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1.
Euhedral quartz and albite crystals are common in Devonian (Givetian-Frasnian) shallow-marine shelf carbonates from the Belgian Ardennes. Several features such as morphology, the presence of carbonate inclusions, inversion temperatures and occurrence in the insoluble residues of stylolitic surfaces indicate that these crystals have developed authigenically. Oxygen isotope ratios point to an intermediate deep burial realm of origin at temperatures of 60–90°C. The predominance of illite and the almost total absence of smectite clay minerals is interpreted as an indication that illitization produced the silica needed for authigenesis. The mineral composition of inclusions indicates that the carbonate host rock must have consisted of low-Mg calcite already at the time of authigenesis. These inclusions represent an earlier diagenetic stage than the present carbonate rock, since they were protected from further diagenetic alteration by the surrounding quartz. The calcite inclusions display a higher Sr/Ca and Mg/Ca ratio than the carbonate host-rock. Because neomorphic diagenesis of the carbonate continued after silicate authigenesis, the contents of Mg and Sr in the calcite of the host carbonate are even lower. The authigenic feldspar mineralogy seems to be determined by the composition of the host-sediment. 相似文献
2.
鄂尔多斯盆地白垩系粘土矿物的分布特征及其沉积-成岩环境意义 总被引：5，自引：0，他引：5
系统地分析了鄂尔多斯盆地白垩系粘土矿物的特征及其沉积、成岩环境意义。研究结果表明:白垩系砂岩、泥质岩的粘土矿物组合以I+C+I/S型、I+C型为主,具有高伊利石含量,较高绿泥石、伊/蒙混层矿物含量的粘土矿物组成特点;其中泥质岩粘土矿物主要为陆源碎屑成因,次为沉积成岩过程中形成的自生粘土矿物,而砂岩粘土矿物兼有陆源碎屑成因和沉积成岩过程自生成因的特征;白垩系沉积时气候总体特征为干旱—半干旱,但局部时段发生干—湿气候波动而处于短暂的湿热气候环境;白垩系沉积物源富含长石等硅酸盐矿物,沉积物质主要自北、南、西向盆地内部搬运沉积;白垩系沉积和埋藏成岩过程中水介质整体上具有盐度较高,偏碱性,富K+、Fe2+、Mg2+的特点,且总体上盆地南部水介质中的这些指标都高于北部。 相似文献
3.
黄骅坳陷三马地区中-深部储层成岩作用及主控因素分析 总被引：12，自引：2，他引：12
黄骅坳陷三马地区储集岩样品的显微特征及成岩矿物的组合关系分析结果表明，三马地区下第三系中深层储层主要处于晚成岩A期，成岩现象包括石英、长石的次生加大、碳酸盐矿物胶结作用、矿物交代作用、溶解作用和粘土矿物转化作用等。其中石英次生加大于2700m左右开始出现，随埋深增大，石英增生加强；长石次生加大现象不十分普遍；碳酸盐胶结作用包括早期自生泥晶方解石胶结作用、连晶方解石和晚期白云石(或铁方解石)的胶结作用。在扫描电镜下可见到方解石与含铁方解石集合体充填在粒间孔隙中或与石英、钠长石及粘土矿物共生，白云岩多呈菱形粒状分布于粒间；常见的交代现象主要有方解石交代长石、石英及粘土矿物，粘土矿物交代长石、石英等；溶解作用主要有长石的溶解、碳酸盐颗粒的溶解和方解石胶结物的溶解等，粘土矿物的转化主要为蒙脱石、高岭石向伊利石(或绿泥石)转化。还讨论了储层岩相、岩性特征、孔隙水中有机酸含量、早期方解石的充填、烃类早期注入等因素对储层成岩演化的控制作用。 相似文献
4.
