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1.
The Cenozoic volcanic rocks of the southern Andes are characterized by low 87Sr/86Sr ratios (0.7040–0.7045), which are consistent with an origin in the downgoing slab of oceanic lithosphere or the overlying mantle. These values are distinctly lower than those from corresponding rocks of the central Andes.The calc-alkaline rocks of the central Andes exhibit higher Sr isotopic values (0.705–0.713) and variable Rb/Sr ratios. Different explanations are possible for this behaviour as well as for the positive correlation between 87Sr/86Sr and Rb/Sr expressed in an apparent isochron of 380 ± 50 m.y. It is postulated that these magmas result from a mixing process between a primary magma with basaltic affinities and crustal material of relatively young age.A model is proposed for the generation of the “andesitic” magmas of the central Andes by which crustal rocks of the upper part of the crust are added to the base of the crust by an accretionary process at the margin of the continent. Melts from these upper crustal rocks act as contaminants in “andesitic” magmas.The role of crustal material is still more significant in the generation of the ignimbritic magmas; they are considered to result from a two-stage melting process by which igneous rocks, belonging to a former stage of development of the Andes, are engulfed in the subduction zone, where they melt.  相似文献   

2.
Oxygen isotope data are reported for 27 igneous rocks of Mesozoic to Quaternary age from the Central Andes. 26–29°S. The plutonic rocks, and most of the volcanics, have δ18O values between 6.2 and 8.3‰.The whole-rock δ18O values show a weak correlation with initial87Sr/86Sr data. This O-Sr array differs from documented trends for calc-alkaline plutonic suites from California, Scotland and northern Italy, but overlaps with data for volcanic and plutonic rocks from Ecuador, northern Chile and southern Perú.The oxygen isotope results indicate that the magmas evolved without significant contamination from supracrustal rocks (e.g., rocks that experienced18O enrichment during surficial weathering). The available O, Sr and Pb isotopic data for these rocks are best explained by magma generation in the upper mantle or lower crust. From the Late Mesozoic on, the87Sr/86Sr values were modified at depth by isotopic exchange between the magma and a continually thickening crust of plutonic rocks of Late Precambrian to early Mesozoic age.  相似文献   

3.
Initial87Sr/86Sr ratios have been determined for a representative suite of Upper Cretaceous granodiorites and associated rocks from the Above Rocks composite stock in central Jamaica and the Terre-Neuve pluton in northwestern Haiti. The average initial87Sr/86Sr ratio for severn samples of the Terre-Neuve intrusion is 0.7036, with a range of 0.7026–0.7047. For two samples of the Above Rocks the initial ratios are 0.7033 and 0.7034. A third sample from this intrusive has an initial ratio of 0.7084, which is tenatively attributed to contamination. The initial87Sr/86Sr ratios indicate that neither ancient sialic crust nor sediments carried down a Benioff zone can be the primary source of the granodioritic magma. K/Rb ratios for these rocks range from 178 to 247, which are much lower than the average values (≥1000) for tholeiitic basalts. It is concluded that the magmas originated primarily by melting of downthrust oceanic crust or adjacent mantle material.  相似文献   

