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1.
Blacic described a transition from basal 〈a〉 to prism 〈c〉 dislocation glide systems as temperature increased or strain-rate decreased in sequences of experiments involving deformation of single crystals of quartz. In this paper theoretical aspects of competition between these systems during plastic deformation are discussed. It is concluded that the basal-prism mechanism switch should have important consequences for the development of crystallographic fabrics during plastic deformation of quartzite, and the Taylor-Bishop-Hill analysis is used in an attempt to predict expected fabric transitions.  相似文献   

2.
《Tectonophysics》2003,361(3-4):171-186
Banded iron formation (BIF) from the Quadrilátero Ferrı́fero (southeastern Brazil) shows a compositional layering with alternating iron-rich and quartz-rich layers. This layering was intensively folded and transposed at a centimeter/millimeter scale through a component of bedding-parallel shear related to flexural slip at middle to high greenschist facies conditions (400–450 °C). The microstructure and c-axis fabrics of normal limbs, inverted limb and hinge zones of a selected isoclinal fold were analyzed combining optical and scanning electron microscopy (SEM) and digital image analysis. In the normal limbs, recrystallized quartz grains show undulose extinction, relatively dry grain boundaries, c-axes at high angle to foliation and a pervasive grain shape fabric (GSF) indicating operation of crystal-plastic processes. In the inverted limb, quartz grains show more serrated and porous (“wet”) grain boundaries; the GSF is similar to that of the normal limb, but c-axes are oriented at 90° to those of the normal limb. We interpreted these characteristics as reflecting operation of solution-precipitation deformation in inverted limbs, as a consequence of grains having been rotated to an orientation that was hard to basal 〈a〉 glide, but easy to dissolution-precipitation creep. This deformation partitioning between crystal-plasticity and solution-transfer during folding/transposition of quartz may explain the common occurrence of layered quartz rocks, where individual layers show alternating c-axis fabrics with opposite asymmetries but a consistent GSF orientation. Such characteristics may reflect an earlier event of pervasive folding/transposition of a preexisting layering.  相似文献   

3.
周建勋 《地质科学》1999,34(1):10-17
商丹糜棱岩带岩湾、沙沟和商南等3个区段石英C-轴组构和显微构造特征表明,该带自西向东石英C-轴组构形式由单一环带型转为Y-轴方向的点极密型,然后变为Ⅰ型交叉环带型,构造变形环境从低绿片岩相过渡到中-高绿片岩相,然后变为高绿片岩相-低角闪岩相。构造变形环境差异是造成石英组构形式变化的主要因素。随着温压条件的升高,石英滑移系从以底面〈a〉滑移系和柱面〈a〉滑移系的共同作用为主转向以单一柱面〈a〉滑移系为主,进而底面〈a〉滑移系和柱面〈a〉滑移系又重新变得活跃,且菱面滑移系的作用也变得十分重要。  相似文献   

4.
We compare three cluster variation method (CVM) models for order-disorder in omphacite (Al0.5Mg0.5)[Na0.5Ca0.5]Si2O6: the generalized point approximation (GPA), generalized pair approximation (GPaA) and an approximation that is based on two eight-body clusters (2X8A). The same Hamiltonian (set of pairwise interactions) is used for all three approximations. Pair probabilities predicted by the GPA obey the geometric constraints of the crysal structure (the frustration constraint), but the exclusion of short-range order (SRO) leads to overestimates of the configurational internal energy (〈E〉), and the critical temperature for cation order-disorder (T c ). The GPaA violates the frustration constraint, and it therefore fails to predict a P2 1/n → C2/c order-disorder transition and yields values for 〈E〉 and SRO that are inconsistent with the omphacite crystal structure. The 2X8A predicts SRO that is consistent with the frustration constraint, and it yields improved (lower) estimates of 〈E〉 and T c relative to the GPA: 〈E〉2X8A<〈E〉GPA, and T c (2X8A)≈0.741 T c (GPA).  相似文献   

5.
《Tectonophysics》1986,125(4):357-370
The Hermitage Granite, situated in the northwest Massif Central (France) is a syntectonic Hercynian leucogranite emplaced along an active transcurrent shear zone. During emplacement and cooling, the progressive deformation is marked by the development of a primary homogeneous foliation gradually affected by ductile shear bands (C-S mylonites). Increase in strain heterogeneity during cooling corresponds to a change of dominant deformation mechanism of the quartz phase from grain growth and migration recrystallization to intracrystalline 〈a〉 slip and rotation recrystallization. Migration recrystallization is characterized by preferred orientations of c axes close to the principal extension direction. We discuss relevant deformation mechanisms and rheological implications for syntectonic plutons. In particular, we argue that the transitions between homogeneous and heterogeneous accumulation of strain cannot generally be correlated with transition between magmatic and solid-state flow.  相似文献   

