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1.
Marine diatomaceous siliceous sediments in Neogene sections of northern Japan contrast with the Monterey Shale of California in containing many intercalations of acidic volcaniclastic sediments. Diagenesis of these sediments from deep boreholes and surface sections was investigated. Three diagenetic zones—biogenic opal, opal-CT and quartz zones—are recognized in siliceous sediments, corresponding roughly to amorphous silica, low cristobalite and quartz zones in acidic vitric volcaniclastic sediments. Opal-CT consists almost exclusively of silica and water, while low cristobalite contains appreciable amounts of A1, Ca, Na and K. In subsurface sections, values of d(101) spacing of opal-CT decrease progressively with increasing burial depth. The progressive ordering is not associated with additional silica cementation. In surface sections, the behaviour of d(101) spacing is complicated owing to the modification of the progressive ordering developed during burial diagenesis by later silica cementation during uplift. The cementing opal-CT is probably precipitated from percolating groundwater which dissolves siliceous skeletons in porous diatomaceous mudstones overlying the opal-CT porcellanite. Opaline cherts that form during burial diagenesis are designated as early opaline chert, while those which form during uplift are later opaline chert. The later opaline chert contains two groups of opal-CT; one is progressively ordered opal-CT and the other is additionally cemented opal-CT with higher d(101) spacing than that in the host porcellanite. In diatomaceous siliceous sediments, early opaline chert is scarce. Most, if not all, opaline cherts in surface sections are of later origin.  相似文献   

2.
A small isolated outlier of Lower Oligocene chalk, which grades upwards into what was originally a sandy marl, has been truncated by a paleokarst surface, which is overlain by cross-bedded, well-sorted glauconitic sands. A sandy clay horizon (probably originally tuffaceous) and a basaltic lava flow of probable Miocene age cap the local sequence. Below the paleokarst surface and roughly parallel to it, the original sediment has been intensely altered to an average depth of 1.5 m. The alteration front is sharply defined, even where it extends along the walls of glauconitic sand-filled fissures in the chalk.In the alteration zone, the chalk has been entirely replaced by silica (opal-CT, largely in the form of lepispheres). The calcareous fraction of the marl has been replaced by montmorillonite and clinoptilolite. Rounded gravel clasts (largely basaltic) in the base of the overlying glauconitic sands also have been replaced (by montmorillonite), which suggests that all alteration followed deposition of the sands. However, neither the glauconite nor any other mineral in the sands appears highly altered. Similarly, the quartz grains show no evidence of dissolution or silica precipitation. Preservation of most silica sponge spicules, the only siliceous microfossils in the chalk, indicates that the source of the silica was extraneous to the carbonate sediments.Migrating interstitial liquid, largely confined to the sands between the impervious cap of sandy clay plus basalt and the porous but less permeable chalk, is inferred to have been the causal agent for the replacement. Silica, and any other components necessary for the formation of opal-CT, montmorillonite and clinoptilolite, were probably derived by chemical alteration of the capping volcanics in a groundwater regimen. Replacement reactions in the chalk and marl presumably were dependent on the original presence of calcium carbonate, and apart from montmorillonitization of volcanic material, occurred only where this compound was present.  相似文献   

3.
Under conditions of unobstructed diagenetic growth, opal-CT usually forms spherical aggregates, so-called lepispheres. From a scanning electron microscope study of deep-sea porcelanites, the development of these structures is described, from isolated opal-CT platelets via complete lepispheres to large coalescent aggregates. The conspicuous symmetric ultrastructure of lepispheres—reflected by the constancy of angles between interpenetrating crystal blades—is crystallographically determined: The lepispheres consist of groups of opal-CT blades intergrown according to the (30–34) and (10–16) twinning laws of tridymite. The same rules of intergrowth can be applied to the morphology of hydrothermally synthesized opal-CT lepispheres.  相似文献   

