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1.
The reactions of alkoxy radicals determine to a large extent the products formed during the atmospheric degradations of emitted organic compounds. Experimental data concerning the decompositions, 1,5-H shift isomerizations and reactions with O2 of several classes of alkoxy radicals are inconsistent with literature estimations of their absolute or relative rate constants. An alternative, although empirical, method for assessing the relative importance under atmospheric conditions of the reactions of alkoxy radicals with O2 versus decomposition was derived. This estimation method utilizes the differences in the heats of reaction, (H)=(Hdecomposition–HO 2 reaction), between these two reactions pathways. For (H)[22–0.5(HO 2 reaction)], alkoxy radical decomposition dominates over the reaction with O2 at room temperature and atmospheric pressure of air, while for (H)[25-0.5(HO 2 reaction)], the O2 reaction dominates over decomposition (where the units of H are in kcal mol–1). The utility and shortcomings of this approach are discussed. It is concluded that further studies concerning the reactions of alkoxy radicals are needed.  相似文献   

2.
The paper considers a puff diffusion in its inertial stage when particle separation obeys the laws of the inertial subrange and depends only on eddy energy dissipation rate . The can be determined in the surface layer by the turbulent kinetic energy equation. Similarity equations connect with diffusion measure .A simple analytical model has been deduced to estimate pollutants diffusion during calms.  相似文献   

3.
This paper considers the near-field dispersion of an ensemble of tracer particles released instantaneously from an elevated source into an adiabatic surface layer. By modelling the Lagrangian vertical velocity as a Markov process which obeys the Langevin equation, we show analytically that the mean vertical drift velocity w(t) is w()=bu *(1–e –(1+)), where is time since release (nondimensionalized with the Lagrangian time scale at the source), b Batchelor's constant, and u *, the friction velocity. Hence, the mean height and mean depth of the ensemble are calculated. Although the derivation is formally valid only when 1, the predictions for w, mean height and mean depth are consistent in the downstream limit ( 1) with surface-layer Lagrangian similarity theory and with the diffusion equation. By comparing the analytical predictions with numerical, randomflight solutions of the Langevin equation, the analytical predictions are shown to be good approximations at all times, both near-field and far-field.  相似文献   

4.
We formulate a method for determining the smallest time interval Tover which a turbulence time series can be averaged to decompose it intoinstantaneous mean and random components. From the random part the method defines the optimal interval (or averaging window) AW over which this part should be averaged to obtain the instantaneous spectrum. Both T and AW vary randomly with time and depend on physical properties of the turbulence. T also depends on the accuracy of the measurements and is thus independent of AW. Interesting features of the method are its real-time capability and the non-equality between AW and T.  相似文献   

5.
Horizontal diffusion in the surface layer is dependent on the standard deviation of wind direction fluctuations . Diurnal variation of this parameter in complex terrain was studied for the July 1979 Geysers, Cal., experiment using data from a network of 11 short meteorological towers in the 25 km2 Anderson Creek watershed Valley side slopes are roughly 20 ° and maximum terrain difference is about 1 km.Values of for wind directions sampled for one hour at a height of 10 m are about 35 ° during the daytime. They slowly decrease to about 20 ° by 8 to 10 p.m. as stability increases but wind speeds are still relatively high. After 10 p.m. the drainage flow sets in at most stations, with speeds of 1 to 2 m s-1, and average increases to about 30° during the period 11 p.m. to 6 a.m. In general, highest values of at night are associated with lowest values of wind speed and greatest static stability. This enhancement of by the terrain suggests that horizontal diffusion at night always conforms to that expected during nearly neutral stabilities. That is, Pasquill class D diffusion applies to the horizontal component all night in complex terrain.  相似文献   

6.
Mesoscale nocturnal jetlike winds have been observed over a flat, open coast. They occur within the planetary boundary layer between 100 and 600 m. At times the wind shear may reach 15 m s-1 per 100 m. Unlike the common low-level jet that occurs most often at the top of the nocturnal inversion and only with a wind from the southerly quadrant, this second kind of jet exists between nocturnal ground-based inversion layers formed by the cool pool, or mesohigh, and the elevated mesoscale inversion layer over the coast. It occurs mostly when light % MathType!MTEF!2!1!+-% feaafiart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr% 4rNCHbGeaGqiVu0Je9sqqrpepC0xbbL8F4rqqrFfpeea0xe9Lq-Jc9% vqaqpepm0xbba9pwe9Q8fs0-yqaqpepae9pg0FirpepeKkFr0xfr-x% fr-xb9adbaqaaeGaciGaaiaabeqaamaabaabaaGcbaGaaiikaiabgs% MiJkaaiwdacqGHsislcaaI2aGaaeyBaiaabccacaqGZbWaaWbaaSqa% beaacqGHsislcaaIXaaaaOGaaiykaaaa!3FCF!\[( \leqslant 5 - 6{\text{m s}}^{ - 1} )\] geostrophic winds blow from land to sea and when the air temperature over adjacent seas is more than 5 °C warmer than that over the coast. This phenomenon may be explained by combined Venturi and gravity-wind effects existing in a region from just above the area a few kilometres offshore to 100–600 m in height approximately 40–50 km inland because this region is sandwiched between the aforementioned two inversion layers.  相似文献   

