共查询到20条相似文献，搜索用时 750 毫秒
1.
The total rare-earth element values(ΣREE)of loess in the Xinjiang region vary over a range of 128-200 ppm ,with an average of 153ppm .The average REE content of loess lies between the earth‘s crust (155ppm) and sedimentary rocks(151ppm).The Xinjiang loess,with the REE distribu-tion patterns characterized by negative slopes ,is rich in the Ce-family elements, and has a distribu-tion pattern characteristic of sedimentary rocks.The North Xinjiang loess is relatively depleted in Tb,but rich in Yb and Lu.The South Xinjiang loess is relatively rich in light rare-earth elements.This is full proof that the Xinjiang loess comes partly from weathered materials(clay rock,sandstone)in the region studied.The REE distribution patterns in the Xinjiang loess are similar to those in the precipitated dust and Aeolian sand,indicating the same material source.The REE distribution pat-terns in the Xinjiang loess are also similar to those in loess from the middle Yellow River Valley,China and Taskent,the former USSR.This implies that loesses of the three locations(Xinjiang,the mid-dle Yellow River Valley and Taskent) come from a common material source.But the REE patterns in the Xinjiang loess are different from those in wall rocks (volcanic rock,K-bearing volcanic rock).Generally ,LREE/HREE,Eu/Eu* and Ce/Ce* ratios reflect the features of parent materials of loess,indicating that the parent rocks were probably in the early stage of alkaline weathering and the weathered materials existed in an oxidation environment with basic mediums under arid-climatic conditions before transport.As a result,the migration ability of the REE is weak. 相似文献
2.
对大同盆地典型高砷地下水开展了稀土元素地球化学研究.研究表明: 高砷地下水具有低∑REE含量及富集重稀土(HREEs)特征.地下水中低含量∑REE与含水层沉积物中Fe-Mn氧化物/氢氧化物对REEs的吸附有关.地下水中重稀土元素相对于轻稀土元素的富集可能是吸附作用和碳酸根离子同REEs发生络合作用的共同结果.采用平均大陆上地壳标准化的地下水稀土元素分布表现出显著的Ce及Eu正异常.地下水Ce/Ce*值及Eu含量与Fe+Mn具有显著相关性, 表明铁锰氧化物还原性溶解是控制Ce/Ce*值及Eu含量特征的主要因素.Ce/Ce*值及Eu含量与As浓度的关系表明, Ce异常及Eu含量特征能对地下水中As的富集进行有效指示. 相似文献
3.
4.
Ion microprobe analyses of rare earth elements (REEs), Ba, and Hf were performed for various types of refractory inclusions including amoeboid olivine aggregates (AOAs) from the Ningqiang ungrouped carbonaceous chondrite to search for possible relationships between REE abundance patterns and bulk chemical compositions of the inclusions. Four types of CI-normalized REE patterns were recognized: (1) nearly flat (unfractionated) pattern with or without Eu (and Yb) anomalies (Groups I, III, or V), (2) depletions of ultrarefractory heavy REEs (HREEs) relative to light REEs (LREEs), and depletions of Eu and Yb (Group II, but without depletion of Yb in some cases), (3) depletions of ultrarefractory HREEs with positive anomalies in Ce, (Eu), and Yb (Modified Group II), and (4) nearly flat pattern with positive anomalies in Ce, (Eu), and Yb (Modified Group I). No systematic correlation was found between bulk chemical compositions and REE patterns of the inclusions. This suggests that the observed REE fractionations occurred prior to condensation of major elements (e.g., Mg and Si) which defined bulk chemical compositions of the inclusions. It is remarkable that 7 out of 19 inclusions show positive anomalies in Ce, Yb, and in some cases, Eu as well (Modified Group I and Modified Group II), suggesting that such anomalies are rather common among inclusions in the Ningqiang and possibly in other primitive meteorites. Two possible mechanisms are considered for the formation of Modified Group II and Modified Group I patterns. In Model 1, Modified Group II is formed by a process similar to that produced Group II but removal of ultrarefractory dust occurred at slightly lower temperatures, where not only ultrarefractory HREEs but some fraction of LREEs had been condensed and removed from the system. Modified Group I may be explained by addition of an unfractionated component to the Modified Group II component, or alternatively, by partial removal of ultrarefractory dust from the system. In Model 2, Modified Group II is formed by later addition of Ce, (Eu), and Yb onto fine-grained dust or inclusions having HREE-depleted, Group II-like