4.
A Tertiary non-marine stratigraphic sequence composed of carbonates(limestone),siliceous carbonates,coaly layers overlain by pyroclastic rocks and lavas,outcrops in the Gavatha area of northwestern Lesvos Island.Pure earbonates eonsist almost completely of calcite,the siliceous carbonate sediments of quartz,opal-CT and calcite,the shales of quartz,opal CT, K-feldspar,smecite-illite and ealcite,and the coaly layers of organic matter,quartz,opal-CT,feldspars and pyrite,Geochemical data indicate that smectite-illite,feldspars and associated elements(La,Zr,Y,Ba,Ce)are the products of alteration of volcanic rocks in a subtropical area A combination of sources in suggested for the formation of silica polymorphs:(a) biogenic or non-biogenic silica(opal-A) that was originally present in the form of diatiom frustules of in the form of inorganically prccipitated silica;(b)transformation o opall-A to opal-CT and quartz opal-C from alteration of volcanic glass of intercalated tuffites and overlying volcanics;and(c)opal-CT deposited primarily from hydrothermal solutions.  相似文献   

5.
A detailed oxygen isotope study of detrital quartz and authigenic quartz overgrowths from shallowly buried (<1 km) quartz arenites of the St. Peter Sandstone (in SW Wisconsin) constrains temperature and fluid sources during diagenesis. Quartz overgrowths are syntaxial (optically continuous) and show complex luminescent zonation by cathodoluminescence. Detrital quartz grains were separated from 53 rocks and analyzed for oxygen isotope ratio by laser fluorination, resulting in an average δ18O of 10.0 ± 0.2‰ (1SD, n = 109). Twelve thin sections were analyzed by CAMECA-1280 ion microprobe (6-10 μm spot size, analytical precision better than ±0.2‰, 1SD). Detrital quartz grains have an average δ18O of 10.0 ± 1.4‰ (1SD, n = 91) identical to the data obtained by laser fluorination. The ion microprobe data reveal true variability that is otherwise lost by homogenization of powdered samples necessary for laser fluorination. Laser fluorination uses samples that are one million times larger than the ion microprobe. Whole rock (WR) samples from the 53 rocks were analyzed by laser fluorination, giving δ18O between 9.8‰ and 16.7‰ (n = 110). Quartz overgrowths in thin sections from 10 rocks were analyzed by ion microprobe and average δ18O = 29.3 ± 1.0‰ (1SD, n = 161).Given the similarity, on average, of δ18O for all detrital quartz grains and for all quartz overgrowths, samples with higher δ18O(WR) values can be shown to have more cement. The quartz cement in the 53 rocks, calculated by mass balance, varies from <1 to 21 vol.% cement, with one outlier at 33 vol.% cement. Eolian samples have an average of 11% cement compared to marine samples, which average 4% cement.Two models for quartz cementation have been investigated: high temperature (50-110 °C) formation from ore-forming brines related to Mississippi Valley Type (MVT) mineralization and formation as silcretes at low temperature (10-30 °C). The homogeneity of δ18O for quartz overgrowths determined by ion microprobe rules out a systematic regional variation of temperature as predicted for MVT brines and there are no other known heating events in these sediments that were never buried to depths >1 km. The data in this study suggest that quartz overgrowths formed as silcretes in the St. Peter Sandstone from meteoric water with δ18O values of −10‰ to −5‰ at 10-30 °C. This interpretation runs counter to conventional wisdom based on fibrous or opaline silica cements suggesting that the formation of syntaxial quartz overgrowths requires higher temperatures. While metastable silica cements commonly form at high degrees of silica oversaturation following rapid break-down reactions of materials such as of feldspars or glass, the weathering of a clean quartz arenite is slower facilitating chemical equilibrium and precipitation of crystallographically oriented overgrowths of α-quartz.  相似文献   

