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1.
Typical Ca---Cl brines occur in crystalline and metamorphic rocks below freshwater horizons at various localities in Sweden and Finland. Total dissolved solids (TDS) range in concentration between 2 and 120 gl−1 and have long been thought to derive from water-rock interactions. The relationships between Na, Cl and Br in these brines suggest, however, that they were derived from freezing of seawater during glacial periods. The brines were subsequently diluted by meteoric waters and their Ca/Mg ratio was increased through water-rock interactions in the subsurface. The hydrogeological model for both the formation of freeze-derived marine brines and their lateral intrusion involves restricted inland marine basins in recent and subrecent polar climatic belts. Seawater in such basins gradually freezes in response to glaciation. The solutes which concentrate in the remaining water body are residual after precipitation of a sequence of minerals which include carbonates, mirabilite and hydrohalite. Hydraulic pressure of the growing ice sheet over the frozen seas is gradually added to the ambient hydrostatic pressure exerted on the brines. This, together with their increased density, increases the intrusional potential of the brines. As the land ice cannot exert hydraulic pressure on continental groundwater in the aquifers, the balance of pressure favours deep landward intrusion of brines. Post-glacial processes cause the subsurface dilution and replacement of the brines both by seawater and fresh waters. The presence of such brines also far from present-day coastal settings reflects the shifting of coastlines as a result of isostatic movements and eustatic sea-level changes associated with glaciation and deglaciation.  相似文献   

2.
《Marine pollution bulletin》2014,78(1-2):118-129
There is a growing concern of seawater intrusion to freshwater aquifers due to groundwater overexploitation in the eastern coastal belt of Southern India. The problem becomes complex in the regions where industrial effluents are also contaminating the freshwater aquifers. In order to understand the hydrochemical complexity of the system, topographic elevation, static water level measurements, major ion chemistry, ionic cross plots, water type contours and factor analysis were applied for 144 groundwater samples of shallow and deep sources from Quaternary and Tertiary coastal aquifers, located within the industrial zone of 25 km2 area near Cuddalore, Southern India. The ionic cross plots indicates dissolution of halite minerals from marine sources and seawater mixing into inland aquifers up to the level of 9.3%. The factor analysis explains three significant factors totaling 86.3% of cumulative sample variance which includes varying contribution from marine, industrial effluent and freshwater sources.  相似文献   

3.
The coastal aquifers and inland waters of the Long Xuyen Quadrangle and Ca Mau Peninsula of southern Vietnam have been significantly impacted by sea water intrusion (SI) as a result of recent anthropogenic activities. This study identified the evolution and spatial distribution of hydrochemical conditions in coastal aquifers at this region using Hydrochemical Facies Evolution Diagram (HFE-D) and Geographical Information System mapping. Hydraulic heads and water chemistry were measured at 31 observation wells in four layered aquifers during dry and rainy seasons in early (2005), and more recent (2016), stages of agricultural development. Hydrochemical facies associated with intrusion or freshening stages were mapped in each aquifer after assigning mixing index values to each facies. The position of groundwater freshening and SI phases differed in Holocene, Upper Pleistocene, Middle Pleistocene, and Lower Pleistocene aquifers. The geographic position of freshening and intrusion fronts differ in dry and rainy seasons, and shifted after 11 years of groundwater abstraction in all four aquifers. The spatial and temporal differences in hydrochemical facies distributions according to HFE-D reflect the relative impact of SI in the four aquifers. The study results provide a better understanding of the evolution of groundwater quality associated with SI in a peninsular coastal aquifer system, and highlight the need for improving groundwater quality and management in similar coastal regions.  相似文献   

4.
Abstract

In the Dobrich region, with an area of a little over 4000 km2, two important aquifer systems can be differentiated, which we have named the Upper and Deep Aquifers. The hydrodynamic and hydrogeochemical characteristics of these two aquifers are different. Agricultural activities, livestock units, and urban waste waters and solid wastes constitute the principal sources of contamination of the Upper Aquifer. Furthermore, signs of marine intrusion in some coastal zones have been detected. The Deep Aquifer is found to be affected by hydrogeochemical processes related to hydrocarbons that generate elevated concentrations of H2S and NO2 (which may exceed 10 mg 1?1). This aquifer has numerous deep overflowing boreholes that lack appropriate capping, with the consequent loss of resource, draining in the order of 4 m3 s?1 of thermal and sulphurous waters.  相似文献   