4.
18O/16O and 87Sr/86Sr ratios were determined for Quaternary calc-alkalic volcanic rocks from six volcanic rock suites in the central and western Japan arcs. The δ18O values relative to SMOW and 87Sr/86Sr ratios range from +6.3 to +9.90/00 and 0.70357 to 0.70684, respectively. Both the O- and Sr-isotopic compositions are higher than those for island-arc primitive magmas and their differentiates. The isotopic compositions of the calc-alkalic rocks cannot be derived by a simple fractional crystallization of the primitive magmas. On the other hand, the 18O- and 87Sr-enrichment is confined to the rock suites located in well-developed island arcs having thick continental-type crust with low or negative Bouguer anomalies. Involvement of 18O- and 87Sr-rich crustal material in the magma formation is suggested.The isotopic compositions vary remarkably within individual rock suites as well as from volcano to volcano. The data points in δ18O vs. 87Sr/86Sr plot accord with a mixing model between primitive magmas and crustal material of dioritic composition on an average, assuming their comparative Sr contents. The primitive magmas involved could not be low-Sr tholeiites, but magmas more or less enriched in incompatible elements including Sr, which correspond to high-alkali tholeiites or alkali basalts and their evolved magmas. The nature of the primitive magmas seems to change from tholeiitic to more alkalic with progressing island-arc evolution.Mixing of crust-derived melts is more plausible than assimilation of solid-rocks for involving 20 to 30% crustal material in the magmas along simple mixing curves. Isotopic variations between the rock suites are ascribed to variable Sr concentration radio of the end-members, variable isotopic compositions of crustal material or variable mixing ratio of the end-members. Extremely high-δ 18O rocks with moderate increase in 87Sr/86Sr ratio suggest another mixing process in shallower magma chambers between andesite magmas and metasedimentary rocks having high δ 18O and 87Sr/86Sr values but low Sr content. Subsequent fractional crystallization of once-derived magmas would be the prominent process for the rock suites showing gradual increase in 18O up to 10/00 with uniform 87Sr/86Sr ratios.  相似文献   

5.
An anorthoclase phenocryst separate from a pantellerite welded tuff and a slightly peralkaline nonhydrated sodatrachyte glass both have87Sr/86Sr ratios of0.7030 ± 0.0002. The sodatrachyte glass, withSiO2 = 63,Al2O3 = 15.5,and CaO= 1.4wt%and Sr= 53ppm, is interpreted as an intermediate member in the differentiation sequence through which pantellerite melts were derived from primary mafic magmas. The very low87Sr/86Sr ratios, in conjunction with K/Rb ratios of 500 to 700 found for the sodatrachytes, show that the primary mafic magmas were derived from mantle material which had been depleted in incompatible elements by a much earlier episode of magma generation.  相似文献   

6.
Abstract Whole‐rock chemical and Sr and Nd isotope data are presented for gabbroic and dioritic rocks from a Cretaceous‐Paleogene granitic terrain in Southwest Japan. Age data indicate that they were emplaced in the late Cretaceous during the early stages of a voluminous intermediate‐felsic magmatic episode in Southwest Japan. Although these gabbroic and dioritic rocks have similar major and trace element chemistry, they show regional variations in terms of initial Sr and Nd isotope ratios. Samples from the South Zone have high initial 87Sr/86Sr (0.7063–0.7076) and low initial Nd isotope ratios (?Nd, ?2.5 to ?5.3); whereas those from the North Zone have lower initial 87Sr/86Sr (usually less than 0.7060) and higher Nd isotope ratios (?Nd, ?0.8 to + 3.3). Regional variations in Sr and Nd isotope ratios are similar to those observed in granitic rocks, although gabbroic and dioritic rocks tend to have slightly lower Sr and higher Nd isotope ratios than granitic rocks in the respective zones. Limited variations in Sr and Nd isotope ratios among samples from individual zones may be attributed partly to a combination of upper crustal contamination and heterogeneity of the magma source. Contamination of magmas by upper crustal material cannot, however, explain the observed Sr and Nd isotope variations between samples from the North and South Zones. Between‐zone variations would reflect geochemical difference in magma sources. The gabbroic and dioritic rocks are enriched in large ion lithophile elements (LILE) and depleted in high field strength elements (HFSE), showing similar normal‐type mid‐ocean ridge basalt (N‐MORB) normalized patterns to arc magmas. Geochronological and isotopic data may suggest that some gabbroic and dioritic rocks are genetically related to high magnesian andesite. Alternatively, mantle‐derived mafic or intermediate rocks which were underplated beneath the crust may be also plausible sources for gabbroic and dioritic rocks. The magma sources (the mantle wedge and lower crust) were isotopically more enriched beneath the South Zone than the North Zone during the Cretaceous‐Paleogene. Sr and Nd isotope ratios of the lower crustal source of the granitic rocks was isotopically affected by mantle‐derived magmas, resulting in similar initial Sr and Nd isotope ratios for gabbroic, dioritic and granitic rocks in each zone.  相似文献   

