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1.
王剑锋 《中国地球化学学报》1991,10(3):277-287
Based on the data of 64 samples ,the REE geochemical characteristics of volcanic rocks in northern Zhejiang and eastern Jiangxi provinces are discussed in this paper.The REE distribution patterns in acid and intermediate-acid volcanic rocks in these areas display some similarities,as indicated by rightward-inclined V-shaped curves with negative Eu anomalies,which are parallel to earch other.In addi-tion,their REE parameters(ΣREE,ΣLREE/ΣHREE,δEu,Ce/Yb,La/Sm,La/Yb,etc)also va-ry over a narrow range with small deviations.HREE are particularly concentrated in the volcanic rocks as-sociated with uranium mineralization.The initial ^87Sr/^86Sr ratio in the volcanic rocks is about 0.7056-0.7139.All these features in conjunction with strontium isotopic data indicate that the rock-forming materials come from the sialic crust.The REE distribution patterns and REE geochemical parameters of the volcanic rocks ,as well as La/Sm-La and Ce/Yb-Eu/Yb diagrams may be applied to the sources of rock-forming and ore-forming materials. 相似文献
2.
REE oxides in loess are estimated to amount to about 200 ppm. The REE distribution patterns of loess and its clay-sized fractions are characterized by the enrichment of rare earth elements of Ce family. The REE distribution patterns of loess in the Middle Huanghe (Yellow River) Valley are identical with those of sands from the Tenger Desert, probably indicating the consistency of their material sources. The REE distribution patterns are similar to one another in the clay-sized fractions of Malan loess everywhere in the Middle Huanghe Valley, indicating their compositional homogeneity. Close to the average value of the earth’s crust, the REE distribution patterns of loess and its clay-sized fractions are similar to those of sedimentary rocks (e.g., North American shales), but different from those of chondrites. It seems to show that large amounts of loessic material were transported from the provenance by moving water to sedimentary systems after they had been separated from the precursor, and then transported by wind to the present loess-accumulated areas. 相似文献
3.
REE studies of apatites in two series of granites, including more than ten types of rock and several tens of rock masses in
eight provinces of South China permit us to come to some new understanding and hence the following conclusions have been drawn.
Apatites in granites of different series show significant differences in REE distribution pattern, probably due to different
material sources. Therefore, REE partition characteristics can be used to discriminate granites of different sources. Apatite
in granite of the Nanling series (of shallow-seated source) has a lower content ofΣ REE (4571 ppm on average). Y is the highest of the REE group.Σ Y is rich relative toΣ Ce, thus giving rise to relatively lowΣCe/ΣY ratio (0.68 on average). Eu shows strong depletion, andδ Eu is extremely low (0.135 on average). The REE distribution patterns are represented by a group of “V”-shaped symmetric
curves. Apatite in granites of the Yangtze series are relatively high inΣ REE (8571.3 ppm on average). Ce is the highest of the REE. group.Σ Ce is rich relative toΣ Y and theΣCe/ΣY is relatively high (7.15 on average). The chondrite-normalized REE distribution patterns are characterized by a group of
rightward-inclined curves. 相似文献
4.
Qizhong Wen Suhua Yu Fuqing Sun Yuqi Wang Bingru Chen Shude Tu Jingxin Sun 《中国地球化学学报》1985,4(2):172-180
TheΣ REE in loesses of different ages in the Luochuan section shows a narrow range of variation, indicating the homogeneity of loessic materials in chemical composition. The REEs in loess are concentrated mainly in silt-sized detrital minerals. Loesses and paleosols of different ages all are relatively enriched in rare-earth elements of the Ce family, and show similar REE distribution patterns. The fractionation among various REEs in the loess is different from that in morainic, marine and lacustrine sediments, but is similar to that in sand samples from deserts in Northwest China. The ratios of Ce/Ce* and Eu/Eu* reflect that the provenance of loessic materials and their accumulating area are all in an oxidation environment with weakly basic mediums under arid or semi-arid climate. 相似文献
5.
