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1.
地壳深熔条件下的转熔矿物研究进展 总被引：1，自引：0，他引：1
夏琼霞 《矿物岩石地球化学通报》2019,(3):508-521,439
地壳深熔作用有两种形式,即流体相缺乏的脱水熔融和流体相存在的加水熔融。由于地壳岩石中水含量的差异(岩石中含水矿物的丰度和外来水的加入量),岩石发生不同形式的部分熔融所需要的温度和压力条件有很大差异。转熔矿物是岩石发生不一致熔融的产物,在形成过程中携带了地壳深熔源区物质和熔体的大量信息,是追溯高温变质岩石经历深熔作用的最可靠依据。它们与高级变质岩中残留的变质矿物和岩浆或熔体中结晶的岩浆矿物具有明显不同的来源,分别代表了岩石曾经历的不同演化历史。通过对不同成因的矿物进行矿物结构、包裹体、主量元素、微量元素和同位素以及共生矿物组合等多方面的综合考察,可以有效识别出高级变质岩中的转熔矿物、变质残余矿物和岩浆矿物。准确识别高温-超高温变质岩以及花岗岩中不同成因的矿物相,是研究高温变质作用的前提条件,对研究混合岩和S型花岗岩的成因都起着非常重要的作用。 相似文献
2.
麻粒岩相变质作用与花岗岩成因-Ⅱ:变质泥质岩高温-超高温变质相平衡与S型花岗岩成因的定量模拟 总被引：12，自引：12，他引：0
高温-超高温变质岩石的矿物组合及组构特点取决于不同的进变熔融反应,不同程度的熔体丢失以及不同程度的退变反应三种过程的综合效应。利用相平衡定量研究方法可以很好地模拟进变熔融反应的类型、P-T条件、熔体含量及其丢失行为、以及熔融过程中熔体与残余物的化学成分变化等,这对探讨高温-超高温变质作用过程以及花岗岩的成因非常重要。对平均泥质岩(APR)进行相平衡模拟表明变质泥质岩在等压(0.8GPa)升温熔融过程中可发生5种熔融反应:饱和流体固相线、白云母脱水熔融、黑云母熔融、钾长石-石榴石熔融和铝铁镁矿物熔融,后两种熔融反应主要发生在超高温条件下。减压过程中发生怎样的熔融反应受减压温度控制:在麻粒岩相(如850℃)减压可发生钾长石熔融、黑云母熔融和钾长石-石榴石熔融反应;在高角闪岩相(如750℃)减压主要发生白云母脱水熔融和钾长石熔融;在超高温麻粒岩相(如950~1000℃)减压主要发生钾长石-石榴石熔融和铝铁镁矿物熔融。熔体成分受熔融反应和P-T条件控制,如在高角闪岩相发生的饱和流体固相线和白云母脱水熔融可形成弱过铝的奥长花岗质和二长花岗质熔体;在麻粒岩相发生的黑云母熔融和钾长石熔融形成的熔体具有强过铝的二长花岗岩成分;在中压超高温发生的钾长石-石榴石熔融和铝铁镁矿物熔融形成强过铝的二长(钾长)花岗岩质熔体,可形成石榴石花岗岩;在低压超高温下发生的铝铁镁矿物熔融可形成堇青石花岗岩。除了极端超高温下的铝铁镁矿物熔融外,其它熔融反应都会使残余物的成分更贫硅,贫Na_2O和K_2O,富FeO和MgO,但Al_2O_3和Mg#基本不变。高温-超高温下发生深熔的岩石只记录降温过程形成的固相线组合,但固相线的类型与温度条件取决于熔体的丢失行为。在不丢失熔体或者获得熔体的岩石中,岩石最后只记录流体饱和固相线组合;发生熔体部分丢失的岩石会记录缺流体固相线组合,并且熔体丢失越多,缺流体固相线的温度越高;发生全部流体丢失的岩石可记录岩石所达到的最高温度。因此,在一个麻粒岩相区,甚至一个野外露头上不同部位的岩石记录不同的P-T条件。熔体丢失是导致使麻粒岩相组合在升温过程中发生超高温变质,在降温过程中得以部分保存的重要条件。