5.
Sea levels are expected to rise as a result of global temperature increases, one implication of which is the potential exacerbation of sea water intrusion into coastal aquifers. Given that approximately 70% of the world's population resides in coastal regions, it is imperative to understand the interaction between fresh groundwater and sea water intrusion in order to best manage available resources. For this study, controlled investigation has been carried out concerning the temporal variation in sea water intrusion as a result of rising sea levels. A series of fixed inland head two‐dimensional sea water intrusion models were developed with SEAWAT in order to assess the impact of rising sea levels on the transient migration of saline intrusion in coastal aquifers under a range of hydrogeological property conditions. A wide range of responses were observed for typical hydrogeological parameter values. Systems with a high ratio of hydraulic conductivity to recharge and high effective porosity lagged behind the equilibrium sea water toe positions during sea‐level rise, often by many hundreds of meters, and frequently taking several centuries to equilibrate following a cease in sea‐level rise. Systems with a low ratio of hydraulic conductivity to recharge and low effective porosity did not develop such a large degree of disequilibrium and generally stabilized within decades following a cease in sea‐level rise. This study provides qualitative initial estimates for the expected rate of intrusion and predicted degree of disequilibrium generated by sea‐level rise for a range of hydrogeological parameter values.  相似文献   

6.
Aquifers are inherently susceptible to contamination and coastal aquifers in specific are highly vulnerable to sea water intrusion. For efficient planning and management of coastal aquifers in Kayalpattu and Tiruchopuram villages, which extend over 4·05 km2, it is essential to delineate and predict the extent of intrusion into the shallow aquifer. Management of ground water in coastal aquifers is composed of major elements that should be properly evaluated, and special attention is given to the sea water intrusion problem. Different data, like hydro‐geomorphological and depth‐wise iso‐apparent resistivity, are integrated spatially using a geographical information system. The stack‐unit mapping approach is used to delineate the zones with iso‐apparent resistivity of less than 10 Ω m have been found to be increasing in areal extent with reference to depth. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

7.
Allen DM 《Ground water》2004,42(1):17-31
Stable isotopes of 18O and 2H in water, and 34S and 18O in dissolved SO4, are used to verify the interpretation of the chemical evolution and proposed sources of salinity for two islands that have undergone postglacial rebound. Results for delta18O and delta34S in dissolved SO4 on the Gulf Islands, southwest British Columbia, Canada, suggest a three-component mixing between (1) atmospheric SO4 derived largely from recharge of meteoric origin, (2) modern marine SO4 associated with either modern-day salt water intrusion or Pleistocene age sea water, and (3) terrestrial SO4. The age of the marine SO4 is uncertain based on the geochemistry and SO4 isotopes alone. Two options for mixing of saline ground waters are proposed--either between current-day marine SO4 and atmospheric SO4, or between older (Pleistocene age) marine SO4 and atmospheric SO4, delta18O and delta2H compositions are relatively consistent between both islands, with a few samples showing evidence of mixing with water that is a hybrid mixture of Fraser River water and ocean water. The isotopic composition of this hybrid water is approximately delta18O = 10 per thousand. delta18O and delta2H values for many saline ground waters plot close to the global meteoric water line, which is distinctly different from the local meteoric water line. This suggests a meteoric origin for ground waters that is different from the current isotopic composition of meteoric waters. It is proposed these waters may be late Pleistocene in age and were recharged when the island was submerged below sea level and prior to rebound at the end of the last glaciation.  相似文献   