Experimental data show that the Ce-family REE are more accessible to hydrolysis than the Y-family REE, and the optimum pH
conditions for REE adsorption vary from one system to another, for example, pH = 3–6 for the chloride system, and 3–4 for
the acutate system. At pH = 3–6, no obvious selective REE adsorption is observed in both the systems. From the deep levels
of the weathered crust towards the surface the percent content of the Ce-family REE tends to increase progressively, whereas
that of the Y-family REE tends to decrease, with La/Ce varying from <1 → > 1 → <1. More or less fractionation would take place
among the rare-earth elements due to their different geochemical behaviors. Nevertheless, the REE distribution patterns in
the weathered crust can still reflect the REE distribution patterns in the parent rocks. Relatively unstable independent REE
minerals, such as bastinaesite, parisite and britholite are considered as the main source of rare-earth elements in the weathered
crust of this area. 相似文献
6.
UKAEGBUV.U. EKWUEMEB.N. 《中国地球化学学报》2005,24(2):129-135
Rock samples representing various igneous and metamorphic rocks of southern Obudu Plateau were analyzed for rare-earth element ( REE ) behavior by ICP-MS. Results of the analyses indicate a range of REE abundances and distinctive patterns from highly fraetionated patterns with negative Eu anomalies in granitic rocks to relatively low abundances and less REE fractionated flat patterns with little Eu anomaly in some paragneisses, schists, enderbites and dolerites to unfractionated patterns with positive Eu anomalies in some paragneisses and charnockites. Over all, there are low to high ∑ REE contents with negative to positive Eu anomalies. The ratios of different parameters, especially La/Yb and Ce/Yb, show behaviors consistent with crustal to mantle derivation. The heterogeneity of REE abundances and REE patterns reflects mantle to crustal petrogenetic variations of different rock suites on the Plateau. The LREE content is higher than the HREE content in the highly differentiated rocks, as evidenced by their La/Yb,Ce/Yb and La/Sm ratios, which are normally higher in residual products than in primary melts. The dominantly intermediate nature of the source rock of the orthogneisses is suggested by the generally low ∑ REE. The granites enriched in LREE and depleted in HREE and some of the charnockites with negative Eu anomalies were probably formed by partial melting and crystallization. 相似文献
7.
长江与黄河沉积物REE地球化学及示踪作用 总被引：66，自引：4，他引：62
长江与黄河沉积物的稀土元素（ＲＥＥ）组成特征不同。长江沉积物ＲＥＥ含量较高,元素含量变化也大于黄河样品;球粒陨石标准化模式表明长江沉积物的（Ｌａ／Ｌｕ）Ｎ、（Ｌａ／Ｙｂ）Ｎ、（Ｇｄ／Ｙｂ）Ｎ的值也相应地比黄河沉积物中的高１０％左右,分布曲线均呈明显的石倾状,轻重稀土分馏明显,相对富集ＬＲＥＥ。且长江样品比黄河样品更富集ＬＲＥＥ,但Ｅｕ亏损不及黄河样品;两者的北美页岩标准化曲线均呈平坦稍右倾状,具有 相似文献
8.
Shallow groundwater and hot springs were collected from northeastern Guangdong Province, Southeast China, to determine the concentrations and fractionation patterns of rare-earth elements(REE). The results show that the La, Ce and Nd of REEs are abundant in groundwater and rock samples, and the ∑REE contents in groundwater and rock samples range from 126.5 to 2875.3 ng/L, and 79.44 to 385.85 mg/L, respectively. The shallow groundwater has slightly HREE-enriched PAAS-normalized patterns. However, the granitic rocks PAAS-normalized patterns, with remarkable negative Eu anomalies, are different from that of shallow groundwater. The enrichment of HREE is considered to be controlled by REE complexation and readsorption for most groundwater has Ce and Eu positive anomalies. The Ce and Eu anomalies in groundwater are controlled by redox conditions. Moreover, the Fe-contain sediments dissolution and/or the reduction of Fe oxyhydroxides are another factor contributing to Ce anomalies. The Eu anomalies in groundwater are controlled by the preferential mobilization of Eu2+ during water-rock interaction compared to Eu3+. 相似文献
9.
