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1.
傅里叶变换拉曼探针测定九种气体的定量因子 总被引：2，自引：0，他引：2
采用傅里叶变换拉曼探针测定出９种与地球化学有关的气体拉曼定量因子;Ｈ２２．２５,ＳＯ２１．０６,ＣＯ２１．１３,Ｏ２０．９１,ＣＯ０．８７,Ｎ２１．００,Ｈ２Ｓ３．１１,ＣＨ４８．４２,Ｃ２Ｈ６３．３０。 相似文献
2.
《Geochimica et cosmochimica acta》1994,58(1):365-375
The hydrogen isotopic measurement (δD) of the non-exchangeable hydrogens in herbivore bone collagen has potential for paleoclimate research. We have developed the methodology for extracting the hydrogen from collagen for isotopic analysis and for correcting the δD results for hydrogen exchange. Preparations of whole bone powders, demineralized bone, or gelatin extracts from fresh bone samples all give reliable δD results and have isotopic results, yields, and proportions of exchangeable hydrogens consistent with that expected for collagen. Gelatin extraction for removal of contaminants remains a valuable option for the study of fossil bone samples.Vacuum preheating under good vacuum at 150°C for two days for whole bone powders and at 100°C for one day for gelatins is an important step to remove all adsorbed water before samples are oxidized for isotopic analysis. Of the remaining hydrogens released following oxidation, 20.5% in whole bone powders and 23.1% in gelatin extracts exchange with laboratory atmospheric water vapor within 48 hours. The δD results can be corrected for this exchange and for minor effects of sample preparation by using a calibration bone standard to determine the δD value of laboratory water vapor. 相似文献
3.
《International Geology Review》2012,54(4):425-432
A review of the various geophysical methods used in prospecting for various mineral deposits, and recommendations for the improvement of known methods and the need for more precision. Methods of prospecting for various metals are discussed as well as means for raising their effective ness in exploration for ore deposits. The need for close cooperation between qualified members of geophysical departments and members of exploration organizations and the geophysical engineer is stressed.- -C. E. Sears, Jr. 相似文献
4.
针对川东北地区通南巴构造带海相碳酸盐岩储层的双孔特征,基于嘉二段、飞三段取芯及测试资料,利用岩心刻度测井的方法,确定储层下限参数,建立适合川东北地区通南巴构造带及邻近地区海相碳酸盐岩储层参数计算模型与评价标准.结果表明:川东北地区通南巴构造带碳酸盐岩储层下限值标准为孔隙度1.6%,裂缝孔隙度0.05%,含气饱和度50%.该成果为川东北地区通南巴构造带海相碳酸盐岩气藏内部参数分布描述与最终形成气藏三维数据体提供了可靠的资料,在实际生产中取得了良好的应用效果,为油田进一步勘探、开发和增产措施提供可靠的依据. 相似文献
5.
应用多光谱ASTER数据对ETM遥感异常的定性判别研究——以东昆仑五龙沟为例 总被引：5，自引：0，他引：5
文中讨论了新的找矿参数——蚀变遥感异常的地质基础和光谱前提,在矿床地质学和蚀变矿物光谱参数特征的基础上,编制了一张用于遥感异常提取及对其地质解释的表格。ETM遥感异常提取技术已在全国推广,ASTER数据可以在三个方面对已推广的ETM起到重要的补充作用：1.利用短波红外增设的波段,对某些矿致异常区分其矿化（矿床）类型;2.利用增设的热红外波段区分某些岩性;3.可有助于解决ETM因第7波段太宽而产生的许多疑难问题。本文以东昆仑五龙沟为例讨论了ASTER对于解决ETM遥感异常性质判别困难方面的作用。 相似文献
6.