6.
Opaline silica (opal-A) has formed in marine, lacustrine and geothermal environments throughout geological time. During diagenesis opal-A normally changes to opal-CT, then opal-C, and finally to quartz. Such changes commonly destroy the original fabrics and any fossils that opal-A contained. The physical changes that accompany the opal-A to opal-CT transition, however, are known poorly. X-ray diffraction analyses, electron microprobe analyses and high-resolution, high-magnification scanning electron microscope imagery of siliceous sinters from the Geysir geothermal area in Iceland show that opal-A is formed of heterometric arrays of randomly packed microspheres (up to 5  μ m diameter) with neighbouring spheres commonly being joined by small connection pads. In contrast, enlarged spheres, lepispheres, inverse opal (two types) and spindle frameworks with hexagonal motifs characterize opal-CT. The textures in opal-CT, which vary on a microscale, reflect the complex interplay between dissolution (e.g. inverse opal) and precipitation (e.g. enlarged spheres, spindle frameworks) that probably was mediated by groundwater in a near-surface environment. The processes deciphered from these young rocks should, however, be applicable to sedimentary opal-A and opal-CT of all ages, irrespective of their origin.  相似文献   

7.
Mineralogical and textural changes accompanying ageing of silica sinter   总被引：3，自引：0，他引：3  
Twenty nine samples of silica sinter, ranging in age from modern to Miocene, record temporal changes in both mineralogy and texture. When first deposited, sinters consist largely of noncrystalline spheres (<1–8 μm diameter) of opal-A exhibiting varying degrees of close-packing. Particle densities range from 1.5 to 2.1 g cm−3, total water 4–10 wt%, and porosities 35–60%. Changes over ∼10,000 years following deposition are slight although the spheres may be invested by an additional film of secondary silica. For the next 10,000 to ∼50,000 years, the silica incrementally crystallises to become poorly crystalline opal-CT and/or opal-C; spherical particles of thin-bladed crystals (lepispheres) replace opal-A particles and coalesce in microbotryoidal aggregates (∼10–30 μm diameter). Amygdaloidal fibrous clusters occur with lepispheres. As silica lattice ordering becomes enhanced, total water content drops to <7 wt%, particle density increases to ∼2.3 g cm−3, and porosity reduces to <30%. The change from opal-A to opal-C takes place over a briefer periods (∼50 years) in silica sinters that contain other materials (e.g. calcite, sulfur, alunite, plant remains). Sinters older than ∼50,000 years have recrystallised to microcrystalline quartz. With the onset of quartz crystallisation at ∼20,000 years, total water is <0.2 wt%, particle density approximates quartz (2.65 g cm−3), and porosity is <4%. The progressive changes in silica species and texture yield ageing profiles for sinters that may serve as guides to the paleohydrology of geothermal systems and/or epithermal ore deposits in areas where surface thermal activity has declined or ceased. Received: 18 November 1998 / Accepted: 6 July 1999  相似文献   

8.
The volcanic origin, primarily basaltic, of most of the surface material in Iceland influences its physical properties and appearance. Size distributions, shape analyses and melting experiments were made for surface material collected in high-erosion dust source areas and fresh volcanic ash deposits to determine whether they differ from one another and from dust from other major dust sources. The major differences found between Icelandic dust and dust from other major dust sources in the world, such as the Sahara, are in the particle shapes, lower density and darker colour. Icelandic dust particles greater than 20 μm retain volcanic morphological properties that are also found in fresh volcanic ash. Dust and fresh volcanic ash particles less than 20 μm are crystalline and blocky in nature, similar to the dust from other global source regions. The finer grained (<20 μm) Icelandic particles will have similar suspension and transport behaviours and be similarly hazardous to health and infrastructure as non-Icelandic dust. The coarser particles (>20 μm) will have different suspension and transport behaviours than other dusts due to the volcanic morphology. Icelandic surface material has between 5% and 30% glassy particles compared to fresh volcanic ash which has more than 50% glassy particles. Glassy particles were observed to melt at a lower temperature than the mineral grains; and, as a result, volcanic ash is found to be more threatening to aircraft engines than the typical dust from Iceland. Icelandic dust was observed to be blocky, or plate-like in the respirable size fraction, suggesting similar health hazards as dust from other regions.  相似文献   