REE patterns. Similarly, Modified Group I is explained by later addition of Ce, (Eu), and Yb onto those with almost unfractionated REE patterns. The observed REE data show that both the degree of HREE-depletion (e.g., Er-depletion) and that of fractionation among HREEs (e.g., depletion in the Er/Gd ratio) for Modified Group II are very similar to those for Group II. Model 1 predicts almost complete removal of ultrarefractory HREEs from the system, resulting in much higher HREE-depletion for Modified Group II, which is not consistent with the present observations. Addition of an unfractionated component may explain moderate depletion of HREEs in Modified Group II, but it will diminish fractionation among HREEs, which is not consistent with the present observations. In contrast, Model 2 predicts no correlations between Ce-(Eu)-Yb-enrichment and HREE-depletion or between Ce-(Eu)-Yb-enrichment and fractionation among HREEs, consistent with the present observations. Hence, Model 2 seems more likely. If this is the case, at least two distinct regions with different REE characteristics are required for the formation of Modified Group II inclusions: one is a high temperature region where Group II-like (HREE-depleted) inclusions or their precursors are formed by condensation from a fractionated gas after removal of ultrarefractory dust, and another is a low temperature region enriched in Ce, Eu, and Yb in the gas phase. Abundant occurrence of positive Ce-(Eu)-Yb anomalies suggests that migration of solid materials from one region to another occurs rather frequently in the solar nebula. The most likely place satisfying such conditions for the formation of these inclusions may be the innermost part of the protoplanetary disk. 相似文献
5.
Concentrations of rare earth elements in topsoil from East China 总被引：3，自引：0，他引：3
Fifty topsoil samples collected from 12 different regions of East China have been analyzed for rare earth elements (REEs).
The average REE concentrations of the 50 topsoil samples are much higher than world average and are characterized by LREE-enrichment,
HREE-depletion, Eu-depletion and Ce-enrichment. However, the REE concentration is not strongly affected by the climate of
the sampling site; it is controlled mainly by parent materials. The plot of Ce/Eu against Eu/Sm is proved to be useful to
distinguish different parent materials of topsoil. Each element in the 50 topsoil has a good correlation with its neighboring
element. Seven of the 13 values are above 0.987. 相似文献
6.
Geochemistry and biogeochemistry of rare earth elements in a surface environment (soil and plant) in South China 总被引：1，自引：0，他引：1
Li Miao Ruisong Xu Yueliang Ma Zhaoyu Zhu Jie Wang Rui Cai Yu Chen 《Environmental Geology》2008,56(2):225-235
Plants and soils derived from different kinds of parent materials in South China were collected for analyses of rare earth
elements (REEs) by inductively coupled plasma-mass spectrometry (ICP-MS). The distribution patterns and transportation characteristics
of REEs in the soil–plant system were studied. The results show that geochemical characteristics of REEs depend on the types
of soils, soils derived from granite being the highest in REE concentration. In a soil profile, REE concentrations are higher
in B and C horizons than those in A horizon, with Eu negative anomaly and Ce positive anomaly. Plants of different genera
growing in the same sampling site have quite similar REE distribution pattern, but plants of the same genera growing in different
soils show considerable variation in characteristics of REEs. The patterns of the different parts of plant resemble each other,
but the slope of the patterns becomes different. REEs have fractionated when they were transported and migrated from soil
to plant root, stem and leaf, revealing that heavy REEs are relatively less available. REEs distributions in plants are influenced
by the soil they grow in and also characterized by their individual biogeochemical characteristics. Biological absorption
coefficients indicate difference of REE absorption capacity of plants.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
7.
