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1.
The Pampean Ranges of northwest Argentina are a basin-and-range tectonic province with a late Precambrian to Paleozoic basement and extensive Miocene-Recent calc-alkaline volcanism. The volcanoes include the large resurgent Cerro Galan caldera, and Recent scoria cones and lava flows. Miocene-Recent volcanic rocks of basalt to dacite composition from the Cerro Galan area exhibit a range of Rb/Sr ratios of 0.043–1.092 and initial87Sr/86Sr ratios of 0.7057–0.7115 with a clear positive correlation between87Sr/86Sr and87Rb/86Sr, indicating an apparent age of ca. 130 Ma. This relationship is interpreted to indicate that the Sr isotope variation in the Cerro Galan volcanic rocks results from mixing of a mantle-derived component with low87Sr/86Sr (<0.7057) and high Sr (>700 ppm) with a crustal component characterized by higher87Sr/86Sr (>0.7115) and lower Sr (<240 ppm). It is concluded that the mixing is best explained as a result of a small degree of selective crustal Sr contamination (ca. 10%) of a range of subsequently erupted magmas produced largely by fractional crystallization within the continental crust. We propose that the mantle-derived end-member is derived by partial melting of sub-Andean mantle with an87Sr/86Sr ratio of ca. 0.704, and that such an Sr isotope ratio characterizes the source region for calc-alkaline volcanic rocks throughout the Andes.  相似文献   

2.
The annular (6–8 km diameter) Golda Zuelva and Mboutou anorogenic complexes of North Cameroun are composed of a suite of alkaline plutonic rocks ranging from olivine gabbro to amphibole and biotite granite. For the Mboutou complex there are two overlapping centres. In the Golda Zuelva complex the plutonic rocks are associated with a later hawaiite to rhyolite volcanic suite. A Rb/Sr whole rock isochron gives an age of 66±3 Ma for the Golda Zuelva granites, with initial87Sr/86Sr ratio of 0.7020, and demonstrates that plutonism and volcanism were essentially contemporaneous and probably cogenetic. For Golda Zuelva and the north Mboutou centre18O/16O (5.6–6.2),87Sr/86Sr (0.7030–0.7045) and Pb isotopic ratios (207Pb/204Pb: 15.60–15.64) support a mantle origin for the initial magmas. Unlike Sr isotopes, the O isotopic ratios of the granitic end members at Golda Zuelva (～7.5) indicate crustal contamination. Post-magmatic alteration was not significant.For the younger south Mboutou centre the O-, Sr- and Pb-isotopic data indicate more extensive magma-crust interaction and in a different (higher level?) crustal environment with δ18O granite=3.3‰,87Sr/86Sr ratios up to 0.706 and Pb isotopic ratios more markedly displaced from the oceanic volcanic field. The low-18O granites probably record, at least in part, a magmatic process with subsequent minor post-magmatic alteration effects. The major and trace element systematics between the north and south Mboutou centres are directly comparable. The evolution of the magmas were dominated by fractional crystallisation and progressive crustal contamination processes.  相似文献   

3.
New strontium isotopic data of calc-alkaline Pliocene-to-Quaternary lavas (southern Peru) confirm their anomalous isotopic composition compared to those of calc-alkaline rocks from active margins where continental crust is not involved. Gradual enrichment of radiogenic Sr occurs during fractional crystallization of calc-alkaline magma. The variation of the isotopic composition of these lavas as well as87Sr/86Sr versus 1/(86Sr) diagrams form the basis for a model involving processes of fractional crystallization combined with mixing and addition of radiogenic Sr that originated in continental crust and was transported by a fluid phase.  相似文献   