9.
Fluid inclusions and clusters of water molecules at nanometer-to submicron-scale in size have been investigated using transmission electron microscopy (TEM) and Fourier transform infrared spectroscopy (FTIR) in jadeite, quartz and symplectite aegirine–augite, albite, taramite and magnetite corona minerals from ultrahigh-pressure (UHP) jadeite–quartzite at Shuanghe, the Dabie Mountains, China. Fluid inclusions from 0.003 μm to 0.78 μm in size occur in jadeite and quartz crystals, and a small number of fluid inclusions from 0.001 μm to 0.25 μm have also been detected in symplectite-forming minerals. Most of the fluid inclusions have round or negative crystal morphology and contain aqueous fluids, but some contain CO2-rich fluids. They are usually connected to dislocations undetectable at an optical scale. The dislocations represent favorable paths for fluid leakage, accounting for non-decrepitation of most fluid inclusions when external pressure decreased at later stages, although there was partial decrepitation of some fluid inclusions unconnected to defect microstructures resulting from internal overpressure. Non-decrepitation and partial decrepitation of fluid inclusions resulted in changes of original composition and/or density. It is clear that identification of hidden re-equilibration features has significant implications for the petrological interpretation of post-peak metamorphic processes. Micro-FTIR results show that all jadeite and quartz samples contain structural water occurring as hydroxyl ions (OH−) and free water (H2O) in the form of clusters of water molecules. The H2O transformed from OH− during exhumation and could have triggered and enhanced early retrograde metamorphism of the host rocks and facilitated plastic deformation of jadeite and quartz grains by dislocation movement, and thus the H2O released during decompression might represent early-stage retrograde metamorphic fluid. The nominally anhydrous mineral (NAM) jadeite is able to transport aqueous fluids in concentrations of at least several hundred ppm water along a subduction zone to mantle depths in the form of clusters of water molecules and hydroxyl ions within crystals.  相似文献   

10.
Sixty five urban road dust samples were collected from different land use areas of ∼240 km2 in Xi’an, China. The concentrations of Ag, As, Cr, Cu, Hg, Pb, Sb and Zn were determined to investigate potentially harmful element (PHE) contamination, distribution and possible sources. In addition, the concentrations in different size fractions were measured to assess their potential impact on human health. The highest concentrations were found in the fraction with particle diameters between 80 μm and 101 μm, the finest particles (<63 μm) were not the most important carriers for Ag, As, Cd, Cr, Cu, Hg, Pb and Zn. The percentages of these elements in particles with diameters less than 63 μm (PM63) and less than 101 μm (PM101) were in the range of 7–15%, and 30–55%, respectively. Three main factors influencing element distributions have been identified: (a) industrial activities; (b) prior agricultural land use; and (c) other activities commonly found in urban areas, such as traffic, coal combustion, waste dumping, and building construction/renovation. The highest concentrations were found in industrial areas for As (20 mg kg−1), Cr (853 mg kg−1), Cu (1071 mg kg−1), Pb (3060 mg kg−1) and Zn (2112 mg kg−1), and in previous agricultural areas for Ag and Hg, indicating significant contributions from industrial activities and prior agricultural activities.  相似文献   

11.
Limestone drains are often implemented in the treatment of acid mine drainage (AMD), but when the AMD contains high levels of dissolved Fe their lifetime is dependent on the rate of precipitation of Fe hydroxide on the limestone surface. This study used a small-scale laboratory experiment to define the longevity of a limestone drain by determining the thickness of the Fe coating encapsulating the limestone particles when the system lost its maximum neutralising potential. Synthetic AMD (100 mg/L Fe, pH 4–4.8) was pumped through a column containing limestone particles for 1110 h, when the effluent pH had dropped from a maximum of 6.45–4.9. The decline in neutralisation during the experiment was due to the formation of Fe hydroxide coatings on the limestone grains. These coatings are composed of lepidocrocite/goethite in three distinct layers: an initial thick porous orange layer, overlain by a dense dark brown crust, succeeded by a layer of loosely-bound, porous orange globules. After 744 h, a marked increase in the rate of pH decline occurred, and the system was regarded as having effectively failed. At this time the Fe hydroxide crust effectively encapsulated the limestone grains, forming a diffusion barrier that slowed down limestone dissolution. Between the coating and the limestone substrate was a 60 μm wide void, so that agitation of the limestone sample would readily remove the coating from the limestone surface.  相似文献   