Kyungik Gil Haeyeon Rho Daeik Kim Michael K. Stenstrom 《Environmental Earth Sciences》2012,65(3):929-936
The Modified Bio-P module was evaluated in terms of the kinetic rate expression and engineering parameters, comparing the
measured data of full-scale plant with simulated data. To simulate step-feed BNR (Biological Nutrient Removal), the ASM3 (Activated
Sludge Model 3) with the EAWAG Bio-P Module (The Swiss Federal Institute for Environmental Science and Technology) and the
ASM3+Modified Bio-P module were used. The RMSEs (root mean square error) of the T-N (total nitrogen) concentration of the
effluent levels of measured and simulated examples were 2.29 for ASM3+Bio-P and 1.28 for ASM3+Modified Bio-P. In the case
of T-P (total phosphorus), the RMSEs were 0.28 for ASM3+Bio-P and 0.25 for ASM3+Modified Bio-P. The annual removal rates for
T-N were 0.77 for the measured, 0.69 for the Bio-P, and 0.74 for the Modified Bio-P samples, while the annual removal rates
for T-P were 0.64 for the measured, 0.72 for the Bio-P, and 0.60 for the Modified Bio-P cases. With simulated data, the Modified
Bio-P model was a better fit for the field data compared to Bio-P. The Modified Bio-P module reproduced the step-feed process
more effectively than the Bio-P module. 相似文献
7.
8.
T. M. Rachkovskaya 《Astronomy Reports》2000,44(4):227-234
Using high-resolution spectra, we have determined the abundances of carbon (logε(C)), nitrogen (logε(N)), oxygen (logε(O)), silicon (logε(Si)), sulphur (logε(S)), and some other elements for three δ Scuti stars. Logε(C) for all three stars and logε(N) for δ Sct and HD 127986 are close to the solar values, while there appears to be a slight (0.15 dex) nitrogen deficiency for 14 Aur. The logε(O) values correspond to a 0.30-dex deficiency for 14 Aur and δ Sct and a 0.20-dex deficiency for HD 127986. The values of logε(Si) for the three stars are close to solar, and the logε(S) values indicate a slight deficiency (0.10 dex) for 14 Aur and HD 127986 and a 0.20-dex excess for δ Sct. Comparison of the elemental abundances for seven δ Scuti stars with those for Am stars shows that the mean deficiencies of C, N, and O are smaller for pulsating δ Scuti stars than for Am stars with similar effective temperatures. The sulphur abundances are virtually the same for both types of stars. 相似文献
9.
This paper sets forth the theoretical background and basic numerical expressions for the incorporation of elastic-plastic constitutive equations for ductile rock into a finite element computer code. The derivation of an expression for the total strain rate is performed both for a total stress formulation and for a formulation that employs the concept of effective stress for inelastic behaviour. Specific expressions for the incremental strain rate are presented for the case of a porous material having a quadratic initial yield surface and observing the associated flow rule with a special hardening law for subsequent plastic deformation. A final section of the paper summarizes the expressions required to insert the quadratic yield surface model into a finite element code. 相似文献
10.
X射线荧光光谱法测定土壤样品中碳氮硫氯等31种组分 总被引：3，自引：3，他引：3
利用新型的ZSX Primus Ⅱ型X射线荧光光谱仪采用粉末压片法直接测定土壤样品中的C、N、S、Cl等31种元素。各元素分析晶体为N采用RX45，C采用RX61，Na、Mg采用RX25，C1、S、P采用Ge，Si、Al采用PET，其余元素均采用LiF200。结果表明，方法的检出限、精密度和准确度对绝大多数元素而言，均可满足多目标地球化学调查样品分析的质量要求： 相似文献
11.
