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为分析贵州遵义二叠纪锰矿的沉积环境,对谢家坝锰矿床进行常量元素、微量和稀土元素地球化学研究。研究认为：谢家坝锰矿赋存于茅口组顶部含锰岩系中,可分为下矿层豆状、角砾状菱锰矿、似层状菱锰矿,以及上矿层碎屑状、块状菱锰矿的二元结构矿石类型组合,可广泛代表遵义锰矿的矿石特征。谢家坝锰矿上下矿层之间主量元素和稀土元素含量差异较大,常量元素SiO2、TiO2、S、Fe2O3含量上矿层均大于下矿层,MnO、MgO与 Al2O3之间均呈负相关关系;上矿层Fe/Mn值较高,属高Fe低P型锰矿,而下矿层Fe/Mn值较低,属中低Fe低P型锰矿。上矿层稀土元素PAAS标准化配分后呈现较明显的重稀土亏损、弱的轻稀土富集、右倾配分的特征,具有弱的Ce正异常,类似海底铁锰结核稀土元素特征;下矿层呈现弱的中稀土富集,轻、重稀土亏损,弱的帽式分配特征,具明显的Ce负异常,类似典型深部海水沉积稀土元素特征。微量元素Th/U、Ni/Co、V/Cr、V/（V+Ni）、AU等沉积环境古氧相分析指标和稀土元素PAAS标准化配分模式指示,谢家坝锰矿下矿层是在贫氧-厌氧条件下Mn2+与CO32-直接形成菱锰矿,上矿层在常氧-贫氧环境下Mn3+、Mn4+以氧化物或氢氧化物形式沉淀。 相似文献
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石榴石是沉积物中常见的重矿物,其可来源于多种岩石,而且不同类型母岩中石榴石具有多样的地球化学组成,因此碎屑石榴石的地球化学分析在沉积物源研究中应用广泛。通过电子探针分析可以容易地获得单颗粒碎屑石榴石的主量元素地球化学组成,可借此探讨其母岩类型,但也存在一定的局限性,比如中酸性火成岩和部分变沉积岩来源的石榴石通常都具有高Fe、Mn的特征,不易于区分。本文系统地收集了不同岩石类型的石榴石微量元素数据,尝试利用微量元素地球化学的差异性对碎屑石榴石物源分析进行补充。最终得出以下结论:(1)石榴石的稀土元素(REE)组成与钇(Y)元素指标可区分中酸性火成岩和变沉积岩来源的碎屑石榴石;(2)基性岩(橄榄岩、辉石岩)及所对应的变基性岩石(榴辉岩)中石榴石的微量元素地球化学组成相近,但部分橄榄岩来源的石榴石在镨/钬(PrN/HoN)值和重稀土总量(ΣHREE含量)上与辉石岩和榴辉岩的有显著差别,这一特点可运用于以基性岩母岩为主的碎屑沉积物源研究中;(3)夕卡岩中的石榴石在主量元素地球化学组成上表现为高度一致的高Ca特征,而稀土元素组成具有两种典型的分配模式,岩浆型(指示富铁、氧化环境)与热液型(指示富铝、还原环境)。综上所述,石榴石微量元素地球化学可以有效地运用于沉积物源分析研究中,是其主量元素物源分析方法的重要补充。 相似文献
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广西东平-足荣大型锰矿床位于桂西南锰矿带上,是广西重要的锰矿富集区。其含矿地层为三叠系北泗组,是一套以硅-泥-灰为主浅海台盆相含锰碳酸盐岩沉积,含锰矿物主要为钙菱锰矿、锰方解石和锰白云石。本文对矿区锰矿层顶部的沉凝灰岩及含锰岩系开展了详细的岩石学、岩石地球化学和锆石U-Pb年代学研究,进而对锰矿成矿时代、成因、沉积环境、沉凝灰岩源区和大地构造背景进行了探讨。锆石SHRIMP U-Pb定年结果显示,3件沉凝灰岩样品的锆石呈自形-半自形板柱状,发育良好的岩浆锆石振荡环带结构。~(206) Pb/~(238)U年龄加权平均值分别为250.8±2.1Ma(MSWD=0.98)、250.6±2.2Ma(MSWD=0.49)和243.6±2.3Ma(MSWD=0.44)。进一步限定了"东平"式锰矿的成矿时代为早-中三叠世(不晚于241～246Ma的范围内)。沉凝灰岩的构造环境判别图解及微量、稀土元素特征显示其岩浆可能形成于与俯冲消减作用相关的碰撞-弧相关或活动大陆边缘相关背景,推测东平-足荣锰矿的形成可能受到广西凭祥-东兴火山作用的影响。含锰岩系的U、V和Mo元素含量及U/Th、V/Cr、V/(V+Ni)、Ni/Co 比值显示东平-足荣锰矿形成于氧化-次氧化的沉积环境。logU-logTh、Fe/Ti-Al/(Al+Fe+Mn)图解及微量元素Ba含量、Ba/Sr值均指示成矿作用受到热水作用的影响。综合矿床地质研究,东平-足荣锰矿形成于弧后盆地拉张构造背景中,锰成矿受同期火山及海底热液作用影响,水体沉积环境为氧化-次氧化条件。 相似文献
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在1∶5万内蒙古察哈尔右翼前旗、隆盛庄、西官村及永善庄4幅区域矿产地质调查的基础上,对以油篓山为代表的侏罗纪岩体从岩石学、岩石化学、稀土及微量元素等特征方面进行了初步研究。采用富集系数来讨论元素富集成矿问题,侏罗纪岩体富集—强富集的元素有Ag、Pb、Zn、As、Sn、Sb、Hg、W、Bi和Mo,说明侏罗纪岩浆活动为成矿提供了含矿热液。岩石化学及地球化学特征研究表明,测区侏罗纪岩体属钙碱性系列的铝饱和—过饱和类型,显示为碰撞阶段岩浆作用产物; 似斑状花岗岩岩体稀土元素配分曲线向右陡倾,倾角较陡,说明轻、重稀土分离明显; 石英斑岩岩体稀土元素配分曲线右倾,倾角平缓,表明轻、重稀土未有明显分馏。 相似文献
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辽东青城子矿集区姚家沟钼矿床成矿物质来源、成矿年代及成矿动力学背景 总被引：1，自引：0，他引：1
本文对辽东青城子矿集区姚家沟钼矿床与成矿密切的姚家沟花岗岩进行了元素地球化学、锆石LA-ICP-MS U-Pb定年和矿床金属硫化物硫同位素系统分析。结果表明:姚家沟花岗岩侵入时代为(167.47±0.87)Ma,具有富硅、富铝、全碱含量中等、过铝质-强过铝质的特征;稀土配分模式呈现轻稀土富集、重稀土亏损的右倾型,Eu弱正异常;富集K、Rb、U、Sr、Pb等大离子亲石元素,亏损Nb、Ti、P等高场强元素,δ34S值为2.0‰~3.9‰,平均值为2.7‰。结合姚家沟矿床辉钼矿Re-Os同位素研究成果进一步得出,姚家沟岩体至少为两期岩浆活动的产物,辉钼矿成矿与本次获得的(167.47±0.87)Ma岩浆活动有关,二者成岩、成矿时代一致。硫同位素指示成矿物质来源于岩浆。姚家沟钼矿成岩、成矿构造背景为受古亚洲洋闭合影响,华北板块与西伯利亚板块后碰撞造山阶段构造-岩浆-流体活动的环境。 相似文献
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Takeru Moriyama Mruganka K. Panigrahi Dinesh Pandit Yasushi Watanabe 《Resource Geology》2008,58(4):402-413