Tungsten minerals (scheelite and wolframite) from two genetic types of granitoids show significant differences in REE distribution,
probably due to different material sources and origins. Tungsten minerals in granite porphyry of the crust-mantle source are
relatively high in ΣREE(1884ppm on average). Σ Ce is rich relative to Σ Y and Σ Ce/ΣY is relatively high (>1). The chondrite-normalized
REE distribution patterns are characterized by a group of rightward-inclined curves. Tungsten minerals in quartz veins intruding
the granites of crust origin have lower ΣREE (335 ppm on average). ΣY is rich relative to ΣCe and ΣCe/ΣY is relatively low
(<1). The chondrite-normalized REE distribution patterns are characterized by a group of leftward-inclined curves. So the
REE distribution patterns can be used to discriminate the sources of rock-and ore-forming materials and the genetic types
of W deposits so as to provide clues to ore prospecting. 相似文献
10.
吴素珍 《中国地球化学学报》1989,8(1):72-83
The metasedimentary-volcanic series of the Wutai and Hutuo groups experienced regional metamorphism and thus turned into moderate-to low-grade metamorphic rocks.REE abundances and REE distribution patterns in the Shizui and Taihuai Subgroup metasedimentary-volcanic rocks are typical of the Archean,whereas the Gaofan Subgroup and the Hutuo Group show post-Archean REE geochemical char-acteristics.Five types of REE distribution pattern are distinguished:(1)rightward inclined smooth curves with little REE anomaly(Eu/Eu*=0.73-0.95) and heavy REE depletion (e.g.the Late Archean metasedimentary rocks);(2)rightward inclined V-shaped curves with sharp Eu anoma-ly (Eu/Eu*=0.48-0.76) and slightly higher ∑REE (e.g.the post-Archean metasedimentary rocks);(3) rightward inclined steep curves with negative Eu anomaly(Eu/Eu*=0.73-0.76) and the lowest ∑REE (e.g.the post-Archean dolomites);(4)rightward inclined,nearly smooth curves with both positive Eu anomaly and unremarkable positive Eu anomaly(Eu/Eu*=0.95-1.25)(e.g.the meta-basic volcanic rocks);and (5) rightward inclined curves with Eu anomaly(Eu/Eu*=1.09-1.19)and heavy REE depletion(e.g.the meta-acid volcanic rocks).Strata of the two groups are considered to have been formed in an island-arc belt-an instable continental petrogenetic environment. 相似文献
11.
本文以丘北大铁铝土矿含铝岩系为研究对象, 通过ICP-MS分析测试, 研究了含铝岩系与下伏灰岩、玄武岩的稀土元素特征。研究结果表明, 丘北大铁铝土矿含铝岩系稀土配分模式曲线为向右倾斜的曲线, 与下伏马平组、黄龙组灰岩的稀土配分曲线相似, 而与峨眉山组玄武岩的稀土配分曲线相差较大; 灰岩具有较明显的Ce负异常和Eu负异常, 部分铝土矿和铁铝质岩具明显的Ce正异常和较明显的Eu负异常, 而多数铝土矿、铁铝质岩和铝质粘土岩则无明显的Ce、Eu异常。含铝岩系的稀土元素特征, 反映出其成矿物质来源于下伏灰岩而非玄武岩, 同时也反映出铝土矿的成矿物质来源于风化壳, 成矿物质搬运距离较近, 与海水的水合作用不甚明显。 相似文献
12.
淮南矿区煤的稀土元素地球化学 总被引：25，自引：2，他引：23
采用INAA测试了淮南矿区 13个煤层煤样的稀土元素含量,研究了稀土元素地球化学特征,得出以下认识 :各煤层样品的稀土元素含量、分布模式变化都很大。煤中稀土元素主要来源于陆源碎屑,来源于海水和植物的不多;稀土元素在粘土矿物中含量高,主要以高岭石的形式赋存。稀土元素具有指相意义,随着成煤沼泽中海水影响的减弱,陆源影响的增强,煤中稀土元素的含量增加;煤的稀土元素分布模式也作有规律的变化,从类似于海相生物的分布模式到类似于陆源碎屑岩的分布模式。Eu异常是由源岩继承下来的,Eu负异常的减弱,估计是由于陆源控制减弱、海水影响增强引起的。在成煤沼泽环境中,海水的影响并未造成Ce严重亏损。 相似文献
13.
