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1.
 A methodology was developed to evaluate and map the contamination potential or aquifer sensitivity of the upper groundwater flow system of a portion of the General Separations Area (GSA) at the Department of Energy's Savannah River Site (SRS) in South Carolina. A Geographic Information System (GIS) was used to integrate diverse subsurface geologic data, soils data, and hydrology utilizing a stack-unit mapping approach to construct mapping layers. This is the first time that such an approach has been used to delineate the hydrogeology of a coastal plain environment. Unit surface elevation maps were constructed for the tops of six Tertiary units derived from over 200 boring logs. Thickness or isopach maps were created for five hydrogeologic units by differencing top and basal surface elevations. The geologic stack-unit map was created by stacking the five isopach maps and adding codes for each stack-unit polygon. Stacked-units were rated according to their hydrogeologic properties and ranked using a logarithmic approach (utility theory) to establish a contamination potential index. Colors were assigned to help display relative importance of stacked-units in preventing or promoting transport of contaminants. The sensitivity assessment included the effects of surface soils on contaminants which are particularly important for evaluating potential effects from surface spills. Hydrogeologic/hydrologic factors did not exhibit sufficient spatial variation to warrant incorporation into contamination potential assessment. Development of this contamination potential mapping system provides a useful tool for site planners, environmental scientists, and regulatory agencies. Received: 1 April 1997 · Accepted: 4 November 1997  相似文献   

2.
浅层地下水氯代烃污染天然衰减速率的估算   总被引：1，自引：0，他引：1  
天然衰减恢复技术是恢复和控制浅层地下水氯代烃污染的技术之一,如何简便获取可靠的氯代烃衰减速率常数是该技术应用的一个关键。趋势线分析方法是一种简便有效的方法,在污染羽状体稳定的条件下,通过地下水流向上至少3口监测井的资料,能够比较准确地估算出污染物的天然衰减速率常数和生物降解速率常数。某氯代烃污染典型区的应用实例研究表明,该区四氯乙烯(PCE)的天然衰减速率常数和生物降解速率常数分别为0·000925d-1和0·000537d-1,证实该区浅层地下水中的PCE存在天然生物降解,但降解速率比较缓慢。忽略吸附作用的天然衰减容量计算所得出的天然衰减速率常数明显小于实际结果,说明尽管典型区包气带及含水层介质的有机碳含量很少,但它们对PCE的吸附作用不容忽视。  相似文献   

3.
基于不同地质统计方法的渗透系数场对污染物运移的影响   总被引：1，自引：0，他引：1  
渗透系数场的空间变异性是影响污染物运移结果的决定因素,而地质统计方法是解决渗透系数空间变异性的主要技术手段。本文利用野外场地实测数据,采用普通克里格法和指示克里格法、顺序高斯模拟法和顺序指示模拟法四种地质统计方法,插值估测和模拟再现随机渗透系数场,进而对比研究四种渗透系数场对大尺度污染物运移的影响。研究结果表明,污染羽的质心位置（一阶矩）主要由渗透系数的平均值来决定;污染羽在空间上的展布范围（二阶矩）主要受渗透系数空间变异方差的影响;条件模拟克服了估计法的平滑效果,较好地再现真实曲线的波动性,渗透系数（ lnK）估计方差与污染羽空间二阶矩随着条件模拟次数的增加而减小,并且顺序指示模拟程度更加明显。  相似文献   

4.
Providing a sound basis for aquifer management or remediation requires that hydrogeological investigations carried out to understand groundwater flow and contaminant transport be based on representative data that capture the heterogeneous spatial distribution of aquifer hydraulic properties. This paper describes a general workflow allowing the characterization of the heterogeneity of the hydraulic properties of granular aquifers at an intermediate scale of a few km2. The workflow involves characterization and data integration steps that were applied on a 12-km2 study area encompassing a decommissioned landfill emitting a leachate plume and its main surface water receptors. The sediments composing the aquifer were deposited in a littoral–sublittoral environment and show evidence of small-scale transitional heterogeneities. Cone penetrometer tests (CPT) combined with soil moisture and electrical resistivity (SMR) measurements were thus used to identify and characterize spatial heterogeneities in hydraulic properties over the study area. Site-specific statistical relationships were needed to infer hydrofacies units and to estimate hydraulic properties from high-resolution CPT/SMR soundings distributed all over the study area. A learning machine approach was used due to the complex statistical relationships between colocated hydraulic and CPT/SMR data covering the full range of aquifer materials. Application of this workflow allowed the identification of hydrofacies units and the estimation of horizontal hydraulic conductivity, vertical hydraulic conductivity and porosity over the study area. The paper describes and discusses data acquisition and integration methodologies that can be adapted to different field situations, while making the aquifer characterization process more time-efficient and less labor-intensive.  相似文献   

