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1.
Comparative planetary geochemistry provides insight into the origin and evolutionary paths of planetary bodies in the inner solar system. The eucrite and angrite achondrite groups are particularly interesting because they show evidence of early planetary differentiation. We present 147Sm‐143Nd and 176Lu‐176Hf analyses of eight noncumulate (basaltic) eucrites, two cumulate eucrites, and three angrites, which together place new constraints on the evolution and differentiation histories of the crusts of the eucrite and angrite parent bodies and their mantle mineralogies. The chemical compositions of both eucrites and angrites indicate similar evolutionary paths and petrogenetic models with formation and isolation of differentiated crustal reservoirs associated with segregation of ilmenite. We report a 147Sm‐143Nd mineral isochron age for the Moama cumulate eucrite of 4519 ± 34 Ma (MSWD = 1.3). This age indicates protracted magmatism within deep crustal layers of the eucrite parent body lasting up to about 50 Ma after the formation of the solar system. We further demonstrate that the isotopic compositions of constituent minerals are compromised by secondary processes hindering precise determination of mineral isochron ages of basaltic eucrites and angrites. We interpret the changes in geochemistry and, consequently, the erroneous 147Sm‐143Nd and 176Lu‐176Hf internal mineral isochron ages of basaltic eucrites and angrites as the result of metamorphic events such as impacts (effects from pressure, temperature, and peak shock duration) on the surfaces of the eucrite and angrite parent bodies.  相似文献   

2.
Abstract— The cumulate eucrite meteorites are gabbros that are related to the eucrite basalt meteorites. The eucrite basalts are relatively primitive (nearly flat REE patterns with La ～ 8–30 × CI), but the parent magmas of the cumulate eucrites have been inferred as extremely evolved (La to > 100 × CI). This inference has been based on mineral/magma partitioning, and on mass balance considering the cumulate eucrites as adcumulates of plagioclase + pigeonite only; both approaches have been criticized as inappropriate. Here, mass balance including magma + equilibrium pigeonite + equilibrium plagioclase is used to test a simple model for the cumulate eucrites: that they formed from known eucritic magma types, that they consisted only of magma + crystals in chemical equilibrium with the magma, and that they were closed to chemical exchange after the accumulation of crystals. This model is tested for major and rare earth elements (REE). The cumulate eucrites Serra de Magé and Moore County are consistent, in both REE and major elements, with formation by this simple model from a eucrite magma with a composition similar to the Nuevo Laredo meteorite: Serra de Magé as 14% magma, 47.5% pigeonite, and 38.5% plagioclase; Moore County as 35% magma, 37.5% pigeonite, and 27.5% plagioclase. These results are insensitive to the choice of mineral/magma partition coefficients. Results for the Moama cumulate eucrite are strongly dependent on choice of partition coefficients; for one reasonable choice, Moama's composition can be modeled as 4% Nuevo Laredo magma, 60% pigeonite, and 36% plagioclase. Selection of parent magma composition relies heavily on major elements; the REE cannot uniquely indicate a parent magma among the eucrite basalts. The major element composition of Y-791195 can be fit adequately as a simple cumulate from any basaltic eucrite composition. However, Y-791195 has LREE abundances and La/Lu too low to be accommodated within the model using any basaltic eucrite composition and any reasonable partition coefficients. Postcumulus loss of incompatible elements seems possible. It is intriguing that Serra de Magé, Moore County, and Moama are consistent with the same parental magma; could they be from the same igneous body on the eucrite parent asteroid (4 Vesta)?  相似文献   

3.
A non-brecciated, relatively coarsely crystalline eucrite was found in 1940 near Moama, southern New South Wales, Australia. The texture and mineralogy (plagioclase 49.1 volume %, pyroxene 48.9%, tridymite 0.72%, chromite 1.0%, troilite 0.24% and metallic iron 0.14%) are characteristic of an adcumulate formed in a terrestrial layered igneous intrusion. Its composition and texture most closely resemble the eucrite Serra de Magé. Moama and Serra de Magé are the best approximations to the pyroxeneplagioclase cumulates which McCarthy et al. (1973) propose have separated from a primary magma to produce the eucrite group of achondrites. Primary (coarse) and secondary (fine) augitic exsolution lamellae in the host hypersthene grains indicate a cooling history for the Moama eucrite similar to that of mafic rocks in slowly cooled, large, layered terrestrial intrusions such as Bushveld.  相似文献   