8.
Sea water intrusion into aquifers is problematic in many coastal areas. The physics and chemistry of this issue are complex, and sea water intrusion remains challenging to quantify. Simple assessment tools like analytical models offer advantages of rapid application, but their applicability to field situations is unclear. This study examines the reliability of a popular sharp‐interface analytical approach for estimating the extent of sea water in a homogeneous coastal aquifer subjected to pumping and regional flow effects and under steady‐state conditions. The analytical model is tested against observations from Canada, the United States, and Australia to assess its utility as an initial approximation of sea water extent for the purposes of rapid groundwater management decision making. The occurrence of sea water intrusion resulting in increased salinity at pumping wells was correctly predicted in approximately 60% of cases. Application of a correction to account for dispersion did not markedly improve the results. Failure of the analytical model to provide correct predictions can be attributed to mismatches between its simplifying assumptions and more complex field settings. The best results occurred where the toe of the salt water wedge is expected to be the closest to the coast under predevelopment conditions. Predictions were the poorest for aquifers where the salt water wedge was expected to extend further inland under predevelopment conditions and was therefore more dispersive prior to pumping. Sharp‐interface solutions remain useful tools to screen for the vulnerability of coastal aquifers to sea water intrusion, although the significant sources of uncertainty identified in this study require careful consideration to avoid misinterpreting sharp‐interface results.  相似文献   

9.
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10.
This article studies the effect of drought and pumping discharge on groundwater supplies and marine intrusion in the Korba aquifer (Cap‐Bon peninsula, Tunisia). The Groundwater Modelling System has been used to model the groundwater flow and to simulate the seawater intrusion. The calibration is based on the groundwater levels in the steady state from 1963, and in the transient state from the groundwater levels from 1963 to 2005. The main objective is to quantify the components of the groundwater mass balance and to estimate the hydraulic conductivity distribution. The impact of pumping discharge on the groundwater level evolution has been examined by two pumping scenarios P1 (no. 8420) and P2 (no. 8862) wells. The hydrodynamic modelling shows the increasing drawdowns after 14 years of pumping: 4 m in P1 well and about 5 m in P2 well below sea level. The drawdowns are accompanied by the inverse hydraulic gradient. The numerical model was used to discuss the management of the groundwater resources of Cap‐Bon. As the population continues to grow and the demand for groundwater pumping intensifies beyond the 1963 level, it can be expected that the actual extent of seawater intrusion in the future would be more severe than the model prediction. Better strategies for groundwater development and management will be necessary to protect the freshwater aquifers to the marine intrusion. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

11.
An integrated study with the use of uranium-isotope and microelement hydrogeochemical methods showed the possibility of studying changes in the dynamics and geoenvironmental condition of groundwater in an urban area by the indicator modeling of groundwater formation and circulation, as well as interaction of waters from different horizons, including water ingress from deeper aquifers.  相似文献   

12.
Frost CD  Toner RN 《Ground water》2004,42(3):418-432
87Sr/86Sr ratios of ground waters in the Bighorn and Laramie basins' carbonate and carbonate-cemented aquifer systems, Wyoming, United States, reflect the distinctive strontium isotope signatures of the minerals in their respective aquifers. Well water samples from the Madison Aquifer (Bighorn Basin) have strontium isotopic ratios that match their carbonate host rocks. Casper Aquifer ground waters (Laramie Basin) have strontium isotopic ratios that differ from the bulk host rock; however, stepwise leaching of Casper Sandstone indicates that most of the strontium in Casper Aquifer ground waters is acquired from preferential dissolution of carbonate cement. Strontium isotope data from both Bighorn and Laramie basins, along with dye tracing experiments in the Bighorn Basin and tritium data from the Laramie Basin, suggest that waters in carbonate or carbonate-cemented aquifers acquire their strontium isotope composition very quickly--on the order of decades. Strontium isotopes were also used successfully to verify previously identified mixed Redbeds-Casper ground waters in the Laramie Basin. The strontium isotopic compositions of ground waters near Precambrian outcrops also suggest previously unrecognized mixing between Casper and Precambrian aquifers. These results demonstrate the utility of strontium isotopic ratio data in identifying ground water sources and aquifer interactions.  相似文献   

