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1.
Bentonites consisting mainly of montmorillonite are widely utilized in various applications. However, natural bentonites contain many kinds of impurities such as quartz, cristobalite, feldspar, zeolite, calcite etc., which can decrease the performance of bentonite. Furthermore, quartz and cristobalite are carcinogenic. Therefore purification of bentonite is critical to its applications. Among the impurities in bentonite, cristobalite is the most difficult one to get rid of because of its tiny particle size and aggregation state.  相似文献   

2.
陈伟  赵太平  魏庆国  徐勇航 《岩石学报》2008,24(10):2301-2312
铁钛磷灰岩仅由磷灰石和铁钛氧化物组成,常赋存于岩体型斜长岩中,成因上有不混溶和分异堆晶两种不同的认识。本文从磷灰石角度讨论河北大庙铁钛磷灰岩的形成机制。大庙铁钛磷灰岩常产出于浸染状Fe—P矿体内部,有时与块状铁矿石交互出现形成韵律条带状矿石,为岩浆结晶分异的产物。铁钛磷灰岩中磷灰石呈浑圆状,含量变化于15％-34％。铁钛磷灰岩的全岩和磷灰石微量元素分析显示,磷灰石比全岩相对富集稀土元素达2．96—6．93倍,但两者的配分型式基本平行。质量平衡计算（Rocl／F）的结果表明,铁钛磷灰岩中几乎100％的稀土元素赋存于磷灰石中。综合上述特征,反映磷灰石为结晶分离的堆晶矿物,铁钛磷灰岩应为堆晶成因。因为如果磷灰石结晶于铁钛磷灰岩不混溶熔体,它的稀土元素分配系数也不会变化达2．3倍（变化于2．96—6．93）。计算出该磷灰石的母岩浆稀土元素组成,与浸染状Fe．P矿石最为相似,结合它与铁钛磷灰岩之间紧密共生的野外特征以及相似的全岩及磷灰石稀土元素配分型式,认为磷灰石最可能是在浸染状Fe．P矿浆中,经结晶分离作用形成铁钛磷灰岩。  相似文献   

3.
Metamorphism of the Gile Mountain Formation and Waits River Formation in the Strafford Dome and Townshend-Brownington Syncline in east-central Vermont records two nappe-style events, D1 and D2, followed by doming. D1 formed a muscovite + biotite ± ilmenite schistosity subparallel to compositional layering, SO, and was followed by heating to garnet grade. The temperature and pressure at the end of D1 are estimated to be c . 450 C and 6-8 kbar. D2 variably crenulated and folded S1 during a nearly isothermal pressure increase of 1-2 kbar, calculated from compositions of garnet, which have inclusions trails with progressive crenulation and rotation of the S1 fabric. Similar P-T paths are computed for most of the area, suggesting that the later schistosity developed during emplacement of a regional nappe 3-6 km thick. There is a general lack of D3 (dome-stage) microstructures.
Near the Strafford-Willoughby Arch, staurolite and kyanite overgrew S2 in pelites, and plagioclase with increasing X An overgrew S2 in calcic pelites, reflecting post-D2 heating to a maximum of 550-600 C. Metamorphic pressures at the end of D2 are fairly constant on the west side of the dome, indicating minor dome-stage uplift. In contrast, pressures at the thermal peak of metamorphism decrease by more than 4 kbar east of the dome. The observed pattern of isotherms and isobars is mainly the result of post-metamorphic, differential uplift and unroofing.
Finally, a minor, retrograde metamorphism produced the assemblage albite + epidote + K-feldspar + muscovite + chlorite, with grade increasing east toward the Connecticut River.  相似文献   

