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1.
二端员物质的混合过程在自然界普遍发生。放射性成因的Sr、Nd同位素体系因其具有源区示踪和长周期时标特性,在混合物组成端员定量分离和混合机制研究中具有特殊意义。本文较详细地介绍了二端员混合过程形成的混合体中元素组成,Sr,Nd同位素组成之间的相互关系。在此基础上,介绍了二端员混合过程的Sr,Nd同位素鉴别准则和混合体中混合比f的确定方法。  相似文献   

2.
中太平洋北部沉积物 ̄(87)Sr/ ̄(86)Sr比值具有亚洲大陆特征B.Peucker-Ehrenbrink等由于Sr和Nd同位素组成不易被风化、搬运和沉积过程改造,所以沉积物Sr、Nd同位素组成记录了源区信息,我们测量了来自太平洋各个区域的152个...  相似文献   

3.
海水的放射成因同位素组成随时间的变化具有提供大陆风化作用、洋底热液活动、大洋环流的变化以及其与构造和气候事件有关系的信息的潜力。所有主要洋盆中铁锰结壳的Sr、Nd和Pb同位素记录已用来研究海水的长期变化。由于分析困难 ,直到现在Hf同位素也没有引起人们的关注。在此 ,我们提供了挖掘自中太平洋海山的两个铁锰结壳的第一个高分辨率和精确的Hf同位素剖面 ,试图限定Hf同位素在中太平洋深水中的演化。目前海水中的Hf同位素组成还不得不直接测定 ,但是可以预料 ,由于以下原因Hf比Nd同位素组成更加易变。第一 ,由地幔…  相似文献   

4.
中太平洋CP25岩心沉积物中钙十辽沸石,蒙脱石/伊利石比值,稀土元素含量,铈异常,铕异常及Sr,Nd同位素特征作为海底火山活动的证据,揭示了中太平洋海盆晚新生代以来火山活动和沉积的历史。其结果是,早中新世约20-17MaB.P.间,火山活动逐渐强烈,在17MaB.P,最强烈,使得沉积物具有高M/I和∈Nd,低δCe和^87Srt/86Sr。  相似文献   

5.
中太平洋CP25岩心沉积物中钙十字沸石、蒙脱石/伊利石比值(M/I)、稀土元素含量、铈异常(δCe)、铕异常(δEu)及Sr、Nd同位素特征作为海底火山活动的证据,揭示了中太平洋海盆晚新生代以来火山活动和沉积的历史。其结果是,早中新世约20~17MaB.P.间,火山活动逐渐强烈,在17MaB.P.最强烈,使得沉积物具有高M/I和∈Nd、低δCe和87Sr/86Sr。17~1MaB.P.发生沉积间断。1MaB.P.至现代,火山活动较早中新世减弱  相似文献   

6.
53°S和66°S之间的太平洋南极海脊(PAR)进行了两个航次的取样,为太平洋南部海底4000km长的地幔构造提供了条件。Castillo等最近报道了53~57°S同位素数据,我们这里报告了56~66°S的资料。与东部微板块北部的多数东太平洋海隆(EPR)相比,PAR53~66°S的样品在Nd-Sr和Sr-Pb同位素图表中一般分别含有低Sr和高Pb。在智利海脊北部和澳大利亚—南极不整合地层(AAD)东部的印度海脊东南部(SEIR)以及30~35°S之间的EPR玄武岩中都可发现这种趋势。为了描绘太…  相似文献   

7.
海洋环境中Nd的同位素组成及其地质意义   总被引:5,自引:3,他引:2  
海水,海洋沉积物中的自生组分,生物壳体乃至全岩的Nd同位素组成可以反应大洋水体和沉积物的来源及大洋水体循环特征,因而具有重要的地质意义。在综合近20年来关于现代世界大洋海水,Fe-Mn沉积,热液,热液沉积物及其它组分的Nd同位素的研究资料基础上,总结了不同洋区,不同深度海水的Nd同位素组成特征及其控制因素;同时,依据Fe-Mn结壳及岩心中有孔虫的Nd同位素组成资料,总结了新生代以来世界海洋中Nd同  相似文献   

8.
以微量元素、稀土元素、Sr和Nd同位素变异特征为依据,确定鲁苏榴辉岩为多成因、多来源和多阶段,指出主要是在印支期扬子陆块与华北陆块碰撞造山作用过程中,挤入的上地幔碎片以及不同原岩类型的壳内高压变质岩碎块。燕山晚期的区域构造热事件使得某些榴辉岩的同位素体系再平衡。  相似文献   