7.
The “Colli Albani” composite volcano is made up of strongly silica-undersaturated leucite-bearing rocks. Magmas were erupted during three main periods, but a complex plumbing system dominated by regional tectonics channelled magmas into different reservoirs. The most alkali-rich magmas, restricted to the caldera-forming period (pre-caldera), are extremely enriched in incompatible trace elements and display more radiogenic Sr (87Sr/86Sr?=?0.71057–0.71067), with slightly less radiogenic Pb with respect to those of the post-caldera period. Post-caldera volcanic activity was concentrated in three different volcanic environments: external to the caldera, along the caldera edge and within the caldera. The post-caldera magmas produced melilite- to leucitite-bearing, plagioclase-free leucitites. In contrast to the pre-caldera lavas, they are characterised by lower incompatible trace element abundances and less radiogenic Sr (87Sr/86Sr?=?0.71006–0.71039). Magmas evolved through crystal fractionation plus minor crustal assimilation in a large magma chamber during the pre-caldera period. The multiple caldera collapses dissected and partially obliterated the early magma chamber. During the post-caldera stage, magmas were channelled through several pathways and multiple shallow-level magma reservoirs were established. A lithospheric mantle wedge previously depleted in the basaltic component and subsequently enriched by metasomatic slab-derived component is suggested as the mantle source of Colli Albani parental magmas. Two different parental magmas are recognised for the pre- and post-caldera stages. The differences may be related to the interplay between smaller degrees of melting for the pre-caldera magmas and more carbonate-rich recycled subducted lithologies in the post-caldera magmas.  相似文献   

8.
Sr and Nd isotope and geochemical investigations were performed on a remarkably homogeneous, high-silica rhyolite magma reservoir of the Aira pyroclastic eruption (22,000 years ago), southern Kyushu, Japan. The Aira caldera was formed by this eruption with four flow units (Osumi pumice fall, Tsumaya pryoclastic flow, Kamewarizaka breccia and Ito pyroclastic flow). Quite narrow chemical compositions (e.g., 74.0–76.5 wt% of SiO2) and Sr and Nd isotopic values (87Sr/86Sr=0.70584–0.70599 and Nd=−5.62 to −4.10) were detected for silicic pumices from the four units, with the exception of minor amounts of dark pumices in the units. The high Sr isotope ratios (0.7065–0.7076) for the dark pumices clearly suggest a different origin from the silicic pumices. Andesite to basalt lavas in pre-caldera (0.37–0.93 Ma) and post-caldera (historical) eruptions show lower 87Sr/86Sr (0.70465–0.70540) and higher Nd (−1.03 to +0.96) values than those of the Aira silicic and dark pumices. Both andesites of pre- and post-caldera stages are very similar in major- and trace-element characteristics and isotope ratios, suggesting that the both andesites had a same source and experienced the same process of magma generation (magma mixing between basaltic and dacitic magmas). Elemental and isotopic signatures deny direct genetic relationships between the Aira pumices and pre- and post-caldera lavas. Relatively upper levels of crust (middle–upper crust) are assumed to have been involved for magma generation for the Aira silicic and dark pumices. The Aira silicic magma was derived by partial melting of a separate crust which had homogeneous chemistry and limited isotope compositions, while the magma for the Aira dark pumice was generated by AFC mixing process between the basement sedimentary rocks and basaltic parental magma, or by partial melting of crustal materials which underlay the basement sediments. The silicic magma did not occupy an upper part of a large magma body with strong compositional zonation, but formed an independent magma body within the crust. The input and mixing of the magma for dark pumices to the base of the Aira silicic magma reservoir might trigger the eruptions in the upper part of the magma body and could produce a slight Sr isotope gradient in the reservoir. An extremely high thermal structure within the crust, which was caused by the uprise and accumulation of the basaltic magma, is presumed to have formed the large volume of silicic magma of the Aira stage.  相似文献   