13.
Abstract

Vertical electrical resistivity soundings were measured near hydrological observation wells in order to ascertain whether geophysical means could be used to map saline water intrusion into a fresh water aquifer in Israel. The soundings showed that the low resistivity layers associated with the salt water are readily discernible. The technique was applied to the entire coastal belt and resulted in a detailed study of the saline water body and its extent. Measurements were repeated six years later and good agreement between the two sets of measurements was noted. This technique is therefore judged to be an accurate tool for the mapping of salt water intrusion in fresh-water aquifers.  相似文献   

14.
Measurements of electrical resistivity have long been used to find freshwater resources below the earth's surface. Recently, offshore resistivity and electromagnetic techniques have been used to map occurrences of submarine groundwater originating from the offshore extension of terrestrial aquifers. In many cases, observations of a high resistivity (low conductivity) anomaly in the seafloor are sufficient to suggest the presence of fresh (and less conductive) pore waters. Data from offshore Wrightsville Beach, NC show highly variable resistivity structure, with moderately high resistivity at depths of ～20 m subsurface that is at least in part caused by lithologic complexity in an underlying limestone unit, the Castle Hayne. These offshore results suggest caution in the interpretation of resistivity anomalies simply in terms of groundwater volumes. In contrast, low onshore resistivities show evidence for intrusion of saltwater into the subsurface beneath the beach, adjacent to areas of pumping for water supply.  相似文献   

15.
Small, inconspicuous fragments of plastic, generally < 0.5 mm across (i.e. microlitter) derived from some hand cleaners and cosmetic preparations, and also used with some airblast cleaning media, are an unusual addition to post-consumer waste entering marine waters. The environmental significance of this material is unknown, but here is a further example of the intrusion of anthropogenic waste of dubious value into marine ecosystems. It could impact sea-surface microlayer ecosystems and the meiofauna of intertidal sediments. It is also speculated that these finely granulated plastics, once dispersed through the oceanic water column, could prejudice the results of some ambitious particulate carbon flux experiments as well as interfere with elemental and mineralogic composition analyses of suspended particles. They may also warrant attention when determining heavy metal concentrations in contaminated fine-grained sediments of estuarine and harbour environments.  相似文献   

16.
The interaction of multiple inflows entering a reservoir (Thomson Reservoir, Australia) is investigated with a field experiment and three-dimensional numerical model simulations. The focus of the study is the mixing and transport patterns within the reservoir of the inflowing water. Data from the field experiment showed the existence of multiple inflows intruding horizontally into the reservoir immediately below the thermocline and selectively propagating into the reservoir at a depth determined by the individual density of each inflow. The results serve to show that inflows slot into a stratified reservoir in an orderly fashion, their depth dependent on the separation of inflow densities and reservoir bed, with minimal mixing between intrusions. Inflows thus do not take their nutrient load into the reservoir as a whole, but rather slot their load into an intrusion layer at an appropriate depth. Nutrients brought in via inflows become accessible only when vertical mixing, either directly at the base of the surface layer, or indirectly via the benthic boundary layer flux, transports the intrusion waters into the surface layer.  相似文献   

17.
Oceanic87Sr/86Sr ratios during Jurassic to Pleistocene have been determined by analysing fresh waters from marine limestone and dolomite aquifers. The results are in good agreement with published data from well preserved fossil material. The87Sr/86Sr ratios obtained are 0.7070 for Lower to Middle Jurassic, 0.7075 for Late Cretaceous, 0.7080 for Lower to Middle Eocene and 0.7087 for Pleistocene aquifer waters. The value of87Sr/86Sr for the Eimer and Amend isotopic standard was 0.7082.  相似文献   