9.
根据放射成因(Sr、Nd和Pb)同位素组分 ,大洋玄武岩地球化学研究确定了几种地幔成分。对大西洋洋中脊南部(Discovery和Shom区段)洋中脊玄武岩(MORB)的最新研究探明了具有同位素极值的地幔组分LO MU的存在 ,它具有低238U/204Pb(μ)、低206Pb/204Pb和∈ND、高 87Sr/86Sr和 207Pb/204Pb易变性的特征。科学家认为LOMU对南大西洋和印度洋的地幔羽状物有影响 ,并将其归于冈瓦纳分裂之后嵌进大洋上地幔的次大陆岩石圈的残余物质。这里 ,我们报道了从南大西洋海…  相似文献   

10.
多金属结核,铁锰结壳的同位素地球化学研究   总被引:1,自引:0,他引:1  
本文介绍国家大洋专项“八·五”重点项目“深海地质研究”中一级专题“东太平洋海盆多金属结核同位素地球化学研究”(DY85-02-03-04)所取得的成果,总结了多金属结核Sr、Pb、O、Si、C同位素地球化学特征,并探讨了铁锰结壳Sr、Pb同位素组成特征及其古环境意义.  相似文献   

11.
端元提取是混合像元分解的基础,也是高光谱遥感的研究热点。对于特定区域的高光谱图像应该使用哪种端元提取算法,需要对各种端元提取算法进行客观地评价。作者针对黄河口湿地CHRIS高光谱图像,使用了重建图像与原图像的均方根误差、有效端元数量两个指数对PPI、N-FINDR、VCA、OSP、IEA和SISAL六种典型的端元提取算法进行了评价。结果表明,SISAL算法重建误差最小,仅有其他算法误差的10%~28%;OSP算法识别了具有物理意义的6种有效端元,多于其他算法识别的地物类型,而SISAL算法识别的端元缺乏物理意义。  相似文献   

12.
图像端元全自动提取方法研究   总被引:1,自引:0,他引:1  
传统端元提取算法一般需要人工指定端元数目,易导致多选或漏选端元。提出了一种端元全自动提取方法,通过研究分类结果的均方根误差、端元间光谱相关性与端元数目的关系,设置两种循环结束条件,当分类结果的均方根误差最小或端元间恰未出现强相关现象时,获得最佳端元数。实验表明,该方法是正确有效的,能够克服现有方法的不足,提高了端元提取自动化程度。  相似文献   

13.
河口海岸沉积动力环境复杂,沉积物粗细组分皆有。对于粗细混杂(同时含有砂砾质和泥质成分)的沉积物样品,单一的粒度分析方法不能覆盖整个粒度分布范围,常采用激光-筛分联合法进行粒度分析。由于两种方法的分析原理不同,经常出现细部的激光法结果与粗部的筛分结果部分重合现象,这会影响整个样品的粒度分布计算。石油天然气行业标准《碎屑岩粒度分析方法》(SY/T 5434-2018)对此问题给出了新的解决方案,但是只有文字描述,没有可操作的计算方法。本研究根据该行业标准提出的方案,推算出激光-筛分联合法粒度分析结果的修正计算公式。以浙江舟山群岛潮间带197个粗细混杂样品为例,采用激光-筛分联合法进行了粒度分析,分别采用直接拼接算法及SY/T 5434-2018算法计算了粒度分布,在此基础上对两套算法所得组分含量和粒度参数进行了比较。结果表明,SY/T 5434-2018算法相较于直接拼接算法,扩大了粗颗粒的体积百分比,减少了细颗粒的体积百分比。两种算法得到的组分含量具有显著的线性相关关系,且砾、砂、粉砂、黏土等组分含量的差异从粗到细依次减少。用两种算法的结果分别计算粒度参数,同样具有显著的线性相关关系,且...  相似文献   