海拉尔盆地乌尔逊-贝尔凹陷下白垩统发育火山熔岩-正常碎屑沉积岩之间的过渡岩石类型,其成岩作用类型与正常沉积岩相比具有特殊性.采用显微镜下描述与扫描电镜分析相结合的方法对研究区成岩作用类型进行了研究,并总结出成岩作用序列.结果显示火山碎屑岩的成岩作用类型包括熔结作用、机械渗滤作用、压实作用、脱玻化作用、重结晶作用、胶结作用、自生矿物转化和溶蚀溶解作用.其中,熔结作用、脱玻化作用以及凝灰质的溶蚀溶解作用是火山碎屑岩所特有的成岩作用类型.研究区具有成因联系的成岩共生组合主要有4类,分别是:(1)微晶石英和微晶方解石;(2)石英的溶解与结晶;(3)自生白云母、蒙皂石、伊利石和绿泥石;(4)沸石与自生长石.成岩序列可以分为熔结作用阶段、机械渗滤作用阶段、脱玻化作用阶段、凝灰质溶蚀溶解作用阶段、粘土矿物混层阶段、自生白云母阶段、沸石胶结阶段、颗粒强烈胶结阶段以及铁白云发育阶段.研究区下白垩统处于早成岩B期至晚成岩B期,主要为晚成岩A期. 相似文献
5.
The reservoirs of the SOngliao Basin are composed of typical unstable sandstones,with high percentages of volcanic fragments and feldspar,In the course of sedimentation and burying,a series of physical and chemical reactions took place between minerals and pore water and water-rock reactions and ion exchange caused changes in ion assemblage of pore water,Hydration-hydrolysis,dissolution and the albitization of feldspar made many ions free from their framework and inter into the pore water,and induced the precipitation of a large amount of authigenic minerals such as smectite and chlorite,During the diagenesis of sandstone.diagenetic reactions involved several stages with increasing depth,and so did the precipitation of authigenic minerals and the transformaiton of minerals.The migration of ions is related with the precipitation,transformation and dissolution of authigenic minerals.Thus,to deepen our study on sandstone diagenesis is an important link for the analysis of ion migration in the evolution of pore water ,the origin and evolution of pore water could be tracked in terms of the geochemistry of fluid inclusions in authigenic minerals.And the isotopic composition of the authigenic mineral calcite can provide its genetic information. 相似文献
6.
Diagenesis of the Newark Rift Basin, Eastern North America 总被引：1，自引：0，他引：1
Late Triassic nonmarine strata in the Newark Rift Basin, eastern North America, accumulated in a subsiding half-graben prior to opening of the Atlantic Ocean. These strata consist, in ascending order, of the Stockton, Lockatong, and Passaic formations. Although different in specific lithology, these formations all exhibit diagenetic fabrics dominated by authigenic albite and analcime. These same minerals have a similar presence in Late Triassic (Newark Supergroup) strata of other rift-related basins to the north, suggesting that related authigenesis is not simply a result of local diagenetic factors. The basal deposit, the Stockton Formation, is composed of fluvial sandstones and overbank mudstones, with nodular pedogenic calcite (calcrete). During burial, original micrite was first recrystallized into sparry calcite and then later subjected to partial replacement by authigenic albite, which is also present as overgrowths and void fillings in overbank mudstones. The Lockatong Formation contains organic-rich shales, carbonates, and evaporative mudstones deposited under cyclic conditions in laterally extensive lacustrine environments. Analcime comprises up to 40% of these strata by volume, occurring within the matrix, as a replacement of original carbonates and evaporites, and as fillings in macrovoids. The overlying Passaic Formation is made up of massive red mudstones, evaporites, and local calcareous lacustrine sequences. Evaporites are replaced by coarse-grained anhydrite together with some authigenic albite. A central question concerns the source for the Na, Si, and Al required for albite and analcime authigenesis. It is suggested that, in addition to alteration of primary siliciclastic material, sodium in particular was supplied in two ways: (1) from high concentrations in original evaporative brines and groundwaters (Lockatong and Passaic formations); and (2) from dissolution of associated sodium-bearing evaporites (Lockatong and Passaic Formation) during diagenesis. It is proposed here that basin-sourced, Na-enriched brines circulated through the section over time. As albite is more stable at elevated temperatures relative to analcime, it developed in the lowermost strata of the basin (Stockton Formation). Analcime is more prevalent in the overlying Lockatong Formation. 相似文献
7.