新疆东天山泥盆纪火山岩岩石学特征及其形成的大地构造环境 总被引：1，自引：0，他引：1
新疆东天山地区泥盆纪火山活动频繁,火山岩广泛发育。火山岩系由钙碱系列(占75％)石英安山岩、英安岩、玄武岩、碱长流纹岩以及大量的火山碎屑岩,和拉斑玄武系列(约占25％)的石英拉斑玄武岩,少量橄榄拉斑玄武岩组成。岩石普遍富含Na_2O,SiO_2,而贫MgO,K_2O,以CaO,属钠质型和普通型。稀有元素配分型式具“三隆起”特征,过渡族元素呈明显的“W”形态,稀土元素为铕平坦或略具亏损的轻稀土富集型。据研究,火山岩由南至北具明显的钾元素地球化学极性。反映其板块构造环境为一俯冲带倾向北的陆壳型岛弧。 相似文献
14.
新疆西天山松湖铁矿床稀土和微量元素地球化学特征及其意义 总被引：5，自引：4，他引：1
松湖铁矿床位于新疆西天山阿吾拉勒成矿带中段,赋存于石炭系大哈拉军山组火山-沉积岩系中。矿体呈似层状、透镜状,主要受近EW向、NWW向高角度逆断层控制。矿石主要呈块状、条带状、团块状构造,结构主要为半自形-他形粒状;矿石矿物主要为磁铁矿,其次为赤铁矿、黄铁矿及黄铜矿,脉石矿物主要为钾长石、绿泥石、方解石、绿帘石及阳起石等。围岩蚀变发育,在垂向和水平方向上具有分带性。矿区围岩是阿吾拉勒地区早石炭世岛弧火山岩的组成部分,不同岩性具有类似的稀土元素配分模式,均为轻稀土元素富集的右倾型,发育弱的负铈异常,中到弱的负铕或正铕异常。矿石中磁铁矿的∑REE值变化于20.75×10-6~65.41×10-6,配分模式为轻稀土元素富集的右倾型,发育中到弱的负铈及负铕异常。磁铁矿与围岩的稀土元素特征表明二者具有成因联系,与岛弧火山作用有关。磁铁矿微量元素特征表明成矿物质来源于深部,磁铁矿为火山热液交代成因。结合矿床地质特征,认为松湖铁矿床为海相火山热液型矿床。 相似文献
15.
REE Geochemistry of the Lead—Zinc Ores from the Jinding Lead—Zinc Deposit,Lanping,Yunnan 总被引：3，自引：1，他引：3
Nineteen volcanic and magmatic rock samples were collectecd from the Jinding leadzinc deposit and its surrounding areas in Yunnan.The ICP and AES analyses,feferred to the previous results,show that the metal minerals and altered rocks in the Jinding lead-zinc deposit display a decreasing trend of ∑REE from the early to late stages of mineralization,and similarities in REE distribution patterns,indicating that the ore fluids are characterized by high LREE enrichment,markedly negative δCe anomaly and slight δEu anomaly.These REE distribution paterns exhibit striking similarities to those of the Pliocene trachyte in the study area,both of which are similar in ∑REE,LREE/HREE ratio,δEu and δCe.The ore fluids besides the basin fluids in the deposit are also closely related to those associated with Pliocene trachyte magmas. 相似文献
16.
辽西北票、义县地区髫髻山旋回火山岩的地球化学特征 总被引：3，自引：0，他引：3
北票、义县地区髫髻山组可分为3个岩性段.髫髻山火山旋回划分为2个亚旋回.髫髻山旋回火山岩属于高钾钙碱性岩系,SiO2=53.67%~75%,Al2O3=13.15%~19.16%,K2O+Na2O=5.17%,里特曼指数δ=1.46~6.83,平均值为3.06;富碱贫镁,Na2O>K2O.Cr、Ni含量低,亲石元素Rb、Sr、Ba等含量高.稀土元素总量较高,富轻稀土,稀土分布模式呈右倾型,稀土元素分馏明显,总体为负铕异常,弱铈异常.成因研究表明,髫髻山旋回火山作用是在与挤压作用相关的大陆边缘活动带构造环境下,受壳断裂控制形成的,具有造山带火山岩特征.火山岩的成岩作用以部分熔融为主,其源区物质为LREE相对富集的下部玄武质地壳. 相似文献
17.