5.
An investigation was conducted at Astrolabe Park landfill, a decommissioned municipal landfill in Sydney, Australia, to assess the physical and chemical processes affecting the distribution of inorganic constituents in the leachate plume. The plume is migrating from the landfill towards a groundwater-fed pond into which leachate-impacted groundwater discharges. Borehole geophysical logging and depth-discrete groundwater sampling were used to delineate the distribution of the leachate plume along two groundwater flow paths between the landfill and the shore of the pond. Borehole geophysical logs indicate a strong correlation between bulk and fluid electrical conductivity (EC) values, and help to identify small-scale heterogeneities that comprise a major constraint on contaminant transport within the aquifer. Variations in the distribution of several indicator parameters (EC, HCO3–, pH, Eh, NH4+/NO3–, S2–/SO42–) are used to assess the dominant processes affecting contaminant distribution along the flow path, including mixing of fresh and contaminated groundwater, oxidation/reduction reactions and ion exchange.  相似文献   

6.
Itu Local Government Area is prone to groundwater contamination occasioned by saltwater due to the geographical location and the aquifer unit inter-transmissibility between the communicating/interconnected pores of the water-bearing units. This inter-transmissibility causes the continuous distribution of contamination among interconnected aquifer repositories. The study integrated the surface electric mapping and laboratory analysis of geologic samples and their corresponding water samples in estimating the transmissibility-dependent petrophysical parameters. The functional relationships between parameters have been determined. Maps of the spatial distribution of the estimated geohydraulic parameters have been drawn. Quantitative links of measured parameters to transmissibility have established. The resulting inferences based on the indices or magnitudes of the parameters measured helped in delineating the directions of water transmission within and across the hydrogeological units under study. The inferred result of permeability serves as a guide in identifying the southern zone of the area under study as having relatively reduced hydraulic pressure gradient differential, while the northern region has on the average, high hydraulic gradient differentials. The results of directions of inter-transmissibility of hydrodynamic properties in aquifer units are promising and capable of increasing the depth of knowledge on groundwater contamination and hence provide substantial input parameters that can enhance groundwater modelling within and near the study location.  相似文献   

7.
地下水污染监测网的设计研究进展   总被引：10，自引：0，他引：10  
地下水污染监测网的设计包括取样点在空间上的采样位置和时间上的取样频率这两方面的确定，其目的是为了准确刻画污染羽在含 水层中随时间的变化状况。概要地回顾了近20年来地下水污染监测网设计的研究成果。分别介绍了统计方法、模拟方法和模拟-优化模型 等监测网设计方法的研究进展。监测网设计方法的选择取决于最终的监测目的以及可供利用的基础资料。指出参数的不确定性是影响污染监 测设计结果的最重要因素。如何将地下水污染监测网设计的理论研究真正与实际应用相结合是今后的主要研究方向。  相似文献   

8.
Unscientific disposal of municipal solid waste causes groundwater contamination. The migration of leachate from the solid waste dumpsite to the aquifer varies according to the geohydrological profile of the dumpsite. A detailed study of the mechanism of leachate percolation to the groundwater helps to design a proper groundwater remediation technique. Multilevel boreholes were drilled in the periphery of the Perungudi dumpsite, Chennai, India. The major lithological layers and the geochemical analysis of the contaminant migrated from the dumpsite to the underlying aquifer has been studied. The distribution of heavy metals such as Pb, Fe, Zn, Cr, and Cd follows a similar trend in the pollutant source, groundwater samples around the dumpsite, and at various litho units beneath the dumpsite. The analysis thus helps to find an appropriate groundwater remediation technique to remove the specific contaminant and thereby provide a safe drinking water for the surrounding community.  相似文献   