REE oxides in loess are estimated to amount to about 200 ppm. The REE distribution patterns of loess and its clay-sized fractions are characterized by the enrichment of rare earth elements of Ce family. The REE distribution patterns of loess in the Middle Huanghe (Yellow River) Valley are identical with those of sands from the Tenger Desert, probably indicating the consistency of their material sources. The REE distribution patterns are similar to one another in the clay-sized fractions of Malan loess everywhere in the Middle Huanghe Valley, indicating their compositional homogeneity. Close to the average value of the earth’s crust, the REE distribution patterns of loess and its clay-sized fractions are similar to those of sedimentary rocks (e.g., North American shales), but different from those of chondrites. It seems to show that large amounts of loessic material were transported from the provenance by moving water to sedimentary systems after they had been separated from the precursor, and then transported by wind to the present loess-accumulated areas. 相似文献
8.
Khadija Semhi Osman A. E. Abdalla Salah Al Khirbash Tabisam Khan Salim Asaidi Sardar Farooq 《Arabian Journal of Geosciences》2009,2(2):143-150
Groundwater samples from six wells and various species of plants from soils developed on ophiolites were collected from an arid area (AlKhod area, Oman) and analyzed for trace elements including rare earth elements (REEs). The distribution patterns of REEs in plants indicated an enrichment in middle REEs (MREEs?=?Sm to Dy) and heavy REEs (HREEs?=?Ho to Lu), when they are normalized to the REE composition of the Post Archean Australian Shale (PAAS), with a significant negative anomaly in Ce and a positive anomaly in Eu. Compared to Oman ophiolites, the REEs in different species of plants are depleted in Ce and enriched in MREEs and slightly enriched in light REE (LREE?=?from La to Nd). Relative to PAAS, the distribution of REEs in groundwaters revealed similar patterns to the REE distribution in plants. The distribution patterns of REEs in plants relative to those in waters are nearly flat. These patterns suggest that the transfer of REEs from soil solutions to the groundwaters in Oman occurs without any significant fractionation. 相似文献
9.
Rare earth element studies of surficial sediments from the southwestern Carlsberg Ridge,Indian Ocean
The rare earth element (REE) contents of sixteen surficial calcareous sediments from the southwestern Carlsberg Ridge, Indian
Ocean, have been determined. The total REE vary from 35 ppm to 126 ppm and are inversely related to the calcium carbonate
content. REEs show a strong positive correlation with Al + Fe + K + Mg + Na (r
2= 0.98) and Mn + Fe + Cu + Ni (r
2= 0.86) suggesting that the REE is associated with a combined phase of clays (mainly illite) and Mn-Fe oxyhydroxides. The
aeolian input into these sediments is suggested from the weak positive Eu/Eu* anomaly. Shale-normalized (NASC) pattern along
with La(n)/Yb(n) ratio suggest enrichment of heavy REE (HREE) relative to the light REE (LREE) with a negative Ce/Ce* anomaly implying retention
of a bottom water REE pattern.
An erratum to this article is available at . 相似文献
10.
Shallow groundwater and hot springs were collected from northeastern Guangdong Province, Southeast China, to determine the concentrations and fractionation patterns of rare-earth elements(REE). The results show that the La, Ce and Nd of REEs are abundant in groundwater and rock samples, and the ∑REE contents in groundwater and rock samples range from 126.5 to 2875.3 ng/L, and 79.44 to 385.85 mg/L, respectively. The shallow groundwater has slightly HREE-enriched PAAS-normalized patterns. However, the granitic rocks PAAS-normalized patterns, with remarkable negative Eu anomalies, are different from that of shallow groundwater. The enrichment of HREE is considered to be controlled by REE complexation and readsorption for most groundwater has Ce and Eu positive anomalies. The Ce and Eu anomalies in groundwater are controlled by redox conditions. Moreover, the Fe-contain sediments dissolution and/or the reduction of Fe oxyhydroxides are another factor contributing to Ce anomalies. The Eu anomalies in groundwater are controlled by the preferential mobilization of Eu2+ during water-rock interaction compared to Eu3+. 相似文献
11.