成岩过程中泥岩的成岩矿物会随成岩体系的改变而发生变化，因此有效地识别成岩矿物组合与划分成岩体系，对深刻
理解有机质生烃的差异性具有重要的意义。文章选取东营凹陷古近系不同层段埋深在1200~4500 m的泥岩，通过岩石薄片、
扫描电镜和X射线衍射等检测，有效地区分了外源输入的矿物（如石英）与成岩矿物（亮晶方解石和白云石）等显微特征的差
异，据此建立了定量估算泥岩中成岩转化的黏土矿物含量的方法：C陆源=（C/Q）沙一×Q样品和C成岩=CXRD-C陆源，其中C为黏土矿物含
量，Q为石英含量，更好地反映了泥岩成岩过程中黏土矿物的演化特征。在埋藏演化过程中泥岩中的成岩矿物和组合呈现出
两段性，3000 m以上黏土矿物和白云石的成岩转化较慢，形成了以伊蒙间层+高岭石的成岩矿物组合，推断其经历了酸性成岩
环境和开放成岩体系；3000 m以下黏土矿物和白云石的成岩转化过程加快，形成了以伊利石+绿泥石+白云石的成岩矿物组
合，推断其经历了碱性成岩环境和封闭成岩体系，充分展现了泥岩在深浅层成岩环境和体系的差异性。与前人研究东营凹陷
泥岩中由有机质生烃产生异常压力造成的开放/封闭体系界限基本吻合，表明泥岩中矿物埋藏演化经历的成岩体系与有机质
生烃形成的压力体系具有较好的响应关系，这对认识不同成岩体系下有机质的生烃过程和生烃机理的差异性具有重要的
意义。 相似文献
8.
成岩过程中泥岩的成岩矿物会随成岩体系的改变而发生变化,因此有效地识别成岩矿物组合与划分成岩体系,对深刻
理解有机质生烃的差异性具有重要的意义。文章选取东营凹陷古近系不同层段埋深在1200~4500 m的泥岩,通过岩石薄片、
扫描电镜和X射线衍射等检测,有效地区分了外源输入的矿物（如石英）与成岩矿物（亮晶方解石和白云石）等显微特征的差
异,据此建立了定量估算泥岩中成岩转化的黏土矿物含量的方法：C陆源=（C/Q）沙一×Q样品和C成岩=CXRD-C陆源,其中C为黏土矿物含
量,Q为石英含量,更好地反映了泥岩成岩过程中黏土矿物的演化特征。在埋藏演化过程中泥岩中的成岩矿物和组合呈现出
两段性,3000 m以上黏土矿物和白云石的成岩转化较慢,形成了以伊蒙间层+高岭石的成岩矿物组合,推断其经历了酸性成岩
环境和开放成岩体系;3000 m以下黏土矿物和白云石的成岩转化过程加快,形成了以伊利石+绿泥石+白云石的成岩矿物组
合,推断其经历了碱性成岩环境和封闭成岩体系,充分展现了泥岩在深浅层成岩环境和体系的差异性。与前人研究东营凹陷
泥岩中由有机质生烃产生异常压力造成的开放/封闭体系界限基本吻合,表明泥岩中矿物埋藏演化经历的成岩体系与有机质
生烃形成的压力体系具有较好的响应关系,这对认识不同成岩体系下有机质的生烃过程和生烃机理的差异性具有重要的
意义。 相似文献
9.
通过薄片鉴定、扫描电镜以及岩石物性分析等方法,对内蒙古林西地区晚二叠世林西组碎屑岩成岩作用及其对储层物性的影响进行了系统研究,结果表明该地区林西组地层碎屑岩成岩作用主要为压实作用、胶结作用、交代作用及溶蚀作用。砂岩胶结物主要为黏土矿物、硅质矿物及碳酸盐矿物3种,其中黏土胶结物出现最多,以伊利石为主,绿泥石次之;碳酸盐胶结物以方解石为主;硅质胶结主要表现为石英次生加大和自生微晶石英。有机质镜质体反射率(Ro)、泥岩伊利石/蒙皂石(I/S)中的S(%)含量、石英次生加大级别、颗粒接触类型、伊利石结晶度等多项数据指标显示林西地区林西组碎屑岩处于晚成岩阶段。储层物性与成岩作用密切相关,压实作用、胶结作用使储层孔隙度和渗透率降低;溶蚀作用使储层孔隙度提高。 相似文献
10.