9.
The use of wastewater for irrigation in sandy soil increases the pollution risk of the soil and may infiltrate to the shallow groundwater aquifer. In such environment, some important parameters need to be obtained for monitoring the wastewater in the unsaturated zone over the aquifer. These parameters include clay content, heterogeneities of the upper soils, depth to the aquifer and the variations of groundwater quality. In the present work, the efficiency of DC resistivity method in forms of 1-D and 2-D measurements was studied for wastewater monitoring in the Gabal el Asfar farm, northeast of Cairo, Egypt. Forty-one Schlumberger soundings (VES) were performed then followed by three pole-dipole 2-D profiles along some considered regions within the area. The resistivity measurements were integrated with the boreholes, hydrogeological and hydrochemical (surface and groundwater samples) information to draw a clear picture for the subsurface conditions. The obtained results were presented as cross sections and 3-D visualization to trace the clay intercalations within the unsaturated zone. In addition, a vulnerability map was created using the obtained results from 1-D Schlumberger survey and confirmed with the 2-D resistivity profiling. The obtained results have shown that the 2-D resistivity imaging technique is a powerful tool for mapping the small-scale variability within the unsaturated zone and the wastewater infiltration. However, limitations of resistivity techniques were observed in the area with limited resistivity contrast such as thin clay layers with brackish water background. Under that condition, the measured pattern of resistivity distributions depends on the applied electrode array, electrode spacing and using the available geological information during the inversion process.  相似文献   

10.
The Nubian Sandstone Aquifer (NSSA) is the main groundwater resource of the El-Bahariya Oasis, which is located in the middle of the Western Desert of Egypt. This aquifer is composed mainly of continental clastic sediments of sandstone with shale and clay intercalations of saturated thickness ranging between 100 and 1500 m. Vulnerability assessment to delineate areas that are more susceptible to contamination from anthropogenic sources has become an important element for sustainable resources management and land use planning. Accordingly, this research aims to estimate the vulnerability of NSSA by applying the DRASTIC model as well as utilising sensitivity analyses to evaluate the relative importance of the model parameters for aquifer vulnerability in the study area. The main objective is to demonstrate the combined use of the DRASTIC and the GIS techniques as an effective method for groundwater pollution risk assessment, and mapping the areas that are prone to deterioration of groundwater quality and quantity. Based on DRASTIC index (DI) values, a groundwater vulnerability map was produced using the GIS. The aquifer analysis in the study area highlighted the following key points: the northeastern and western parts of the NSSA were dominated by ‘High’ vulnerability classes while the northwestern and southeastern parts were characterised by ‘Medium’ vulnerability classes. The elevated central part of the study area displayed ‘Low’ aquifer vulnerability. The vulnerability map shows a relatively greater risk imposed on the northeastern part of the NSSA due to the larger pollution potential of intensive vegetable cultivation. Depth-to-water, topography and hydraulic conductivity parameters were found to be more effective in assessing aquifer vulnerability.  相似文献   

11.
A geographic information system (GIS) raster technique has been developed and used interactively with remediation designers to evaluate the optimum extent of excavating soil contaminated by chlorinated solvents. The technique and the results of its application are presented. The site was a former chemical storage plant for acids and solvents. Two distinct solvent plumes were detected within the ground using a photo-ionisation detector. The solvents were found to be dissolved in the groundwater and migrating in the general direction of groundwater flow. A remediation strategy was proposed involving the localised excavation of contamination ‘hot spots’ followed by the implementation of a groundwater remediation system. A number of excavation options were discussed and the GIS raster technique was developed to evaluate these options in terms of contaminant removed and excavation cost.

The plumes were initially mapped using a triangular irregular network (TIN). These TIN models were rasterised to produce a regular grid of rectangular cells, each cell having a value relating to the concentration of contaminant at that spatial point. The proposed excavation zones were then overlaid on to the raster models as masks. The relationship between the value of contaminant concentration of cells within the mask (or excavation zone) and the total value of contaminant concentration of cells within the solvent plume was used to determine the efficiency of the excavation.