12.
We present first data on the geochemistry, mineralogy and morphology of near-vent sediments (35 and 200 m from active vent) and ridge flank sediments (approximately 3 km from the vent field) as well as oxyhydroxide deposits from the Endeavour segment, Juan de Fuca Ridge. The purpose of the study was to understand better the origin and characteristic features of metalliferous sediments associated with base and precious metal massive sulfides in volcanic terrains. Hydrothermal components in sediments are Fe-Si ± S-rich and Mn-Fe-Si-rich phases, sulfides and barite, which were exclusively derived from plume fallout. Sulfides are only a minor constituent of near-vent sediments (2-4 wt%) and were not detected in ridge flank sediments. The study suggests that the distribution of hydrothermal phases and associated elements in near-vent and ridge flank sediments is affected mainly by processes of agglomeration, dissolution, absorption and settling that take place within a plume and to a lesser extent post-depositional processes. Rapid deposition of sulfides in the vicinity of the vents is reflected in a sharp drop of the Cu concentrations in sediments with increasing distance from the vents. Besides sulfides, important carriers of Pb, Cu, Zn and Co in near-vent sediments are Fe-Mn oxyhydroxides that occur together with silica as aggregates of gel-like material and flaky particles and as coatings on filaments. Away from the vents, trace metals are mostly in Fe-Mn oxyhydroxides and authigenic Fe-rich montmorillonite. Oxyhydroxides at the Main Endeavour field are interpreted to have originated from oxidation of mound sulfides accompanied by precipitation of primary Fe-oxyhydroxide + silica from low-temperature fluids. At the Mothra field, seafloor deposits and chimney crusts composed of Fe-oxyhydroxide ± Mn + silica are considered to be direct precipitates from hydrothermal fluids that have been less diluted with seawater. Oxyhydroxide deposits exhibit unique microtextures that resemble mineralized microorganisms and may indicate existence of diverse microbial communities.  相似文献   

13.
Grain size analyses of three hilltop, primary eolian loess sequences in the Negev desert, southern Israel, show a bimodal grain-size distribution at 50-60 μm and 3-8 μm. Using analyses of mineralogy and OSL ages we demonstrate that the coarse mode is composed mostly of quartz grains and its relative magnitude increases regionally with time, suggesting an enhancement of a time-transgressive proximal dust source compared to a distal, Saharan fine-grain dust. The only proximal dust source for large amount of coarse silt quartz grains is the sands that advanced into Sinai and the Negev concurrently with the loess accretion during the late Pleistocene as a result of the exposure of the Mediterranean shelf. We therefore propose that the coarse silt quartz grains were formed through eolian abrasion within the margins of an advancing sand sea. This relationship between desert sand seas as a source for proximal coarse dust and desert margin loess deposits can be applicable to other worldwide deserts such as Northern Africa, China and Australia.  相似文献   