6.
Quartz c-axis fabrics have been investigated within a suite of quartz veins and monomineralic layers around a major post-nappe fold hinge (the Wandfluhhorn Fold) in the Bosco area (Swiss-Italian border) within the lower Penninic nappes.Two kinematic domains which are separated by the axial plane trace of the Wandfluhhorn Fold are recognized; on the lower limb the measured quartz c-axis fabric asymmetry indicates a sense of shear in which the overlying layers move to the southwest (i.e. top-to-SW) whereas on the upper limb the shear sense is reversed with the top moving to northeast. The shear direction (N60°E–N80°E), however, is constant in both areas and oblique to an older stretching lineation as well as to the D3 fold hinge. Such a distribution of asymmetric quartz c-axis fabrics and the constant orientation of their interpreted shear direction, which is apparent only from the fabric data and not from field evidence, indicates fabric development pre- or early syn-Wandfluhhorn folding, with subsequent folding and modification of the existing textures and possibly rotation of the initial fold axis.An overall westward-directed shear has been suggested for the whole of the Lepontine Alps. However, this study demonstrates that this simple general pattern has been modified locally by later folding. It also demonstrates that the dominant lineation may be a finite stretching lineation due to more than one phase of deformation and is not necessarily related to any particular transport direction.  相似文献   

7.
Fine grained dolomite has been deformed in over twenty compression experiments in a Griggs-type piston-cylinder apparatus at various P and T conditions. Preferred orientation determined quantitatively using X-ray techniques and spherical harmonic analysis of the data is presented in inverse pole-figures of — 2/m symmetry. In most cases specimens display strong preferred orientation which varies mainly as a function of temperature. At all conditions it is very different from calcitic limestone. Although there is no significant grain growth even at 1000 °C the simple c-axes maximum fabric above 700 °C might be the result of recrystallization or translation on c. Below 700 °C, the preferred orientation is much weaker and complex. The primary maximum in the inverse pole-figure is near e, a secondary maximum near a high angle positive rhomb, principal minima are at c and f. This inverse pole-figure is consistent with f-twinning and translation gliding on r (t = a ?), two mechanisms which counteract each other. The latter is a new deformation mechanism for dolomite which we propose in order to explain the pattern of preferred orientation. The minimum at c is less pronounced below 100 ° C suggesting that c-translation may be active, but in these fine-grained aggregates it appears to be less important than is expected from single crystal experiments (Higgs and Handin, 1959), at least at low temperatures.  相似文献   

8.
Quartz c axis fabrics and microstructures have been investigated within a suite of quartzites collected from the Loch Eriboll area of the Moine Thrust zone and are used to interpret the detailed processes involved in fabric evolution. The intensity of quartz c axis fabrics is directly proportional to the calculated strain magnitude. A correlation is also established between the pattern of c axis fabrics and the calculated strain symmetry.Two kinematic domains are recognized within one of the studied thrust sheets which outcrops immediately beneath the Moine Thrust. Within the upper and central levels of the thrust sheet coaxial deformation is indicated by conjugate, mutually interfering shear bands, globular low strain detrital quartz grains whose c axes are aligned sub-parallel to the principal finite shortening direction (Z) and quartz c axis fabrics which are symmetric (both in terms of skeletal outline and intensity distribution) with respect to mylonitic foliation and lineation. Non-coaxial deformation is indicated within the more intensely deformed and recrystallized quartzites located near the base of the thrust sheet by single sets of shear bands and c axis fabrics which are asymmetric with respect to foliation and lineation.Tectonic models offering possible explanations for the presence of kinematic (strain path) domains within thrust sheets are considered.  相似文献   

9.
The Canisp Shear Zone transects layered Lewisian gneisses near Lochinver, NW Scotland. It is a vertical ductile shear zone with a dextral shear sense, formed during Laxfordian amphibolite facies metamorphism, transposing the layering to new foliation and linear structures. Minerals in the layered gneisses show little or no shape fabric, while a strong shape fabric defines the foliation. For quartz, this shape fabric is accompanied by development of a preferred crystal orientation with fabric patterns reflecting the geometry of the shear deformation. The quartz fabric shows a pole-free area around the lineation with the c-axes concentrated in an asymmetric cross-girdle or a point maximum perpendicular to the shear plane, and a monoclinic symmetry consistent with the shear sense.  相似文献   