The excavation options were compared taking into account the percentage of the contaminant plume removed, the excavation area (soil volumes) and related costs. Once the GIS raster technique had been developed, it proved very quick to rerun the analysis for the other excavation zones. The optimum excavation zone, based upon cost and contaminant recovery, was found for the site. The technique helped by targeting the worst area of contamination and provided the client with a cost-benefit analysis of the different remediation options.  相似文献   


12.
Applying the EPIK parametric method, a vulnerability assessment has been made for a small karstic groundwater system in southern Belgium. The aquifer is a karstified limestone of Devonian age. A map of intrinsic vulnerability of the aquifer and of the local water-supply system shows three vulnerability areas. A parameter-balance study and a sensitivity analysis were performed to evaluate the influence of single parameters on aquifer-vulnerability assessment using the EPIK method. This approach provides a methodology for the evaluation of vulnerability mapping and for more reliable interpretation of vulnerability indices for karst groundwater resources. Received, March 1999/Revised, December 1999, February 2000/Accepted, February 2000  相似文献   

13.
Groundwater vulnerability assessments calculate the sensitivity of quality of groundwater to an imposed contaminant load which is essential element of the aquifer management plans. Seventy five groundwater samples have been analyzed for different chemical parameters to understand the groundwater quality of the lower Varuna river basin, Uttar Pradesh, India. The intrinsic groundwater vulnerability map of the lower Varuna catchment area in the north of the city of Varanasi (India) shows a high dependency on the depth to groundwater. The topmost layer of alluvial silty clay, protects the groundwater against contamination in this urban area, but the retention time in the unsaturated zone can be estimated to several months only. The input dataset is very sparse i.e. groundwater levels were measured twice (pre- and post-monsoon 2009) and the geological map shows only alluvium as the outcrop. Several boreholes in this area show, that the alluvium has a thickness of about 4 m and below that are fine grained sands. The surface information does not allow the development of a risk map since land use changes very fast and contamination areas can not be identified accurately. The vulnerability maps developed in this study have become important tools for environmental planning and predictive management of the groundwater resources in the fast urbanizing region in the Varanasi area.  相似文献   

14.
The combined influence of dip angle and adsorption heterogeneity on solute transport mechanisms in heterogeneous media can be understood by performing simulations of steady-state flow and transient transport in a heterogeneous aquifer with dipping anisotropy. Reactive and non-reactive contaminant transport in various types of heterogeneous aquifer is studied by simulations. The hydraulic conductivity (K) of the heterogeneous aquifer is generated by HYDRO_GEN with a Gaussian correlation spectrum. By considering the heterogeneity of the adsorption distribution coefficient (K d), a perfect negative correlation between lnK and lnK d is obtained by using the spherical grains model. The generated K and K d are used as input to groundwater flow and transport models to investigate the effects of dipping sedimentary heterogeneity on contaminant plume evolution. Simulation results showed that the magnitude of the dip angle strongly controls the plume evolution in the studied anisotropic and heterogeneous aquifer. The retarded average pore-water velocity (v/R) of the adsorption model significantly controls the horizontal spreading of the plume. The bottom plume is intensively retarded in the zones between the dipping lenses of lower hydraulic conductivity and the no-flow bottom boundary. The implications of these findings are very important for the management of contaminated heterogeneous aquifers.  相似文献   

15.
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16.
Coastal aquifer of northern Sfax (Tunisia) suffers from the high risk to seawater intrusion and the water quality degradation due to the overexploitation. Hence, assessing the study area vulnerability to pollution is highly crucial so as to protect the groundwater resources. The assessment has been performed by applying the GALDIT method using Geographic Information System (GIS) software and multi-criteria evaluation techniques, and the sensitivity analysis approach to evaluate the effect of each GALDIT parameter on the vulnerability assessment. The GALDIT vulnerability map classifies the study area into three vulnerability classes: low vulnerability (30–50), moderate vulnerability (50–70), and high vulnerability (70–90), which represent 5, 30, and 65 % of the study area, respectively. The map illustrates that the coastal zones of the aquifer are the most threatened areas. The sensitivity analysis results show that the aquifer hydraulic conductivity (A) and the thickness of the aquifer (T) represent the determining factors in the modified vulnerability model. The real weight was used to elaborate the modified GALDIT model which was correlated with resistivity values for validation. This study could serve as a scientific basis for sustainable land planning and groundwater management in the study area.  相似文献   

17.
A simplified methodology for mapping groundwater vulnerability and contamination risk is proposed, and the first application of the methodology, in a mountainous tropical karst area, is presented. The test site is the Tam Duong area, one of the poorest and remotest regions in northern Vietnam. The methodology requires a minimum of input data, which makes it particularly useful for developing countries. Vulnerability is assessed on the basis of two factors, which take into account the duality of recharge processes in karst aquifer systems: the overlying layers (O) and the concentration of flow (C). The risk map is obtained by putting together the vulnerability map and a simplified hazard assessment. The resulting maps provide a basis for groundwater protection zoning and land-use planning. Tracer tests and microbiological data confirmed the vulnerability and risk assessment in the test site.  相似文献   