4.
河北矾山杂岩体中单斜辉石的研究   总被引：3，自引：1，他引：2  
牛晓露  陈斌  马旭 《岩石学报》2009,25(2):359-373
河北矾山杂岩体属于二氧化硅不饱和的超钾质碱性-过碱性岩浆系列,由单斜辉石岩、辉石正长岩和碱长正长岩等不同类型岩石组成。各类型岩石主要组成矿物为单斜辉石、黑云母、石榴石和正长石。本文利用电子探针对单斜辉石进行了详细研究,发现所有单斜辉石属于高钙透辉石,随着岩浆的演化,主要表现为Fe2+对Mg2+的替代关系,结晶趋势为透辉石→钙铁辉石,这揭示矾山杂岩体岩浆体系的特点是高温、中等大小的氧逸度、贫硅、富碱（尤其是钾）。辉石中的AlIV含量取决于岩浆的硅饱和度,硅越不饱和,AlIV含量越高;AlVI含量则与体系中的Al含量呈正相关关系。由Al对Si的替代引起的电荷不平衡主要由八面体位置的Fe3+来补偿,其次为少量的Ti4+和更少量的Al3+。体系中的Ti含量与体系的温度呈正相关关系,而Na含量则与辉石中的Ti和Fe3+含量成正相关关系。不同类型岩石中单斜辉石从核部到边部随着Mg#的降低,Al、Ti含量呈现不同的演化趋势,这是因为它们于岩浆演化的不同阶段开始结晶,经历了不同的岩浆演化史。碱性岩中高钙辉石的出现和成分环带的普遍发育是由岩浆的贫硅富钾特征决定的。单斜辉石的成分不仅受控于结晶时的温度、压力条件,也受控于岩浆的总成分及其变异。  相似文献   

5.
In the Sesia Zone of the Western Alps, Italy, early Alpine blueschist to eclogite facies metamorphism of rocks of quartzofeldspathic composition has produced the same high-pressure assemblage of; quartz, Na-pyroxene, Na-amphibole, paragonite, phengite, zoisite, garnet, magnetite, sphene and Fe-sulphide (=the QFS assemblage) over an area (> 150 km2. Relative gradients in pressure and temperature over this region are reflected in the variations in mineral chemistries of the individual phases of the quartzofeldspathic assemblage through continuous reactions. Mineralogical discontinuities do not occur in the QFS assemblage of this region. Increases in the Jadeite content of the pyroxenes (X Jd 0.48 to X Jd 0.93) and in the glaucophane content of the amphiboles (X Gl 0.89 to X Gl 0.96) occur from the southwest to the northeast of the region studied. Analysis of coexisting garnets and pyroxenes indicate that the compositional variation of amphiboles and pyroxenes is associated with a decrease in the grossular component of the coexisting garnet. Zoned pyroxenes and garnets, together with the regional trends in mineral chemistries suggest that the evolution of the QFS assemblage with increasing pressure may be modelled by pressure-sensitive continuous reactions in which amphibole, zoisite and the more jadeitic pyroxene constitute the high-pressure assemblage. Chemographic constraints permit the positioning in pressure/temperature space of the compositional isopleths of those model continuous reactions involving these phases which meet the textural and chemical criteria observed in the natural assemblages. The low dP/dT slope (–20 bars/° C) of these isopleths causes the continuous reactions to be useful for geobarometric calculations at pressures above the absolute breakdown of albite to jadeite plus quartz. In addition the pseudobinary loops for the other continuous reactions which are potentially useful geobarometers and involve either the NaAlCa–1Mg–1 exchange or the MgCa–1 exchange are calculated. Comparison of mineral chemistries with the isopleths yields a relative barometric scheme for the localities studied. With these barometric observations, it is possible to show that the P-T path which the Sesia body travelled towards the final recorded state was one of increasing pressure. Other blueschist and eclogite occurrences from Syros and Sifnos which contain rocks of quartzofeldspathic composition are also examined.  相似文献   

6.
The paper describes an early and primitive sauropod dinosaur, Gongxianosaurus shibeiensis (gen. et sp. nov.), from the Dongyuemiao Member of the Lower Jurassic Ziliujing Formation in Shibei Township, Gongxian County, Sichuan Province, China, which is one of the 5 dinosaur fossils discovered in Gongxian in 1997. Except the skull which is incomplete, the fossils are well preserved. It has some features of both sauropods and prosauropods. It is an intermediate type in the evolution of dinosaurs from prosauropods to sauropods and provides materials for the study of the origin and evolution of the sauropod dinosaur fauna. The discovery of this new sauropod furnishes a way for the stratigraphic correlation between the Early Jurassic Ziliujing Formation in the Sichuan basin and the Lower Jurassic Lufeng Formation in the Central Yunnan basin.  相似文献   