14.
Smelting slags associated with base-metal vein deposits of the Sierra Almagrera area (SE Spain) show high concentrations of Ag (<5–180 ppm), As (12–750 ppm), Cu (45–183 ppm), Fe (3.2–29.8%), Pb (511–2150 ppm), Sb (22–620 ppm) and Zn (639–8600 ppm). The slags are mainly composed of quartz, fayalite, barite, melilite, celsian, pyrrhotite, magnetite, galena and Zn–Pb–Fe alloys. No glassy phases were detected. The following weathering-related secondary phases were found: jarosite–natrojarosite, cotunnite, cerussite, goethite, ferrihydrite, chalcanthite, copiapite, goslarite, halotrichite and szomolnokite. The weathering of slag dumps near the Mediterranean shoreline has contaminated the soils and groundwater, which has caused concentrations in groundwater to increase to 0.64 mg/L Cu, 40 mg/L Fe, 0.6 mg/L Mn, 7.6 mg/L Zn, 5.1 mg/L Pb and 19 μg/L As. The results of laboratory leach tests showed major solubilization of Al (0.89–12.6 mg/L), Cu (>2.0 mg/L), Fe (0.22–9.8 mg/L), Mn (0.85–40.2 mg/L), Ni (0.092–2.7 mg/L), Pb (>2.0 mg/L) and Zn (>2.5 mg/L), and mobilization of Ag (0.2–31 μg/L), As (5.2–31 μg/L), Cd (1.3–36.8 μg/L) and Hg (0.2–7 μg/L). The leachates were modeled using the numerical code PHREEQC. The results suggested the dissolution of fayalite, ferrihydrite, jarosite, pyrrhotite, goethite, anglesite, goslarite, chalcanthite and cotunnite. The presence of secondary phases in the slag dumps and contaminated soils may indicate the mobilization of metals and metalloids, and help to explain the sources of groundwater contamination.  相似文献   

15.
This paper mainly describes mineralogy and geochemistry of coals from the Weibei coalfield in the southeastern Ordos Basin, North China. A number of Al-hydroxide/oxyhydroxide minerals were detected in the Late Carboniferous coals (Nos. 5, 10 and 11 coals), especially in the No. 10 coal. Aluminum-hydroxide/oxyhydroxide minerals (nordstrandite, boehmite and diaspore) in the No. 10 coal are associated with kaolinite, suggesting that these minerals are derived from the breakdown of kaolinite. A model in which Al-hydroxide/oxyhydroxide minerals form from the incongruent dissolution of kaolinite is presented. Nordstrandite and boehmite mainly occur as massive lenses (<500 μm in length). Diaspore appears as massive aggregates and as single euhedral crystals (<50 μm in length) in a kaolinite matrix. The presence of high temperature quartz, and zircon indicates that there was input of felsic volcanic debris during accumulation of the Late Carboniferous coals. These volcanic materials have also had a significant influence on the enrichment of certain trace elements including Li, Be, Ga, Zr, Nb, Mo, Sn, W and U in the Late Carboniferous coals (Nos. 5, 10, and 11 coals). SEM-EDX results show that Ga in the No. 10 coal (whole coal average 33.4 μg/g; n = 2) mainly occurs within Al-hydroxide/oxyhydroxide minerals (nordstrandite, boehmite, and diaspore), kaolinite and organic matter.  相似文献   

16.
Some of the Lower Pleistocene bentonites of Milos and Kimolos islands, Greece, are valued for their white colour and physicochemical properties. They contain opal-CT and, sometimes, zeolite along with smectite, and have been derived from the alteration of rhyolitic volcanic rocks. The Miloan white bentonites contain Tatatilla-type montmorillonite and beidellite. The Kimolian ones have Chambers-type montmorillonite. The alteration process involved removal of alkalis and uptake of Mg, probably from sea water. Si is either redistributed or partially removed. The Kimolian white bentonites have higher brightnesses, L* and whiteness index values, and lower yellowness index and ΔE*ab values compared with the Miloan ones. The variations in white colour are inversely related to the abundance of Fe oxides and anatase, the occurrence of Fe in the smectite structure and its oxidation state. The presence of silica minerals is not an important factor affecting colour, but is undesirable since it imparts high abrasiveness in commercial products. The formation of white bentonites of high quality requires the removal of alkalis and silica during alteration of acid volcanics in order to avoid crystallization of zeolites and opal-CT. Fe needs to be incorporated into the smectite structure. Such conditions are rarely attained. Received: 25 September 1996 / Accepted: 17 January 1997  相似文献   