18.
Contaminant leaks released from landfills are a threat to groundwater quality. The groundwater monitoring systems installed in the vicinity of such facilities are vital. In this study the detection probability of a contaminant plume released from a landfill has been investigated by means of both a simulation and an analytical model for both homogeneous and heterogeneous aquifer conditions. Since the detection probability is a sensitive quantity, we first compare the two methods for homogeneous aquifer conditions to assess the errors that are encountered by performing simulations. The analysis shows that the simulation model yields the detection probabilities of a contaminant plume at a given monitoring well quite well in the homogeneous case. For heterogeneous aquifers we apply the approximated analytical model based on macro-dispersivities. Here we find that this model is insufficient in monitoring system design, since the obtained analytical values of the detection probabilities at a given monitoring well differ significantly from those computed by simulation.  相似文献   

19.
 Land-use changes on the Sheyenne Delta in southeastern North Dakota, USA, have prompted research on impacts to the unconfined Sheyenne Delta aquifer (SDA). This study examines effects of the saline discharge of a flowing artesian well that taps the Dakota aquifer (DAK) on SDA groundwater chemistry and soil salinity. Objectives were to map the saline plume in the SDA using induction techniques, to assess chloride migration in the SDA, and to evaluate induction sensitivity to moderately saline sands. Induction data, collected in a 2.9-ha grid, were compared to 31 soil profiles analyzed for gravimetric moisture, electrical conductivity, and chloride. Soil salinization is widespread, but only 7% of the area meets the 4-dS/m threshold for saline soils. SDA chloride distribution was determined on transects oriented with and perpendicular to the flow path determined from induction readings. Chloride was detected in the aquifer 550 m from the source, indicating a transport rate of 21 m/yr. Complex recharge and discharge patterns and hummocky relief contribute to a wide chloride plume at this site. A mass balance based on soil-water content and chloride concentration shows that only 4% of the chloride from the DAK well remains in the grid volume. Received, January 1998 · Revised, January 1999 · Accepted, March 1999  相似文献   

20.
The fate and transport of As was examined at an industrial site where soil- and groundwater contamination are derived from the application of As2O3 as a herbicide. Application of arsenical herbicides was discontinued in the 1970s and soils in the source area were partially excavated in 2003. Arsenic contamination (up to 280 mg/kg) remains in the source area soils and a plume of As-contaminated groundwater persists in the surficial aquifer downgradient of the source area with maximum observed As concentrations of 1200 μg/L near the source area. The spatial extent of As contamination as defined by the 10 μg/L contour appears to have remained relatively stable over the period 1996–2006; the boundary of the 1000 μg/L contour has retreated over the same time period indicating a decrease in total As mass in the surficial groundwater.In column experiments conducted with source area soil, the As concentrations in the column effluent were comparable to those observed in groundwater near the source area. A substantial fraction of the As could be leached from the source area soil with ammonium sulfate and ammonium phosphate. Exhaustive extraction with background groundwater removed most of the total As. These results indicate that As in the source area soils is geochemically labile. Source area soils are low in extractable Fe, Mn and Al, and characterization by X-ray absorption spectroscopy and electron microscopy indicated that As is present primarily as arsenate sorbed to (alumino)silicate minerals. Batch sorption experiments showed much less sorption on surficial aquifer sediments than on sediments from the Jackson Bluff Formation (JBF), a presumed confining layer. This limited capacity of the surficial aquifer sediments for As sorption is consistent with the similar As contents observed for these sediments within and upgradient of the As plume. The apparent stability of the As plume cannot be explained by sequestration of As within the surficial aquifer. Sorption to JBF sediments may contribute to As sequestration, but As enrichment in JBF sediments within the plume (i.e., as compared with JBF sediments upgradient) was not observed. These results indicate that neither the persistence of As in the source area soils or the apparent stability of the plume of As-contaminated groundwater at this site can be explained by geochemical controls on As mobility. The absence of demonstrable geochemical bases for such observations suggests that possible hydrologic controls should be further investigated at this site.  相似文献   

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