9.
143Nd/144Nd,87Sr/86Sr and REE results are reported on volcanic rocks from the islands of Dominica and St. Kitts in the Lesser Antilles. Particular attention is given to the lavas and xenoliths of the Foundland (basalt-andesite) and the Plat Pays (andesite-dacite) volcanic centres on Dominica. Combined major and trace element [2] and isotope results suggest that the bulk of the andesites and dacites on Dominica, and by analogy in the rest of the arc, are produced by fractional crystallisation of basaltic magma. The differences in the erupted products of the two volcanoes do not appear to be related to any significant differences in the source rocks of the magmas.Along the arc87Sr/86Sr ratios range from 0.7037 on St. Kitts, to 0.7041–0.7047 on Dominica, and 0.7039–0.7058 on Grenada [5], and these are accompanied by a parallel increase in K, Sr, Ba and the light REE's. Moreover, compared with LIL-element-enriched and -depleted rocks from MOR and intraplate environments, the basic rocks from the Lesser Antilles are preferentially enriched in alkaline elements (K, Ba, Rb, Sr) relative to less mobile elements such as the rare earths.143Nd/144Nd varies from 0.51308 on St. Kitts, to 0.51286 on Dominica, and 0.51264–0.51308 on Grenada [5], and all these samples have relatively high87Sr/86Sr ratios compared with the main trend of Nd and Sr isotopes for most mantle-derived volcanic rocks. Alkaline elements and87Sr appear to have been introduced from the subducted ocean crust, but the results on other, less mobile elements are more ambiguous — island arc tholeiites (as on St. Kitts) do not appear to contain significant amounts of REE's, Zr, Y, etc., from the subducted oceanic crust, but such a contribution may be present in more LIL-element-enriched calc-alkaline rock types.  相似文献   

10.
Examples of positive correlations between initial 87Sr/86Sr and δ18O have now been shown to be very common in igneous rock series. These data in general require some type of mixing of mantle-derived igneous rocks with high-18O, high-87Sr crustal metamorphic rocks that once resided on or near the Earth's surface, such as sedimentary rocks or hydrothermally altered volcanic rocks. Mixing that involves assimilation of country rocks by magmas, however, is not a simple two-end-member process; heat balance requires appreciable crystallization of cumulates. In such cases, the isotopic compositions may strongly reflect this open-system behavior and indicate the process of assimilation, whereas the major element chemical compositions of the contaminated magmas will be largely controlled by crystal-melt equilibria and crystallization paths fixed by multicomponent cotectics. A variety of oxygen and strontium isotope “mixing” curves were therefore calculated for this process of combined assimilation-fractional crystallization. The positions and characteristics of the resultant curves on δ18O-87Sr/86Sr diagrams markedly diverge from simple two end-member mixing relationships. Based on the above, model calculations can be crudely fitted to two igneous rock suites (Adamello and Roccamonfina in Italy), but the shapes of the calculated curves appear to rule out magmatic assimilation as an explanation for most δ18O-87Sr/86Sr correlations discovered so far, including all of those involving calc-alkaline granitic batholiths and andesitic volcanic rocks. The isotopic relationships in such magma types must be inherited from their source regions, presumably reflecting patterns that existed in the parent rocks (or magmas) prior to or during melting.  相似文献   