14.
Dissolved organic matter(DOM) from freshwater, mid-salinity, and seawater endmember samples in the Jiulong River Estuary, China were fractionated using cross-flow ultrafiltration with a 10-kDa membrane. The colloidal organic matter(COM; 10 kDa–0.22 μm) retentate, low molecular weight(LMW) DOM(10 kDa) permeate, and bulk samples were analyzed using absorption spectroscopy and three-dimensional fluorescence excitation-emission-matrix spectroscopy. The UV-visible spectra of COM were very similar to those obtained for permeate and bulk samples, decreasing monotonically with increasing wavelength. Most of the chromophoric DOM(CDOM, expressed as the absorption coefficient a355) occurred in the LMW fraction, while the percentage of CDOM in the colloidal fraction was substantially higher in the freshwater endmember(13.4% of the total) than in the seawater endmember(6.8%). The bulk CDOM showed a conservative mixing behavior in the estuary, while there was removal of the COM fraction and a concurrent addition of the permeate fraction in the mid-salinity sample, implying that part of the colloidal CDOM was transformed into LMW CDOM. Two humic-like components(C1: 250, 325/402 nm; and C2: 265, 360/458 nm) and one protein-like component(C3: 275/334 nm) were identified using parallel factor analysis. The contributions of the C1, C2, and C3 components of the COM fraction to the bulk sample were 2.5%–8.7%, 4.8%–12.6%, and 7.4%–14.7%, respectively, revealing that fluorescent DOM occurred mainly in the LMW fraction in the Jiulong River Estuary. The C1 and C2 components in the retentate and permeate samples showed conservative mixing behavior, but the intensity ratio of C2/C1 was higher in the retentate than in the permeate fractions for all salinity samples, showing that the humic component was more enriched in the COM than the fulvic component. The intensity ratio of C3/(C1+C2) was much higher in the retentate than in the permeate fraction for mid-salinity and seawater samples, revealing that the protein-like component was relatively more enriched in COM than the humic-like component. The contribution of the protein-like component(C3) to the total fluorescence in the retentate increased from 14% in the freshwater endmember to 72% for the seawater endmember samples, clearly indicating the variation of dominance by the humic-like component compared to the protein-like component during the estuarine mixing process of COM.  相似文献   

15.
To investigate the factors controlling lead (Pb) concentration and identify the sources of Pb in Yellow Sea sediments along the Korean coast, the concentration of Pb and Pb isotopes in 87 surface and 6 core sediment samples were analyzed. The 1 M HCl leached Pb concentrations had a similar geographic distribution to those of fine-grained sediments, while the distribution of residual Pb concentrations resembled that of coarse-grained sediments. Leached Pb was presumed to be associated with manganese (Mn) oxide and iron (Fe) oxy/hydroxide, while residual Pb was associated with potassium (K)-feldspar, based on good linear relationships between the leached Pb and the Fe/Mn concentrations, and the residual Pb and K concentrations. Based on a ratio–ratio plot with three isotopes (207Pb/206Pb and 208Pb/206Pb) and the geographic location of each sediment, sediments were categorized into two groups of samples as group1 and group2. Group 1 sediments, which were distributed in Gyeonggi Bay and offshore (north of 36.5°N), were determined to be a mixture of anthropogenic and natural Pb originating from the Han River, based on a 208Pb/206Pb against a Cs/Pbleached mixing plot of core and surface sediments. Group 2 sediments, which were distributed in the south of 36.5°N, also showed a two endmembers mixing relationship between materials from the Geum River and offshore materials, which had very different Pb concentrations and isotope ratios. Based on the isotopes and their concentrations in core and surface sediments, this mixing relationship was interpreted as materials from two geographically different origins being mixed, rather than anthropogenic or natural mixing of materials with the same origin. Therefore, the relative percentage of materials supplied from the Geum River was calculated using a two endmembers mixing model and estimated to be as much as about 50% at 35°N. The spatial distribution of materials derived from the Geum River represented that of fine-grained sediments originating from the Geum River. It was concluded that Pb isotopes in sediments could be used as a tracer in studies of the origin of fine-grained sediments along the Korean Yellow Sea coast.  相似文献   

16.
The empirical and analytical relationships between the vertical scale of intrusions, which are formed owing to the layering of the mixed boundary layer at a sloping bottom, and the determining parameters are obtained on the basis of field measurements in the coastal zone and energy considerations. An estimate of the vertical diffusion coefficient is given which allows us to determine the role of tidal mixing at the rigid boundaries as a mixing factor for the entire world's oceans.Translated by Mikhail M. Trufanov.  相似文献   