The major, trace and rare earth element (REE) composition of Late Archean manganese, ferromanganese and iron ores from the Iron Ore Group (IOG) in Orissa, east India, was examined. Manganese deposits, occurring above the iron formations of the IOG, display massive, rhythmically laminated or botryoidal textures. The ores are composed primarily of iron and manganese, and are low in other major and trace elements such as SiO2, Al2O3, P2O5 and Zr. The total REE concentration is as high as 975 ppm in manganese ores, whereas concentrations as high as 345 ppm and 211 ppm are found in ferromanganese and iron ores, respectively. Heavy REE (HREE) enrichments, negative Ce anomalies and positive Eu anomalies were observed in post‐Archean average shale (PAAS)‐normalized REE patterns of the IOG manganese and ferromanganese ores. The stratiform or stratabound shapes of ore bodies within the shale horizon, and REE geochemistry, suggest that the manganese and ferromanganese ores of the IOG were formed by iron and/or manganese precipitation from a submarine, hydrothermal solution under oxic conditions that occurred as a result of mixing with oxic seawater. While HREE concentrations in the Late Archean manganese and ferromanganese ores in the IOG are slightly less than those of the Phanerozoic ferromanganese ores in Japan, HREE resources in the IOG manganese deposits appear to be two orders of magnitude higher because of the large size of the deposits. Although a reliable, economic concentration technique for HREE from manganese and ferromanganese ores has not yet been developed, those ores could be an important future source of HREE. 相似文献
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GREGORY E. WEBB LUKE D. NOTHDURFT BALZ S. KAMBER† J. T. KLOPROGGE‡ JIAN-XIN ZHAO§ 《Sedimentology》2009,56(5):1433-1463
Rare earth element geochemistry in carbonate rocks is utilized increasingly for studying both modern oceans and palaeoceanography, with additional applications for investigating water–rock interactions in groundwater and carbonate diagenesis. However, the study of rare earth element geochemistry in ancient rocks requires the preservation of their distribution patterns through subsequent diagenesis. The subjects of this study, Pleistocene scleractinian coral skeletons from Windley Key, Florida, have undergone partial to complete neomorphism from aragonite to calcite in a meteoric setting; they allow direct comparison of rare earth element distributions in original coral skeleton and in neomorphic calcite. Neomorphism occurred in a vadose setting along a thin film, with degradation of organic matter playing an initial role in controlling the morphology of the diagenetic front. As expected, minor element concentrations vary significantly between skeletal aragonite and neomorphic calcite, with Sr, Ba and U decreasing in concentration and Mn increasing in concentration in the calcite, suggesting that neomorphism took place in an open system. However, rare earth