塔里木盆地塔北隆起奥陶系-侏罗系泥岩稀土元素地球化学特征 总被引：12，自引：0，他引：12
分析了塔里木盆地塔北隆起奥陶系、三叠系和侏罗系泥岩的稀土元素丰度。不同时代泥岩都表现出轻稀土富集、重稀土含量均一和具有Eu负异常特征;但它们∑LREE/∑HREE、LaN/YbN、(La/Yb)UCC、Eu/Eu和Ce/Ce等参数则显示这些泥岩形成时的物源和环境有差别。奥陶纪时,研究区处于相对稳定的沉积环境,物源为成熟度高的大陆上地壳;二叠纪到三叠纪构造-火山活动强烈,部分沉积物来自火山岩的风化;侏罗纪塔北隆起区则进入稳定构造沉降阶段。这一差别对认识塔里木盆地及周边造山带形成演化研究有指示意义。 相似文献
12.
腾格里沙漠南缘武威黄土沉积元素地球化学特征 总被引：18，自引：1，他引：18
对腾格里沙漠南缘武威黄土剖面１８个样品系统的元素地球化学分析结果表明，剖面中８种常量元素氧化物总量平均值为８８.９９%，且整个剖面中变化微弱（８７.２６%～９０.４６%），显示了构成武威黄土物质组成的均一性；反映风化程度的Ｆｅ２Ｏ３/ＦｅＯ和Ａｌ２Ｏ３/ＳｉＯ２，值变化较为明显，平均值分别为１.４６（１.０２～２.８６）和０.１９（０.１７～０.２２）；稀土元素总含量平均值为１８５.４２（１６９.３１～１９９.８２）μｇ/ｇ，稀土分布斜率较大、有较明显Ｅｕ异常，ΣＬＲＥＥ/ΣＨＲＥＥ值平均为８.２３（７.３８～９.６０），表现出较显著的轻重稀土的分镏作用，指示着一定程度的风化作用；而代表原岩特征的稀土参数Ｅｕ/Ｓｍ、Ｓｍ/Ｎｄ、Ｎｄ/Ｌａ、δＣｅ、δＥｕ等变化不大，反映了不同时代黄土物质来源的一致性 相似文献
13.
Chunying Chang Fangbai Li Chengshuai Liu Jianfeng Gao Hui Tong Manjia Chen 《中国地球化学学报》2016,35(4):329-339
Soil secondary minerals are important scavengers of rare earth elements (REEs) in soils and thus affect geochemical behavior and occurrence of REEs. The fractionation of REEs is a common geochemical phenomenon in soils but has received little attention, especially fractionation induced by secondary minerals. In this study, REEs (La to Lu and Y) associated with soil-abundant secondary minerals Fe-, Al-, and Mn-oxides in 196 soil samples were investigated to explore the fractionation and anomalies of REEs related to the minerals. The results show right-inclined chondrite-normalized REE patterns for La–Lu in soils subjected to total soil digestion and partial soil extraction. Light REEs (LREEs) enrichment features were negatively correlated with a Eu anomaly and positively correlated with a Ce anomaly. The fractionation between LREEs and heavy REEs (HREEs) was attributed to the high adsorption affinity of LREEs to secondary minerals and the preferred activation/leaching of HREEs. The substantial fractions of REEs in soils extracted by oxalate and Dithionite-Citrate-Bicarbonate buffer solutions were labile (10 %–30 %), which were similar to the mass fraction of Fe (10 %–20 %). Furthermore, Eu was found to be more mobile than the other REEs in the soils, whereas Ce was less mobile. These results add to our understanding of the distribution and geochemical behavior of REEs in soils, and also help to deduce the conditions of soil formation from REE fractionation. 相似文献
14.