4.
Erciyes stratovolcano, culminating at 3917 m, is located in the Cappadocian region of central Anatolia. During its evolution, this Quaternary volcano produced pyroclastic deposits and lava flows. The great majority of these products are calc-alkaline in character and they constitute Kocdag and Erciyes sequences by repeated activities. Alkaline activity is mainly observed in the first stages of Kocdag and approximately first-middle stages of Erciyes sequences. Generally, Kocdag and Erciyes stages terminate by pyroclastic activities. The composition of lavas ranges from basalt to rhyolite (48.4–70.5 wt.% SiO2). Calc-alkaline rocks are represented mostly by andesites and dacites. Some compositional differences between alkaline basaltic, basaltic and andesitic rocks were found; while the composition of dacites remain unchanged. All these volcanics are generally enriched in LIL and HFS elements relative to the orogenic values except Rb, Ba, Nb depleted alkaline basalt. 87Sr/86Sr and 143Nd/144Nd isotopic composition of the volcanics range between 0.703344–0.703964, 0.512920–0.512780 for alkaline basalts and change between 0.704322–0.705088, 0.512731–0.512630 for alkaline basaltic rocks whereas calc-alkaline rocks have relatively high Sr and Nd isotopic ratios (0.703434–0.705468, 0.512942–0.512600). Low Rb, Ba, Nb content with high Zr/Nb, low Ba/Nb, La/Yb ratio and low Sr isotopic composition suggest an depleted source component, while high Ba, Rb, Nb content with high La/Yb, Ba/Nb, low Zr/Nb and low 87Sr/86Sr ratios indicate an OIB-like mantle source for the generation of Erciyes alkaline magma. These elemental and ratio variations also indicate that the different mantle sources have undergone different degree of partial melting episodes. The depletion in Ba, Rb, Nb content may be explained by the removal of these elements from the source by slab-derived fluids which were released from pre-collisional subduction, modified the asthenospheric mantle. The chemically different mantle sources interacted with crustal materials to produce calc-alkaline magma. The Ba/Nb increase of calc-alkaline samples indicates the increasing input of crustal components to Erciyes volcanics. Sr and Nd isotopic compositions and elevated LIL and HFS element content imply that calc-alkaline magma may be derived from mixing of an OIB-like mantle melts with a subduction-modified asthenospheric mantle and involvement of crustal materials in intraplate environments.  相似文献   

5.
Cenozoic volcanism in the Great Basin is characterized by an outward migration of volcanic centers with time from a centrally located core region, a gradational decrease in the initial Sr87/Sr86 ratio with decreasing age and increasing distance from the core, and a progressive change from calc-alkalic core rocks to more alkalic basin margin rocks. Generally each volcanic center erupted copious silicic ignimbrites followed by small amounts of basalt and andesite. The Sr82/Sr86 ratio for old core rocks is about 0.709 and the ratio for young basin margin rocks is about 0.705. Spatially and temporally related silicic and mafic suites have essentially the same Sr87/Sr86 ratios. The locus of older volcanism of the core region was the intersection of a north-south trending axis of crustal extension and high heat flow with the northeast trending relic thermal ridge of the Mesozoic metamorphic hinterland of the Sevier Orogenic Belt. Derivation of the Great Basin magmas directly from mantle with modification by crustal contamination seems unlikely. Initial melting of lower crustal rocks probably occurred as a response to decrease in confining pressure related to crustal extension. Volcanism was probably also a consequence of the regional increase in the geothermal gradient that is now responsible for the high heat flow of the Basin and Range Province. High Sr isotopic ratios of the older core volcanic rocks suggests that conditions suitable for the production of silicic magmas by partial fusion of the crust reached higher levels within the crust during initial volcanism than during production of later magmas with lower isotopic ratios and more alkaline chemistry. As the Great Basin became increasingly attenuated, progressively lower portions of the crust along basin margins were exposed to conditions suitable for magma genesis. The core region became exhausted in low temperature melting components, and volcanism ceased in the core before nearby areas had completed the silicic-mafic eruption cycle leading to their own exhaustion of crustal magma sources.  相似文献   

