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1.
以固体废弃物粉煤灰基地质聚合物为基本骨架,通过水热合成法将其原位转化为自支撑Na P型沸石分子筛型体,并研究了水热过程中碱液浓度、碱液体积、水热温度和水热时间对NaP型沸石分子筛结晶程度、形貌和机械强度的影响,得到粉煤灰基地质聚合物原位转化Na P型沸石分子筛型体的适宜条件为水热温度100℃、NaOH浓度2.0mol/L、NaOH体积50 m L、水热时间24 h。所得Na P型沸石分子筛型体的抗压强度为23.21 MPa,BET比表面积为50.46 m~2/g,已达到工业生产P型沸石的水平。该法工艺简单,环境友好,可控成型。在此方法的基础上通过改变原料配比和反应条件,可以合成其他类型的沸石分子筛型体。 相似文献
2.
利用粉煤灰处理含铜废水的实验研究 总被引：8，自引：0，他引：8
研究了粉煤灰去除废水中铜离子的速率、粉煤灰投加量对粉煤灰去除废水中铜离子的影响和粉煤灰对质量浓度不同的含铜离子废水的去除效果,进一步探讨了粉煤灰去除铜离子的机理,实验结果显示粉煤灰在去除废水中铜离子的过程中反应3 h后就达到了平衡,粉煤灰对Cu2 的去除率随粉煤灰投加量的增加而增加,但是就充分利用吸附剂粉煤灰的角度而言,并非其投加量越多去除量越大,粉煤灰吸附废水中的铜离子更符合Langmuir模型,而不是Freundlich模型;粉煤灰去除废水中的Cu2 主要是静电吸附、阳离子交换吸附和表面络合吸附作用,但是,当用碱性粉煤灰处理质量浓度较低的含Cu2 废水时,生成Cu(OH)2的沉淀作用可能占主要的地位. 相似文献
3.
利用粉煤灰制备高纯氧化铝纳米粉体的研究 总被引：1，自引：0，他引：1
地球资源的充分利用已成为当今人们普遍关注的问题之一。采用苏打(Na2CO3)焙烧沥滤工艺从粉煤灰烧结料浸出液中制取了高纯超细氢氧化铝,进而通过控制煅烧制得氧化铝纳米粉体。对制备氧化铝的活化过程、浸出过程和煅烧过程的化学原理与工艺控制进行了研究与分析,确定了制备高纯氧化铝纳米粉体的较佳实验条件和工艺参数。应用XRD、TEM、BET和ICP等微观分析手段对所得Al2O3 的形态、结构和纯度进行了表征。结果表明:焙烧、水煮粉煤灰和Na2CO3,并精确调节溶出液的pH值,可使超细的氢氧化铝沉淀析出。在85 ℃充分干燥后,分别于800 ℃、1 100 ℃煅烧2 h,得到晶型结构分别为γAl2O3 和αAl2O3 的氧化铝纳米粉体,其形态为纤维状和球状,比表面积分别为238.9 m2/g和16.82 m2/g,平均粒径为20~40 nm,纯度大于99.9%。 相似文献
4.
以燃煤电厂中的粉煤灰为载体,采用水浴加热法将氢氧化镁负载在粉煤灰表面制备成复合粉体而应用于吸附矿山地质灾害发生后水溶液中的铜离子。通过扫描电镜加自带EDS能谱、比表面积分析仪、X射线衍射、红外光谱等技术对改性后的粉煤灰进行了表征。结果表明,改性后粉煤灰明显具有H3型滞回线,表明改性粉煤灰具有丰富的介孔,具体表现为平均孔容从0.005 m3/g增加至0.035m3/g,平均孔径由10.23nm增加至13.52nm,孔隙宽度从11.36nm增加至14.05nm,比表面积由原来粉煤灰1.09m2/g增加至35.31m2/g。改性后复合粉体去除Cu(Ⅱ)的效率明显高于粉煤灰。复合粉体材料对Cu(Ⅱ)吸附主要通过静电吸引、沉淀反应等方式进行。 相似文献
5.
采用辽宁某矿山的硼废水,研究了轻烧白云石对废水中硼的吸附及其影响因素,硼在矿物表面的吸附状态以及吸附作用机理,确定了实验最佳条件。在20mL反应体系中,反应温度为25℃,溶液pH为9.5～10.5,白云石(热处理温度750℃,粒径200～300目)矿样用量为2.0g,反应3h后,除硼率可达90%以上。pH9.2时,矿物对硼的吸附作用甚微;9.2pH12(轻烧白云石的零电荷点)时,溶液中的B(OH)4-被吸附到矿物表面,吸附机制为外层络合模式,此过程中OH-浓度是硼吸附量的重要控制因素;pH12时,矿物表面带负电,无静电吸附作用。通过XPS及红外光谱分析,硼以硼氧四面体的络合结构形式吸附于矿样表面。 相似文献
6.