XU Hai GAO Junbo YANG Ruidong DU Lijuan LIU Zhichen CHEN Jun FENG Kangning YANG Guanghai 《《地质学报》英文版》2020,94(1):90-102
The Zunyi manganese deposits, which formed during the Middle to Late Permian period and are located in northern Guizhou and adjacent areas, are the core area of a series of large-medium scale manganese enrichment minerogenesis in the southern margin and interior of the Yangtze platform, Southern China. This study reports the universal enrichment of rare earth elements(REEs) in Zunyi manganese deposits and examines the enrichment characteristics, metallogenic environment and genesis of REEs. The manganese ore bodies present stratiform or stratoid in shape, hosted in the silicon–mud–limestones of the Late Permian Maokou Formation. The manganese ores generally present lamellar, massive, banded and brecciated structures, and mainly consist of rhodochrosite, ropperite, tetalite, capillitite, as well as contains paragenetic gangue minerals including pyrite, chalcopyrite, rutile, barite, tuffaceous clay rock, etc. The manganese ores have higher ΣREE contents range from 158 to 1138.9 ppm(average 509.54 ppm). In addition, the ΣREE contents of tuffaceous clay rock in ore beds vary from 1032.2 to 1824.5 ppm(average 1396.42 ppm). The REEs from manganese deposits are characterized by La, Ce, Nd and Y enriched, and existing in the form of independent minerals(e.g., monazite and xenotime), indicating Zunyi manganese deposits enriched in light rare earth elements(LREE). The Ce_(anom) ratios(average-0.13) and lithofacies and paleogeography characteristics indicate that Zunyi manganese deposits were formed in a weak oxidation-reduction environment. The(La/Yb)_(ch), Y/Ho,(La/Nd)_N,(Dy/Yb)_N, Ce/Ce* and Eu/Eu* values of samples from the Zunyi manganese deposits are 5.53–56.92, 18–39, 1.42–3.15, 0.55–2.20, 0.21–1.76 and 0.48–0.86, respectively, indicating a hydrothermal origin for the manganese mineralization and REEs enrichment. The δ~(13) C_(V-PDB)(-0.54 to-18.1‰) and δ~(18) O_(SMOW)(21.6 to 26.0‰) characteristics of manganese ores reveal a mixed source of magmatic and organic matter. Moreover, the manganese ore, tuffaceous clay rock and Emeishan basalt have extremely similar REE fractionation characteristic, suggesting REEs enrichment and manganese mineralization have been mainly origin from hydrothermal fluids. 相似文献
15.
The distribution and content of rare-earth elements (REEs) were determined in two radish species, the cultivated Raphanus sativus and the wild Raphanus raphanistrum, that were grown under laboratory-controlled conditions, in three substrates consisting of illite for one and two smectite substrates for the others, with the two smectite substrates being characterised by different porosities. The plants were split into leaves and stems + roots for analysis. The results indicate that both species take up systematically higher amounts of REEs when grown in the illite substrate, even considering that the smectite equivalent contains about three times more REEs. The REE uptake is also more plant species than mineral composition dependent: R. raphanistrum takes up 3.5–6.7 times more REEs than R. sativus, depending on the substrate, its porosity and the considered plant segments. Increased substrate porosity favours the take up of the REEs, but no specific uptake is observed in leaves relative to that in the combined stems and roots. The transfer of the REEs from minerals to plant organs does not appear to induce systematically identical patterns: (1) in the case of R. sativus, a positive Eu anomaly is visible in all patterns from both segment groups grown in both substrates. When grown in illite, the heavy REEs are also enriched in the stems and roots, which has not been observed in any other organ or in the other substrate and (2) in the case of R. raphanistrum, a very significant positive Gd anomaly, which is not expected to fractionate relative to the other REEs as do Ce and Eu, is observed in all segments of the plants grown in both substrates. A slight negative Ce anomaly is also visible in some of the REE patterns, suggesting some changes in the oxidation–reduction conditions in the substrates near the roots during plant growth. The comparison of the REE patterns from leaves relative to those of the roots + stems shows that those of R. raphanistrum grown in illite provide a spectrum that is very specific with significant deficits in La, Ce, Gd, Tm, Yb and Lu in the leaves. In the other cases, the patterns do not outline significant differences except for R. sativus grown in illite, in which the leaves are enriched in light and medium REEs from La to Gd relative to the stems + roots. 相似文献
16.