7.
Summary Nickenichite is a new mineral found close to the village of Nickenich at the Nickenicher Sattel, Eifel, Germany. The chemical composition is NaxCayCuz(Mg, Fe, Al)3(AsO4)3, x 0.8, y 0.4, 0.4 and was derived by means of electron microprobe analyses and by a crystal structure investigation. The latter was determined from single-crystal X-ray data:a = 11.882(4)Å,b = 12.760(4)Å,c = 6.647(2)Å, = 112.81(2)°, space group C2/c,Z = 4;R = 0.053 andR w = 0.033 from 984 observed data and 102 free variables. Nickenichite is structurally related to the minerals o'danielite and johillerite. The two crystallographically different octahedrally coordinated cation positionsMe = (Mg, Fe, Al) have averageMe-O distances of 2.108 Å and 2.056 Å, octahedra share edges to form zig-zag chains in ; the chains are interconnected by AsO4 tetrahedra. In addition the compound is characterized by partially occupied Na[4+4], Ca[6+2] and Cu[4] positions.
Nickenichit, ein neues Arsenat aus der Eifel, Deutschland
Zusammenfassung Nickenichit ist ein neues Mineral, das nahe dem Ort Nickenich, am Nickenicher Sattel, Eifel, Deutschland, gefunden wurde. Die chemische Formel ist NaxCayCuz, (Mg, Fe, Al)3(AsO4)3, x 0,8, y 0,4, z 0,4 und wurde mittels Elektronenstrahl-Mikrosondenanalysen und einer Kristallstrukturuntersuchung ermittelt. Letztere wurde mit Einkristall-Röntgendaten durchgeführt:a = 11,882(4) Å,b = 12,760(4) Å,c = 6,647(2) Å, = 112,81(2)°, Raumgruppe C2/c,Z = 4;R = 0,053 undR w = 0,033 für 984 beobachtete Daten und 102 freie Variable. Nickenichit zeigt enge strukturelle Beziehungen zu den Mineralen O'Danielit und Johillerit. Die zwei kristallographisch verschiedenen oktaedrisch koordinierten KationpositionenMe = (Mg, Fe, Al) haben mittlereMe-O-Abstände von 2,108 Å und 2,056 Å, die Oktaeder werden über Kanten zu zick-zack-artigen Ketten in verknüpft, diese werden untereinander über AsO4-Tetraeder vernetzt. Des weiteren ist die Verbindung durch partiell besetzte Na[4+4]-, Ca[6+2]- und Cu[4]-Positionen charakterisiert.

With 2 Figures  相似文献   

8.
Mineralogy and petrography of six eelogite xenoliths from the Obnazhennaya kimberlite pipe ar e described. Based upon modal and mineral compositions, these eclogites can be divided into Group A (five samples) and Group B (one sample), as per Coleman et al. (1965) and Shervais et al. (1988). Group-A eclogites are orthopyroxene-bearing, and their constituent minerals have high Mg# and Cr2O3 content. The clinopyroxenes in this type of eelogite have low jadeite component. The geochemical features of Group-A eclogites are similar to garnet pyroxenite, and e believed to be the product of high-pressure fractionates from an alkaline basaltic melt in thear upper mantle. Group-B eelogite (0-82/91) contains higher Al2O3 and FeO and lower MgO and Cr2O3; its composition is similar to a high-aluminum basalt or gabbro. This eelogite could have crystallized under high pressure in the upper mantle from a basaltic melt, without significant fractionation. Alternatively, it also could be the relict of subducted oceanic crust. However, no evidence exists at present that definitively indicates a crustal origin for this Group-B eelogite xenolith.  相似文献   