10.
The effect of deformation history on the development of crystallographic preferred orientation in quartzities has been simulated using a computer program based on the Taylor-Bishop-Hill analysis. Model quartzities with different combinations of glide systems have been subjected to various coaxial and non-coaxial deformation histories. It is possible to obtain information from the fabrics that develop during simple histories; for example, the location of the axis of extension is generally associated with a pole free area on a c-axis plot, and progressive axial shortening, plane strain and axial shortening produce characteristic fabrics. In progressive simple shear the fabric skeleton becomes asymmetric relative to the sense of shear and a-axes preferentially align in the flow plane parallel to the flow direction. However, this example illustrates that the fabric orientation and characteristics are controlled by the kinematic framework and bear only an indirect relationship to the finite strain accumulated to that point in the history.The imprint of the closing stages of deformation limits to some degree the use of crystallographic fabrics as a tool for structural geologists, but in favourable circumstances data can be obtained concerning characteristics of the deformation history, on the scale of the hand-specimen, for the last part of this history.  相似文献   

11.
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12.
Single crystals of Li-aegirine LiFe3+Si2O6 were synthesized at 1573?K and 3?GPa, and a polycrystalline sample suitable for neutron diffraction was produced by ceramic sintering at 1223?K. LiFe3+Si2O6 is monoclinic, space group C2/c, a=9.6641(2)?Å, b= 8.6612(3)?Å, c=5.2924(2)?Å, β=110.12(1)° at 300?K as refined from powder neutron data. At 229?K Li-aegirine undergoes a phase transition from C2/c to P21 /c. This is indicated by strong discontinuities in the temperature variation of the lattice parameters, especially for the monoclinic angle β and by the appearance of Bragg reflections (hkl) with h+k≠2n. In the low-temperature form two non-equivalent Si-sites with 〈SiA–O〉=1.622?Å and 〈SiB–O〉=1.624?Å at 100?K are present. The bridging angles of the SiO4 tetrahedra O3–O3–O3 are 192.55(8)° and 160.02(9)° at 100?K in the two independent tetrahedral chains in space group P21 /c, whereas it is 180.83(9)° at 300?K in the high-temperature C2/c phase, i.e. the chains are nearly fully expanded. Upon the phase transition the Li-coordination changes from six to five. At 100?K four Li–O bond lengths lie within 2.072(4)–2.172(3)?Å, the fifth Li–O bond length is 2.356(4)?Å, whereas the Li–O3?A bond lengths amount to 2.796(4)?Å. From 57Fe Mössbauer spectroscopic measurements between 80 and 500?K the structural phase transition is characterized by a small discontinuity of the quadrupole splitting. Temperature-dependent neutron powder diffraction experiments show first occurrence of magnetic reflections at 16.5?K in good agreement with the point of inflection in the temperature-dependent magnetization of LiFe3+Si2O6. Distinct preordering phenomena can be observed up to 35?K. At the magnetic phase transition the unit cell parameters exhibit a pronounced magneto-striction of the lattice. Below T N Li-aegirine shows a collinear antiferromagnetic structure. From our neutron powder diffraction experiments we extract a collinear antiferromagnetic spin arrangement within the a–c plane.  相似文献   

13.
Quartz microfabrics and associated microstructures have been studied on a crustal shear zone—the Main Central Thrust (MCT) of the Himalaya. Sampling has been done along six traverses across the MCT zone in the Kumaun and Garhwal sectors of the Indian Himalaya. The MCT is a moderately north-dipping shear zone formed as a result of the southward emplacement of a part of the deeply rooted crust (that now constitutes the Central Crystalline Zone of the Higher Himalaya) over the less metamorphosed sedimentary belt of the Lesser Himalaya. On the basis of quartz c- and a-axis fabric patterns, supported by the relevant microstructures within the MCT zone, two major kinematic domains have been distinguished. A noncoaxial deformation domain is indicated by the intensely deformed rocks in the vicinity of the MCT plane. This domain includes ductilely deformed and fine-grained mylonitic rocks which contain a strong stretching lineation and are composed of low-grade mineral assemblages (muscovite, chlorite and quartz). These rocks are characterized by highly asymmetric structures/microstructures and quartz c- and a-axis fabrics that indicate a top-to-the-south sense that is compatible with south-directed thrusting for the MCT zone. An apparently coaxial deformation domain, on the other hand, is indicated by the rocks occurring in a rather narrow belt fringing, and structurally above, the noncoaxial deformation domain. The rocks are highly feldspathic and coarse-grained gneisses and do not possess any common lineation trend and the effects of simple shear deformation are weak. The quartz c-axis fabrics are symmetrical with respect to foliation and lineation. Moreover, these rocks contain conjugate and mutually interfering shear bands, feldspar/quartz porphyroclasts with long axes parallel to the macrosopic foliation and the related structures/microstructures, suggesting deformation under an approximate coaxial strain path.On moving towards the MCT, the quartz c- and a-axis fabrics become progressively stronger. The c-axis fabric gradually changes from random to orthorhombic and then to monoclinic. In addition, the coaxial strain path gradually changes to the noncoaxial strain path. All this progressive evolution of quartz fabrics suggests more activation of the basal, rhomb and a slip systems at all structural levels across the MCT.  相似文献   