CO2流体-长石相互作用实验研究 总被引：1，自引：0，他引：1
不同温度下(100、200、300℃)CO2流体与富钾长石和斜长石的水热实验表明:随着温度的升高,长石的溶蚀强度逐渐加大,且钠长石的溶蚀程度强于钾长石。在CO2流体与富钾长石及斜长石反应后,200℃和300℃时样品表面均有球粒状、棒状及花状的水铝矿生成,且200℃时样品表面有菱铁矿生成;在CO2流体与斜长石反应后,300℃时样品表面有球形的氧化亚铁析出。这表明CO2能够以碳酸盐的形式在矿物中"固定",其被"固定"的上限温度为200℃左右。 相似文献
7.
水热条件下利用微波加热从粉煤灰合成沸石研究 总被引：14，自引：0，他引：14
着重选用NaOH水溶液为反应前驱物, 通过改变反应温度、NaOH浓度与合成时间等参数, 在水热条件下利用微波加热直接对粉煤灰进行晶化, 合成得到了浊沸石、菱沸石、NaP1沸石3种沸石.粉煤灰转化为沸石率约15%~40%.研究表明: (1) 反应体系在15min左右即有合成沸石产生, 30min左右合成沸石转化率达到最佳; (2) 为保证沸石晶核生成和晶体的生长, 反应体系的溶液/粉煤灰比不应低于2.5; (3) 在溶液/粉煤灰比为2.5时, 应控制加热时间在30min左右. 相似文献
8.
低阶煤显微组分对一氧化碳的吸附性能 总被引：1，自引：0，他引：1
研究低阶煤中不同显微组分对CO气体的吸附性能,对低阶煤自燃发火的预测与防治具有指导意义。对低阶煤中的惰质组与镜质组分别进行了30℃、40℃、50℃、55℃、60℃和65℃的等温吸附实验以及煤质分析、煤岩分析和傅立叶红外光谱(FTIR)分析。结果表明:当温度一定(T≤50℃)时,煤对CO的吸附量与压力之间的关系可用Langmuir方程来描述;当温度较高(T>50℃)时,煤对CO的吸附量与压力之间呈线性增加关系,且可采用Henry方程来描述,但此时温度对煤吸附CO的影响较复杂,有待进一步研究;此外,因低阶煤中的丝质体、含氧官能团和负电性官能团含量普遍较高,尤其羟基—OH含量较高,从而对煤中惰质组吸附CO产生较大的影响,而对镜质组吸附CO的影响较小。 相似文献
9.
本文研究了Na2O添加量和烧结温度对粉煤灰合成莫来石材料性能、晶体结构和显微形貌的影响。结果表明,Na2O可较大辐度降低粉煤灰合成莫来石的温度。在1300℃,Na2O添加至2%时,生成的莫来石细小,含量较高,但试样强度不高;Na2O添至4%时,莫来石发育为长柱状,长径比约8～12,并且相互交错成网状,材料的机械强度较高,抗折强度为97.71MPa,莫来石相对含量为76.1%;Na2O添加至8%时,莫来石含量明显减少,晶形变为不规则状。在一定范围内,材料的体积密度、烧成线收缩率和抗折强度均随温度的升高而增大,莫来石含量也相应增多。 相似文献
10.
利用测温法和核磁共振法测量了不同浓度典型盐溶液（NaCl、Na2CO3）饱和重塑粉土的冻结温度及冻结特征曲线，并与不同浓度的NaCl、Na2CO3纯溶液作对比分析，研究初始含盐量对冻结温度及未冻水含量的影响。结果表明：土样冻结温度随初始含盐量的增加而逐渐降低；相同浓度NaCl溶液饱和土样的冻结温度低于相应纯溶液的冻结温度，但相同浓度 （<0.6 mol/L）Na2CO3溶液饱和土样的冻结温度却比纯溶液的冻结温度高；同一负温下，土样中未冻水含量随NaCl初始含盐量的增加而增多，但随Na2CO3初始含盐量的变化不明显。通过机制分析，表明盐类型和含盐量对土水势具有不同的影响。基于改进的广义Clapeyron方程，将含盐分土冻结温度表达式引入未冻水含量预测模型，得到了能够考虑不同含盐量影响的土体未冻水含量的定量表达，并与实测数据进行对比，验证了该模型能够较为合理的预测不同温度下含盐土体的未冻水含量。 相似文献
11.
Emily Keeble David I. Whiteside Michael J. Benton 《Proceedings of the Geologists' Association. Geologists' Association》2018,129(2):99-119
Pant-y-ffynnon Quarry in South Wales yielded a rich cache of fossils in the early 1950s, including articulated specimens of new species (the small sauropodomorph dinosaur Pantydraco caducus and the crocodylomorph Terrestrisuchus gracilis), but no substantial study of the wider fauna of the Pant-y-ffynnon fissure systems has been published. Here, our overview of existing specimens, a few described but mostly undescribed, as well as freshly processed material, provides a comprehensive picture of the Pant-y-ffynnon palaeo-island of the Late Triassic. This was an island with a relatively impoverished fauna dominated by small clevosaurs (rhynchocephalians), including a new species, Clevosaurus cambrica, described here from a partially articulated specimen and isolated bones. The new species has a dental morphology that is intermediate between the Late Triassic Clevosaurus hudsoni, from Cromhall Quarry to the east, and the younger C. convallis from Pant Quarry to the west, suggesting adaptive radiation of clevosaurs in the palaeo-archipelago. The larger reptiles on the palaeo-island do not exceed 1.5?m in length, including a small carnivorous crocodylomorph, Terrestrisuchus, and a possible example of insular dwarfism in the basal dinosaur Pantydraco. 相似文献
12.