4.
We conducted a transmission electron microscope study of the exsolution microstructures of Ca-rich pyroxenes in type I chondrules from the Paris CM and Renazzo CR carbonaceous chondrites in order to provide better constraints on the cooling history of type I chondrules. Our study shows a high variability of composition in the augite grains at a submicrometer scale, reflecting nonequilibrium crystallization. The microstructure is closely related to the local composition and is thus variable inside augite grains. For compositions inside the pyroxene miscibility gap, with a wollastonite (Wo) content typically below 40 mole%, the augite grains contain abundant exsolution lamellae on (001). For grain areas with composition close to Wo40, a modulated texture on (100) and (001) is the dominant microstructure, while areas with compositions higher than Wo40 do not show any exsolution microstructure development. To estimate the cooling rate, we used the spacing of the exsolution lamellae on (001), for which the growth is diffusion controlled and thus sensitive to the cooling rate. Despite the relatively homogeneous microstructures of augite grains with Wo < 35 mole%, our study of four chondrules suggests a range of cooling rates from ~10 to ~1000 °C h−1, within the temperature interval 1200–1350 °C. These cooling rates are comparable to those of type II chondrules, i.e., 1–1000 °C h−1. We conclude that the formation of type I and II chondrules in the proto-solar nebula was the result of a common mechanism.  相似文献   

5.
Abstract— We studied the texture, mineralogy, and bulk chemical composition of Dhofar 007, a basaltic achondrite. Dhofar 007 is a polymict breccia that is mostly composed of coarse‐grained granular (CG) clasts with a minor amount of xenolithic components, such as a fragment of Mg‐rich pyroxene. The coarse‐grained, relict gabbroic texture, mineral chemistry, and bulk chemical data of the coarse‐grained clast indicate that the CG clasts were originally a cumulate rock crystallized in a crust of the parent body. However, in contrast to monomict eucrites, the siderophile elements are highly enriched and could have been introduced by impact events. Dhofar 007 appears to have experienced a two‐stage postcrystallization thermal history: rapid cooling at high temperatures and slow cooling at lower temperatures. The presence of pigeonite with closely spaced, fine augite lamellae suggests that this rock was cooled rapidly from higher temperatures (>0.5 °C/yr at ˜1000 °C) than typical cumulate eucrites. However, the presence of the cloudy zone in taenite and the Ni profile across the kamacite‐taenite boundaries indicates that the cooling rate was very slow at lower temperatures (˜1–10 °C/Myr at <600–700 °C). The slow cooling rate is comparable to those in mesosiderites and pallasites. The two‐stage thermal history and the relative abundance of siderophile elements similar to those for metallic portions in mesosiderites suggest that Dhofar 007 is a large inclusion of mesosiderite. However, we cannot rule out a possibility that Dhofar 007 is an anomalous eucrite.  相似文献   

6.
Abstract— An evaluation of trapped melts effects during crystallization and subsolidus equilibration of cumulates is necessary to constrain the composition of their parental magmas. In this paper, a simple mass balance approach is described. It allows estimation of trace element abundances in these parental melts from phase compositions. It is used to discuss the genesis of cumulate eucrites and diogenites. The REE behavior is in full agreement with the view that cumulate eucrites formed from melts similar to noncumulate eucrites. Trapped melt fractions ranging from <10 wt% for Moama to ?30 wt% for Moore County were involved. The origin of diogenites is more complex. The assumption that eucrites and diogenites shared the same parental melts cannot satisfactorily explain the diversity of incompatible trace element ratios (e.g., Dy/Yb) observed in diogenitic orthopyroxenes, even if interstitial melt effects are taken into account. Moreover, some diogenites unambiguously crystallized from magmas displaying significant HREE (heavy rare earth elements) enrichments. More likely, diogenites formed from distinct batches of parental magmas, as previously proposed by Mittlefehldt (1994), Fowler et al. (1995), and Shearer (1997).  相似文献   