9.
近2～3年来,陕西省考古研究院科研人员再次对蓝田县的新街遗址进行了抢救性发掘,经过清理整理,发现于新街遗址灰坑、探沟和探方中的全新世鸟类骨骼共70件.鸟类化石均为分散保存骨骼,但此次发现的鸟类骨骼保存不仅数量多,而且形态也较完好,是国内全新世鸟类化石发现记录所罕见的.本文记述了对这批鸟类化石开展形态解剖学的鉴定,并系统完成分类学研究的成果,新街遗址中总计鸟类所属8目、8科、8属,共9种,其中以水生鸟类居多.此外,根据鸟类的生存习性及鸟类骨骼上残存的人工痕迹,还针对新街遗址全新世时期的环境和古人类的生活行为进行了全方位多角度的分析和推理,为新街遗址在传统考古学研究的基础上提供了全新的科学信息和有益的补充.  相似文献   

10.
Harkerite, found in metamorphic ejecta of the Alban Hills associated with cuspidine, grossular, phlogopite, vesuvian, biotite, and minor amounts of diopside, aegirinaugite, leucite, magnetite and calcito, shows cubic Laue symmetry m3m, possible space groups Fm3m, F432, F43m, a0 = 14.82 Å.On the basis of isomorphous replacements suggested by the crystal structure analysis, chemical data may be represented by the formula: Ca48Mg16(AlSi4O16)4(BO3)12(CO3)20 · 4H2O. Refractive index nD = 1.6490.The relations between harkerite from Albano, harkerite from Skye and other known harkerites and sakhaites are discussed.  相似文献   

11.
This study investigated the surge dynamics of Aavatsmarkbreen, a glacier in Svalbard and its geomorphological impact based on remote sensing data and field observations. The main objective was to analyse and classify subglacial and supraglacial landforms in the context of glacial deformation and basal sliding over a thin layer of thawed, water‐saturated deposits. The study also focused on the geomorphological evidence of surge‐related sub‐ and supraglacial crevassing and glacier front fracturing. From 2006 to 2013, the average recession of Aavatsmarkbreen was 363 m (52 m a−1). A subsequent surge during 2013–2015 resulted in a substantial advance of the glacier front of over 1 km and an increase in its surface area of more than 2 km2. The surface of Aavatsmarkbreen was severely fractured. Significant ice‐flow acceleration was noted whereby the highest surface velocity reached 4.9 m day−1. The ephemeral water‐escape structures and mini‐flutings on the fine‐grained till surface that formed during the surge are indicative of high subglacial pore‐water pressure and enhanced basal sliding. Two genetic types of clast pavements occur in the marginal zone of Aavatsmarkbreen. The results of this study will help to constrain glaciological and geomorphological processes involved in surge phenomena. Understanding the scale and effects of these processes provides insight into the behaviour of fast‐flowing glaciers and ice streams and reveals their relationships with external factors.  相似文献   

12.
The tectonics of the Chenoua massif suggests block rotations of Neogene nappes associated with the African–European plate convergence. To estimate the extent of these rotations, a Paleomagnetic study on rhyolites and andesites of Langhian–Serravallian age and sandstones of Burdigalian age was carried out on 23 sites (200 specimens). The sites are distributed in the northwestern, southeastern and southern Chenoua massif. One or two components of magnetization, mainly carried by magnetite, pyrrhotite and/or hematite, were isolated in sandstones and volcanics. The sandstone sites reveal magnetizations in sandstones from the Cap Blanc syncline that are post-folding. However, both polarities are found, which is consistent with data from Africa during the Upper Miocene. Clockwise and counterclockwise rotations were recorded, dating back to the Neogene times in volcanics and sediments. From the faulted Cap Blanc syncline counterclockwise rotations of 1?±?4° to 18?±?28° around a vertical axis occurred in sediments since the Miocene with respect to Africa. In fact, remagnetizations occurred at several periods of time and in different sites, providing information on the evolution of post-tectonic rotations. Some volcanics record counterclockwise rotations of about 30° since the Miocene, whereas others do not show any significant rotation. This can be explained by the direction of the principal compressive stress axis σ 1 and by lateral extrusions related to an indentation model, in which we expect both clockwise and counterclockwise rotations.  相似文献   