11.
Rosemary  Hickey-Vargas 《Island Arc》2005,14(4):653-665
Abstract Basalts and tonalites dredged from the Amami Plateau in the northern West Philippine Basin have the geochemical characteristics of intraoceanic island arc rocks: low 87Sr/86Sr (0.70297–0.70310), intermediate 143Nd/144Nd (0.51288–0.51292), moderate light rare earth element (LREE) enrichment (La/Yb = 4.1–6.6) and high La/Nb (1.4–4.3). The incremental heating of hornblende from tonalites yielded well‐defined plateaus and 40Ar/39Ar isochron ages of 115.8 ± 0.5 Ma and 117.0 ± 1.1 Ma, while plagioclase yielded disturbed Ar release patterns, with ages ranging from 70 to 112 Ma. Taken together, these results show that the Amami Plateau was formed by subduction‐related magmatism in the Early Cretaceous period, earlier than indicated by prior K/Ar results. The results support tectonic models in which the West Philippine Basin was opened within a complex of Jurassic–Paleocene island arc terranes, which are now scattered in the northern West Philippine Basin, the Philippine Islands and Halmahera. The Amami Plateau tonalites and basalts have higher Sr/Y and lower Y and 87Sr/86Sr compared with younger tonalitic rocks from the northern Kyushu–Palau Ridge and the Tanzawa complex, which were formed by the subduction of the Pacific Plate beneath the Philippine Sea Plate. Based on the geochemical characteristics of the basalts, the Early Cretaceous subduction zone that formed the Amami Plateau may have been the site of slab melting, which suggests that a younger and hotter plate was being subducted at that time. However, the Amami tonalites were probably formed from basaltic magma by fractional crystallization or by partial melting of basaltic arc crust, rather than by melting of the subducted slab.  相似文献   

12.
New Sr and Pb isotope data are presented for a selection of lavas and associated coarse-grained blocks from Ascension Island. K-Ar dates for the lavas range up to1.5±0.2Ma. Initial87Sr/86Sr ratios are consistent with earlier measurements and for most rocks are ca. 0.7029, but range up to 0.7135 in the case of the most evolved lavas and blocks. Pb isotope data are also consistent with earlier measurements, but the Pb in two gabbroic blocks is less radiogenic than Pb in the other rocks. It is suggested that these gabbroic blocks crystallized from a magma of tholeiitic composition whose source was similar to that of mid-oceanic ridge basalt whereas the lavas and other blocks crystallized from mildly alkaline magmas derived from a source further from the crest of the Mid-Atlantic Ridge. The high87Sr/86Sr ratios result from contamination of the most silicic magma by radiogenic Sr from pelagic sediments. These data and their interpretation are consistent with the petrological and geochemical observations that the granite blocks are the coarse-grained equivalents of the volcanic suite [11] and not fragments of relict continental material [2,3].  相似文献   

13.
Purico-Chascon is an acid igneous complex less than 1.5 Ma old rising to 5800 m in the North Chilean Andes, and consisting of andesite-dacite cones and dacite domes on an ignimbrite shield. The rocks are subdivided into two groups: those from Chascon appear to exhibit evidence for magma mixing with more basic material now preserved as xenoliths, whereas among those at Purico no xenoliths have been found.87Sr/86Sr=0.7095?0.7081 at Purico, 0.7079?0.7069 at Chascon, and 0.7061-0.7057 in the xenoliths from the Chascon lavas:143Nd/144Nd=0.51222?0.51236 overall. The Purico lavas are characterised by higher SiO2, Rb/Sr,87Sr/86Sr, and REE abundances, and lower Sr/Nd, Sr/Ba and143Nd/144Nd than most Andean igneous suites. There is no indication ofselective crustal contamination of Sr, or any systematic change in isotope ratios during differentiation. Nonetheless the trend of, for example, high Sr/Nd and Sr contents in rocks with low87Sr/86Sr (0.704, Ecuador) to low Sr/Nd and Sr and high SiO2 in rocks with87Sr/86Sr=0.7081?0.7095 at Purico is interpreted as a shift from subduction zone related magmatism to one with greater crustal affinity. The formation of the least evolved Purico lavas (~60%SiO2) is discussed in terms of bulk assimilation of crustal material, mixing between crustal- and mantle-derived magmas, and partial melting of pre-existing crust. Although such models are still extremely primitive, the simplest explanation of the observed chemical variations is that the Purico rocks evolved from parental magmas derived by crustal anatexies. Thermal considerations suggest that such late-stage crustal anatexis is a predictable response to crustal thickening which in the Andes is thought to have taken place during the Cenozoic.  相似文献   