7.
Abstract— Eucrite meteorites are igneous rocks that derived from a large asteroid, probably 4 Vesta. Past studies have shown that after most eucrites formed, they underwent metamorphism in temperatures up to ≥800°C. Much later, many were brecciated and heated by large impacts into the parent body surface. The less common basaltic, unbrecciated eucrites also formed near the surface but, presumably, escaped later brecciation, while the cumulate eucrites formed at depths where metamorphism may have persisted for a considerable period. To further understand the complex HED parent body thermal history, we determined new 39Ar‐40Ar ages for 9 eucrites classified as basaltic but unbrecciated, 6 eucrites classified as cumulate, and several basaltic‐brecciated eucrites. Precise Ar‐Ar ages of 2 cumulate eucrites (Moama and EET 87520) and 4 unbrecciated eucrites give a tight cluster at 4.48 ± 0.02 Gyr (not including any uncertainties in the flux monitor age). Ar‐Ar ages of 6 additional unbrecciated eucrites are consistent with this age within their relatively larger age uncertainties. By contrast, available literature data on Pb‐Pb isochron ages of 4 cumulate eucrites and 1 unbrecciated eucrite vary over 4.4–4.515 Gyr, and 147Sm‐143Nd isochron ages of 4 cumulate and 3 unbrecciated eucrites vary over 4.41–4.55 Gyr. Similar Ar‐Ar ages for cumulate and unbrecciated eucrites imply that cumulate eucrites do not have a younger formation age than basaltic eucrites, as was previously proposed. We suggest that these cumulate and unbrecciated eucrites resided at a depth where parent body temperatures were sufficiently high to cause the K‐Ar and some other chronometers to remain as open diffusion systems. From the strong clustering of Ar‐Ar ages at ?4.48 Gyr, we propose that these meteorites were excavated from depth in a single large impact event ?4.48 Gyr ago, which quickly cooled the samples and started the K‐Ar chronometer. A large (?460 km) crater postulated to exist on Vesta may be the source of these eucrites and of many smaller asteroids thought to be spectrally or physically associated with Vesta. Some Pb‐Pb and Sm‐Nd ages of cumulate and unbrecciated eucrites are consistent with the Ar‐Ar age of 4.48 Gyr, and the few older Pb‐Pb and Sm‐Nd ages may reflect an isotopic closure before the large cratering event. One cumulate eucrite gives an Ar‐Ar age of 4.25 Gyr; 3 additional cumulate eucrites give Ar‐Ar ages of 3.4–3.7 Gyr; and 2 unbrecciated eucrites give Ar‐Ar ages of ?3.55 Gyr. We attribute these younger ages to a later impact heating. Furthermore, the Ar‐Ar impact‐reset ages of several brecciated eucrites and eucritic clasts in howardites fall within the range of 3.5–4.1 Gyr. Among these, Piplia Kalan, the first eucrite to show evidence for extinct 26Al, was strongly impact heated ?3.5 Gyr ago. When these data are combined with eucrite Ar‐Ar ages in the literature, they confirm that several large impact heating events occurred on Vesta between ?4.1–3.4 Gyr ago. The onset of major impact heating may have occurred at similar times for both Vesta and the moon, but impact heating appears to have persisted for a somewhat later time on Vesta.  相似文献   

8.
Abstract— The microstructure and composition of the matrix of one carbonaceous inclusion (K1) in the Krymka LL3.1 chondrite were studied using transmission electron microscopy (TEM). K1 has previously shown an enigmatic nature and similarities with volatile‐rich, fine‐grained, dark inclusions of Krymka called “mysterite.” In the present study, four minerals were identified by TEM. Olivine, pyroxene, and pyrrhotite typically have grain sizes of one micrometer; graphite occurs as flakes of a similar size. Olivine shows a moderately high dislocation density most probably caused by shock. Pyroxene shows coexisting ortho‐ and clinoenstatite lamellae that probably originated from shear stress after a shock event or from the rapid cooling of the protoenstatite stability field. However, we demonstrate that in this case, a shock trigger is more likely. Pyrrhotite in the studied sample occurs as a 4C monoclinic superstructure. The graphite flakes in the fragment are well crystallized, as can be seen by discrete spots in the diffraction pattern. In graphite, the degree of crystallization increases with the metamorphic grade. Based on the microstructure of this mineral we conclude that after a first moderate shock event, the residual temperature between 300 °C and 500 °C led to thermal metamorphism. A second shock event, possibly at excavation from the parent body, is responsible for the shock features observed in olivine, pyroxene, and graphite.  相似文献   