elements were largely retained during neomorphism, with precipitating cements taking up excess rare earth elements released from dissolved carbonates from higher in the karst system. Preserved rare earth element patterns in the stabilized calcite closely reflect the original rare earth element patterns of the corals and associated reef carbonates. However, minor increases in light rare earth element depletion and negative Ce anomalies may reflect shallow oxidized groundwater processes, whereas decreasing light rare earth element depletion may reflect mixing of rare earth elements from associated microbialites or contamination from insoluble residues. Regardless of these minor disturbances, the results indicate that rare earth elements, unlike many minor elements, behave very conservatively during meteoric diagenesis. As the meteoric transformation of aragonite to calcite is a near worst case scenario for survival of original marine trace element distributions, this study suggests that original rare earth element patterns may commonly be preserved in ancient limestones, thus providing support for the use of ancient marine limestones as proxies for marine rare earth element geochemistry. 相似文献
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Petrogenesis of Group I Kimberlites from Kimberley, South Africa: Evidence from Bulk-rock Geochemistry 总被引：8，自引：6，他引：8
Fresh samples of hypabyssal kimberlite from the five major kimberlitepipes in the Kimberley area of South Africa have been analysedfor their bulk-rock major and trace element geochemistry. Thegeochemical data allow identification of the influence of crustalcontamination in certain samples, best illustrated in termsof elevated SiO2, Al2O3, Pb and heavy rare earth element (HREE)contents. Samples devoid of such crustal contamination showcoherent major and fluid-immobile trace element variations,whereas fluid-mobile trace elements are scattered. Kimberlitesrich in macrocrysts are shown to reflect substantial (up to35%) entrainment of mantle peridotite, with Ni–SiO2 andSc–SiO2 variations defining mixing trajectories towardsgarnet lherzolite. The likely primary magma(s) parental to theKimberley kimberlites is suggested to have a composition of26–27 wt % MgO, 26–27 wt % SiO2, 相似文献
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贺兰山—六盘山地区是研究华北板块西部大地构造背景的关键区域。在研究区内中侏罗统直罗组地层采集了20件样品,应用全岩分析和ICP-MS方法对采集的样品进行主、微量及稀土元素测试并对其地球化学特征做出分析。测试结果显示,样品中Al2O3/SiO2值介于0.17~0.31之间,平均值为0.25;K2O/Na2O值介于0.77~73.77之间,平均值为9.78;Al2O3 /(Na2O+CaO)值介于0.49~96.00之间,平均值为15.68。上述含量和比值与样品成分成熟度、元素迁移、热液流体影响和风化程度有关。部分元素之间存在良好的相关性,能够反映物源及环境的变化。稀土元素值总和(ΣREE)变化较大(132.16~394.47μg·g-1),其球粒陨石标准化配分模式与大陆上地壳(UCC)极为相似,表现为轻稀土富集、重稀土平坦、Eu负异常,Ce异常不明显等特征。结合UCC标准化曲线、La/Yb值、GdN/YbN值、La/Th值和Hf含量,认为直罗组源岩主要为长英质岩石,混杂了少量古老沉积岩和基性岩或者特殊矿物,且后太古界地层提供主要物源。微量元素构造背景判别图揭示研究区中侏罗统直罗组地层的物源区具有大陆岛弧和活动大陆边缘的特征,物源可能来自于兴蒙造山带和祁连造山带。化学蚀变指数(CIA)值和A-CN-K图反映源岩经历了较强的风化作用,但不同区域之间的风化程度存在差异。 相似文献