17.
The extent of quartz cementation in shallow marine sandstones of the Brora Arenaceous Formation (Oxfordian) is closely related to the occurrence and abundance of Rhaxella perforata sponge spicules. Three cement morphologies are identified, chalcedonic quartz, microquartz and mesoquartz. Chalcedonic quartz forms matrix-supported cements which preserve moulds of Rhaxella spicules. Chalcedonic quartz crystals have inequant development of crystal faces, on average 0·1 μm in diameter, and are the first formed cement and reveal homogeneous dark grey tones on the SEM-CL/BEI. Microquartz forms 5–10 μm diameter crystals, which commonly grow on chalcedonic quartz substrates and show various grey tones under SEM-CL/BEI. Mesoquartz crystals grow in optical continuity with their host grains, have >20 μm a-axial diameter crystals, and exhibit distinctly zoned luminescence. Although no opaline silica is preserved, the quartz cement is interpreted to have formed from an opaline precursor. Detrital quartz has an average δ18O composition of + 12·2‰ and mesoquartz (syntaxial overgrowth) has an average δ18O composition of +20·0‰. Estimates of the δ18O compositions of microquartz and chalcedonic quartz are complicated by the problem of isolating the two textural types; mixtures of the two give consistently higher δ18O compositions than mesoquartz, the higher estimate being +39·2‰. From oxygen isotope data the formation of quartz, microquartz and chalcedonic quartz is interpreted to have taken place between 35 and 71°C in marine derived pore waters. Organic and inorganic maturation data constrain the upper temperature limit to less than 60°C.  相似文献   

18.
Batch and column experiments were conducted to examine the capability of naturally formed hematite and siderite to remove As from drinking water. Results show that both minerals were able to remove As from aqueous solutions, but with different efficiencies. In general, each material removed arsenate much more efficiently than As–DMA (dimethylarsinic acid), with the lowest adsorption efficiency for arsenite. The best removal efficiency for As species was obtained using a hematite, with a grain size range between 0.25 and 0.50 mm. The adsorption capacity for inorganic As(V) reached 202 μg/g. The pH generally had a great impact on the arsenate removal by the Fe minerals studied, while arsenite removal was slightly dependent on the initial pH of between 3 and 10. The presence of phosphate always had a negative effect on arsenate adsorption, due to competitive adsorption between them. A column packed with hematite in the upper half and siderite in the lower half with a grain size range of 0.25–0.5 mm proved to be an efficient reactive filter for the removal of all As species, causing a decrease in As concentration from 500 μg/L (including 200 μg/L As(V) as arsenate, 200 μg/L As(III) as arsenite and 100 μg/L As(V) as DMA) to less than 10 μg/L after 1055 pore volumes of water were filtered at a flow rate of 0.51 mL/min. After 2340 pore volumes passed through the column filter, the total inorganic As in the effluent was less than 5 μg/L. The total As load in the column filter was estimated to be 0.164 mg/g. Results of μ-synchrotron X-ray fluorescence analysis (μ-XRFA) suggest that coatings of fresh Fe(III) oxides, formed on the surface of the siderite grains after two weeks of operation, greatly increased the adsorption capacity of the filling material towards As.  相似文献   