9.
Abstract— Ibitira is a strongly recrystallized and unbrecciated noncumulate eucrite. We measured Ca compositional profiles of Ibitira pyroxene by electron microprobe and computed the cooling rate and burial depth from pyroxene exsolution profiles to gain information on early thermal history of Ibitira. Pyroxene begins to exsolve at 1082 °C and cools down to 550 °C at a rate of 0.02 °C/year, forming an augite lamella about 7.0 μm in width. A notable characteristic of the Ca profile of augite lamellae in Ibitira pyroxene is a gradient near the interface between augite and low‐Ca pyroxene (pigeonite). This profile suggests that after thermal metamorphism Ibitira pyroxene experienced a sudden temperature rise to above solidus temperature of pyroxene (～1082 °C), and subsequent rapid cooling. The 39Ar‐40Ar age of 4.485 Ga for Ibitira, which is the oldest 39Ar‐40Ar age for noncumulate eucrites, may date this reheating event.  相似文献   

10.
We report petrology and geochemistry of an achondrite EET 92023 and compare it with normal and anomalous eucrites. EET 92023 is an unbrecciated achondrite and shows a granular texture mainly composed of low‐Ca pyroxene and plagioclase, petrologically similar to normal cumulate eucrites such as Moore County. However, this rock contains a significant amount of kamacite and taenite not common in unbrecciated, crystalline eucrites. EET 92023 contains a significant amount of platinum group elements (PGEs) (ca. 10% of CI), several orders of magnitude higher than those of monomict eucrites. We suggest that the metallic phases carrying PGEs were incorporated by a projectile during or before igneous crystallization and thermal metamorphism. The projectile was likely to be an iron meteorite rather than chondritic materials, as indicated by the lack of olivine and the presence of free silica. Therefore, the oxygen isotopic signature is indigenous, rather than due to contamination of the projectile material with different oxygen isotopic compositions. A significant thermal event involving partial melting and metamorphism after the impact event indicates that EET 92023 records early impact events which took place shortly after the crust formation on a differentiated protoplanet when the crust was still hot.  相似文献   

11.
The Agoudal IIAB iron meteorite exhibits only kamacite grains (~6 mm across) without any taenite. The kamacite is homogeneously enriched with numerous rhabdite inclusions of different size, shape, and composition. In some kamacite domains, this appears frosty due to micron‐scale rhabdite inclusions (~5 to 100 μm) of moderate to high Ni content (~26 to 40 wt%). In addition, all the kamacite grains in matrix are marked with a prominent linear crack formed during an atmospheric break‐up event and subsequently oxidized. This feature, also defined by trails of lowest Ni‐bearing (mean Ni: 23 wt%) mm‐scale rhabdite plates (fractured and oxidized) could be a trace of a pre‐existing γ–α interface. Agoudal experienced a very slow rate of primary cooling ~4 °C Ma?1 estimated from the binary plots of true rhabdite width against corresponding Ni wt% and the computed cooling rate curves after Randich and Goldstein (1978). Chemically, Agoudal iron (Ga: 54 ppm; Ge: 140 ppm; Ir: 0.03 ppm) resembles the Ainsworth iron, the coarsest octahedrite of the IIAB group. Agoudal contains multiple sets of Neumann bands that are formed in space and time at different scales and densities due to multiple impacts with shock magnitude up to 130 kb. Signatures of recrystallization due to postshock low temperature mild reheating at about 400 °C are also locally present.  相似文献   