7.
Increasing reliance on natural gas (methane) to meet global energy demands holds implications for atmospheric CO2 concentrations. Analysis of these implications is presented, based on a logistic substitution model viewing energy technologies like biological species invading an econiche and substituting in case of superiority for existing species. This model suggests gas will become the dominant energy source and remain so for 50 years, peaking near 70 percent of world supply. Two scenarios of energy demand are explored, one holding per capita consumption at current levels, the second raising the global average in the year 2100 to the current U.S. level. In the first (efficiency) scenario concentrations peak about 450 ppm, while in the second (long wave) they near 600 ppm. Although projected CO2 concentrations in a methane economy are low in relation to other scenarios, the projections confirm that global climate warming is likely to be a major planetary concern throughout the twenty-first century. A second finding is that data on past growth of world per capita energy consumption group neatly into two pulses consistent with longwave theories in economics.  相似文献   

8.
E- turbulence model predictions of the neutralatmospheric boundary layer (NABL) are reinvestigated to determine thecause for turbulence overpredictions found in previous applications. Analytical solutions to the coupled E and equations for the case of steady balance between transport and dissipation terms, the dominant balance just below the NABL top, are derived. It is found that analytical turbulence profiles laminarizeat a finite height only for values of closure parameter ratio c 2 /e equal toor slightly greater than one, with laminarization as z for greater . The point = 2 is additionally foundthat where analytical turbulent length scale (l) profilesmade a transition from ones ofdecreasing ( < 2) to increasing ( > 2)values with height. Numerically predicted profiles near the NABL topare consistent with analytical findings. The height-increasingvalues of l predicted throughout the NABL with standard values ofclosure parameters thus appear a consequence of 2.5(> 2), implied by these values (c 2 = 1.92, = 1.3, e = 1). Comparison of numericalpredictions with DNS data shows that turbulence overpredictions obtained with standard-valued parameters are rectifiedby resetting and e to 1.1 and 1.6, respectively, giving, with c 2 = 1.92, 1.3, and laminarization of the NABL's cappingtransport-dissipation region at a finite height.  相似文献   

9.
Jackson and Hunt's (1975) equation for the depth of the inner layer of flows over low hills does not depend on any closure assumption as contrarily supposed in literature. This equation contains a constant which can arbitrarily be specified. It is suggested that this inner-layer constant should be determined from experimental data. A preliminary check with some data from the Askervein experiment suggests that Jackson and Hunt's equation fits these data almost as well as Jensen's equation provided that fitted inner-layer constants are used.  相似文献   

10.
Turbulence measurements from a 30 m tower in the stably stratifiedboundary layer over the Greenland ice sheet are analyzed. The observationsinclude profile and eddy-correlation measurements at various levels. Atfirst, the analysis of the turbulence data from the lowest level (2 m aboveground) shows that the linear form of the non-dimensional wind profile(m) is in good agreement with the observations for z/L <0.4, whereL represents the Obukhov length. A linear regression yieldsm=1+5.8z/L. The non-dimensional temperature profile (h) at the2m level shows no tendency to increase with increasing stability. The datafrom the upper levels of the tower are analyzed in terms of both localscaling and surface-layer scaling. The m and the h values show atendency to level off at large stability (z/>0.4) where represents the local Obukhov length. Hence, the linear form of the functions is no longer appropriate under such conditions. The bestcorrespondence to the data can be achieved when using the expression ofBeljaars and Holtslag for m and h. The vertical profiles of theturbulent fluxes, the wind velocity variances and temperature variance arealso determined. The momentum flux profile and the profiles of wind speedvariances are in general agreement with other observations if a welldeveloped low-level wind maximum occurs, and the height of this maximum isused as a height scale.  相似文献   