Metamorphic and Thermal History of a Fore-Arc Basin: the Fossil Bluff Group, Alexander Island, Antarctica 总被引：2，自引：0，他引：2
The Himalia Ridge Formation (Fossil Bluff Group), AlexanderIsland is a 2·2-km-thick sequence of Upper Jurassic–LowerCretaceous conglomerates, sandstones and mudstones, derivedfrom an andesitic volcanic arc and deposited in a fore-arc basin.The metamorphic and thermal history of the formation has beendetermined using authigenic mineral assemblages and vitrinitereflectance measurements. Metamorphic effects include compaction,pore-space reduction, cementation and dissolution and replacementof detrital grains by clay minerals (smectite, illite/smectite,corrensite and kaolinite), calcite, chlorite, laumontite, prehnite,pumpellyite, albite and mica, with less common quartz, haematite,pyrite and epidote. The authigenic mineral assemblages exhibita depth-dependence, and laumontite and calcite exhibit a strongantipathetic relationship. Detrital organic matter in the argillaceouslayers has vitrinite reflectance values (Ro) ranging from 2·3to 3·7%. This indicates considerable thermal maturation,with a systematic increase in reflectivity with increasing depth.There is good correlation of metamorphic mineral assemblageswith chlorite crystallinity and vitrinite reflectance values—allindicating temperatures in the range of 140 ± 20°Cat the top of the sequence to 250 ± 10°C at the baseof the sequence. The temperatures suggest a geothermal gradientof 36–64°C/km and a most likely gradient of 50°C/km.It is suggested that this higher-than-average gradient for afore-arc basin resulted either from rifting during basin formationor from a late-stage arc migration event. KEY WORDS: Antarctica; diagenesis; fore-arc basin; low-temperature metamorphism; vitrinite reflectance 相似文献
11.
文章通过对泥质岩的黏土质矿物组分、成岩作用中黏土质矿物变化综合研究,认为泥质岩中存在大量黏土矿物,且泥质沉积物由松散到固结成岩实质上是黏土矿物组成的变化。泥质岩中主要黏土矿物包括高岭石、蒙皂石、绿泥石、伊利石以及其组成的混层型矿物伊利石/蒙皂石、绿泥石/蒙皂石,其成岩过程可划分为成岩早期的压实阶段、成岩晚期的黏土矿物转化阶段。压实阶段的泥质沉积物中黏土矿物具有物源的继承性、沉积水体古环境指示意义;受压实作用孔隙水、层间水被排出,原生絮凝团被压破,使片状质点趋于平行排列,黏土矿物与孔隙水发生反应,亦形成少量的新生作用矿物,因而黏土矿物具继承源和新生作用源特性。成岩晚期阶段发生层间水释放及层间阳离子交换,从而使得矿物晶体结构与成分发生变化,主要表现为一元黏土矿物向二元混层型转化,最后再到一元型黏土矿物的转化,最终形成转变源黏土矿物。 相似文献
12.
Inorganic minerals in mudstone are composed of clay minerals,carbonate and detrital minerals.Detrital minerals(such as quartz and feldspar)are mainly original deposit.However,clay minerals(kaolinite,illite,and chlorite)and carbonate(calcite and dolomite)are mostly diagenetic minerals.Furthermore,conversion of the four kinds of clay minerals are common.The formation of clay minerals and carbonate is controlled by temperature,pressure,p H,Eh and type of cations during diagenesis.Therefore mineral assemblage can indicate the characteristics and change of diagenetic environment.In addition to inorganic minerals,there are also organic matter of different sources and chemical properties in mudstone.Traditionally,it is considered that evolution of organic matter is controlled by thermal effect.Now studies show that inorganic and organic matter can interact with each other and form clay-organic complexes.This suggest that attention should be paid to the influence of diagenetic mineral assemblage and diagenetic environment on the evolution of organic matter* Samples of mudstone from 1500-4500m of the Palaeogene in the Dongying Depression,China,were collected to investigate the changes of mudstone diagenetic environment.XRD,thin section and SEM were used to detect diagenetic minerals and assemblage characteristics.Results showed that content of detrital minerals,which are floating in mud matrix or preserved as silt laminae,is basically unchanged from shallow to deep strata.Clay minerals which are gathered as argillaceous matrix or preserved as argillaceous laminae have growth and decline relation to carbonate which mainly appear as micropoikilitic ferriferous calcite and ferriferous dolomite.All these characteristics indicate that detrital minerals are exogenetic,whereas carbonate is diagenetic minerals.Based on the SEM analysis of the clay minerals,it was found that smectite present honeycomb and reticulate structure,while illite present filiform and schistose structure and there are growth and decline relationship between them.Nevertheless,hexagonal tabular and stratified kaolinite has the highest content from 2400m to3300m.Rosette and stratified chlorite shows increase trend when the burial depth is deeper than 3300m.These characteristics indicated that clay minerals are diagenetic minerals and there are conversions among the four types.Therefore form shallow to deep,three diagenetic mineral assemblage zones can be divided based on the characteristics of carbonate and clay minerals in mudstone.Namely,smectite+illite/smectite zone in the depth of 2000-2500m;kaolinite+illite/smectite zone in the depth of 2500-3300m and illite+chlorite+carbonate zone below 3300m.Previous studies showed that kaolinite is stable under acidic conditions,while other clay minerals and carbonate are stable under alkaline conditions.Hence according to mineral assemblages feature,it was inferred that diagenetic environment of mudstonehasundergonethechangeof alkaline-acid-alkaline.For the organic matter with different chemical properties in mudstone,the hydrocarbon generation will be different in the acidic and alkaline diagenetic environment even if the conditions of temperature and pressure are the same.Therefore,for hydrocarbon generation we should not only focus on thermal effect,but also pay more attention to the differences of diagenetic environment which have great significance for the understanding of hydrocarbon generation,hydrocarbon expulsion and reservoir formation in mudstone. 相似文献
13.