6.
Andesites from the Peruvian Andes and the Banda arc of Indonesia are characterized by unusually high and variable 87Sr/86Sr ratios. The Banda arc samples, including two cordierite-bearing lavas from Ambon, show a clear positive correlation between 87Sr/86Sr and δ18O. The andesitic rocks have δ18O values that range from 5.6 to 9.2‰. Over that range in δ18O, 87Sr/86Sr increases from 0.7044 to 0.7095. The cordierite-bearing lavas have δ18O values of approximately 15‰ and 87Sr/86Sr ratios of approximately 0.717. The similarity between δ18O values and 87Sr/86Sr ratios in total rocks and separated plagioclase phenocrysts of the Banda arc samples indicates that the measured isotope ratios are primary and have not been affected by secondary, low-temperature post-eruptive alteration. The observed variation between O and Sr isotopic ratios can be modeled by two-component mixing in which one component is of mantle isotopic composition. As the crust beneath the Banda arc is probably oceanic, contamination of the manle component may have resulted from the subduction of either continentally-derived sediments or continental crust. Mixing calculations indicate that the contaminant could have an isotopic composition similar to that observed in the cordierite-bearing lavas.The Andean samples, despite petrographic evidence of freshness, exhibit whole-rock δ18O values significantly higher than those of corresponding plagioclase phenocryst separates, indicating extensive low-temperature post-eruptive alteration. The plagioclase mineral separates show a range of δ18O values between 6.9 and 7.9‰. The 87Sr/86Sr ratios of these same samples are, in most instances, not significantly different from those measured for the whole rock, thus signifying that the phenocrysts and groundmass were in isotopic equilibrium at the time of eruption. Unlike the lavas of the Banda arc, the Andean lavas show no strong positive correlation between 87Sr/86Sr ratios and δ18O values, but instead lower 87Sr/86Sr ratios appear to be associated with higher δ18O values. The δ18O and 87Sr/86Sr values of the Peruvian samples are both slightly higher than those of “normal” island arc volcanics.The small proportions of contaminant implied by the O isotope results seem to preclude continental crustal contamination as a primary cause of high 87Sr/86Sr ratios. The most plausible process that can explain both O and Sr isotope results is one in which sediments of continental origin are partially melted in the subduction zone. These melts rise into overlying mantle material and subsequently participate in the formation of calc-alkaline magmas.If the involvement of a sialic component in the genesis of andesitic magma occurs in the subduction zone, melting of that sialic material signifies temperatures of at least 750–800°C at the top of the subducted lithospheric slab at depths of approximately 150 km. The fact that contamination has apparently occurred in the Banda arc samples without producing any simple widespread correlations between Sr and O isotopic compositions on the one hand and major or trace element abundances on the other, shows that isotopic correlations, possibly including pseudo-isochrons, can be produced by mixing without producing trace element mixing correlations. Because O versus Sr isotope correlations are little affected by processes of partial melting of differentiation, they provide a direct means of testing whether Sr isotopic variations in volcanic rocks are of mantle origin or are due instead to mixing with sialic material.  相似文献   

7.
Alkali basalts of Pliocene age are the last episode of volcanism in the SE Spain Volcanic Province, postdating a complex series of Miocene calc-alkaline to ultrapotassic rocks. This volcanism is represented by small outcrops and vents NW of Cartagena that has been interpreted as a volcanic episode similar to the contemporaneous monogenetic alkaline basaltic volcanism of the Iberian Peninsula and Western/Central Europe. However, their geochemical signature is characterised by relatively higher 87Sr/86Sr ratios as well as distinct trace element anomalies which, at different scale, are only found in the spatially related calc-alkaline to ultrapotassic volcanism. Quantitative modelling of these data demonstrate that the geochemical signature of the Pliocene alkali basalts of Cartagena can be explained by the interaction between primitive melts generated from a sublithospheric mantle source similar to that identified for other volcanic regions of Spain, and liquids derived from the overlying lithospheric mantle. This interaction implies that the alkali basalts show some geochemical features only observed in mantle lithosphere-derived melts (e.g. Sr isotope enrichment and Th–U–Pb positive anomalies), while retaining an overall geochemical signature similar to other Iberian basalts (e.g. Rb–K negative anomalies). This model also implies that beneath the SEVP, enriched (metasomatized) portions were still present within the lithospheric mantle after the Miocene magmatic episodes.  相似文献   