发生部分熔融的高级变质岩中随着温度升高,熔体含量增加,会发生锆石分解,只有在降温过程中发生锆石结晶,因此,麻粒岩中新生锆石只记录降温过程到固相线及以后的年龄,一般不会记录麻粒岩相峰期时代。对泥质高压麻粒岩来说,如果经历ITD型变质演化,会发生递进减压熔融,变质反应易于达到平衡,但如果减压速度快并使岩石直接抬升到地壳浅部,会出现一些ITD型结构标志,如残留金红石、蓝晶石,或在石榴石周围出现堇青石的反应冠状体等,此时锆石记录的退变质年龄会与峰期变质年龄相差不大(如10~30Myr);但如果泥质高压麻粒岩减压至中、深地壳,受其中有滞留熔体影响易于发育IBC型结构特征,表现为麻粒岩组合被(中压)角闪岩相组合叠加,在泥质岩中出现黑云母+夕线石构成的暗色条带,或者出现退变白云母和含白云母的浅色体。在中、深地壳经历IBC过程的麻粒岩锆石记录的退变质年龄会与峰期年龄相差很大(如~100Myr)。高级变质岩中由于出现熔体使水流体活度降低,麻粒岩作为排除部分熔体的残余物,其水活度更低。从这一角度来说,水活度低是麻粒岩相变质作用的结果,而不是条件。某些麻粒岩区之所以出现多期麻粒岩相变质叠加受流体行为控制。在亚固相线下流体饱和岩石变质熔融作用从饱和水固相线开始,然后依次发生含水矿物的脱水熔融和无水矿物熔融,这一过程中流体是内部缓冲的,在麻粒岩相温度峰期形成一组平衡矿物组合,难以保留峰期之前的信息。而流体不饱和岩石(如已形成的麻粒岩或岩浆侵入体)变质作用受外部注入流体控制,与构造变形密切相关。如果发生两期麻粒岩相变质叠加变质,在强应变域会形成晚期麻粒岩组合;在弱应变域,会出现两期麻粒岩组合,其中晚期矿物表现为反应冠状体或细粒交生体;而在一些应变非常弱的区域,可能只保留早期矿物组合。 相似文献
3.
深熔过程中熔体成分与锆石行为模拟计算 总被引：3，自引：2，他引：1
发生深熔作用是高级变质作用的一个重要特征。深熔过程中产生的熔体可为淡色花岗岩提供潜在的源区;深熔过程中锆石的行为直接影响对变质锆石记年地质意义的理解。在含Zr体系下的相平衡模拟显示泥质成分深熔过程中产生熔体的成分在P-T空间中规律变化。温度升高时熔体Zr/Si值、Zr、FeO、MgO以及CaO等含量明显增加,压力较高时K2O含量也随温度升高而明显增加。Na2O含量随温度升高而降低,但随压力升高而增加。压力升高时Al/Si值显著升高。温度较高时Na/(Na+K)等值线较陡,减压熔融过程不会显著改变熔体Na/(Na+K)值,而升温减压过程以及近等压升温过程都会明显降低熔体Na/(Na+K)值。中压时随温度升高熔体Fe/(Fe+Mg)值缓慢升高,而石榴石的生长发育会迅速降低熔体Fe/(Fe+Mg)值。不同温压条件下对应的固相线熔融、白云母脱水熔融以及黑云母脱水熔融形成的熔体成分具有明显差异。对比模拟熔体成分在P-T空间的演化,喜马拉雅地区电气石淡色花岗岩对应熔体的形成温压条件应低于二云母淡色花岗岩,同类型淡色花岗岩之间在形成条件上也可能存在一定差异,并经历了差异性演化过程。含Zr体系下的相平衡关系显示进变过程是消耗锆石的过程,因而在进变过程中变质锆石难以生长,发生深熔作用的岩石中的变质锆石主要在退变过程中形成并记录退变质年龄。熔体丢失相关模拟显示不同温度阶段发生熔体丢失对锆石稳定性的影响不同。温度较低时Zr含量较少的熔体丢失会扩大持续进变过程中锆石的稳定范围,而温度较高时富Zr熔体的丢失会降低持续进变过程中锆石的稳定温度。类似于分离熔融作用的过程最利于残留相中剩余锆石在持续进变过程中的保存。 相似文献
4.