松辽盆地白垩系营城组埋藏火山机构岩相定量模型及储层流动单元特征 总被引：7，自引：1，他引：6
松辽盆地营城组火山机构类型划分为碎屑岩火山机构、熔岩火山机构和复合火山机构3种。碎屑岩火山机构中火山通道相占9.3%,爆发相占55.3%,喷溢相占29.2%,侵出相占1.4%,火山沉积相占4.8%;火山机构半径为0.5～1.5 km,高度为50～220 m。熔岩火山机构中火山通道相占8.1%,爆发相占23.4%,喷溢相占62.6%,侵出相占5.1%,火山沉积相占0.8%;火山机构半径为1～2 km,高度为200～300 m。复合火山机构中火山通道相占4.9%,爆发相占34.4%,喷溢相占56.8%,侵出相占2.6%,火山沉积相占1.3%;火山机构半径为2～4 km,厚度为300～450 m。亚相控制储层流动单元的规模,碎屑岩火山机构的储层流动单元范围为0.3～1.5 km,厚度小于60 m。熔岩火山机构的储层流动单元范围为1～2 km,厚度小于80 m。复合火山机构的储层流动单元范围为1.5～3.0 km,厚度小于100 m。各类火山机构气藏开发时的井距和压裂方案均存在差异。 相似文献
12.
等离子体质谱法直接测定地球化学样品中金铂钯 总被引：19，自引：0，他引：19
建立了王水分解地球化学样品报直接用等离子体质谱法测定Au、Pd和Pt的分析方法。方法测定下限为Au4,0ng/g,Pd3.6ng/g,Pt2.4ng/g，方法精密度（RSD，n=12）为Au14.2%,Pd3.6%-5.2%,Pt6.6%-10.8%，三个元素的线性范围都为0.02-300μg/L。采用文中制定的分析方法直接测定了国家一级地球化学标准物质中的Au、Pd、Pt，在测定下限以上的测定结果与标准值吻合。 相似文献
13.
电感耦合等离子体质谱法同时测定地下水中硼溴碘 总被引：6，自引：4，他引：2
建立了电感耦合等离子体质谱法同时测定地下水中B、Br、I的方法。选定φ=2%(体积分数)的稀NH3.H2O介质消除碘的记忆效应。采用干扰较少的10B和79Br同位素。B、Br、I在0~10 000 ng/mL呈良好的线性关系。方法的检出限为10B 0.176 ng/mL,79Br 0.876ng/mL,127I 0.132 ng/mL;精密度(RSD,n=12)为10B 2.86%,79Br 3.36%,127I 2.69%;10B的阶梯加标回收率为94.6%~101.5%,79Br为98.3%~104.9%,127I为96.5%~102.0%。 相似文献
14.
初论地质异常数字找矿模型 总被引：5，自引：0，他引：5
数字找矿模型是实施数字找矿工程的强有力工具.根据地质异常致矿原理初步论述了数字找矿模型的理论基础; 地质、地球化学、地球物理和遥感信息的特征及其找矿功能; 致矿信息提取、关联、转换与综合以及地质异常数字找矿模型的建立方法.事实上致矿信息提取与综合的过程亦是数字找矿模型建立的过程. 相似文献
15.
H. Cynn A. M. Hofmeister P. C. Burnley A. Navrotsky 《Physics and Chemistry of Minerals》1996,23(6):361-376
Infrared absorption measurements were taken from 100 to 5000 cm?1 of a natural chondrodite and three dense hydrous magnesium silicates: phase A, phase B, and superhydrous phase B (shy-B). Raman spectra were also acquired from phase B and the chondrodite. Roughly half of the lattice modes are represented and our data are the first report of the low frequency modes. Comparison of our new spectra to symmetry analyses suggests that multiple sites for hydrogen exist for all the phases. The shy-B we examined crystallizes in P21 nm with two OH sites. Models for the density of states are constructed based on band assignments for the lattice modes and for the OH stretching vibrations. Heat capacity CP and entropy S calculated using Kieffer's formulation should be accurate within 3% from 200 to 800 K. Model values for CP at 298 K are 299.6 J/mol-K for chondrodite, 421.5 J/mol-K for phase A, 529.4 J/mol-K for shy-B, and 618.9 J/mol-K for phase B. Model values for S298 0 are 234.2 J/mol-K for chondrodite, 303.5 J/ mol-K for phase A, 377.9 J/mol-K for shy-B, and 473.3 J/mol-K for phase B. Debye temperatures are near 1000 K. 相似文献
16.