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Dong-Guang Yang Xue-Gang Hou An-Qi Mao Zong-Yuan Tang Zhen Qin 《International Geology Review》2018,60(8):1038-1060
This paper presents major element, trace element, and new zircon Hf isotopic data for the Early Mesozoic intrusive rocks in the south Hunchun, Yanbian area, Northeast China. These data are used to constrain the petrogenesis of these intrusive rocks and their implications for the Phanerozoic continental growth of the Central Asian Orogenic Belt (CAOB). Combining geology, geochronology, and whole-rock geochemistry, we identify three distinct episodes of magmatism as Early–Middle Triassic (249–237 Ma), Late Triassic (224–206 Ma), and Early Jurassic (200–187 Ma). The Early–Middle Triassic (249–237 Ma) adakitic tonalite and granodiorite were produced by the partial melting of subducted oceanic slabs, and the melts were contaminated by mantle peridotite during their ascent, whereas the coeval non-adakitic diorite and monzogranite were most likely derived from partial melting of crustal material. The remarkably high zircon Hf isotopic signature (εHf(t) = + 9.4 – +18.9), the enrichment in large-ion lithophile element and light rare earth elements, and the depletion in high field strength element suggest that these 224 Ma gabbros were derived from the partial melting of depleted mantle modified by subduction-related fluids. The 212 Ma monzogranite was most likely derived from juvenile material mixed with old crustal material as evidenced by their high SiO2, low MgO, and low Cr concentrations and variable εHf(t) values (–4.6 to +10.0). Except for the 197 Ma tonalites with affinity to the high silica adakites, the overall geochemical evolution of Early Jurassic (200–187 Ma) rocks was consistent with fractional crystallization from quartz diorite, granodiorite, and monzogranite to syenogranite. Both the Early Jurassic syn-subduction lateral continental growth by accretion of arc complexes and the Late Triassic post-collisional vertical continental growth by accretion of mantle-derived material played an important role in the Phanerozoic continental growth of the CAOB. 相似文献
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Datangpo-type sedimentary manganese deposits, which are located in northeastern Guizhou province and its adjacent areas, are Mn carbonate-type deposits hosted in black carbonaceous shale that represent a series of medium to large deposits containing a huge tonnage of reserves. PAAS-normalized rare earth element distribution patterns of manganese ores record “hat-shaped” REY (REE + Y) plots characterized by pronounced middle rare earth element enrichment, evident positive Ce anomalies, weak to strong positive Eu anomalies and negligible negative Y anomalies. These REY geochemical characteristics are different from those of country rocks and record the processes and features of sedimentation and diagenesis. Manganese was precipitated as Mn-oxyhydroxide particles in oxidized water columns with the