石榴石是高压-超高压变质岩石中最重要的变质矿物之一,是研究俯冲带深部变质和熔融过程的理想研究对象.通过对俯冲带内不同条件下形成的石榴石进行详细研究,确定了岩浆成因、变质成因和转熔成因石榴石.岩浆石榴石是岩浆熔体在冷却过程中结晶形成,成分主要为锰铝榴石-铁铝榴石,通常含有石英、长石、磷灰石等晶体包裹体.变质石榴石是在亚固相条件下通过变质反应形成,包裹体为参与变质反应的矿物组合;进变质生长的石榴石通常显示核部到边部锰铝榴石降低的特征.转熔石榴石是在超固相条件下通过转熔反应形成,通常含有晶体包裹体,其中既有从转熔熔体结晶的矿物包裹体,也有转熔反应残留的矿物包裹体.对超高压变质岩石中转熔石榴石的识别,可以为深俯冲陆壳岩石的部分熔融提供重要的岩石学证据,是大陆俯冲带部分熔融研究的重要进展之一. 相似文献
5.
高级变质岩中深熔作用的相平衡研究 总被引：3，自引：0，他引：3
深熔作用在高级变质岩中非常普遍并受到广泛关注。自20世纪90年代以来,随着变质相平衡研究的突破性发展,利用THERMOCALC程序和视剖面图方法可以定量研究固相线以上的熔体形成、熔体分馏和退变质反应。变质沉积岩中的熔融作用主要有三种机制饱和水固相线上的熔融、白云母脱水熔融和黑云母脱水熔融。在模拟泥质岩石的KFMASH体系和NCKFMASH体系中的相平衡计算表明,NCKFMASH体系中铁镁矿物的相平衡关系受KFMASH亚体系中矿物相平衡关系的控制,但KFMASH亚体系中固相线位置要比实际的高50~60℃。因此,模拟泥质岩石的固相线以上的相平衡关系最好在NCKFMASH或组分更多的体系中进行。相平衡研究表明麻粒岩相岩石的保存与熔体丢失有关;混合岩的形成过程包括部分熔融作用、不同程度熔体分凝与汲取和不同程度的逆反应和退变反应。 相似文献
6.
大别—苏鲁超高压地体折返过程中岩石组合演化的地球化学约束 总被引：7，自引：2，他引：5
大别—苏鲁超高压地体现今的岩石组合是超高压变质岩石经历快速折返过程中各种地质作用叠加改造的最终产物, 其中拆沉、底侵、构造体制转换是改造的动力; 退变质作用、构造置换、深熔作用是改造的主要方式.超高压地体的主要岩石组合有榴辉岩、大理岩、硬玉石英岩、斜长角闪岩、片麻岩和面理化花岗岩.地质、常量、微量、同位素地球化学研究表明, 斜长角闪岩是榴辉岩退变的产物, 片麻岩、面理化花岗岩是榴辉岩退变的斜长角闪岩递进深熔的产物, 即退变榴辉岩折返到中下地壳, 初次熔融产生相当于片麻岩成分的半原地英云闪长质-花岗闪长质-花岗质岩浆, 片麻岩再次熔融产生成分相当于面理化花岗岩的A型花岗岩岩浆. 相似文献
7.
朝鲜半岛西北部古元古代高温变质-深熔作用:宏观和微观岩石学以及锆石U-Pb年代学制约 总被引：8，自引：8，他引：0
朝鲜半岛左接中国大陆右连日本岛链,其地质位置重要不言而喻,对其区域地质演化历史和构造属性的准确厘定,直接关系到对整个东北亚地质的全面理解和认识。本文对朝鲜半岛狼林地块西部的南浦群和甄山群的相关岩石进行了研究。野外露头、手标本和岩相学观察表明,南浦群和甄山群岩石保存了深熔作用的宏观和微观证据,矿物组合以及矿物间的反应结构表明南浦群和甄山群混合岩经历了角闪岩相到麻粒岩相的变质作用,并且在晚期熔体结晶过程中发生了逆反应或退变质过程。7件样品的锆石U-Pb定年结果显示,朝鲜半岛西北部地区在古元古代经历了多阶段(期)的变质和深熔作用过程。南浦群岩石在1917Ma可能经历了第一阶段(期)变质作用,在1877~1855Ma经历了第二阶段(期)变质深熔和石榴石持续生长,熔体冷却结晶时代为1842Ma。甄山群样品给出的变质深熔和石榴石生长的时代为1841~1830Ma,1785Ma可能代表深熔作用中抽取的熔体冷却的时代。但是,为何南浦群和甄山群样品记录的变质和深熔作用时代显示较大的差异,尚需更进一步的研究。综述前人研究成果可知,狼林地块与华北克拉通东部辽吉活动带,在变质和深熔作用类型方面存在不同之处,然而它们所记录的古元古代高温变质-深熔时代的一致性,表明二者可能至少在古元古代之前就形成了统一的大陆。 相似文献
8.