11.
The paper describes various aspects of the wind regime in coastal areas as obtained from several experimental programs along the Baltic coast of Sweden. The studies include the change with distance inland of mean wind structure as well as the turbulence structure in various conditions. It is found that wind spectra are usually well described by local similarity in its high frequency part, even in complex terrain. The low frequency parts of the spectra show clear spectral lag effects. The effects of a small slope, ca 5 m height change over 300 m travel distance, is clearly seen in some spectra, and it is shown that current flow over a hill theory can be used to account for it. The change of mean wind speed throughout the entire boundary layer as the wind passes a low but wooded island (Gotland), ca 30 km wide, has been studied in a series of relatively strong wind, near neutral cases. Some unexpected features are found; in particular the wind speed decreases more rapidly with distance inland than predicted by current numerical models. Two cases with a low level jet are discussed in some detail. Arguments are presented for the phenomenon to be caused by frictional decoupling at the Latvian coast, about 200 km upwind — the jet being thus an analogy in space to the classical Blackadar nocturnal jet frequently observed in continental areas.  相似文献   

12.
Equilibrium evaporation beneath a growing convective boundary layer   总被引：1，自引：1，他引：0  
Expressions for the equilibrium surface Bowen ratio ( s ) and equilibrium evaporation are derived for a growing convective boundary layer (CBL) in terms of the Bowen ratio at the top of the mixed layer i and the entrainment parameter A R . If AR is put equal to zero, the solution for s becomes-that previously obtained for the zero entrainment or closed box model. The Priestley-Taylor parameter is also calculated and plotted in terms ofA R and i . Realistic combinations of the atmospheric parameters give values of in the range 1.1 to 1.4.  相似文献   

13.
The structure of atmospheric turbulence in the surface layer over the open ocean is examined under conditions of local free convection. The raw data consist of profile and fluctuation measurements of wind and temperature as obtained from a meteorological buoy. For near neutral conditions and for waves running approximately along the wind direction, wave-induced wind fluctuations can be described by a simplified linear theory based on Miles (1957). In this case, the spectrum of wind velocity is given as the sum of two parts; for the turbulent part, the parameterization as obtained by Kaimal et al. (1972) applies, while the wave-induced part is parameterized using a simplification of Miles' linear theory. For cases of local free convection, the measurements of the vertical component of the wind velocity are well described by similarity theory; as expected, w /(-uw)1/2 is proportional to (- z/L)1/3. In order to scale the longitudinal wind velocity component, it seems to be reasonable to extend the list of relevant parameters by the height of the mixed layer z i. We obtain u /(- uw)1/2 (z/z i)1/3(- z/L)1/3 with only a poor correlation coefficient of r = 0.6. Overall, the results of local free convection scaling obtained from direct measurements show good agreement with those obtained from profile measurements. A comparison between direct and indirect determination of turbulent fluxes of momentum shows an unexplained difference of about 20%. This discrepancy is mainly due to a gap in the uw-cospectrum at the swell frequency.  相似文献   

14.
A numerical case study with a second-order turbulence closure model is proposed to study the role of urban canopy layer (UCL) for the formation of the nocturnal urban boundary layer (UBL). The turbulent diffusion coefficient was determined from an algebraic stress model. The concept of urban building surface area density is proposed to represent the UCL. Calculated results were also compared with field observation data. The height of the elevated inversion above an urban center was simulated and found to be approximately twice the average building height. The turbulent kinetic energy k, energy dissipation rate , and turbulence intensities u 2 and w 2 increase rapidly at the upwind edge of the urban area. The Reynolds stress uw displayed a nearly uniform profile inside the UBL, and the vertical sensible heat flux w had a negative value at the inversion base height. This indicates that the downward transport of sensible heat from the inversion base may play an important role in the formation of the nocturnal UBL.  相似文献   

15.
The influence of the main large-scale wind directions on thermally driven mesoscale circulations at the Baltic southwest coast, southeast of Sweden, is examined. The aim of the study is to highlight small-scale alterations in the coastal atmospheric boundary layer. A numerical three-dimensional mesoscale model is used in this study, which is focused on an overall behaviour of the coastal jets, drainage flows, sea breezes, and a low-level eddy-type flow in particular. It is shown that synoptic conditions, together with the moderate terrain of the southeast of Sweden (max. height h0 206 m), governs the coastal mesoscale dynamics triggered by the land-sea temperature difference T. The subtle nature of coastal low-level jets and sea breezes is revealed; their patterns are dictated by the interplay between synoptic airflow, coastline orientation, and T.The simulations show that coastal jets typically occur during nighttime and vary in height, intensity and position with respect to the coast; they interact with downslope flows and the background wind. For the assigned land surface temperature (varying ±8 K from the sea temperature) and the opposing constant geostrophic wind 8 m s-1, the drainage flow is more robust to the opposing ambient flow than the sea breeze later on. Depending on the part of the coast under consideration, and the prevailing ambient wind, the sea breeze can be suppressed or enhanced, stationary at the coast or rapidly penetrating inland, locked up in phase with another dynamic system or almost independently self-evolving. A low-level eddy structure is analyzed. It is governed by tilting, divergence and horizontal advection terms. The horizontal extent of the coastal effects agrees roughly with the Rossby radius of deformation.  相似文献   