8.
Oxygen isotope data are reported for 27 igneous rocks of Mesozoic to Quaternary age from the Central Andes. 26–29°S. The plutonic rocks, and most of the volcanics, have δ18O values between 6.2 and 8.3‰.The whole-rock δ18O values show a weak correlation with initial87Sr/86Sr data. This O-Sr array differs from documented trends for calc-alkaline plutonic suites from California, Scotland and northern Italy, but overlaps with data for volcanic and plutonic rocks from Ecuador, northern Chile and southern Perú.The oxygen isotope results indicate that the magmas evolved without significant contamination from supracrustal rocks (e.g., rocks that experienced18O enrichment during surficial weathering). The available O, Sr and Pb isotopic data for these rocks are best explained by magma generation in the upper mantle or lower crust. From the Late Mesozoic on, the87Sr/86Sr values were modified at depth by isotopic exchange between the magma and a continually thickening crust of plutonic rocks of Late Precambrian to early Mesozoic age.  相似文献   

9.
Neodymium isotope and REE analyses of recent volcanic rocks and spinel lherzolite nodules from the Afar area are reported. The143Nd/144Nd ratios of the volcanic rocks range from 0.51286 to 0.51304, similar to the range recorded from Iceland. However, the87Sr/86Sr ratios display a distinctly greater range (0.70328–0.70410) than those reported from the primitive rocks of Iceland. Whole rock samples and mineral separates from the spinel lherzolite nodules exhibit uniform143Nd/144Nd ratios (ca. 0.5129) but varied87Sr/86Sr ratios in the range 0.70427–0.70528.The SrNd isotope variations suggest that the volcanic rocks may have been produced by mixing between two reservoirs with distinct isotopic compositions. Two possible magma reservoirs in this area are the source which produced the “MORB-type” volcanics in the Red Sea and Gulf of Aden and the anomalous source represented by the nodule suite. The isotopic composition of the volcanics is compatible with mixing between these two reservoirs.It is shown that the anomalous source with a high87Sr/86Sr ratio cannot have been produced by simple processes of partial melting and mixing within normal mantle. Instead the high87Sr/86Sr is equated with a fluid phase. A primitive cognate fluid, subducted seawater or altered oceanic lithosphere may have been responsible for the generation of the source with a high87Sr/86Sr ratio.  相似文献   

10.
143Nd/144Nd,87Sr/86Sr and trace element results are reported for volcanic and plutonic rocks of the Aleutian island arc. The Nd and Sr isotopic compositions plot within the mantle array with εNd values of from 6.5 to 9.1 and87Sr/86Sr ratios of from 0.70289 to 0.70342. Basalts have mildly enriched light REE abundances but essentially unfractionated heavy REE abundances, while andesites exhibit a greater degree of light to heavy REE fractionation. Both the basalts and andesites have significant large ion lithophile element to light rare earth element (LILE/LREE) enrichments. Variations in the isotopic compositions of Nd and Sr are not related to the spatial distribution of volcanoes in the arc, nor are they related to temporal differences. εNd and87Sr/86Sr do not correlate with major element compositions but do, however, correlate with certain LILE/LREE ratios (e.g. BaN/LaN). Plutonic rocks have isotropic and trace element characteristics identical to some of the volcanic rocks. Rocks that make up the tholeiitic, calc-alkaline and alkaline series in the Aleutians do not come from isotopically distinct sources, but do exhibit some differing LILE characteristics.Given these elemental and isotopic constraints it is shown that the Aleutian arc magmas could not have been derived directly from homogeneous MORB-type mantle, or fresh or altered MORB subducted beneath the arc. Mixtures of partially altered MORB with deep-sea sediment can in principle account for the isotopic characteristics and most of the observed LILE/LREE enrichments. However, some samples have exceedingly high LILE/LREE enrichments which cannot be accounted for by sediment contamination alone. For these samples a more complex scenario is considered whereby dehydration and partial melting of the subducted slab, containing less than 8% sediment, produces a LILE-enriched (relative to REE) metasomatic fluid which interacts with the overlying depleted mantle wedge. The isotopic and LILE characteristics of the mantle are extremely sensitive to metasomatism by small percentages of added fluid, whereas major elements are not substantially effected, Major element compositions of Aleutian magmas are dominantly controlled by the partial melting of this mantle and subsequent crystal fractionation; whereas isotopic and LILE characteristics are determined by localized mantle heterogeneities.  相似文献   