铙钹寨镁铁-超镁铁质岩体被认为是北大别地体下方岩石圈地幔的碎块,并随着三叠纪的华北和华南的大陆碰撞而一同经历了深俯冲和折返过程,对其进行详细的研究可以为我们更好地理解陆-陆碰撞过程中的壳幔相互作用、物质迁移、多期变质和熔流体交代等地球动力学过程提供信息。本文应用电子探针和LA-ICP-MS对铙钹寨榴辉岩进行了系统的元素环带、出溶结构和熔体包裹体研究,揭示出该岩体至少经历了三期变质事件,两期矿物出溶和两期熔体交代过程。峰期变质矿物组合为含金红石出溶体的石榴石核部+其内包裹的绿辉石,石榴石中金红石±磷灰石矿物出溶体和绿辉石包裹体中的金红石±石英±磷灰石出溶片晶指示该岩体确定经历过超高压变质作用,流体活动以高盐度的卤水±氮气的流体为主,峰期变质作用过程中无熔体活动痕迹。高压麻粒岩相变质矿物组合为Ⅱ期石榴石+紫苏辉石+基质具有出溶石英片晶结构的富Na单斜辉石,流体活动以CO2流体为主,熔体包裹体记录了在折返初期,高压麻粒岩相变质之前存在一期小规模的硫化物熔体活动。晚期角闪岩相退变质矿物组合为透辉石+角闪石+长石,流体活动以低盐度水溶液为主,并伴随着一期壳源的硅酸盐熔体交代事件。根据矿物环带、出溶结构和熔体包裹体化学组合及分布特征,并结合前人的研究成果,我们得出了该岩体较为完整的变质演化和熔-流体交代的P-T-t-E/F/M轨迹。 相似文献
9.
基于岩石相平衡，对富铝泥质岩K2O-Al2O3-SiO2一H2O(KASH)和K2O-FeO—MgO—A12O3-SiO2-H2O(KFMASH)体系的混合岩化深熔作用相关系进行了模拟计算，得到泥质岩深熔作用的成岩格子、熔体成分变化特征、熔体含水量及其温压条件、石榴石变斑晶成分演化趋势和泥质岩进变质、退变质矿物组合特征、各种压力条件下S型花岗质熔体特征等，并进一步将模拟结果应用于内蒙古固阳等地的泥质岩，根据相关岩石的矿物组合及结构特征，获得了变质反应历史和P—T轨迹。 相似文献
10.
混合岩形成模式历来是地质学家研究的重要课题。混合岩在许多情况下形成于进变质的脱水熔融作用 ,并伴随着有限量的熔体分离作用。熔融过程中形成熔体的多少受到熔体中水含量的控制 ,而水含量又是温度、压力、熔体成分和水活度的函数。在水活度低和温度高的情况下 ,产生在地壳中的熔体 (如A型花岗岩的 )含水量比以前的假设要高。顺时针的P -T轨迹可能有利于流体从结晶熔体中释放出来 ,同时产生脱水矿物组合 ,而释放出来的水可以导致相邻岩石的水饱和熔融。熔体形成后的不完全汲取的特点 ,改变了局部原岩的总体成份 ,导致原地结晶的熔体和剩余物质随着温度降低而发生退变质反应。这种退变质反应具有不完全性 ,经常在混合岩晚期的结构中被记录下来。由此推导的P -T轨迹压力值的误差较大 ,其准确性受到了怀疑 ,与之相应的大地构造环境也应该重新考虑 相似文献
11.
试论阜平杂岩的深熔作用 总被引：2，自引：0，他引：2
阜平杂岩中广泛产出浅色脉体,从而显示强烈的混合岩化作用。前人把引起混合岩化作用的机制归因于岩汁交代、重熔或无水深熔作用,似乎与实际的岩相结构不是很一致。矿物自形晶、钠长石净边结构和一些典型的矿物转化反应表明,阜平杂岩的混合岩化作用实际上经历了复杂的过程,主要表现为有水条件下的深熔作用。所形成的熔体有较大的流动性,可迁移一定的距离而进入邻近的岩石,对这些部位而言相当于发生了外来熔体的注入活动,造成熔体注入式混合岩化作用,形成一些交代反应和结构。因此,阜平杂岩混合岩化作用中的变质反应过程既包括长英质矿物的熔融(溶解),还涉及一种含水矿物(如黑云母)转化形成另外一种含水矿物(如角闪石)的化学反应。阜平杂岩的混合岩化作用最重要的机制是水致熔融或含水深熔作用,溶解性重熔或无水深熔作用则较为次要。 相似文献
12.