12.
Zak?odzie is an enstatite meteorite of unknown petrogenesis. Chemically, it resembles enstatite chondrites, but displays an achondrite‐like texture. Here we report on fabric and texture analyses of Zak?odzie utilizing X‐ray computed tomography and scanning electron microscopy and combine it with a nanostructural study of striated pyroxene by transmission electron microscopy. With this approach we identify mechanisms that led to formation of the texture and address the petrogenesis of the rock. Zak?odzie experienced a shock event in its early evolution while located at some depth inside a warm parent body. Shock‐related strain inverted pyroxene to the observed mixture of intercalated orthorhombic and monoclinic polymorphs. The heat that dissipated after the peak shock was added to primary, radiogenic‐derived heat and led to a prolonged thermal event. This caused local, equilibrium‐based partial melting of plagioclase and metal‐sulfide. Partial melting was followed by two‐stage cooling. The first phase of annealing (above 500 °C) allowed for crystallization of plagioclase and for textural equilibration of metal and sulfides with silicates. Below 500 °C, cooling was faster and more heterogeneous at cm scale, allowing retention of keilite and quenching of K‐rich feldspathic glass in some parts. Our study indicates that Zak?odzie is neither an impact melt rock nor a primitive achondrite, as suggested in former studies. An impact melt origin is excluded because enstatite in Zak?odzie was never completely melted and partial melting occurred during equilibrium‐based postshock conditions. Texturally, the rock represents a transition of chondrite and achondrite and was formed when early impact heat was added to internal radiogenic heat.  相似文献   

13.
Abstract— The Sayh al Uhaymir (SaU) 150 meteorite was found on a gravel plateau, 43.3 km south of Ghaba, Oman, on October 8, 2002. Oxygen isotope (δ17O 2.78; δ18O 4.74), CRE age (?1.3 Ma), and noble gas studies confirm its Martian origin. SaU 150 is classified as an olivine‐phyric basalt, having a porphyritic texture with olivine macrocrysts set in a finer‐grained matrix of pigeonite and interstitial maskelynite, with minor augite, spinel, ilmenite, merrillite, pyrrhotite, pentlandite, and secondary (terrestrial) calcite and iron oxides. The bulk rock composition, in particular mg (68) [molar Mg/(Mg + Fe) x 100], Fe/Mn (37.9), and Na/Al (0.22), are characteristic of Martian meteorites. Based on mineral compositions, cooling rates determined from crystal morphology, and crystal size distribution, it is deduced that the parent magma formed in a steady‐state growth regime (magma chamber) that cooled at <°C/hr. Subsequent eruption as a thick lava flow or hypabyssal intrusion entrained a small fraction of xenocrystic olivine and gave rise to a magmatic foliation, with slow cooling allowing for near homogenization of igneous minerals. SaU 150 experienced an equilibration shock pressure of 33–45 GPa in a single impact event. Post‐shock heat gave rise to localized melting (?11 vol%). Larger volume melts remained fluid after pressure release and crystallized dendritic olivine and pyroxene with fractal dimensions of 1.80–1.89 and 1.89–1.95, respectively, at ‐ΔT >70–365 °C. SaU 150 is essentially identical to SaU 005/094, all representing samples of the same fall that are similar to, but distinct from, the DaG shergottites.  相似文献   

14.
Mesosiderites are breccias composed of roughly equal parts of metal phases and silicate clasts. However, the parent body and formation process of mesosiderites remain enigmatic. Northwest Africa (NWA) 12949 is a newly found mesosiderite belonging to type 2A. One type of ultramafic clasts and four types of mafic clasts (gabbroic, poikilitic, subophitic, and cataclastic), compositionally consistent with diogenites and eucrites, have been identified in NWA 12949. However, these clasts have undergone different thermal histories, with cooling rates varying from ~0.0044 °C year−1 to a few °C h−1, and equilibrium temperatures varying from ~880 to 910 °C to ~1000 to 1100 °C. All the lithic clasts have undergone redox reactions during extensive metamorphism, forming excess troilite, chromite, merrillite, tridymite, and pyroxene with lower Fe/Mg and Fe/Mn. The petrology and mineralogy of NWA 12949 support a formation scenario involving two major impact events, and a candidate parent body of 4 Vesta.  相似文献   