18.
The paper presents an attempt to determine the characteristics of karst aquifers using information on groundwater level (GWL) in natural holes and boreholes with different data quantity and time resolution of GWL measurements. In this paper the particulars of karst aquifers were analysed for four examples from the Dinaric karst. In all four study areas, aquifers are formed in bare, deep and well‐developed Dinaric karst consisting of Cretaceous limestones. The first example represents a wide area of Imotsko polje in the karst. The aquifer was analysed on the basis of infrequent water level monitoring in natural karst water features (jamas, lakes, wells) and discharges of springs and rivers. The karst aquifer in this example is complex, non‐homogenous and variable in space and time, which is frequent in the Dinaric karst. Regardless of the aforementioned it was possible to determine its elementary characteristics. The second example represents 10 wells used for the water supply for the city of Pula. The GWL and salinity were measured once a week in the period between 1981 and 1996. Even though these measurements were relatively infrequent in space and time, they served as bases for assessment of average and maximum aquifer conditions as well as boundaries of saltwater intrusion. In the third example only a portion of aquifer of the karst spring Blaz, which is in the contact with the Adriatic Seas, has been analyzed. It is a spring with an intrusion of salt water. For purposes of study of saltwater intrusion, 26 piezometers were drilled in its vicinity in which GWL, salinity and temperature were measured once a day during 168 days, a period comprising one complete cycle of seawater intrusion and retreat. These measurements proved the existence of dispersed discharge from the aquifer into the sea and its non‐homogeneity in space. In the fourth example GWL was measured continuously in 10 deep (up to 300 m) piezometers in the hinterland of the Ombla Spring catchment. The measurement period lasted 2 years (January 1988 to December 1989). The analyses are made with hourly data. The results made it possible to determine numerous characteristics of the karst aquifer and a significant non‐homogeneity of groundwater distribution in karst aquifers, depending more on the underground karst phenomena than the surface karst forms. Copyright © 2000 John Wiley & Sons, Ltd.  相似文献   

19.
The transition area between rivers and their adjacent riparian aquifers, which may comprise the hyporheic zone, hosts important biochemical reactions, which control water quality. The rates of these reactions and metabolic processes are temperature dependent. Yet the thermal dynamics of riparian aquifers, especially during flooding and dynamic groundwater flow conditions, has seldom been studied. Thus, we investigated heat transport in riparian aquifers during 3 flood events of different magnitudes at 2 sites along the same river. River and riparian aquifer temperature and water‐level data along the Lower Colorado River in Central Texas, USA, were monitored across 2‐dimensional vertical sections perpendicular to the bank. At the downstream site, preflood temperature penetration distance into the bank suggested that advective heat transport from lateral hyporheic exchange of river water into the riparian aquifer was occurring during relatively steady low‐flow river conditions. Although a small (20‐cm stage increase) dam‐controlled flood pulse had no observable influence on groundwater temperature, larger floods (40‐cm and >3‐m stage increases) caused lateral movement of distinct heat plumes away from the river during flood stage, which then retreated back towards the river after flood recession. These plumes result from advective heat transport caused by flood waters being forced into the riparian aquifer. These flood‐induced temperature responses were controlled by the size of the flood, river water temperature during the flood, and local factors at the study sites, such as topography and local ambient water table configuration. For the intermediate and large floods, the thermal disturbance in the riparian aquifer lasted days after flood waters receded. Large floods therefore have impacts on the temperature regime of riparian aquifers lasting long beyond the flood's timescale. These persistent thermal disturbances may have a significant impact on biochemical reaction rates, nutrient cycling, and ecological niches in the river corridor.  相似文献   

20.
Groundwater flow-paths through shallow-perch and deep-regional basaltic aquifers at the Golan Heights, Israel, are reconstructed by using groundwater chemical and isotopic compositions. Groundwater chemical composition, which changes gradually along flow-paths due to mineral dissolution and water–rock interaction, is used to distinguish between shallow-perched and deep-regional aquifers. Groundwater replenishment areas of several springs are identified based on the regional depletion in rainwater δ18O values as a function of elevation (−0.25‰ per 100 m). Tritium concentrations assist in distinguishing between pre-bomb and post-bomb recharged rainwater.

It was found that waters emerging through the larger springs are lower in δ18O than surrounding meteoric water and poor in tritium; thus, they are inferred to originate in high-elevation regions up to 20 km away from their discharge points and at least several decades ago. These results verify the numerically simulated groundwater flow field proposed in a previous study, which considered the geological configuration, water mass balance and hydraulic head spatial distribution.  相似文献   


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