13.
In polymetamorphic pelites of the Rappold complex in the Wölz crystalline basement (Eastern Alps) reaction rim garnets at staurolite-quartz interfaces (type I) and single grain garnets along previous staurolite-white mica interfaces (type II) were formed. The garnet reaction rims were formed during the Cretaceous amphibolite facies metamorphic overprint of the pre-existing mineral assemblages comprising garnet, staurolite, and kyanite from an amphibolite facies metamorphic event probably of Variscian age. The newly formed garnet may take the form of reaction rims along the margins of large pre-existing staurolite blasts. The initial growth increments of garnet have low grossular content, and reaction rim growth was controlled by the transfer of Fe, Mg and Mn components from the staurolite-garnet interface to the quartz-garnet interface. Later garnet growth increments have relatively high grossular content due to consumption of matrix plagioclase, which was destabilized by successive pressure increase. The grossular content of newly formed garnet shows systematic increase towards sites where plagioclase breaks down indicating that transport of calcium through the matrix was sluggish. On the basis of reaction microstructures it is demonstrated that the mineral assemblage garnet?+?kyanite?+?biotite?+?paragonite was formed at the conditions of eo-alpine amphibolite facies overprint while staurolite and plagioclase broke down successively with increasing pressure.  相似文献   

14.
The results of recent magnetic measurements in the southern part of the Sea of Galilee, Israel and in the land area south of it, indicate the presence in the subsurface of elongated intrusive bodies of basic composition. These bodies are thought to be associated with faults which formed a rhomb shaped graben during movement along the main Jordan Rift Valley shear system and may mark the southern boundary of that graben. If that is the case, the Sea of Galilee may be considerably shorter in the N-S direction than previously thought. The proposed new dimensions of the graben as outlined in this study are more readily explained by the accepted mechanisms for the formation of rhomb shaped grabens.  相似文献   

15.
A new partial skeleton of the armoured ornithischian dinosaur Polacanthus found in the Wadhurst Clay Formation (Valanginian stage) of Bexhill, Sussex is the oldest recorded occurrence of this taxon. Previous discoveries suggested that at least two armoured ornithischians occur in the Wealden succession: Polacanthus, which was mostly restricted to the Barremian, and Hylaeosaurus, which was recorded as present only in the Valanginian. The new discovery extends the stratigraphic range of Polacanthus into the Valanginian. Although these two taxa appear to be closely similar anatomically, their osteology now suggests they are not synonymous. The new specimen includes the first known jugal as well as a comparatively rare polacanthid plate/spine (splate) which probably comes from the shoulder (pectoral) area of these animals.  相似文献   

16.
Nineteen volcanic and magmatic rock samples were collectecd from the Jinding leadzinc deposit and its surrounding areas in Yunnan.The ICP and AES analyses,feferred to the previous results,show that the metal minerals and altered rocks in the Jinding lead-zinc deposit display a decreasing trend of ∑REE from the early to late stages of mineralization,and similarities in REE distribution patterns,indicating that the ore fluids are characterized by high LREE enrichment,markedly negative δCe anomaly and slight δEu anomaly.These REE distribution paterns exhibit striking similarities to those of the Pliocene trachyte in the study area,both of which are similar in ∑REE,LREE/HREE ratio,δEu and δCe.The ore fluids besides the basin fluids in the deposit are also closely related to those associated with Pliocene trachyte magmas.  相似文献   

17.
A first report of discovery of spherules, glassy balls, highly magnetic fine dust and microbracciated matrix in the Fatehgarh Formation of Barmer Basin, Rajasthan, India is being presented in this paper. The Fatehgarh Formation is a mixed siliciclastic, carbonate and phosphorite formation of Cretaceous age in the Barmer Basin that comprises sediments of Middle Jurassic to Lower Eocene age. The phosphorite zone in the Fatehgarh Formation is 8 metre-thick zone that comprises phosphatic sandstone, bone bed, bedded phosphorite and phosphatic and non phosphatic gastropod beds. The spherules occur in a thin phosphatic-clay mud and silt band of bone bed, which also yielded a very rich and diverse microvertebrate assemblage with a dominant Late Cretaceous (Maastrichtian) form of Igdabatis along with forms comprising of Semionodontid, Lapisosteum and Enchodontid. The end Cretaceous is marked for a mass extinction of numerous species including dinosaurs. An extraterrestrial impact is interpreted as the reason for this mass extinction. Whether these spherules are related to the volcanic source or K/T Boundary impact ejecta found at Caribbean and Gulf of Mexico region needs detailed chemical and age characterization for which study is in progress.  相似文献   