14.
Two groups of rhyolites have been recognized at San Vincenzo (Tuscany, Italy). Group A rhyolites are characterized by plagioclase, quartz, biotite, sanidine and cordierite mineral assemblages. They show constant MgO and variable CaO and Na2O contents. Initial87Sr/86Sr ratios in group A samples range between 0.71950 and 0.72535, whereas the Nd isotopic compositions are relatively constant (0.51215–0.51222). Group B rhyolites are characterized by orthopyroxene and clinopyroxene as additional minerals, and show textural, mineralogical and chemical evidence of interaction with more mafic magmas. The Sr and Nd isotopic ratios range between 0.71283–0.71542 and 0.51224–0.51227 respectively. Magmatic inclusions of variable size (1 mm to 10 cm) were found in groups B rhyolites. These inclusions consist mainly of diopsidic clinopyroxene and minor olivine and biotite. They are latitic in composition and represent blobs of hybrid intermediate magmas entrained in the rhyolitic melts. These magmatic inclusions have relatively high Sr contents (996–1529 ppm) and Sr and Nd isotope-ratios of 0.70807–0.70830 and 0.51245–0.51252 respectively.87Sr/87Sr data on minerals separated from both group A and B rhyolites and magmatic inclusions reveal strong isotopic disequilibria due to the presence of both restitic and newly crystallized phases in group A rhyolites and due to interaction of rhyolites with a mantle-de-rived magma in group B rhyolites. Isotopic data on whole rocks and minerals allow us to interpret the group A rhyolites as representative of different degrees of melting of an isotopically fairly homogeneous pelitic source; conversely, group B rhyolites underwent interactions with a mantle-derived magma. The crustal source as inferred from isotopic systematics would be characterized by87Sr/86Sr and143Nd/144Nd ratios close to 0.7194 and 0.51216 respectively. The sub-crustal magma would have Sr isotopic composition close to 0.7077 and a143Nd/144Nd ratio greater than or equal to 0.51252. These isotopic features are different from those reported for the parental magmas postulated for Vulsini and Alban Hills in the nearby Roman Magmatic Province, and are similar to those of the Vesuvius and Ischia magmas.  相似文献   

15.
Compositional and isotopic zoning patterns in plagioclase and amphibole phenocrysts from El Chichón record multiple cycles of country rock assimilation, magma injection, hybridization, and mixing. Laser ablation ICP-MS and electron microprobe analyses of plagioclase crystals from 7 eruptions spanning 3100 years reveal four types of zoning. These compositional and isotopic zones are often associated with textural changes observed in the crystals in thin section (e.g. sieved or patchy regions). Amphiboles are frequently zoned in Al and Si, and, in two magmas, may have clinopyroxene rims. Interestingly, most plagioclase show multiple and repeated zoning patterns. Moreover, all magmas contain all zoning patterns and textures, and crystals with substantially different sequences of zones occur within mm of one another. The most reasonable explanation for the origin of these textures is a frequently recharged chamber. Plagioclase zones with increasing anorthite contents (An) and decreasing 87Sr/86Sr ratios record injection by a hotter, possibly wetter, and more primitive magma (lower 87Sr/86Sr ratio). Zones with decreasing An and increasing 87Sr/86Sr ratios record assimilation of country rock and/or hybridization of the host and injected magmas; injection of hot magma may provide the heat for country rock assimilation. Changes in An without corresponding changes in 87Sr/86Sr ratio likely record slight variations in pressure or temperature during crystallization, or the far-field thermal effects of magma injection. Variations in 87Sr/86Sr ratio unaccompanied by Anzoning record assimilation of country rock. Amphibole zoning patterns also record periodic heating events; amphibole with clinopyroxene rims record episodes where the magma was heated beyond the amphibole stability field. Bulk compositional homogeneity and the juxtaposition of many crystals with disparate zoning patterns in single pumice require the magmatic system to be well mixed. Strontium diffusion rates indicate that the plagioclase zoning patterns cannot have persisted at magmatic pressures and temperatures for more than ~ 500 years, thus cycles of injection and assimilation occur on timescales equal to or shorter than the eruption recurrence interval. Long-term compositional and isotopic homogeneity indicate that there is a balance between recharge, assimilation, and crystallization.  相似文献   