11.
Inception of volcanism at late Oligocene to Recent centers in the eastern Coast Ranges of California (ECR suite) regularly decreases in age northward and is correlated with the northward migration of the transform-transform-trench Mendocino triple junction (MTJ). Miocene volcanism in the southern California basin (SCB suite) is spatially and temporally associated with the transform-ridge-trench Rivera triple junction (RTJ). The tholeiitic to calc-alkaline rocks in both suites were erupted through older trench melange while arc magmatism was occurring several hundred kilometers to the east. Therefore they are not related to subduction zone magmatism, but instead to interactions of the MTJ and RTJ with the continental margin.The ECR rocks, dominantly intermediate to silicic in composition, have relatively high δ18O values up to 11.3, 87Sr/86Sr ratios up to 0.7055, as well as relatively high Th contents, suggesting that crustal anatexis played a dominant role in their generation. Coupled crystal fractionation and crustal assimilation by an initially basaltic magma cannot explain the high δ18O values and 87Sr/86Sr ratios because greater than 95% of the basalt would need to crystallize. In contrast, the SCB rocks, dominantly mafic to intermediate in composition, have relatively low δ18O values down to 5.2 and 87Sr/86Sr ratios down to 0.7025 suggesting that these rocks were derived dominantly from a mantle source.Whether crustal anatexis occurs is determined largely by the type of stress a triple junction imposes upon the continental margin. Both the MTJ and RTJ are associated with high heat flow and magma fluxes from the mantle. The transform-transform-trench MTJ is associated with locally variable mild extension to compression and therefore allows pooling of basaltic magma in the crust to initiate crustal melting. The high rates of continental extension associated with the transform-ridge-trench RTJ prevents such pooling of magma.The space created by decoupling of the subducted slab at a transform-transform-trench triple junction might promote passive upwelling of mantle material to fill it and induce melting to generate basalts. Mafic volcanic rocks of this origin may provide a unique view of the subcontinental mantle at the continental margin. 87Sr/86Sr ratios as low as 0.70255 for mafic volcanic rocks in the Sonoma-Tolay center associated with the MTJ contrast with high La/Sm ratios of 1.1 to 1.3 and low Zr/Nb,Hf/Ta,La/Th, and La/Ta ratios of 5.0 to 6.7, 2.6 to 3.5, 4.7 to 8.8, and 10.2 to 12.5, respectively. These data suggest that the mantle beneath parts of western California may have originally been depleted but has been enriched relatively recently. Such enrichment might have occurred by metasomatic processes associated with crustal accretion and/or juxtaposition of differing lithospheric mantle in the Mesozoic and Cenozoic.  相似文献   