The giant sediment-hosted Jinding zinc-lead deposit is located in the Lanping Basin, northwestern Yunnan Province, China. The genesis of the deposit has long been debated and the sources of the ore-forming fluids and metals are controversial. This study presents rare earth element (REE) and noble gas isotope data that constrain the origins of the ore fluids and the heat source driving the hydrothermal circulation. The early-stage sulfides are enriched in light REEs and have high ∑REE values (30.8–94.8 ppm) and weakly negative Eu (δEu 0.85–0.89) and Ce anomalies (δCe 0.84–0.95), suggesting that the fluids were likely derived from dissolution of Upper Triassic marine carbonates with input of REEs from aluminosilicate rocks in the basin. In contrast, the late-stage sulfides have irregular REE patterns, generally low ∑REE values (0.24–10.8 ppm) and positive Eu (δEu 1.22–10.9) and weakly negative Ce anomalies (δCe 0.53–0.90), which suggest that the ore-forming fluids interacted with evaporite minerals. The 3He/4He (0.01–0.04 Ra) and 40Ar/36Ar values (301–340) of the ore-forming fluids indicate crustal and atmospheric origins for these noble gases. These findings are in agreement with the published fluid inclusion microthermometry data and the results of H, O, C, S, Pb and Sr isotope studies. Our data, in combination with published results, support a two-stage hydrothermal mineralization model, involving early-stage basinal brines and late-stage meteoric water that acquired metals and heat from crustal sources. 相似文献
17.
贵州水银洞金矿构造蚀变体稀土元素地球化学特征 总被引：3，自引：0，他引：3
水银洞金矿构造蚀变体(SBT)为产出于茅口租(P2m)和龙潭组(P3l)之间不整合面上的一套强硅化灰岩、灰岩角砾岩、硅化粘土岩组合.呆用ICP-MS测定钻孔岩芯中构造蚀变体样品稀土元素组成,对比研究SBT围岩、区域岩浆岩及现代海底热水系统流体稀土元素组成.结果显示,SBT的轻重稀土分馏明显[LREE/HREE=4.92～17.51,(La/Yb)N=5.94～38.37],曲线右倾型;轻稀土分异明显,曲线右倾程度大;重稀土分异不明显,曲线平坦;负Eu(0.61～0.94)、Ce(0.52～1.07)异常明显;SBT及围岩均具有明显W型稀土元素四分组效应,而不同于区域岩浆岩和现代海底热水系统流体,表明热液流体来源以壳源为主. 相似文献
18.