16.
In this paper we analyse diabatic wind profiles observed at the 213 m meteorological tower at Cabauw, the Netherlands. It is shown that the wind speed profiles agree with the well-known similarity functions of the atmospheric surface layer, when we substitute an effective roughness length. For very unstable conditions, the agreement is good up to at least 200 m or z/L–7(z is height, L is Obukhov length scale). For stable conditions, the agreement is good up to z/L1. For stronger stability, a semi-empirical extension is given of the log-linear profile, which gives acceptable estimates up to ~ 100 m. A scheme is used for the derivation of the Obukhov length scale from single wind speed, total cloud cover and air temperature. With the latter scheme and the similarity functions, wind speed profiles can be estimated from near-surface weather data only. The results for wind speed depend on height and stability. Up to 80 m, the rms difference with observations is on average 1.1 m s–1. At 200 m, 0.8 m s–1 for very unstable conditions increasing to 2.1 m s–1 for very stable conditions. The proposed methods simulate the diurnal variation of the 80 m wind speed very well. Also the simulated frequency distribution of the 80 m wind speed agrees well with the observed one. It is concluded that the proposed methods are applicable up to at least 100 m in generally level terrain.  相似文献   

17.
Measurements of the appropriate parameters for the calculation of the latent heat flux over a black spruce forest in northern Quebec were carried out in August, 1980. Values of the Priestley-Taylor parameter, , were derived by exploiting the Bowen-ratio-energy-balance (BREB) technique. Derived values of are then related to synoptic-scale warm air advection, derived from surface synoptic charts and tephigrams of the planetary boundary layer. It is found that when warm air advection is present, > 1.26, especially when the surface is wet. When advection enhancement is removed, however, values of approach unity. A new approach to calculating the latent heat flux, when warm air advection is present, is therefore proposed.  相似文献   

18.
Neutral surface layer flow over low hills and varying surface roughness is considered with emphasis on closure schemes in relation to the prediction of turbulence quantities. The equations are linearised, Fourier transformed in the two horizontal directions and solved by means of a finite difference method in the vertical. Three closure schemes are. employed, namely mixing length, E- and e-- closure where E, and indicate that differential equations are used for turbulent kinetic energy, dissipation rate and shear stress. Model calculations are compared with experimental data for the step in roughness problem and for the Askervein hill. The mean flow results turn out to be relatively insensitive to the closure scheme. The shear stress and the dimensionless shear, however, are much better predicted with the E- equations than with mixing length closure. In the outer layer of the hill problem, advection of shear stress becomes important. An equation for is needed here.  相似文献   

19.
Observations have been made of the structure of turbulence and turbulent exchange within plant canopy layers. A new three-dimensional anemometer was used to measure the eddy fluxes of heat and momentum, and the related cospectra, within and above a corn crop and above a red pine forest. Measured values of momentum and heat fluxes, at each height within the corn canopy, were relatively constant proportions of the flux above the canopy, for the period of a day's observation. Extensive regions obeying a –5/3 power relation were found. Isotropy was found above the forest at high frequencies while above and within the corn crop, the ratios of the lateral and vertical spectral densities to the longitudinal component were less than the expected value in the – 5/3 region. In all situations, the vertical velocity spectra were more peaked than a universal curve, particularly a vertical velocity spectrum from above the forest. It is suggested that the additional variance results from the mixing caused by the individual roughness elements. As expected, the spectra could not be normalized using the height above the soil surface to calculate a non-dimensional frequency, but scaling heights were estimated by matching the frequencies of the peak of each curve with that of the universal curve. Cospectra of uw and wT within the corn canopy were of similar shape and frequency regime, and were basically similar in shape to cospectra above the crop. All of the cospectra were more sharply peaked than universal cospectral curves.  相似文献   

20.
Measurements in the atmospheric surface layer of sixth-order velocity structure functions and of sixth-order mixed velocity-temperature structure functions support values of and previously obtained in the laboratory at moderate turbulence Reynolds numbers.  相似文献   

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