14.
We performed deformation experiments on a foliated mylonite under high temperature and pressure conditions in this study. To investigate the effect of pre‐existing fabric on the rheology of rocks, our samples were drilled from natural mylonite with the cylinder axis parallel to the foliation (PAR) and perpendicular to the foliation (PER). We performed 25 tests on seven PAR samples and 21 tests on seven PER samples at temperatures ranging from 600 to 890 °C, confining pressures ranging from 800 to 1400 MPa, and steady‐state strain rates of 1 × 10−4, 1 × 10−5 and 2.5 × 10−6 s−1. In the temperatures of 600–700 °C, the deformation is accommodated by semi‐brittle flow, with the average stress exponent being 6–7 assuming power law flow; in the temperature range of 800–890 °C, deformation is mainly by plastic flow, with an average stress exponent of n = 3 and activation energies of Q = 354 ± 52 kJ/mol (PER and PAR samples). The experimental results show that the strengths of PER samples are higher than those of PAR samples. Deformation microstructures have been studied by optical and electron microscopy. The original foliation of PER samples is destroyed by deformation and replaced by a new foliation, but the deformation of PAR samples followed the original foliation. Electron backscatter diffraction (EBSD) measurements show a strong lattice preferred orientation (LPO) of the quartz c axis fabrics of the starting samples and deformed PER and PAR samples. However, the c axis fabric of quartz in experimentally deformed PER and PAR samples varied with temperature and strain rate is different from that seen in the starting mylonite sample. The initial quartz c axis fabric of the starting mylonite sample has been transformed into a new fabric during experimental deformation. Dehydration melting of biotite and hornblende occurred in both PER and PAR samples at temperatures of 800–890 °C. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

15.
Dolomite single crystals of six different crystallographic orientations were tested in compression under confining pressure at temperatures of 20 to 800° C. The chosen orientations favoured slip or twinning on particular systems. The deformed crystals were analysed by optical and high voltage transmission electron microscopy to determine activated deformation systems, dislocation behaviour, etc., and to assist in interpreting stress-strain data. It is shown that slip on c≡(0001) and on \(f \equiv (\bar 1012)\) ), and twinning on f between 300 and 600° C, are the principal modes of deformation. At low temperatures there is considerable cataclasis, and shear-fracturing must be counted as a significant deformation mechanism. The effects of climb become apparent at temperatures ?600° C. A pronounced increase in strength with testing temperature shown by some orientations of the crystals is largely associated with c slip, but f twinning also shows similar although weaker tendencies. The yield stress for f slip decreases markedly with temperature. Values of critical resolved shear stress are obtained for c and f slip, and for f twinning. Major and minor slip systems, dislocation and twin configurations generated by deformation under different regimes are documented and illustrated. Some of the characteristics of the deformation systems are attributed to the details of atomic displacements. In particular, the increase in strength with temperature for c slip is explained by friction of CO 3 2? groups during dislocation movement, which is unique for c slip. This friction increases with thermal vibration, expansion and rotation of the CO 3 2? groups.  相似文献   

16.
Temperature factors for oxygen and silicon atoms in β-quartz were calculated on a Born-von Karman lattice dynamical model of an ordered structure. The calculated thermal ellipsoids were in excellent agreements with those of the previous structure refinements of the order model, for both magnitudes and orientations of the principal axes. The temperature factors are contributed mainly by the soft optic modes in Γ-M and the lowest-lying acoustic modes along Γ-A, which are also strongly temperature-dependent. The cusp-shaped temperature dependence of mean square displacements, 〈u2〉, of oxygen atom, observed previously around the α-β transition, are resulted from the softening of these modes. The temperature-dependent modes in Γ-A were also found to cause diffuse scattering extending along ±c* of the fourth hexagon of the hk0 reciprocal lattice plane. The negative expansion known in β-quartz were interpreted in terms of asymmetrical forces exerting on oxygen atoms in Si-O-Si bending modes. In β-quartz, librational motions of oxygen atoms around Si-Si lines with large amplitudes, whose center is just on the β-position of high symmetry, must be possible under the condition that bending tetrahedral O-Si-O angles is energetically more favourable than compressing or stretching Si-O bonds.  相似文献   