This work, which was done within the Swedish nuclear waste management program, was carried out in order to increase the understanding of the mobility and fate of rare earth elements (REEs) in natural boreal waters in granitoidic terrain. Two areas were studied, Forsmark and Simpevarp, one of which will be selected as a site for spent nuclear fuel. The highest REE concentrations were found in the overburden groundwaters, in Simpevarp in particular (median ∑REE 52 μg/L), but also in Forsmark (median ∑REE 6.7 μg/L). The fractionation patterns in these waters were characterised by light REE (LREE) enrichment and negative Ce and Eu anomalies. In contrast, the surface waters had relatively low REE concentrations. They were characterised either by an increase in relative concentrations throughout the lanthanide series (Forsmark which has a carbonate-rich till) or flat patterns (Simpevarp with carbonate-poor till), and had negative Ce and Eu anomalies. In the bedrock groundwaters, the concentrations and fractionation patterns of REEs were entirely different from those in the overburden groundwaters. The median La concentrations were low (just above 0.1 μg/L in both areas), only in a few samples were the concentrations of several REEs (and in a couple of rare cases all REEs) above the detection limit, and there was an increase in the relative concentrations throughout the lanthanide series. In contrast to these large spatial variations, the temporal trends were characterised by small (or non existent) variations in REE-fractionation patterns but rather large variations in concentrations. The Visual MINTEQ speciation calculations predicted that all REEs in all waters were closely associated with dissolved organic matter, and not with carbonate. In the hydrochemical data for the overburden groundwater in particular, there was however a strong indication of association with inorganic colloids, which were not included in the speciation model. Overall the results showed that within a typical boreal granitoidic setting, overburden groundwaters are enriched in REEs, organic complexes are much more important than carbonate complexes, there is little evidence of significant mixing of REEs between different water types (surface, overburden, bedrock) and spatial variations are more extensive than temporal ones. 相似文献
19.
《Applied Geochemistry》1999,14(1):27-39
One hundred and fifty Norwegian bedrock groundwater samples, from Bergen and from Vestfold (Oslofjord), have been analysed by ICP-MS techniques at two laboratories for a large suite of trace elements including rare earth elements (REEs) and Y. The bedrock lithologies include granites (dominated by the Permian Drammen Granite) and Permian latites/rhomb porphyries from Oslofjord, and Caledonian/Precambrian granitic and gneissic lithologies in the Bergen area. The REEs show good correlation with each other, with the exception of Eu. REEs generally show a weak negative correlation with pH. REE concentrations are highest in waters in acidic lithologies and generally decrease with increasing atomic weight. Yttrium, La, Ce and Nd are the most abundant REEs in the waters, with median concentrations exceeding 0.1 μg/l. On crustal (PAAS)-normalised plots, distinct geochemical signatures are observed for the different lithologies. Most groundwaters exhibit negative Eu anomalies on such plots, except for latitic waters from the Oslo area which show a positive Eu anomaly. Aquifer host-rock-normalised plots for groundwaters from Vestfold indicate minor enrichment in heavier REEs and depletion in Ce during water–rock interaction. 相似文献
20.
黑龙江省东部绥滨坳陷下白垩统泥岩稀土元素地球化学特征 总被引：2，自引：0，他引：2
通过对滨参1井下白垩统泥岩的取样分析,认为黑龙江省东部绥滨坳陷下白垩统泥岩的稀土元素具如下地球化学特征：（1）各组泥岩的稀土元素球粒陨石标准化配分模式都表现出轻稀土相对于重稀土明显富集和具有明显负Eu异常的特点，但∑REE、∑LREE/∑HREE、LaN/YbN 、LaN/SmN、GdN/YbN、Eu/Eu*、Ce/Ce*和（La/Yb）UCC等参数则显示出明显的不同，反映了泥岩形成时的物源有差别。滴道组和城子河组的物源可能主要为绥滨坳陷南部桦南隆起地区的花岗岩、东南部宝清地区的沉积岩和东部东三江盆地的沉积岩；穆棱组和东山组物源可能主要为绥滨坳陷东南部宝清地区的沉积岩和东部东三江盆地的沉积岩。在穆棱组和东山组沉积期，还可能有来自下地壳或幔源的深部物质加入，导致物源发生了很大的变化。（2）Ce/Ce*和Ceanom指数显示绥滨坳陷早白垩世各组泥岩的古环境均为还原环境，对油气生成十分有利。（3）绥滨坳陷早白垩世为大陆边缘环境，其构造演化过程为活动-稳定-活动。 相似文献