /86Sr)i=0.70503– 0.70589; δ18O = + 5.50 – + 6.89 ‰ ), it can be considered that the basanitic magmas in the Wudalianchi volcanic area came from the upper mantle and have not yet been contaminated probably by continental crust materials.  相似文献   

12.
肯登高尔是新疆西天山备受关注的一处铜钼矿,它处于博罗霍洛古生代岛弧带.矿体呈板状、不规则脉状和透镜状产在晚石炭世花岗闪长岩与上石炭统碳酸盐岩外接触带矽卡岩中,矿石中金属矿物以黄铜矿、辉钼矿为主,脉石矿物以透辉石、钙铁榴石为主;硫化物矿物呈自形晶或他形结构,网脉状、浸染状分布于矽卡岩中.内生成矿作用明显经历了矽卡岩和石英...  相似文献   

13.
娄元林  陈武  袁永盛  杨桃 《矿床地质》2018,37(5):1124-1140
西藏隆子县恰嘎锑矿位于藏南喜马拉雅特提斯造山带的中东部,属藏南江孜-隆子金锑多金属成矿带。综合研究该矿床的石英流体包裹体特征和H-O-S同位素的组成,发现其流体成矿过程包括:黄铁矿-石英阶段发育富液相包裹体(W型),均一温度集中在170~180℃,盐度w(NaCleq)为2.86%~7.17%,成矿压力平均为47.15MPa,成矿深度平均为1.57 km;石英-硫化物阶段主要发育富液相包裹体(W型),其次为CO2-H2O三相包裹体(C型),均一温度位于200~220℃区间,盐度w(NaCleq)为2.20%~5.11%,成矿压力平均为47.46 MPa,成矿深度平均为1.58 km。矿区总体上流体属含微量CO2气体的中低温、低盐度的NaCl-H2O热液体系。H-O和S同位素结果表明存在地幔流体参与成矿,其赋矿浅变质沉积岩地层也为成矿提供了部分成矿流体,以上研究证明,恰嘎锑矿属于多来源流体浅层中低温矿床。  相似文献   

14.
湖南瑶岗仙钨矿稳定同位素地球化学研究   总被引:2,自引:0,他引:2  
祝新友 《地质与勘探》2014,50(5):947-960
瑶岗仙矿区拥有大规模脉型钨矿和矽卡岩型钨矿,以及中型铅锌矿床。石英脉型钨矿床脉体中的多阶段性、空间分带性均不明显,围岩蚀变规模小。矽卡岩型钨矿床蚀变规模大,多阶段,成矿温度跨度大,分带明显。石英脉型钨矿床硫化物δ34S=-2.6~3.9‰,平均-0.35‰,范围集中于0值附近,塔式分布;δ18O=12.4‰~14.4‰,δD=-60‰~-54‰,δ18O值、δD值集中,变化范围很小。矽卡岩矿床δ34S=-1.3~3.6‰,平均0.99‰,略高于石英脉型钨矿床;石英δ18O=1.5‰~11.7‰(杮竹园数据),变化范围大。铅锌矿床δ34S=-2.9~1.4‰,平均-0.8‰,略低于钨矿;石英δ18O=12.1‰~15.4‰,δD=43‰~51‰,变化范围更大。石英脉型、矽卡岩型钨矿和铅锌矿铅同位素组成范围相似,206Pb/204Pb=18.548~18.701,207Pb/204Pb=15.691~15.811,206Pb/204Pb=38.809~39.212。地质和S、Pb、H、O同位素研究说明,瑶岗仙矿区脉型钨矿与矽卡岩型钨矿床含不同的稳定同位素,显示成矿物质和成矿流体来源的差异性,成矿过程也不相同。脉型矿床成矿物质和成矿流体具体较单一的岩浆来源,没有明显的大气降水参与;而矽卡岩型矿床成矿物质主要来自于岩浆,也有沉积岩围岩的贡献,早阶段成矿流体来自于岩浆,中晚阶段有大量的大气降水参与成矿。与矽卡岩型钨矿床相比,脉型矿床成矿作用具有较低的水/岩比值。铅锌矿的地质地球化学特征更加相似于矽卡岩外围的分带形成的铅锌矿,即铅锌矿化属于矽卡岩演化至硫化物阶段的成果,而与石英脉型钨矿床无明显关系。  相似文献   

15.
湖南郴县华塘地区的长兴阶   总被引:2,自引:0,他引:2  
<正> 湖南南部郴县、桂阳交界的华圹地区,晚二叠世晚期地层发育良好。在东西长6公里,南北宽1.3公里的华塘向斜范围内(图1),岩相变化很大,既有以硅质岩为主含菊石的“大隆组”,又有以厚层白云质灰岩为主,含筵类、菊石、腕足类等的“长兴组”。笔者在采集化石、测制剖面进行生物地层工作的同时,对上述两种岩相的变化关系进行了追索和研究,现将我们的认识概述如下。 (一)郴县华塘公社三合小学剖面  相似文献   

16.
X射线荧光光谱法同时测定煤中砷硫磷氯   总被引:1,自引:0,他引:1  
采用人工混配有限煤炭标准样品粉末直接压片制样,X射线荧光光谱仪同时测量煤中的砷、硫、磷、氯。优化了样品粒度、样品量、助磨剂、制样压力和保压时间等实验条件,用可变α系数法进行基体校正。方法测定范围为As0.0015%-0.0051%、S0.21%-1.44%、P0.003%~0.096%、C10.01%-0.11%;检出限为As 1.2μg/g、S22μg/g、P2.1μg/g、C12.0μg/g。与标准方法对照,结果基本一致。方法快速、简便,满足了煤炭检验需要。  相似文献   