16.
The Bishop Tuff represents a single eruption of chemically zoned rhyolitic magma. Six whole rock samples spanning the compositional and temperature range yield initial87Sr/86Sr of 0.7060–0.7092 andδ18O of 5.9–10.3‰. Six constituent sanidines yield smaller ranges of initial87Sr/86Sr of 0.7061–0.7069 andδ18O of 6.7–7.9. In contrast143Nd/144Nd ratios for the six whole rocks and two constituent magnetites exhibit negligible variation with a mean of0.51258 ± 1. These data are used to show that the phenocrysts were precipitated from an already chemically zoned liquid, that the zoning process involved negligible assimilation of, or exchange with, country rocks and that the extreme Sr and O isotopic disequilibria are probably the result of post-eruptive interaction with meteoric water. The parent magma had?Nd = ?0.9, ?Sr = +23 andδ18O = 7‰ and was formed from mantle-derived magmas and/or melts of lower crustal rocks isotopically similar to parts of the Sierra Nevada Batholith.  相似文献   

17.
The isotopic compositions of Sr, Nd and Pb together with the abundances of Rb, Sr, U and Pb have been determined for mafic and felsic potassic alkaline rocks from the young Virunga volcanic field in the western branch of the East African rift system.87Sr/86Sr varies from 0.7055 to 0.7082 in the mafic rocks and from 0.7073 to 0.7103 in the felsic rocks. The latter all come from one volcano, Sabinyo. Sabinyo rocks have negative εNdvalues ofεNd = ?10. Nd and Sr isotopic variations in the basic potassic rocks are correlated and plot between Sabinyo and previously reported [1] compositions (εNd = +2.5;87Sr/86Sr≈ 0.7047) for Nyiragongo nephelinites. The Pb isotopic compositions for Sabinyo rocks are nearly uniform and average206Pb/204Pb≈ 19.4,207Pb/204Pb= 15.79–15.84,208Pb/204Pb≈ 41.2. The basic potassic rocks have similar206Pb/204Pb values but range in207Pb/204Pb and208Pb/204Pb from the Sabinyo values to less radiogenic compositions.Excellent correlations of87Sr/86Sr with Rb/Sr, 1/Sr and207Pb/206Pb for Sabinyo rocks suggest these to be members of a hybrid magma series. However, the nearly uniform Pb compositions for this series points to radiogenic growth of87Sr in the magma source region following an event which homogenized the isotopic compositions but not Rb/Sr. The Rb-Sr age derived from the erupted Sabinyo isochron-mixing line is consistent with the ~500 Myr Pb-Pb age from Nyiragongo [1], which suggests that this event affected all Virunga magma sources. The event can again be traced in the Pb-Pb, Pb-Sr and Nd-Sr isotopic correlations for all Virunga rocks, including Nyiragongo, when allowances are made for radiogenic growth subsequent to this mixing or incomplete homogenization event. Inferred parent/daughter element fractionations point to a metasomatic event during which a mantle fluid invaded two lithospheric reservoirs: a +εNd reservoir sampled by the Nyiragongo nephelinites and suggested to be the subcontinental mantle and a ?εNd reservoir sampled by the mafic and felsic potasssic volcanism. Whether this ?εNd reservoir is the crust, continental crustal material in the mantle or anomalous mantle cannot be decided from the data. The simplest answer, that this reservoir is the continental crust, seems to be at variance with experimental evidence suggesting a subcrustal origin for basic potassic magmas. Partial melting of the ancient metasomatised lithospheric domains and ensuing volcanism seems to be entirely a response to decompression and rising geotherms during rifting and thinning of the lithosphere.  相似文献   