Making a distinction between partial melting and subsolidus segregation in amphibolite facies migmatites is difficult. The only significant melting reactions at lowpressures, either vapour saturated or muscovite dehydration melting, do not produce melanocratic peritectic phases. If protoliths are Si-rich and K-poor, then peritectic sillimanite and K-feldspar will form in scarce amounts, and may be lost by retrograde rehydration. The Roded migmatites of southern Israel (northernmost Arabian Nubian Shield) formed at P = 4.5 ± 1 kbar and T ≤ 700 °C and include Si-rich, K-poor paragneissic paleosome and trondhjemitic leucosomes. The lack of K-feldspar in leucosomes was taken as evidence for the non-anatectic origin of the Roded migmatites (Gutkin and Eyal, Isr J Earth Sci 47:117, 1998). It is shown here that although the Roded migmatites experienced significant post-peak deformation and recrystallization, microstructural evidence for partial melting is retained. Based on these microstructures, coupled with pseudosection modelling, indicators of anatexis in retrograded migmatites are established. Phase diagram modelling of neosomes shows the onset of muscovite dehydration melting at 4.5 kbar and 660 °C, forming peritectic sillimanite and K-feldspar. Adjacent non-melted paleosomes lack muscovite and would thus not melt by this reaction. Vapour saturation was not attained, as it would have formed cordierite that does not exist. Furthermore, vapour saturation would not allow peritectic K-feldspar to form, however K-feldspar is ubiquitous in melanosomes. Direct petrographic evidence for anatexis is rare and includes euhedral plagioclase phenocrysts in leucosomes and quartz-filled embayments in corroded plagioclase at leucosome-melanosome interfaces. In deformed and recrystallized rocks muscovite dehydration melting is inferred by: (1) lenticular K-feldspar enclosed by biotite in melanosomes, (2) abundant myrmekite in leucosomes, (3) muscovite–quartz symplectites after sillimanite in melanosomes and associated with myrmekite in leucosomes. While peritectic K-feldspar formed in melanosomes by muscovite dehydration melting reaction, K-feldspar crystallizing from granitic melt in adjacent leucosome was myrmekitized. Excess potassium was used in rehydration of sillimanite to muscovite. 相似文献
13.
Partial melting in the Inzie Head gneisses: the role of water and a petrogenetic grid in KFMASH applicable to anatectic pelitic migmatites 总被引：5，自引：0，他引：5
A sequence of prograde isograds is recognized within the Dalradian Inzie Head gneisses where pelitic compositions have undergone variable degrees of partial melting via incongruent melting reactions consuming biotite. Three leucosome types are identified. At the lowest grades, granitic leucosomes containing porphyroblasts of cordierite (CRD‐melt) are abundant. At intermediate grades, CRD‐melt mingles with garnetiferous leucosomes (GT‐melt). At the highest grades, CRD‐melt coexists with orthopyroxene‐bearing leucosomes (OPX‐melt), while garnet is conspicuously absent. The prograde metamorphic field gradient is constrained to pressures of 2–3 kbar below the CRD‐melt isograd, and no greater than 4.5 kbar at the highest grade around Inzie Head. A petrogenetic grid, calculated using thermocalc , is presented for the K2O–FeO–MgO–Al2O3–SiO2–H2O (KFMASH) system for the phases orthopyroxene, garnet, cordierite, biotite, sillimanite, H2O and melt with quartz and K‐feldspar in excess. For the implied field gradient, the reaction sequence predicted by the grid is consistent with the successive prograde development of each leucosome type. Compatibility diagrams suggest that, as anatexis proceeded, bulk compositions may have been displaced towards higher MgO content by the removal of (relatively) ferroan granitic leucosome. An isobaric (P = 4 kbar) T–aH2O diagram shows that premigmatization fluids must have been water‐rich (aH2O > 0.85) and suggests that, following the formation of small volumes of CRD‐melt, the system became fluid‐absent and melting reactions buffered aH2O to lower values as temperatures rose. GT‐ and OPX‐melt formed by fluid‐absent melting reactions, but a maximum of 7–11% CRD‐melt fraction can be generated under fluid‐absent conditions, much less than the large volumes observed in the field. There is strong evidence that the CRD‐melt leucosomes could not have been derived by buoyantly aided upwards migration from levels beneath the migmatites. Their formation therefore required a significant influx of H2O‐rich fluid, but in a quantity insufficient to have exhausted the buffering capacity of the solid assemblage plus melt. Fluid : rock ratios cannot have exceeded 1 : 30. The fluid was channelled through a regionally extensive shear zone network following melt‐induced failure. Such an influx of fluid at such depths has obvious consequences for localized crustal magma production and possibly for cordierite‐bearing granitoids in general. 相似文献
14.