19.
Rare felsic volcanic rocks of dacitic to rhyolitic composition occur in the central part of the Jack Hills metasedimentary belt in the Narryer Terrane of Western Australia, interleaved with clastic sedimentary rocks and amphibolite. Representative samples of the four identified felsic volcanic units reveal a similar complex pattern of zircon age distribution, with all samples containing zircon populations at ∼3.3–3.4, ∼3.0–3.1, ∼2.6 and ∼1.8–1.9 Ga. The ∼3.3–3.4 Ga zircons show well-developed oscillatory zoning in cathodoluminescence (CL) images and are interpreted as inherited igneous zircon derived from granitic precursors, similar to the ∼3.3 Ga trondhjemitic granitoids currently exposed along the northern and southern margins of the belt. The ∼3.0–3.1 Ga zircons also reveal well-developed oscillatory zoning in CL and are most likely derived from granitoid and/or volcanic rocks of this age, as recorded in the Murchison domain to the south and possibly also present in the Narryer Terrane. The ∼2.6 Ga population matches the age of nearby late Archean granitoids intruding the Jack Hills belt and their oscillatory zoning and U–Th chemistry is consistent with their origin from such a source. The youngest discrete group of zircon grains, with ages ranging from ∼1970 to ∼1775 Ma, show strong oscillatory zoning and average Th/U ratios of 0.76, features consistent with an igneous origin. These younger zircons are therefore interpreted as defining the age of crystallisation of the volcanic rocks. These results establish that the Jack Hills metasedimentary belt contains significant post-Archean components. Taken together with similar results obtained from zircon occurring as detrital grains in clastic sedimentary rocks at Jack Hills, these results overturn the generally-accepted view that the belt is entirely Archean in age and that sedimentation was completed around 3.0 Ga ago. Instead, there is a distinct possibility that much of the material currently exposed in the Jack Hills belt formed in the Proterozoic. A further implication of this study is that the metamorphism affecting these rocks also occurred in the Proterozoic and consequently the rocks should not be considered as forming an Archean greenstone or metasedimentary belt. The paucity of zircons >4 Ga in the known Proterozoic sedimentary rocks and their total absence in the felsic volcanic rocks suggests that such ancient source rocks were no longer present in the area.  相似文献   

20.
In soils, silicon released by mineral weathering can be retrieved from soil solution through clay formation, Si adsorption onto secondary oxides and plant uptake, thereby impacting the Si-isotopic signature and Ge/Si ratio of dissolved Si (DSi) exported to rivers. Here we use these proxies to study the contribution of biogenic Si (BSi) in a soil-plant system involving basaltic ash soils differing in weathering degree under intensive banana cropping. δ30Si and Ge/Si ratios were determined in bulk soils (<2 mm), sand (50-2000 μm), silt (2-50 μm), amorphous Si (ASi, 2-50 μm) and clay (<2 μm) fractions: δ30Si by MC-ICP-MS Nu Plasma in medium resolution, operating in dry plasma with Mg doping (δ30Si vs. NBS28 ± 0.12‰ ± 2σSD), Ge/Si computed after determination of Ge and Si concentrations by HR-ICP-MS and ICP-AES, respectively. Components of the ASi fraction were quantified by microscopic counting (phytoliths, diatoms, ashes). Compared to fresh ash (δ30Si = −0.38‰; Ge/Si = 2.21 μmol mol−1), soil clay fractions (<2 μm) were enriched in light Si isotopes and Ge: with increasing weathering degree, δ30Si decreased from −1.19 to −2.37‰ and Ge/Si increased from 4.10 to 5.25 μmol mol−1. Sand and silt fractions displayed δ30Si values close to fresh ash (−0.33‰) or higher due to saharian dust quartz deposition, whose contribution was evaluated by isotopic mass balance calculation. Si-isotopic signatures of bulk soils (<2 mm) were strongly governed by the relative proportions of primary and secondary minerals: the bulk soil Si-isotopic budget could be closed indicating that all the phases involved were identified. Microscopic counting highlighted a surface accumulation of banana phytoliths and a stable phytolith pool from previous forested vegetation. δ30Si and Ge/Si values of clay fractions in poorly developed volcanic soils, isotopically heavier and Ge-depleted in surface horizons, support the occurrence of a DSi source from banana phytolith dissolution, available for Si sequestration in clay-sized secondary minerals (clay minerals formation and Si adsorption onto Fe-oxide). In the soil-plant system, δ30Si and Ge/Si are thus highly relevant to trace weathering and input of DSi from phytoliths in secondary minerals, although not quantifying the net input of BSi to DSi.  相似文献   

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