The effect of water on accessory phase solubility in subaluminous and peralkaline granitic melts 总被引：4，自引：0，他引：4
The solubilities of columbite, tantalite, wolframite, rutile, zircon and hafnon were determined as a function of the water contents in peralkaline and subaluminous granite melts. All experiments were conducted at 1035 °C and 2 kbar and the water contents of the melts ranged from nominally dry to approximately 6 wt.% H2O. Accessory phase solubilities are not affected by the water content of the peralkaline melt. By contrast, solubilities are affected by the water content of the subaluminous melt, where the solubilities of all the accessory phases examined increase with the water content of the melt, up to 2 wt.% H2O. At higher water contents, solubilities are nearly constant. It can be concluded that water is not an important control of accessory phase solubility, although the water content will affect diffusivities of components in the melt, thus whether or not accessory phases will be present as restite material. The solubility behaviour in the subaluminous and peralkaline melts supports previous spectroscopic studies, which have observed differences in the coordination of high field strength elements in dry vs. wet subaluminous granitic glasses, but not for peralkaline granitic glasses. Lastly, the fact that wolframite solubility increases with increasing water content in the subaluminous melt suggests that tungsten dissolved as a hexavalent species. 相似文献
13.
Muriel Rocher Stéphane Baize Stéphane Jaillet Edward Marc Cushing Yannick Lozac&#x;h Francis Lemeille 《Comptes Rendus Geoscience》2003,335(8):701-708
Calcite samples were extracted both from the rock matrix and the superficial coating of a karstified fault plane of an underground quarry, located in the eastern border of the Paris basin. The karstification is dated as Quaternary. Analysis of mechanical calcite twinning reveals that only the calcite matrix has also undergone a compression trending WNW that can be attributed to the Mio-Pliocene alpine collision. Both coating and matrix have undergone a strike-slip regime with σ1 roughly trending north–south, that could correspond to the regional present-day state of stress, a strike-slip compression rather trending NNW, modified by local phenomena. To cite this article: M. Rocher et al., C. R. Geoscience 335 (2003). 相似文献
14.
正20141756 Chen Ruige(Mathematical College,China University of Geosciences,Beijing100083,China);Zhou Xun Numerical Simulation of Groundwater Level Fluctuation in a Coastal Confined Aquifer with Sloping Initial Groundwater Level Induced by the Tide(Geological Bulletin of China,ISSN1671-2552,CN11-4648/P,32(7),2013,p.1099-1104,6 illus.,16 refs.) Key words:confined water,groundwater level 相似文献
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正20141408 Cai Jia(Institute of Geology,Chinese Academy of Geological Sciences,Beijing100037,China);Liu Fulai Petrogenesis and Metamorphic P-T Conditions of Garnet-Spinel-Biotitebearing Paragneiss in Danangou Area,Daqingshan-Wulashan Metamorphic Complex Belt(Acta Petrologica Sinica,ISSN1000-0569,CN11-1922/P,29(7), 相似文献
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正20142386An Guoying(China Aero Geophysical Survey and Remote Sensing Center for Land and Resources,Beijing 100083,China)Application of Satellite Remote Sensing in Regional Hydrogeological Investigation:Taking Cenozoic Strata in Wenquan Sheet(1∶250 000)of Karakoram Range as an Example(Geosci- 相似文献
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正20141016An Chengbang(Key Laboratory of Western China’s Environmental Systems,Ministry of Education,Lanzhou University,Lanzhou 730000,China);Zhao Yongtao Lake Records during the Last Glacial Maximum from Xinjiang,NW China and Their Climatic Impli- 相似文献
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正20141538 Cao Qing(School of Earth Sciences and Engineering,Xi’an Petroleum University,Xi’an 710065,China);Zhao Jingzhou Characteristics and Significance of Fluid Inclusions from Majiagou Formation,Yichuan Huangling Area,Ordos Basin(Advances in Earth Science,ISSN1001-8166,CN62-1091/P,28(7),2013,p.819-828,7 illus.,3 tables,43 refs.) 相似文献
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正20142002 Wei Hualing(Institute of Geophysical and Geochemical Exploration,Chinese Academy of Geological Sciences,Langfang065000,China);Zhou Guohua Element Content and Mineral Compositions in Different Sizes of Soil in Tongling Area,Anhui Province(Geological Bulletin of China,ISSN1671-2552,CN11-4648/P,32(11),2013,p.1861 相似文献