18.
The Pampean Ranges of northwest Argentina are a basin-and-range tectonic province with a late Precambrian to Paleozoic basement and extensive Miocene-Recent calc-alkaline volcanism. The volcanoes include the large resurgent Cerro Galan caldera, and Recent scoria cones and lava flows. Miocene-Recent volcanic rocks of basalt to dacite composition from the Cerro Galan area exhibit a range of Rb/Sr ratios of 0.043–1.092 and initial87Sr/86Sr ratios of 0.7057–0.7115 with a clear positive correlation between87Sr/86Sr and87Rb/86Sr, indicating an apparent age of ca. 130 Ma. This relationship is interpreted to indicate that the Sr isotope variation in the Cerro Galan volcanic rocks results from mixing of a mantle-derived component with low87Sr/86Sr (<0.7057) and high Sr (>700 ppm) with a crustal component characterized by higher87Sr/86Sr (>0.7115) and lower Sr (<240 ppm). It is concluded that the mixing is best explained as a result of a small degree of selective crustal Sr contamination (ca. 10%) of a range of subsequently erupted magmas produced largely by fractional crystallization within the continental crust. We propose that the mantle-derived end-member is derived by partial melting of sub-Andean mantle with an87Sr/86Sr ratio of ca. 0.704, and that such an Sr isotope ratio characterizes the source region for calc-alkaline volcanic rocks throughout the Andes.  相似文献   

19.
West Yunnan is made of the Yangtze Craton, theSouth China Block, the Indochina Block and severalother micro-terranes formed at different times. It iscross-cut by the NW-SE-trending Ailao Shan-RedRiver (ASRR) fault, which runs over 1000 km fromthe eastern margin of the Qinghai-Tibet Plateau,through Vietnam and to the North Gulf (fig. 1). TheASRR fault is an important geological and topog-raphic boundary in East Asia. The sinistral movementof the Indochina Block along this fault ev…  相似文献   

20.
The Tertiary volcanism of Eastern Macedonia and Western Thrace (Greece) developed in association with the sedimentary basin which formed, from Eocene to Oligocene, along the southern margin of the Rhodope Massif.The volcanic products, ranging in composition from basaltic andesites to rhyolites, show an overall calc-alkaline orogenic affinity, while chemical characteristics identify different groups of rocks, probably reflecting minor differences among parent magmas. The observed evolution within any group of rocks is compatible with fractional crystallization processes acting on relatively shallow magma bodies.The Sr isotopic composition of rhyolitic member shows an initial87Sr/86Sr ratio comparable with that of basaltic andesites, reinforcing the hypothesis of a crystal/liquid line of descent.Geochemical and petrographic evidence, on the whole, suggests that the investigated orogenic association developed on an active continental margin characterized by a relatively thick crust, acting as a density filter for the basic magmas and facilitating their storage and fractionation within the crust itself. Minor contamination by interaction with host materials may also have occurred.Stratigraphic and K/Ar geochronological data indicate that the volcanic activity started in Upper Eocene and reached its maximum development in Upper Oligocene. From Lower Miocene, the volcanism shifted southward in the Central Aegean area and in part of Western Anatolia, coming to an end by Middle Miocene.The southward migration of the volcanic front has been interpreted as a consequence of the increase in the dipping of the Benioff zone, due to the decrease of penetrative strength after the main phase of continental collision.  相似文献   

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