15.
The distribution of shock melts in four shergottites, having both vein and pocket geometry, has been defined and the conductive cooling time over the range 2500 °C to 900 °C calculated. Isolated 1 mm2 pockets cool in 1.17 s and cooling times increase with pocket area. An isolated vein 1 × 7 mm in Northwest Africa (NWA) 4797 cools to 900 °C in 4.5 s. Interference between thermal haloes of closely spaced shock melts decreases the thermal gradient, extending cooling times by a factor of 1.4 to 100. This is long enough to allow differential diffusion of Ar and Xe from the melt. Small pockets (1 mm2) lose 2.2% Ar and 5.2% Xe during cooling, resulting in a small change in the Ar/Xe ratio of the dissolved gas over that originally trapped. With longer cooling times there is significant fractionation of Xe from Ar and the Ar/Xe ratio increases rapidly. The largest pockets show less variation of Ar/Xe and likely preserve the original trapped gas composition. Considering all of the model calculations, even the smallest isolated pockets have cooling times greater than the duration of the pressure pulse, i.e., >0.01 s. The crystallization products of these shock melts will be unrelated to the peak shock pressure experienced by the meteorite.  相似文献   

16.
Some of the tridymite in the monomict Northwest Africa (NWA) 11591 eucrite are found to have sulfide‐rich replacement textures (SRTs) to varying degrees. The SRTs of tridymite in NWA 11591 are characterized by the distribution of loose porous regions with aggregates of quartz and minor troilite grains along the rims and fractures of the tridymite, and we propose a new mechanism for the origin of this texture. According to the volume and density conversion relationship, the quartz in the SRT of tridymite with a hackle fracture pattern was transformed from tridymite. We suggest that the primary tridymite grains are affected by the S‐rich vapors along the rims and fractures, leading to the transformation of tridymite into quartz. In addition, the S‐rich vapors reacted with Fe2+, which was transported from the relict tridymite and/or the adjacent Fe‐rich minerals, and/or the S‐rich vapors react with the exotic metallic Fe to form troilite grains. The sulfurization in NWA 11591 most likely occurred during the prolonged subsolidus thermal metamorphism in the shallow crust of Vesta and might be an open, relatively high temperature (>800 °C) process. Sulfur would be an important component of the metasomatic fluid on Vesta.  相似文献   

17.
Abstract— The microtextures of pigeonite in four ureilites, Allan Hills (ALH) 77257, Reckling Peak (RKP) A80239, Yamato (Y‐) 791538, and Allan Hills A81101, chosen to span a range of composition and shock level, were investigated by transmission electron microscopy (TEM); two of the samples were also investigated by single crystal X‐ray diffraction to determine Fe2+‐Mg cation site partitioning. The low‐shock and compositionally homogeneous pigeonites in ALHA77257 and RKPA80329 (Wo 6.4 for both, mg 86.3 and 84.3 respectively) display irregularly spaced, shock‐induced stacking faults oriented parallel to (100), and large antiphase domains (50–100 nm). Antiphase domains have no preferential orientation. No evidence of exsolution was observed. The low‐shock Y‐791538 pigeonite is homogeneous and has higher Ca and mg (Wo 9.4, mg 91.2). TEM investigation showed spinodal decomposition, indicative of incipient exsolution; small antiphase domains were observed (～5 nm). Single crystal refinement yielded R4s? = 5.71%, with Fe2+‐Mg partitioning coefficient kd = 0.077(8) and Tc = 658(35) °C. ALHA81101 has compositionally heterogeneous pyroxenes, with large local variations in Wo and mg (Wo = 4–13, mg = 86–68). No compositional gradients from core to rim of grains were observed, and the heterogeneity is interpreted as related to cation migration during shock. In one relatively Ca‐rich region (Wo～12), TEM analysis showed augite‐pigeonite exsolution lamellae, with spacing 145(20) nm. Results for ALHA77257, RKPA80239, and Y‐791538 support a model of rapid cooling following breakup of the ureilite parent body. The presence of exsolution lamellae in ALHA81101 can be related to a local shock‐induced Ca enrichment and provides no constraint on the late cooling history.  相似文献   