Adel A. A. Abdel Wahed Khaled G. Ali Magdy M. A. Khalil Ahmed E. Abdel Gawad 《Arabian Journal of Geosciences》2012,5(1):29-44
The Dokhan volcanics are represented by a thick stratified lava flows succession of basalt, andesite, imperial porphyry, dacite,
rhyodacite, rhyolite, ignimbrites, and tuffs. These lavas are interbanded with their pyroclastics in some places including
banded ash flow tuffs, lithic tuffs, crystal lapilli tuffs, and agglomerates. They are typical calc–alkaline and developed
within volcanic arc environment. All rocks show moderate enrichment of most large ion lithophile elements relative to high
field strength elements (HFSE). The incompatible trace elements increase from basalt through andesite to rhyolite. The felsic
volcanics are characterized by moderate total rare earth elements (REE) contents (162 to 392 ppm), less fractionated patterns
{(Ce/Yb)N = (1.24 to 10.93)}, and large negative Eu anomaly {(Eu/Eu*) = (0.15 to 0.92)}. The mafic volcanics have the lowest REE contents
(61 to 192 ppm) and are relatively steep {(Ce/Yb)N = (3.2 to 8.5)}, with no negative Eu anomalies {(Eu/Eu*) = (0.88 to 1)}. The rhyolite displays larger negative Eu anomaly
(Eu/Eu* = 0.28) than those of other varieties, indicating that the plagioclase was an early major fractionating phase. The
mineralogical and chemical variations within volcanics are consistent with their evolution by fractional crystallization of
plagioclase and clinopyroxene. 相似文献
18.
REE data, with major element and other trace element data are reported for a suite of Archean sedimentary rocks (2800 million years old) from Kalgoorlie, Western Australia. The REE patterns fall into two groups with ?LREE/?HREE ratios of 6 and 15, respectively. The first group have either no Eu anomaly relative to chondrites, or a positive Eu anomaly, in contrast to the pronounced Eu depletion (Eu/Eu ~ 0.67) shown by younger (Post-Archean) sedimentary rocks.The problem of positive Eu enrichment relative to chondritic patterns, is examined by analysing a suite of Devonian greywackes, derived from calc-alkaline volcanic rocks. Some of these samples also show positive Eu anomalies, attributable to local accumulation of feldspar. This explanation is preferred to models involving an early anorthositic crust. The group of samples showing heavy REE depletion patterns (complementary to those observed in garnet) appear to be derived from adjacent Na-rich granites which display identical REE patterns. Locally abundant K-rich granites do not appear to have made any contribution to the Archean sedimentary rocks.The majority of the sedimentary rocks have REE patterns indistinguishable from those of recent island arc calc-alkaline rocks, and so could constitute evidence that the Archean crust was principally formed by processes analogous to present day island-arc type volcanism. However, similar REE patterns may be produced by an appropriate mixture of the common bimodal tholeiitic-felsic igneous suite commonly observed in Archean terrains. The REE data presented here do not distinguish between these two models. 相似文献
19.
20.
渤海湾盆地石炭二叠系稀土元素特征及其地质意义 总被引：7，自引：2，他引：5
采集了渤海湾盆地周缘露头剖面和盆内钻井岩心的泥岩及少量灰岩样品,采用电感耦合等离子质谱技术对样品进行了系统的稀土元素测试分析。测试样品稀土总量平均值为290.39 μg/g ,明显大于北美页岩组合样。各样品δEu为0.42~0.83,平均0.67,中度Eu负异常;大多样品Ce含量正常,δCe为0.51~1.22,平均0.97。稀土元素配分模式总体为轻稀土富集、重稀土亏损型,轻稀土段曲线明显“右倾”,重稀土段则较为“平坦”。灰岩及部分泥岩中Ce的负异常指示了晚石炭世本区陆表海的沉积环境特点,古海水为氧化环境。根据稀土元素的Eu异常及总的元素组合特点,判断渤海湾盆地石炭—二叠系沉积物主要来自盆地北缘的阴山古陆,母岩类型为花岗岩。 相似文献