在碰撞造山带构造演化过程中,中下地壳深熔作用对于深部地壳物理性质与化学成分具有重要控制作用.作为深熔作用的"见证者",纳米花岗岩包裹体是寄主岩石部分熔融作用的产物,能够为确定陆壳岩石中天然熔体特征及分析熔融机制提供关键信息.在喜马拉雅东构造结南迦巴瓦岩群的代表性岩石单元（泥质片麻岩与长英质片麻岩）中,石榴石与锆石中常包含有典型的纳米花岗岩包裹体,其代表性子矿物组合为钾长石+斜长石+石英±黑云母,这是在黑云母脱水熔融过程中、寄主片麻岩中熔体被主要转熔矿物（如石榴石等）捕获所形成一类特殊包裹体.在观测基础上,采用高温高压与高温常压手段,对纳米花岗岩包裹体进行均一化实验并获得均一化玻璃质熔体.成分分析表明,均一化熔体成分以过铝质花岗岩为主,其主/微量元素特征能够有效反演部分熔融作用的演化过程.因此,纳米花岗岩包裹体的天然观测与实验研究对于确定天然熔体特征与深入剖析碰撞造山带的地壳深熔作用具有重要启示意义. 相似文献
15.
The St. Malo migmatitic dome represents an interesting example wherein migmatites arise from the anatexis of the surrounding gneisses. Petrographical and chemical data suggest that leucosome compositions are compatible with partial melting of the quartzo-feldsphathic fraction of the parent gneiss. The contribution of the incongruent melting of biotite to the melt does not exceed 5% of the parent rock.Petrogenetic modelling based on experimental data and assuming non modal batch melting show that the K, Rb, Ca, Sr, U and Th chemical patterns of these migmatites result in fact from the interaction of several mechanisms, namely: equilibrium partial melting, mixing between melts and refractory minerals (biotite and accessories), melt removal and late hydrothermal alteration. Zr, Y and Th which are mostly hosted in accessory minerals are significantly withheld from the melts and remain stored in melanosomes (metatexites) except when leucosomes are affected by mixing (diatexites). U is frequently enriched in the leucosomes as well as in some melanosomes suggesting external supply. 相似文献
16.
S. Ferrero R. Braga M. Berkesi B. Cesare N. Laridhi Ouazaa 《Journal of Metamorphic Geology》2014,32(2):209-225
Garnet brought to the surface by late Miocene granitoids at La Galite Archipelago (Central Mediterranean, Tunisia) contains abundant primary melt and fluid inclusions. Microstructural observations and mineral chemistry define the host garnet as a peritectic phase produced by biotite incongruent melting at ~800 °C and 0.5 GPa, under fluid‐present conditions. The trapped melt is leucogranitic with an unexpected metaluminous and almost peralkaline character. Fluid inclusions are one phase at room temperature, and contain a CO2‐dominated fluid, with minor H2O, N2 and CH4. Siderite and an OH‐bearing phase were identified by Raman and IR spectroscopy within every analysed inclusion, and are interpreted as products of a post‐entrapment carbonation/hydration reaction between the fluid and the host during cooling. The fluid present during anatexis is therefore inferred to have been originally richer in both H2O and CO2. The production of anatectic melt with a metaluminous signature can be explained as the result of partial melting of relatively Al‐poor protoliths assisted by CO2‐rich fluids. 相似文献
17.