早期形成的碳酸盐结核在埋藏期间会经历多种碳酸盐矿物相沉淀的复杂胶结作用,岩石学研究是探究结核成因的关键。通过野外剖面观察、岩石学观察和阴极发光技术,分析了鄂尔多斯盆地渭北地区上三叠统延长组长7油层组泥页岩中各种形状的方解石和白云石结核中自生碳酸盐矿物的特征。这些结核为成岩早期的产物,构成结核的自生碳酸盐矿物特征显著:(1)球粒方解石结核中,方解石呈纤维状或刃片状,球粒间充填晶粒方解石或因压实呈贴面结合,纤维状方解石发桔红色和暗红色2种光,刃片状方解石发暗红色光;(2)粉晶方解石结核中,方解石呈他形粒状,含有机质包裹体或纤维状晶形残余,晶间含沥青和纤维状方解石残余,主要发暗红色光;(3)白云石结核有泥晶和粉晶2种晶体类型,粉晶白云石结核含较多泥质,泥质条带或有机质条带处常见纤柱状白云石;(4)沿裂缝充填的方解石和白云石常呈纤维状或纤柱状结构,发暗红色光或不发光。研究区长7油层组碳酸盐结核中的方解石和白云石具有不同的成因类型和复杂的胶结作用:球粒方解石和泥晶白云石代表了结核开始形成时的胶结作用,可以准确地反映结核的成因;粉晶方解石、粉晶白云石反映了交代成因;裂缝中纤维状、纤柱状方解石和白云石集合体则为结核经历了较强压实作用之后充填裂缝而成。 相似文献
14.
塔里木盆地西北地区苏盖特布拉克组发育一套潮坪相沉积,是该层系油气勘探的主要目标。基于什艾日克剖面、奇格布拉克剖面、肖尔布拉克剖面的地质测量,采用薄片鉴定、阴极发光、扫描电镜、流体包裹体测温及黏土矿物X衍射等分析手段开展海相碎屑岩成岩作用和成岩演化研究,为塔里木盆地苏盖特布拉克组进一步开展油气勘探部署和甜点储层预测提供地质依据。结果表明：（1）研究区苏盖特布拉克组发育潮坪沉积环境的砂体,砂岩类型以岩屑石英砂岩、岩屑砂岩为主,偶见长石岩屑砂岩,成分成熟度和结构成熟度中等;（2）苏盖特布拉克组砂岩经历了压实（溶）作用、胶结作用、溶蚀作用及交代作用等成岩作用,压实作用是造成储层致密的直接原因,钙质胶结和硅质胶结是储层致密化的根本因素;（3）苏盖特布拉克组砂岩的成岩演化阶段已达到中成岩B期,成岩演化序列为：压实作用/自生黏土矿物（绿泥石）环边—第一期长石、岩屑溶蚀作用—第一期硅质胶结—第一期泥微晶方解石胶结/压溶作用/黏土矿物的伊利化—第二次硅质胶结/第二期铁方解石胶结—钙质胶结物溶蚀。据此建立的成岩演化模式为塔里木盆地超深层致密砂岩中甜点储层预测提供可靠的地质依据。 相似文献
15.