12.
The isotopic compositions of Sr, Nd and Pb together with the abundances of Rb, Sr, U and Pb have been determined for mafic and felsic potassic alkaline rocks from the young Virunga volcanic field in the western branch of the East African rift system.87Sr/86Sr varies from 0.7055 to 0.7082 in the mafic rocks and from 0.7073 to 0.7103 in the felsic rocks. The latter all come from one volcano, Sabinyo. Sabinyo rocks have negative εNdvalues ofεNd = ?10. Nd and Sr isotopic variations in the basic potassic rocks are correlated and plot between Sabinyo and previously reported [1] compositions (εNd = +2.5;87Sr/86Sr≈ 0.7047) for Nyiragongo nephelinites. The Pb isotopic compositions for Sabinyo rocks are nearly uniform and average206Pb/204Pb≈ 19.4,207Pb/204Pb= 15.79–15.84,208Pb/204Pb≈ 41.2. The basic potassic rocks have similar206Pb/204Pb values but range in207Pb/204Pb and208Pb/204Pb from the Sabinyo values to less radiogenic compositions.Excellent correlations of87Sr/86Sr with Rb/Sr, 1/Sr and207Pb/206Pb for Sabinyo rocks suggest these to be members of a hybrid magma series. However, the nearly uniform Pb compositions for this series points to radiogenic growth of87Sr in the magma source region following an event which homogenized the isotopic compositions but not Rb/Sr. The Rb-Sr age derived from the erupted Sabinyo isochron-mixing line is consistent with the ～500 Myr Pb-Pb age from Nyiragongo [1], which suggests that this event affected all Virunga magma sources. The event can again be traced in the Pb-Pb, Pb-Sr and Nd-Sr isotopic correlations for all Virunga rocks, including Nyiragongo, when allowances are made for radiogenic growth subsequent to this mixing or incomplete homogenization event. Inferred parent/daughter element fractionations point to a metasomatic event during which a mantle fluid invaded two lithospheric reservoirs: a +εNd reservoir sampled by the Nyiragongo nephelinites and suggested to be the subcontinental mantle and a ?εNd reservoir sampled by the mafic and felsic potasssic volcanism. Whether this ?εNd reservoir is the crust, continental crustal material in the mantle or anomalous mantle cannot be decided from the data. The simplest answer, that this reservoir is the continental crust, seems to be at variance with experimental evidence suggesting a subcrustal origin for basic potassic magmas. Partial melting of the ancient metasomatised lithospheric domains and ensuing volcanism seems to be entirely a response to decompression and rising geotherms during rifting and thinning of the lithosphere.  相似文献   

13.
We have investigated 24 whole rocks and mineral separates of five different rock types from the Cantal shield volcano in France, applying high-precision Rb-Sr techniques. The chemical and isotopic systematics suggest the distinction of two series throughout the different rock classes, one practically uncontaminated, the other seriously influenced by wall rock assimilation. The first group comprises basalts and intermediate rocks with87Sr/86Sr= 0.70340–0.70382. The second group in addition includes rhyolites and the corresponding87Sr/86Sr ratios vary between 0.70421 and 0.71270. The data of mineral separates support the hybridization hypothesis and possibly suggest an original87Sr/86Sr ratio of 0.7028 for the magma source region. Moreover they provide internal isochron ages which place a period of extensive volcanic activity at 8.1–8.8 m.y. ago in accord with K-Ar ages of volcanic rocks from the center of the Cantal volcano.  相似文献   

14.
87Sr/86Sr ratios of three hydrothermal waters collected on the East Pacific Rise at 21°N define a mixing line between seawater and a hydrothermal end-member at 0.7030 which is derived by seawater-basalt interaction at ca. 350°C and water/rock ratio of about 1.5. Sr concentrations are not affected in the process while Mg uptake from seawater is almost complete. Up to2/3 of this hydrothermal component is involved in anhydrite precipitation while the Sr isotopic ratio in sulfides (chalcopyrite + sphalerite) cannot be distinguished from that of sulfate. It is estimated that ca. 1 × 1010 moles of strontium are yearly cycled in the hydrothermal systems of mid-oceanic ridges, thereby affecting the87Sr/86Sr budget of seawater. Mass balance between river runoff, limestone precipitation and ridge basalt alteration suggests that the87Sr/86Sr ratios of the river runoff are in the range 0.7097–0.7113, and are largely dominated by limestone alteration.  相似文献   