The first minting of Digital Object Identifiers (DOI) for research data happened in 2004 in the context of the project “Publication and citation of primary scientific data” (STD-DOI). Some of the concepts and perceptions about DOI for data today have their roots in the way this project implemented DOI for research data and the decisions made in those early days still shape the discussion about the use of persistent identifiers for research data today. This project also laid the foundation for a tighter integration of journal publications and data. Promoted by early adopters, such as PANGAEA, DOI registration for data has reached a high level of maturity and has become an integral part of scientific publishing. This paper discusses the fundamental concepts applied in the identification of DOI for research data and how these can be interpreted for alternative and future applications of persistent identifiers for research data. 相似文献
17.
Concentrations of chalcophile elements (As, Co, Cu, Hg, Mo, Ni, Pb, Sb and Zn) in western Canadian coals were determined using INAA and AAS. The concentrations of these elements in western Canadian coals are within the range for most world coals. However, there are some high values for coals from outcrops and from areas which are not currently being mined.Arsenic content in the majority of western Canadian coals, particularly those currently being mined, is low (0.2–3 ppm). However, there are coals with high arsenic content; for example, lignites from Hat Creek A zone contain between 4.0 and 14.0 ppm As. In some samples from Comox and Suquash, the As concentration is as high as 240 ppm and 1400 ppm, respectively. The enrichment of As in high arsenic coals is related to the geology and nature of country rocks associated with the coal seams. The concentration of other elements for most western Canadian coals, particularly those being mined, are within the range for most world coals. In these coals, the concentration ranges (in ppm) of chalcophile elements are 0.3-3.6 for Sb, 0.8-4.6 for Co, 7–35 for Cu, <0.1 for Hg, 2–6 for Mo, 4–94 for Ni, 6–22 for Pb, 2–7 for Se and 7–110 for Zn. 相似文献
18.
Niels Schütze Sebastian Kloss Franz Lennartz Ahmed Al Bakri Gerd H. Schmitz 《Environmental Earth Sciences》2012,65(5):1511-1521
In this contribution, we introduce a stochastic framework for decision support for optimal planning and operation of water
supply in irrigation. This consists of (1) a weather generator for simulating regional impacts of climate change on the basis
of IPCC scenarios, (2) a tailor-made evolutionary optimization algorithm for optimal irrigation scheduling with limited water
supply, (3) a mechanistic model for simulating water transport and crop growth in a sound manner, and (4) a kernel density
estimator for estimating stochastic productivity, profit, and demand functions by a nonparametric method. As a result of several
simulation/optimization runs within the framework, we present stochastic crop-water production functions (SCWPF) for different
crops which can be used as a basic tool for assessing the impact of climate variability on the risk for the potential yield
for specific crops and specific agricultural areas. A case study for an agricultural area in the Al Batinah region of the
Sultanate of Oman is used to illustrate these methodologies. In addition, microeconomic impacts of climate change and the
vulnerability of the agro-ecological system are discussed. 相似文献
19.
The influence of salts in the pore water in freezing soils is examined from the experimental viewpoint, using the differential scanning calorimetry technique for generation of multiple endotherms of the frozen test samples. The experimental values obtained for montmorillonite, kaolinite and grundite, are evaluated in terms of unfrozen water contents for the respective soils at various subfreezing temperatures for various concentrations of NaCl. Comparison of experimental values with theoretical predictions using a combined salt exclusion and diffuse double-layer model shows excellent quantitative agreement for the montmorillonite soil samples, but only qualitative agreement for the kaolinite and grundite soils. The reasons for this lie in the theoretical model requirement for interlamellar migration of water in soil freezing for suitable application of the diffuse double-layer part of the model. 相似文献
20.
项目国家审计是一种执法监督活动,设计方满足审计要求是必不可少的义务和职责。通过铁路建设项目国家审计,初步分析国家审计对设计方要求,提出设计方满足项目国家审计要求的措施,为设计方适应国家投资市场规则及其变化趋势,规避设计风险,拓展设计方生存空间提供思路。 相似文献