The origin and form of quartz in mudrocks has significant implications for interpretation of depositional environments, diagenetic pathways, mechanisms of porosity reduction and rock mechanical-property evolution. Quartz types in the Upper Pennsylvanian Cline Shale, Midland Basin, Texas, were examined using a combination of field-emission scanning electron microscopy-based energy-dispersive spectroscopy elemental mapping (to determine mineralogy) and scanning electron microscopy-based cathodoluminescence imaging (to determine quartz types) with the goal of elucidating a high-resolution imaging protocol at the micrometre scale for shale petrology. Also, the unconfined compressive rock strength of shale samples with contrasting proportions of different quartz types was measured using Equotip Bambino analyses. The results suggest that extrabasinal detrital quartz, which accounts for an average of 26 vol.% of the rock in all analyzed samples, is the dominant form of quartz in the Cline Shale. The intergranular clay-size microquartz, which accounts for an average of 10 vol.% of the rock in all analyzed samples, is the dominant form of authigenic quartz. Dissolved radiolarians and sponge spicules are likely sources of silica for clay-size microquartz and other authigenic quartz showing pale-mauve to dark greyish cathodoluminescence colour. Some authigenic quartz in the form of intragranular pore filling and mollusc skeletal replacement displays bright-reddish cathodoluminescence colour, which may be associated with silica released at a different time in the rock's diagenetic history, such as during smectite illitization. Porosity reduction in the Cline Shale predominantly resulted from compaction because of extremely low intergranular volume and the general lack of early cementation. Quartz form significantly impacts rock mechanical properties in the Cline Shale: widely distributed intergranular clay-size microquartz cement is a major factor controlling rock strength. This correlation also applies to other mudrock successions of various geological ages, tectonic histories and lithologies. 相似文献
16.
台地泥质组分沉积记录了源—汇过程和环境演化等沉积学领域信息,可作为古气候和古环境重建的重要载体。然而,利用沉积物中的泥质组分进行古气候和古环境恢复时仍存在相当大的复杂性和局限性。鉴于此,笔者以上寺剖面中二叠统茅口组为例,通过研究该层位富泥质组分灰岩—泥灰岩韵律的宏微观形貌学和矿物学特征,发现其泥质组分主要由成岩黏土矿物海泡石构成,其次为少量滑石和蒙脱石。基于前人认识,进一步运用电子探针和激光原位元素地球化学分析手段,综合认为海泡石中镁元素来源于继承海水的孔隙水以及亚稳定矿物的转化释放,硅元素可能来源于上扬子台地的同沉积期断裂热液。此外,滑石主要形成于海泡石埋藏过程中的成岩转化,蒙脱石可能也具有类似成因,但不排除有少量蒙脱石来源于火山物质的海底改造。结合区域资料,华南中二叠统浅水碳酸盐台地上广泛发育自生成因（早期成岩作用和埋藏成岩作用）泥质组分。因此,在利用泥质组分来恢复古环境的时候,需要谨慎识别其成因,这将有利于提高沉积旋回识别和环境解释的准确性;另一方面,对自生成因泥质组分进行专门研究,在成岩过程以及成岩地球化学信号识别上也具有参考价值。 相似文献
17.
Minoru Utada 《Resource Geology》2003,53(4):293-304
Abstract. The Tsukiyoshi uranium deposit in Gifu Prefecture is the largest one in Japan. It is embedded in lower part of the Mizunami Group of Miocene age. Relating to the existence of this uranium deposit, the constituent minerals in sediments were studied by XRD and SEM, using many drilling cores. The most abundant authigenic mineral is smectite. The amount of smectite increases generally from upper to lower horizons, and a highly smectitized zone is situated around the uranium deposit. Smectitization predominated in mafic glassy grains of sediments, which was probably formed in early burial diagenesis. Zeolites including clinoptilolite-heulandite, mordenite, analcime, chabazite and philipsite are secondly abundant authigenic minerals. They seem to have been formed at early to late diagenetic stages. Opaline silica is rather rare. Carbonate minerals, including cal-cite, dolomite, siderite and rhodochrosite are common. They may be formed by diagenesis as well. Gypsum and pyrite occur in upper horizons and lower horizons, respectively. In particular, a highly smectitized zone including pyrite probably played an important role for retarding the migration of uranium and as a result keeping the uranium deposit for past one million years. This smectite-zeolite envelope surrounding the Tsukiyoshi uranium deposit is regarded as a natural analogue of the buffer materials surrounding the high-level radioactive waste repository. 相似文献
18.