Insights into the complexity of crustal differentiation: K2O‐poor leucosomes within metasedimentary migmatites from the Southern Marginal Zone of the Limpopo Belt,South Africa 
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下载免费PDF全文 G. Nicoli G. Stevens J‐F. Moyen A. Vezinet M. Mayne 《Journal of Metamorphic Geology》2017,35(9):999-1022
Differentiation of the continental crust is the result of complex interactions between a large number of processes, which govern partial melting of the deep crust, magma formation and segregation, and magma ascent to significantly higher crustal levels. The anatectic metasedimentary rocks exposed in the Southern Marginal Zone of the Limpopo Belt represent an unusually well‐exposed natural laboratory where the portion of these processes that operate in the deep crust can be directly investigated in the field. The formation of these migmatites occurred via absent incongruent melting reactions involving biotite, which produced cm‐ to m‐scale, K2O‐poor garnet‐bearing stromatic leucosomes, with high Ca/Na ratios relative to their source rocks. Field investigation combined with geochemical analyses, and phase equilibrium modelling designed to investigate some aspects of disequilibrium partial melting show that the outcrop features and compositions of the leucosomes suggest several steps in their evolution: (1) Melting of a portion of the source, with restricted plagioclase availability due to kinetic controls, to produce a magma (melt + entrained peritectic minerals in variable proportions relative to melt); (2) Segregation of the magma at near peak metamorphic conditions into melt accumulation sites (MAS), also known as future leucosome; (3a) Re‐equilibration of the magma with a portion of the bounding mafic residuum via chemical diffusion (H2O, K2O), which triggers the co‐precipitation of quartz and plagioclase in the MAS; (3b) Extraction of melt‐dominated magma to higher crustal levels, leaving peritectic minerals entrained from the site of the melting reaction, and the minerals precipitated in the MASs to form the leucosome in the source. The key mechanism controlling this behaviour is the kinetically induced restriction of the amount of plagioclase available to the melting reaction. This results in elevated melt H2O and K2O and chemical potential gradient for these components across the leucosome/mafic residuum contact. The combination of all of these processes accurately explains the composition of the K2O‐poor leucosomes. These findings have important implications for our understanding of melt segregation in the lower crust and minimum melt residency time which, according to the chemical modelling, is <5 years. We demonstrate that in some migmatitic granulites, the leucosomes constitute a type of felsic refractory residuum, rather than evidence of failed magma extraction. This provides a new insight into the ways that source heterogeneity may control anatexis. 相似文献
18.
In the biotite-sillimanite and biotite-sillimanite-cordierite gneisses from the Haut Allier (French Massif Central), the biotite grains are partially melted: they are embayed and replaced by an isotropic material associated with metallic oxides. The complete study of this glass by optical microscopy, Raman spectroscopy, electronic microanalysis and X-Ray diffraction was performed: the glassy state is well established (locally some very fine kaolinite crystals are present in the glass as hydrothermal reconstruction). This glass results from the incongruent melting of biotite. The alumino-silicate melt corroded the preexistent quartz and feldspar grains. Anhydrous phases crystallized from this melt: successively sillimanite-cordierite and quartz. Correlatively, the melt must have become water-saturated and a new highly hydrated fluid phase should then have coexisted with it. Potassium and silicium, together with water, may have been components of the relatively mobile hydrous phase and this one may have been responsible for some hydration reactions such as muscovitization of feldspars. The petrological implications must be emphasized: in the studied gneisses, biotite cannot be considered as a resister. In fact, biotite melts and this melting is probably an important agent of the regional anatexis. 相似文献
19.
Sieve-textured clinopyroxene and spinel are common in mantle xenoliths and have been interpreted to be the result of partial
melting, mantle metasomatism and host magma–xenolith reaction during transport. In this paper, we test the latter hypothesis
with a series of reduced and oxidized experiments at 1,200 and 1,156°C at one atmosphere using a synthetic leucitite melt
and discs of natural peridotite. Our results show that sieve texture development on clinopyroxene and spinel in mantle xenoliths
is the result of a multistage reaction process. In the first step, orthopyroxene undergoes incongruent dissolution to produce
a silica and alkali-rich melt together with olivine. As this melt migrates along grain boundaries it causes incongruent dissolution
of clinopyroxene and spinel. The incongruent dissolution mechanism involves complete dissolution of the clinopyroxene or spinel
followed by nucleation and growth of a secondary clinopyroxene or spinel once the reacting melt is saturated. The reaction
of orthopyroxene, clinopyroxene and spinel with infiltrated host magma results in a range of melt compositions that are very
similar to those interpreted to be due to very small degrees of partial melting.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献