17.
《Chemical Geology》2006,225(1-2):30-39
The discovery of mass-independent isotope effects observed in Archean rocks, certain classes of meteorites, and atmospheric aerosols has had profound implications to our understanding of ancient and present atmospheric sulfur chemistry. We present a new technique that takes advantage of continuous He flow isotope-ratio-monitoring gas chromatography–mass spectrometry to achieve precise analysis of all four stable sulfur isotopes (32S, 33S, 34S, and 36S) at nanomole level samples. The technique involves fluorination of sulfide (silver sulfide or pyrite), and separation of product gas by gas chromatography and the removal of mass-131 interference by a liquid-nitrogen ethanol slush at − 110 °C. This technique works with an optimum sample size of 100 to 200 nmol with precision for Δ33S and Δ36S at 0.1 and 0.5‰ (2σ). Samples, as small as tens of nanomole, can be analyzed using this new method. One of the major sources of error in irm-GCMS is found to be tailing of the major ion beam (32SF5+) onto minor beams (33SF5+ and 36SF5+), which results in contraction of the measured δ33S and δ36S scales. This effect is corrected by measuring a series of reference sulfide samples with mass-dependent sulfur isotope compositions. This methodology increases the spatial resolution of the laser ablation in situ analysis and considerably reduces the analysis time as compared with conventional dual inlet methods.  相似文献   

18.
A fine exposure of perennially frozen ice-rich silt and associated flora and vertebrate fauna of late-Quaternary age exists at Mamontova Gora along the Aldan River in central Yakutia, Siberia, U.S.S.R. The silt deposit caps a 50-m-high terrace and consists of three units. An upper layer 1–2 m thick overlies a 10–15-m-thick brownish to black silt layer. The lower silt layer is greenish to gray and about 15 m thick. All the silt is well sorted with 60% of the particles falling between 0.005 and 0.5 mm in diameter and is generally chemically and mineralogically homogeneous. The middle unit contains may extinct vertebrate mammal remains and ice wedges. The lower unit contains little vegetation and no ice wedges. The silt is widespread and exists as a loamy blanket on terraces at various elevations on both sides of the lower Aldan River. The origin of the silt blanket of late-Quaternary age in central Yakutia has long been controversial. Various hypotheses have been suggested, including lacustrine and alluvial, as well as frost-action origins. It is sometimes referred to as loess-like loam. Péwé believes the silt at Mamontova Gora is loess, some of which has been retransported very short distances by water. The silt probably was blown from wide, braided, unvegetated flood plains of rivers draining nearby glaciers. The silt deposits are late Quaternary in age and probably associated with the Maximum glaciation (Samarov) and Sartan and Syryan glaciations of Wisconsinan age. On the basis of biostratigraphy, 10 radiocarbon dates, and their relation to the nearby glacial record, it is felt that the upper unit at Mamontova Gora is Holocene and the middle unit is Wisconsinan. The youngest date available from the middle unit at this particular location is 26,000 years. Dates greater than 56,000 years were obtained in the lower part of the middle unit. The lower unit is definitely beyond the range of radiocarbon dating and probably is older than the last interglacial. The sediment, fauna, ice wedges, stratigraphy, and age of perennially frozen slit deposits in central Alaska are remarkably similar to those of the deposits exposed in central Yakutia. Both areas consist of unglaciated rolling lowlands and river terraces surrounded by high mountains that were extensively glaciated in Pleistocene time. The glaciers extended from the high mountains to the edges of the ranges. In both regions, extensively braided, silt-charged rivers drained the mountains and flowed through the lowlands on their way to the sea. It follows that there should be a similar late-Quaternary history.  相似文献   

19.
新疆维宝铅锌矿床位于东昆仑祁漫塔格地区西段,铅锌矿体受地层及岩性控制,多呈层状、似层状赋存于蓟县纪狼牙山组中下部条带状绿帘石(透辉石)矽卡岩中,矿石类型主要为绿帘石-透辉石矽卡岩型铅锌(铜)矿石。矿石矿物主要为方铅矿、闪锌矿、黄铜矿等,脉石矿物主要为透辉石、绿帘石、方解石、绿泥石、石榴子石等。金属硫化物电子探针分析表明,闪锌矿中Fe质量分数为2.206%~2.679%,贫Ga、Ge、Cd,Zn/Cd为143~150,方铅矿中Ag质量分数较低(0.163%~0.210%),具有与岩浆热液有关的金属硫化物特征。流体包裹体以富气相两相包裹体和富液相两相包裹体为主,均一温度平均值分别为268.2和273.1 ℃,含有CO2、CH4、N2、H2等成分,成矿流体可能来源于岩浆流体,具中温、高盐度、低密度的特征,成矿过程中发生了不混溶作用。金属硫化物的δ34SV-CDT为0.49‰~2.41‰,主要来源于岩浆;金属硫化物的206Pb/204Pb为18.254~18.336,207Pb/204Pb为15.556~15.664,208Pb/204Pb为38.060~38.367,主要来源于区内深源岩浆活动,有少量地壳铅的混染。综合分析认为维宝铅锌矿床为与印支期岩浆作用有关的层控矽卡岩型矿床。  相似文献   

20.
The structure and history of several Devonian cauldron-subsidences and related granitic intrusions showing evidence of sub-surface ring-fracturing in South Eastern Australia are discussed. The Marysville Igneous Complex includes fish and plant bearing beds in the Acheron Cauldron, which has a diameter of 15 miles, and contains 6000 ft. of acid lavas, with subordinate andesites and basalts. Most of the occurrences are consanguineous. The parent magma is intermediate, close to the hypersthene dacites of the region, and is believed to have been injected as a magma wedge from the east.  相似文献   

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