A.E.KELEPERTSIS E.KONTIS 《中国地球化学学报》1997,16(1):8-19
The mineralogy and geochemistry data are presented for thirty-seven shales,four concretions,two carbonate sediments and seven lignites from the Marathousa coal field of the Megalopolis Basin in Greece.The argillaceous rocks consist of chlorite,illite,kaolinte,albite,quartz.opal-A,calcite and dolomite;the concretions of aragonite,gypsum and pyrite;and the carbonate rocks of calcite,quartz and illite.The mineral matter in the lignites consists of gypsum,quartz,albite,chlorite,illite,opal-A,dolomite,pyrite,and rarely calcite and kaolinite Athree-factor model explains the total variaition of major and trace elements in the argillaceous sediments.The first factor is an aluminosilicate factor and involves the following elements:Al,Si,Mg,Na,K,Ti,Mn,Nb,Y,Rb,Zn,Cu,Ni,Cr,Nband V,associated with chlorite,albite and illite.The second factor involves the elements Ca,Sr,Ba,Znand Sc and is related to carbonate lithology and mainly the carbonate concretions with gypsum.The third factor involves Fe and Ce with a weak association with Mn.The diagenesis of the Marathousa sediments and lignites was not very advanced as indicated by (a) the total thickness of the sequence (500m),(b) the presence of biogenic silica(opal-A) and (c) the age of the deposit(Pleistocene).FOr these reasons the rpresence of chlorite,illite and kaolinite in the sediments and lignite is due not to diagenetic reactions but to weathering of the flysch and metamorphic rocks at the edges of the Megalopolis Basin and transport of the weathering products(illite,chlorite,kaolinite)into the basin of deposition.The diagenetic minerals of the Marathousa sequence include pyrite,gypsum,dolomite and aragonite. 相似文献
19.
西藏日喀则地区蛇绿质沉积岩的成岩后生变化及其地质意义 总被引：1，自引：0，他引：1
洋壳裂开后,发展成新的扩张中心,形成了新洋壳,除典型的镁铁质蛇绿岩外,在板块迁移过程中,它们的上面还沉积有蛇绿质沉积物,这套沉积岩系的产生、形成和变化与海底扩张及板块运动有着密切关系。对这类沉积物的组合、沉积特征和成岩变化的研究,随着板块学说研究的深入,越来越为广大地质学家所重视,其研究结果不但能反映这类沉积的性质和特殊环境,而且还可以从一个侧面来验证板块演化的过程。作为大陆碰撞型板块造山运动典型的地区,西藏雅鲁藏布缝合带上,也沉积和保存着这类属于洋壳上部的岩层,对此,作者于1980-1981年相继进行了考察,本文就是在野外工作的基础上通过岩石学、地球化学研究,来讨论这类沉积物的成岩后生变化及其地质意义。 相似文献
20.
页岩粒度细小、岩石致密、微观非均质性显著,在成岩作用改造下发育形成页岩气储层,成岩作用的研究可以为优质页岩储层发育机理提供依据。以渝西地区綦江观音桥剖面、南川泉浅1井、南川三泉剖面、大足Z-203井等代表性剖面、钻孔为例,通过X射线衍射、氩离子抛光—场发射扫描电镜、能谱、岩石薄片/光片显微观察、有机地球化学测试、力学特征测试等手段,对储层成岩作用及其对储层力学脆性的影响展开系统研究。结果表明,研究区五峰组—龙马溪组页岩物质组分、岩石结构、力学性质存在层段性差异,成岩作用阶段介于晚成岩作用阶段至极低级变质作用阶段之间;储层主要成岩作用类型可以划分为压实作用等物理性成岩作用、矿物溶蚀作用等矿物相关化学性成岩作用和有机质生烃作用等有机质相关化学性成岩作用三类。研究区五峰组—龙马溪组底部存在部分脆性矿物高于80%的超高脆性矿物含量层段,碳质—硅质富层理页岩在特殊储层成岩作用的影响下形成大量自生微晶石英,构成以微晶石英+赋孔有机质为主的显微物相组合,兼具良好的力学脆性与储集能力,而其他层段缺乏持续演化不断形成微晶石英的物质基础。储层成岩作用发生的物质基础、岩石结构、类型、作用强度在层段间的差异,是储层脆性矿物与力学性质差异的关键影响因素,应纳入储层评价与优质储层机理研究的关注范畴。 相似文献