sorption of a certain amount of rare earth elements, subsequently transforming from Mn-oxyhydroxides to rhodochrosite and redistributing REY in reducing alkaline pore-water during early diagenesis. A number of similarities can be observed through a comparison of Datangpo-type manganese ores and modern marine ferromanganese oxyhydroxide precipitates based on their rare earth elements. The precipitation of Datangpo-type manganese ores is similar to that of hydrogenetic crusts and nodules based on their positive Ce anomalies and relatively higher total REY concentrations. However, several differences also exist. Compared to hydrogenetic crusts and nodules, Datangpo-type manganese ores record smaller positive Ce anomalies, lower total REY concentrations, unobvious fractionation between Y and Ho, and weak to strong positive Eu anomalies. These were caused by quicker sedimentary rates in the oxic water columns of the shallower basin, after which pore water became strongly reducing and alkaline due to the degradation of organic matter in the early diagenetic stage. In addition, compared to typical deposits in the world, Datangpo-type manganese ores are similar to hydrogenetic deposits and different than hydrothermal deposits. All of these characteristics of manganese ores indicate that Datangpo-type manganese ores, the principal metallogenic factors of which include oxidation conditions during deposition and reducing conditions during early diagenetic stages, represent hydrogenetic deposits. 相似文献
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右江盆地微细浸染型金矿成矿物质来源分析 总被引：5，自引：0，他引：5
通过成矿元素地球化学、矿石与围岩Pb同位素、S同位素、C同位素、Co和Ni等微量元素、稀土元素的对比研究，认为金矿质主要来源于沉积岩地层，其中中三叠统浊积岩为最重要的矿源岩。 相似文献
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张书义 《吉林大学学报(地球科学版)》2020,50(1):129-138
新巴尔虎右旗塔木兰沟组火山岩主要由玄武岩、玄武安山岩和安山岩组成。TIMS锆石U-Pb定年结果显示,火山岩形成于约154 Ma的晚侏罗世。岩石主体属碱性系列,镁质量分数较低（w（MgO）为0.55%~3.36%）,镁值较小（Mg#为0.17~0.49）;稀土元素配分模式呈轻稀土富集右倾型,轻重稀土分馏明显（（La/Yb）N为9.51~17.21）,存在微弱的Eu异常（δEu为0.78~1.04）;微量元素以富集大离子亲石元素（如Rb、Ba、K）和轻稀土元素（LREE）、亏损高场强元素（如Nb、Ta、Ti）和相容元素（Cr、Co、Ni）为特征。综合研究表明,岩浆源区为俯冲板片流体交代过的岩石圈地幔,岩浆上升过程中未受到地壳物质的明显混染。结合区域地质构造演化特征,认为塔木兰沟组火山岩是蒙古-鄂霍茨克洋闭合造山后岩石圈伸展环境下的产物。 相似文献
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印度—亚洲大陆主碰撞过程的火山作用响应 总被引：203，自引：7，他引：203
广泛发育在西藏冈底斯岩浆岩带中的林子宗火山岩及其与下伏地层间的区域性不整合 ,提供了印度—亚洲大陆碰撞 (在西藏南部 )的构造火成岩新证据。岩石学、主元素、微量元素、稀土元素及Nd Sr Pb同位素地球化学研究表明 ,林子宗火山岩早期带有较多陆缘弧火山岩特征 ,中期开始出现标志陆内岩浆活动的钾玄岩 ,晚期更多地显示了加厚陆壳条件下火山岩的特点 ,记录了由新特提斯俯冲消减末期过渡到印度—亚洲大陆碰撞的信息。系统的40 Ar/3 9Ar同位素测年确定林子宗火山岩的年龄区间为 4 0 .84～ 6 4 .4 7Ma ;其底部年龄给出了林子宗火山岩与下伏地层间不整合形成时间的最晚时限 (～ 6 5Ma)。该不整合面上、下之地层在沉积相、变形样式与变形程度上均截然不同 ,反映形成环境的重大变化 ,标志着一次重大的地质事件。根据上述事实 ,结合青藏高原岩浆活动的区域时空分布 ,及西藏南部地层、古生物与沉积研究成果 ,笔者认为印度—亚洲大陆碰撞开始于 6 5Ma左右(K/T界限时间 )。 相似文献
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David W. Valentino Jeffrey R. Chiarenzelli 《Proceedings of the Geologists' Association. Geologists' Association》2014