18.
Zinner and Göpel ( 1992 , 2002 ) found clear evidence for the former presence of 26Al in the H4 chondrites Ste. Marguerite and Forest Vale. They assumed that the 26Al‐26Mg systematics of these chondrites date “metamorphic cooling of the H4 parent body.” Plagioclase in these chondrites can have very high Al/Mg ratios and low Mg concentrations, making these ion probe analyses susceptible to ratio bias, which is inversely proportional to the number of counts of the denominator isotope (Ogliore et al. 2011 ). Zinner and Göpel ( 2002 ) used the mean of the ratios to calculate the isotope ratios, which exacerbates this problem. We analyzed the Al/Mg ratios and Mg isotopic compositions of plagioclase grains in thin sections of Ste. Marguerite, Forest Vale, Beaver Creek, and Sena to evaluate the possible influence of ratio bias on the published initial 26Al/27Al ratios for these meteorites. We calculated the isotope ratios using total counts, a less biased method of calculating isotope ratios. The results from our analyses are consistent with those from Zinner and Göpel ( 2002 ), indicating that ratio bias does not significantly affect 26Al‐26Mg results for plagioclase in these chondrites. Ste. Marguerite has a clear isochron with an initial 26Al/27Al ratio indicating that it cooled to below 450 °C 5.2 ± 0.2 Myr after CAIs. The isochrons for Forest Vale and Beaver Creek also show clear evidence that 26Al was alive when they cooled, but the initial 26Al/27Al ratios are not well constrained. Sena does not show evidence that 26Al was alive when it cooled to below the Al‐Mg closure temperature. Given that metallographic cooling rates for Ste. Marguerite, Forest Vale, and Beaver Creek are atypical (>5000 °C/Myr at 500 °C) compared with most H4s, including Sena, which have cooling rates of 10–50 °C/Myr at 500 °C (Scott et al. 2014 ), we conclude that the Al‐Mg systematics for Ste. Marguerite, Forest Vale, and Beaver Creek are the result of impact excavation of these chondrites and cooling at the surface of the parent body, instead of undisturbed cooling at depth in the H chondrite parent body, like many have assumed.  相似文献   

19.
Eucrites represent one of the major lithologies of the Vestan upper crust, which had experienced pervasive and intense thermal metamorphism. To better constrain the timing and mechanism of thermal metamorphism, we carried out in situ Pb‐isotope analysis of an unbrecciated basaltic eucrite NWA 6594 on the basis of detailed mineralogical and petrographic investigations. Zircon Pb‐Pb dating reveals that NWA 6594 emplaced before or at 4547 ± 11 Ma (95% confidence, MSWD = 1.3). Studies of silica minerals indicate that NWA 6594 had experienced intense thermal metamorphism after emplacement, followed by a late impact reheating and rapid cooling. Apatite grains yield a weighted mean Pb‐Pb age of 4523 ± 2 Ma (95% confidence, MSWD = 0.76). This age could not be attributed to slow cooling after the initial crystallization, but most likely related to an independent thermal event that induced thermal metamorphism. The protracted time lag (~24 ± 13 Myr) between zircon and apatite closure ages indicates that this thermal event is most probably induced by an intense impact event that was synchronous with the metal–silicate mixing event recorded by mesosiderites. HEDs may have experienced multiple stages of thermal metamorphism after emplacement. The late impact reheating occurred after thermal metamorphism, which caused crystallization of tridymite.  相似文献   

20.
Abstract— La Villa is an unshocked H4 chondrite. Chemical compositions require crystallization at temperatures >1250 °C for enstatite and >1211 °C for augite. Widespread (100) polysynthetic twins and (001) contraction cracks in enstatite indicate crystallization as protoenstatite, inverted to either ortho‐ or clinoenstatite or both on cooling. High‐resolution transmission electron microscopy shows a range of ortho‐clinoenstatite intergrowths: heavily faulted clinoenstatite in radial and poikilitic chondrules, almost regular orthoenstatite in a microgranular chondrule and in the matrix. In the former, the clinoenstatite lamellae are both even or odd multiples of the 9Å periodicity, a few unit cells thick, twinned and interleaved with minor orthoenstatite. In the latter, orthoenstatite lamellae are regularly stacked for more than 2000 Å. Localized annealing effects, reversing clinoenstatite to orthoenstatite, are revealed by “U‐shaped” and “Z‐shaped” terminations. The variable microstructures suggest different cooling rates for the different chondrule types, soon after the liquidus‐to‐solidus transition (1200 to 1300 °C) but prior to accretion. In particular, clinoenstatite‐rich crystals from radial and poikilitic chondrules give cooling rates on the order of 100 and 10 °C/h. Comparisons with previous works on dynamic crystallization experiments and orthopyroxene Fe‐Mg cation ordering indicate a nonlinear cooling path from the high chondrule formation temperatures to a postaccretionary low‐temperature (340–480 °C) evolution.  相似文献   

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