15.
Twenty-nine isotopic ages, ranging from 41 to 27 Ma, are presented for the alkali-rich intrusive rocks and their coexisting alkaline volcanic rocks, lamprophyres and acidic porphyries, indicating that they are Tertiary in age. The alkali-rich intrusive rocks have143Nd/144Nd ratios from 0. 512 415 to 0. 512 544, and87Sr/86Sr ratios from 0.705 4 to 0.706 8, suggesting that their material originates from an enriched mantle source. Project supported by the National Natural Science Foundation of China and the Special Grant of the President of Chinese Academy of Sciences.  相似文献   

16.
We report the results of a detailed study of dissolved Sr isotopes in the Solimões and Beni‐Madeira Rivers of the Amazon basin. This study developed data collected over 8 years indicating large spatial and temporal variations in dissolved Sr isotopes among the rivers of the Amazon basin. The large 87Sr/86Sr variations were found to be correlated with the geology of the source areas of the suspended sediments. The Beni‐Madeira River displays a high average 87Sr/86Sr ratio and large 87Sr/86Sr fluctuations during the hydrological cycle. This large average value and fluctuations were related to the presence of Precambrian rocks and Ordovician sediments in the source area of the suspended sediment of the river. In contrast, the Solimões River displays a narrow range of Sr isotope ratio variations and an average value close to 0.709. This river drains mostly Phanerozoic rocks of northern Peru and Ecuador that are characterized by low Sr isotope ratios. The isotopic fluctuations in the Beni‐Madeira River were observed to propagate downstream at least as far as Óbidos. This signal is characterized by an inverse relationship between the concentration of elemental Sr and its isotopic ratios. We further demonstrate that the Sr isotopic composition and content in the Beni‐Madeira River is controlled by suspended sediments derived from the Andes. Despite draining areas underlain by Precambrian rocks and having high 87Sr/86Sr ratios, such rivers as the Negro and Tapajós play a minor role in the total Sr budget of the Amazon basin. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

17.
Subduction‐related volcanic rocks are widespread in the Central Pontides of Turkey, and represented by the Hamsaros volcanic succession in the Sinop area to the north. The volcanic rocks display high‐K calc‐alkaline, shoshonitic and ultra‐K affinities. 40Ar/39Ar age data indicate that the rocks occurred during the Late Cretaceous (ca 82 Ma), and the volcanic suites were coeval. Primitive mantle‐normalized trace element patterns of all the lavas are characterized by strong enrichments in large ion lithophile elements (LILE) (Rb, Ba, K, and Sr), Th, U, Pb, and light rare earth elements (LREE; La, Ce) and prominent negative Nb, Ta, and Ti anomalies, all typical of subduction‐related lavas. There is a systematic increase in the enrichment of incompatible trace elements from the high‐K calc‐alkaline lavas through the shoshonitic to the ultra‐K lavas. In addition, the shoshonitic and ultra‐K lavas have significantly higher 87Sr/86Sr (0.70666–0.70834) and lower 143Nd/144Nd (0.51227–0.51236) initial ratios than coexisting high‐K calc‐alkaline lavas (87Sr/86Sr 0.70576–0.70613, 143Nd/144Nd 0.51245–0.51253). Geochemical and isotopic data show that the shoshonitic and ultra‐K rocks cannot be derived from the high‐K calc‐alkaline suite by any shallow level differentiation process, and point to a derivation from distinct mantle sources. The shoshonitic and ultra‐K rocks were derived from metasomatic veins related to melting of recycled subducted sediments, but the high‐K calc‐alkaline rocks from a lithospheric source metasomatized by fluids from subduction zone.  相似文献   