18.
Alkali amphiboles from Type III and Type IV metamorphic zonesin blueschist facies rocks of Cazadero, California, and fromcomparable New Caledonian rocks have been characterized by X-raycrystallographic, optical, and chemical methods. The compositionof any particular alkali amphibole is strongly controlled bythe bulk composition of the host rock. Within the blueschistfacies, metamorphic zones are not characterized by changes inamphibole composition. All the alkali amphiboles studied hereinbelong to the C2/m space group and complete miscibility betweenglaucophane and riebeckite has been demonstrated for the conditionsprevailing during metamorphism in the Cazadero and New Caledonianblueschists. Linear relationships are found between unit-celldimensions and variations in composition between glaucophaneand riebeckite. The alkali amphiboles of glaucophane compositionsbelong to the high pressure-low temperature series, glaucophaneII-riebeckite. Limited miscibility of actinolite in glaucophanemay be characteristic of blueschist facies metamorphism.  相似文献   

19.
西藏罗布莎铬铁矿体围岩方辉橄榄岩中的异常矿物   总被引：14，自引：8，他引：6  
近些年,我们在西藏罗布莎蛇绿岩型铬铁矿中发现金刚石和柯石英等超高压矿物和异常地幔矿物,成果多次在美国AGU会议上做特邀报告,发表在2007年(Geology)和国内期刊上,并有4个新矿物获得国际新矿物委员会批准.这些成果在国内外引起广泛关注,也引发出一系列新的科学问题,例如,金刚石的赋存状态,物质来源和成因?与其伴随的铬铁矿的成因,与金刚石的关系?两者形成的地质背景、物理化学环境、保存和运移的规律、机制,等等.为了探讨这些问题,我们认为除了研究罗布莎铬铁矿之外,还应该开展铬铁矿的围岩地幔橄榄岩的研究,看看它们中都有什么矿物,与铬铁矿中的矿物究竟存在什么异同以及两者之间的成因联系?为此,我们从西藏罗布莎铬铁矿31号矿体不同高度取回两个各自为1吨重的方辉橄榄岩围岩样品,开展人工重砂矿物的分选.通过矿物成分、激光拉曼和X射线衍射光谱的研究,从中识别出金刚石等50余种矿物.经初步对,认为铬铁矿围岩方辉橄榄岩中发现的矿物组合与铬铁矿中相似,表明两者存在成因上的联系,并可能共同经历了从深部到浅部的地质过程.  相似文献   

20.
扬子板块西北缘新元古代岩浆作用的研究对于探讨Rodinia超大陆的构造演化具有重要意义,对米仓山新民地区角闪辉长岩的岩石学和地球化学分析结果表明,岩石Si O2含量较低且变化范围较小,岩石富Al和Ca,低K、Ti、P,Mg#值中等,属于亚碱性低钾拉斑岩石系列。岩石具有稀土元素总量相对较低、相对富集轻稀土元素和轻重稀土元素分馏程度低的特征,具弱Eu正异常,δEu=1.03~2.36。岩石总体上富集大离子亲石元素(Rb、Ba、Sr),亏损高场强元素(Nb、Zr、Hf、Th等),87Sr/86Sr=0.703 858,143Nd/144Nd=0.512 617,εNd(t)=+3.1。综合区域地质、地球化学特征,该岩体岩浆起源于亏损地幔的部分熔融,在上升侵位过程中可能受到了地壳物质的混染。在这时期,扬子板块北缘处于汇聚环境,新民角闪辉长岩形成于弧后盆地的构造环境,是Rodinia超大陆在新元古代期间演化过程中岩浆作用的产物。  相似文献   

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