Structural, petrographic, and geochemical criteria are applied in combination to determine the petrologic origins of slaty rocks in polydeformed metasedimentary terranes. Multiple lines of evidence suggest that the Peach Bottom slate (PBs), mined over several centuries, is an ultraphyllonite. It occurs within an Alleghanian dextral retraining bend within the Appalachian Piedmont, as a segment of the Pleasant Grove-Huntington Valley shear zone system (>200 km long). The PBs differs markedly from other slates, in that, it contains abundant, micro-scale remnant porphyroclasts of higher-grade minerals. The PBs has major, trace and rare earth element geochemistry and 147Sm/143Nd ratios that are similar to the surrounding pelitic rocks. When compared to average slates, the geochemistry of the PBs exhibits depletion in alkali earth and alkali elements. 相似文献
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Four muscovite-biotite granites from the Western Metamorphic Belt of South-eastern Australia have rare earth element patterns characterized by: (i) light rare earth element enrichment; (ii) slight Eu depletion; (iii) varying degrees of heavy rare earth element depletion. The rare earth element and major element chemistry of three of these muscovite-biotite granites (the Koetong, Lockharts and Yabba Granites) can be approximated very closely by a model involving 20% partial melting of an ultrametamorphosed pelitic sediment and contamination of this minimum melt by the residual material left after melting, in the ratio 60% melt: 40% residue. Granitoids can be very largely solid material at the time of emplacement.The other muscovite-biotite granite studied (the Hawksview Granite) has major and trace element characteristics which distinguish if from the other three granitoids and these differences are attributed to variations in source material at the site of melt generation.The rare earth element and major element chemistry of a garnet-cordierite gneiss from the Western Metamorphic Belt can be modelled assuming 5% partial melting of a pelitic metamorphic rock and contamination of the minimum melt by the residue in the ratio 30% melt: 70% residue.Separated granitic and biotitic portions of a migmatite from the Western Metamorphic Belt have rare earth element characteristics which are inconsistent with a simple partial-melting model, but it is suggested that re-equilibration following, or during, separation of the vein material could obscure the process by which the vein of the migmatite developed. It is however certain that the vein developed in situ from a pelitic meta-sediment leaving the biotite rich selvage, without the introduction of material from an external source.Leucogranites which crop out to the east of the Western Metamorphic Belt are high level intrusions of highly fractionated granitic melt. Their Sr isotopic characteristics and features of their major and trace element chemistry suggest that they derive from an igneous source and are not directly related to the granites and gneisses to the west. 相似文献