17.
《Ocean Modelling》2007,16(1-2):1-16
In many global ocean climate models, mesoscale eddies are parameterized as along isopycnal diffusion and eddy-induced advection (or equivalently skew-diffusion). The eddy-induced advection flattens isopycnals and acts as a sink of available potential energy, whereas the isopycnal diffusion mixes tracers along neutral directions. While much effort has gone into estimating diffusivities associated with this closure, less attention has been paid to the details of how this closure (which tries to flatten isopycnals) interacts with the mixed layer (in which vertical mixing tries to drive the isopycnals vertical). In order to maintain numerical stability, models often stipulate a maximum slope Smax which in combination with the thickness diffusivity Agm defines a maximum eddy-induced advective transport Agm1Smax. In this paper, we examine the impact of changing Smax within the GFDL global coupled climate model. We show that this parameter produces significant changes in wintertime mixed layer depth, with implications for wintertime temperatures in key regions, the distribution of precipitation, and the vertical structure of heat uptake. Smaller changes are seen in details of ventilation and currents, and even smaller changes as regards the overall hydrography. The results suggest that not only the value of the coefficient, but the details of the tapering scheme, need to be considered when comparing isopycnal mixing schemes in models.  相似文献   

18.
The use of dissolved organic matter fluorescence as a tracer of river-sea mixing was examined in two South Carolina estuaries. Fluorescence declined linearly with seawater dilution in laboratory mixing studies, and also behaved conservatively in an estuary where a single river emptied into a bay. Fluorescence-salinity relationships were also studied in another estuary where a piedmont river (high suspended sediment, low fluorescence) and a coastal plains river (low sediment, high fluorescence) mixed with ocean water. The factor of 2 or greater difference in fluorescence between the two rivers allowed their relative contribution to the estuarine water mass to be distinguished. Petroleum hydrocarbons, measured in estuarine water at 0·7-1·8 μg l−1 concentrations, contributed negligibly to water fluorescence.  相似文献   

19.
利用1994年85-904航次获取的冲绳海槽中段表层沉积物样品,测定其硅酸盐相的^87Sr/^86Cr和^143Nd/^144Nd比值,以定量研究冲绳海槽中段表层沉积物硅酸盐物质的来源,结果表明,冲绳海槽中段陆坡区表层沉积物硅酸盐相的^87Sr/^86Sr/^143Nd/^144Nd与东海陆架沉物硅酸盐相的^87Sr/^86Sr和^143Nd/^143Nd相当,槽底和东坡沉积物硅酸盐相的^87Sr/^86Cr和^143Nd/^144Nd值介于中国大陆硅酸盐物质和海槽水山碎屑的^87Sr/^86Sr,^143Nd/^144Nd比值之间,并大致具有两端员混合特征,利用以Sr同位素为参数的二端员混合方程进行物源定量分析的结果表明,冲绳海槽中段的西坡和槽底表层沉积物硅酸盐相以陆源物质为主,最大值为91.07%,由西向东,陆源物逐渐减少,在海槽东坡含量最小,最小值为9.93%,火山源物质在东坡含量最高,量大值为64.92%,由东向西,由北向东,火山源物质逐渐减少为零。  相似文献   

20.
The nature and characteristics of the mixed layer depth (MLD) remain uncertain in the northern South China Sea. Using in situ data, we examined the quality of different MLD definitions, investigated the spatial and diurnal variation in the MLD, and examined the mechanisms of mixed layer development during March 23–31, 2014. We made distinct calculations of the MLD; of which two are (a) the depths between two different temperatures (0.2, 0.6 °C) and (b) the depths between two density differences (0.125, 0.25 kg/m3); and the fifth calculation is a depth derived from the optimal linear fitness method. We found that the optimal linear fitness MLD was the best definition for our study region ,and that it deepened from the shelf to the slope. Twenty-four-hour diurnal variation in the MLDs and mixing layers was observed when the ship was moored. Mixing layers were characterized by turbulent dissipation rates. We found that the mixed layer underwent a ‘stable-decaying–developing’ process. During the stable period, the MLD was close to that of the mixing layer, but during the decay/development periods, the MLDs were larger/smaller than those of the mixing layers. We suggest that both velocity shear and buoyancy flux were important in mixed layer development. We quantitatively examined the mechanisms of mixing in the shelf region, with air–sea net heat flux determined to be the major factor, rather than wind speed or current velocity.  相似文献   

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