18.
The Cenozoic volcanic rocks of the southern Andes are characterized by low 87Sr/86Sr ratios (0.7040–0.7045), which are consistent with an origin in the downgoing slab of oceanic lithosphere or the overlying mantle. These values are distinctly lower than those from corresponding rocks of the central Andes.The calc-alkaline rocks of the central Andes exhibit higher Sr isotopic values (0.705–0.713) and variable Rb/Sr ratios. Different explanations are possible for this behaviour as well as for the positive correlation between 87Sr/86Sr and Rb/Sr expressed in an apparent isochron of 380 ± 50 m.y. It is postulated that these magmas result from a mixing process between a primary magma with basaltic affinities and crustal material of relatively young age.A model is proposed for the generation of the “andesitic” magmas of the central Andes by which crustal rocks of the upper part of the crust are added to the base of the crust by an accretionary process at the margin of the continent. Melts from these upper crustal rocks act as contaminants in “andesitic” magmas.The role of crustal material is still more significant in the generation of the ignimbritic magmas; they are considered to result from a two-stage melting process by which igneous rocks, belonging to a former stage of development of the Andes, are engulfed in the subduction zone, where they melt.  相似文献   

19.
143Nd/144Nd,87Sr/86Sr and REE results are reported on volcanic rocks from the islands of Dominica and St. Kitts in the Lesser Antilles. Particular attention is given to the lavas and xenoliths of the Foundland (basalt-andesite) and the Plat Pays (andesite-dacite) volcanic centres on Dominica. Combined major and trace element [2] and isotope results suggest that the bulk of the andesites and dacites on Dominica, and by analogy in the rest of the arc, are produced by fractional crystallisation of basaltic magma. The differences in the erupted products of the two volcanoes do not appear to be related to any significant differences in the source rocks of the magmas.Along the arc87Sr/86Sr ratios range from 0.7037 on St. Kitts, to 0.7041–0.7047 on Dominica, and 0.7039–0.7058 on Grenada [5], and these are accompanied by a parallel increase in K, Sr, Ba and the light REE's. Moreover, compared with LIL-element-enriched and -depleted rocks from MOR and intraplate environments, the basic rocks from the Lesser Antilles are preferentially enriched in alkaline elements (K, Ba, Rb, Sr) relative to less mobile elements such as the rare earths.143Nd/144Nd varies from 0.51308 on St. Kitts, to 0.51286 on Dominica, and 0.51264–0.51308 on Grenada [5], and all these samples have relatively high87Sr/86Sr ratios compared with the main trend of Nd and Sr isotopes for most mantle-derived volcanic rocks. Alkaline elements and87Sr appear to have been introduced from the subducted ocean crust, but the results on other, less mobile elements are more ambiguous — island arc tholeiites (as on St. Kitts) do not appear to contain significant amounts of REE's, Zr, Y, etc., from the subducted oceanic crust, but such a contribution may be present in more LIL-element-enriched calc-alkaline rock types.  相似文献   

20.
The87Sr/86Sr ratio of seawater strontium (0.7091) is less than the87Sr/86Sr ratio of dissolved strontium delivered to the oceans by continental run-off (～0.716). Isotope exchange with strontium isotopically lighter oceanic crust during hydrothermal convection within spreading oceanic ridges can explain this observation. In quantitative terms, the current87Sr/86Sr ratio of seawater (0.7091) may be maintained by balancing the continental run-off flux of strontium (0.59 × 1012 g/yr) against a hydrothermal recirculation flux of 3.6 × 1012 g/yr, during which the87Sr/86Sr ratio of seawater drops by 0.0011. A concomitant mean increase in the87Sr/86Sr ratio of the upper 4.5 km of oceanic crust of 0.0010 (0.7029–0.7039) should be produced. This required87Sr enrichment has been observed in hydrothermally metamorphosed ophiolitic rocks from the Troodos Massif, Cyprus.The post-Upper Cretaceous increase in the strontium isotopic composition of seawater(～0.7075–0.7091) covaries smoothly with inferred increase in land area. This suggests that during this period the main factor which has caused variability in the87Sr/86Sr ratio of seawater strontium could have been variation in the magnitude of the continental run-off flux caused by variation in land area. Variations in land area may themselves have been partly a consequence of variations in global mean sea-floor spreading rate.  相似文献   

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