17.
The transition between extensional and compressional-driven magnetic fabrics in sedimentary rocks is explored in this paper through the study of an example of the Basque–Cantabrian basin. In the area where extensional structures prevail and no superimposed deformation is observed, except for gentle large-scale folds, the magnetic fabric is interpreted as extensional, in consistency with mesostructural (tension gashes) and macrostructural (large-scale faults) data. Compressional tectonic fabrics are unequivocally interpreted in the area with cleavage development related to the buttressing of the syn-rift sequence against faults located near the northern basin margin. In this area, kmax is oriented according either to the intersection lineation or the dip direction of cleavage planes. In the area located in-between, where no macroscopic evidence of either compression or extension exist, there is a transitional fabric between compressional (resulting from the modification during inversion of a previous sedimentary or extensional fabric) and extensional (inherited from the extensional stage) magnetic fabrics that correlate with subtle evidences at the microscopic scale (pressure shadows, deformation and re-orientation of nodules). Therefore, the magnetic fabric is revealed as an exceptionally sensitive marker of deformation in sedimentary rocks. This transition in the magnetic fabric occurs within a length of 6.25 km along the cross-section that correlates with a thickness of 200 m of the stratigraphic pile. These results indicate that even in the absence of clear structural markers of compressional deformation, extensional magnetic fabrics can be only interpreted when there is a minimum separation (in the vertical or the horizontal) to the cleavage front.  相似文献   

18.
Quartz crystallographic fabric transitions in well-exposed mylonites immediately beneath the Moine Thrust at the Stack of Glencoul (NW Scotland) have been investigated by optical microscopy, X-ray texture goniometry and Orientation Distribution Function analysis. A progressive change is observed from asymmetrical kinked single girdle c-axis fabrics at 0.5 cm beneath the Moine Thrust, through asymmetrical Type I cross-girdle fabrics to symmetrical Type I cross-girdle fabrics at 30 cm beneath the thrust. This c-axis fabric transition is accompanied by a transition from asymmetrical single a-axis maximum fabrics (0.5 cm beneath the thrust) through asymmetrical two maxima fabrics to essentially symmetrical two maxima a-axis fabrics. ODF analysis of these S >L and L - S tectonites indicates that c-axis positions on the ‘leading edge’ of the fabric skeleton are related by a common (a) direction oriented within the XZ plane at a moderate angle to the lineation (X). In contrast, c-axis positions on the peripheral ‘trailing edge’ are related by a positive (r) rhomb pole oriented close to Z; (a) directions lying within this common rhomb plane progressively change through 180° in orientation traced around the c-axis fabric skeleton. Such contrasting ‘single crystal’ rhomb (a) preferred orientations on the ‘leading’ and ‘trailing’ edges of the fabric skeleton are interpreted as indicating localized (grain scale) plane strain and flattening deformation, respectively. They result in tectonites with essentially symmetrical c- and a-axis fabrics which display strongly asymmetrical positive (r) and negative (z) rhomb pole figures. The observed transition in quartz c- and a-axis fabrics is interpreted as indicating an increasing importance of non-coaxial plane-strain deformation as the Moine Thrust is approached. Even immediately (<1 cm) beneath the thrust, however, flow has still significantly departed from bulk simple shear and involved an important (heterogeneous) component of contemporaneous flattening deformation.  相似文献   

19.
Kinematic models of various types of transpression have been used to explain fabric features and strain in many natural deformation studies. Here, a mathematical model that encompasses all monoclinic and triclinic transpressional deformations including triclinic deformation with inclined simple shear (ϕ) and/or inclined extrusion orientations (υ) can be tested using a step-by-step approach with available field evidence. Two cases are presented. The first case from the Wabigoon–Quetico boundary in the Archean Superior Province utilizes both fabric orientation and quantified strain data. The best fit of the field evidence to the model indicates that deformation likely took place along subvertical shear zones via transpression with subhorizontal simple shear (ϕ = 0–20°) and variable inclined extrusion direction (extrusion can be either east or west and υ typically indicates extrusion orientations between 0 and 50° from vertical). The second case of the South Iberian shear zone has fabric orientation data, but no quantifiable strain possibilities. The best fit of the field evidence to the model indicates that deformation likely took place along a moderately inclined shear zone via transpression with subhorizontal simple shear (ϕ = 0–20°) and variable inclined extrusion direction (υ values between 0° and 80° from the true dip of the shear zone). Using this protocol in other examples of natural deformation will allow further constraints to be applied to kinematic models.  相似文献   

20.
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