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1.
Climate change is expected to increase temperatures and lower rainfall in Mediterranean regions; however, there is a great degree of uncertainty as to the amount of change. This limits the prediction capacity of models to quantify impacts on water resources, vegetation productivity and erosion. This work circumvents this problem by analysing the sensitivity of these variables to varying degrees of temperature change (increased by up to 6·4 °C), rainfall (reduced by up to 40%) and atmospheric CO2 concentrations (increased by up to 100%). The SWAT watershed model was applied to 18 large watersheds in two contrasting regions of Portugal, one humid and one semi‐arid; incremental changes to climate variables were simulated using a stochastic weather generator. The main results indicate that water runoff, particularly subsurface runoff, is highly sensitive to these climate change trends (down by 80%). The biomass growth of most species showed a declining trend (wheat down by 40%), due to the negative impacts of increasing temperatures, dampened by higher CO2 concentrations. Mediterranean species, however, showed a positive response to milder degrees of climate change. Changes to erosion depended on the interactions between the decline in surface runoff (driving erosion rates downward) and biomass growth (driving erosion rates upward). For the milder rainfall changes, soil erosion showed a significant increasing trend in wheat fields (up to 150% in the humid watersheds), well above the recovery capacity of the soil. Overall, the results indicate a shift of the humid watersheds to acquire semi‐arid characteristics, such as more irregular river flows and increasingly marginal conditions for agricultural production. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

2.
Connectivity has recently emerged as a key concept for understanding hydrological response to vegetation change in semi‐arid environments, providing an explanatory link between abiotic and biotic, structure and function. Reduced vegetation cover following woody encroachment, generally promotes longer, more connected overland flow pathways, which has the potential to result in an accentuated rainfall‐runoff response and fluxes of both soil erosion and carbon. This paper investigates changing hydrological connectivity as an emergent property of changing ecosystem structure over two contrasting semi‐arid grass to woody vegetation transitions in New Mexico, USA. Vegetation structure is quantified to evaluate if it can be used to explain observed variations in water, sediment and carbon fluxes. Hydrological connectivity is quantified using a flow length metric, combining topographic and vegetation cover data. Results demonstrate that the two woody‐dominated sites have significantly longer mean flowpath lengths (4 · 3 m), than the grass‐dominated sites (2 · 4 m). Mean flowpath lengths illustrate a significant positive relationship with the functional response. The woody‐dominated sites lost more water, soil and carbon than their grassland counterparts. Woody sites erode more, with mean event‐based sediment yields of 1203 g, compared to 295 g from grasslands. In addition, the woody sites lost more organic carbon, with mean event yields of 39 g compared to 5 g from grassland sites. Finally, hydrological connectivity (expressed as mean flowpath length) is discussed as a meaningful measure of the interaction between structure and function and how this manifests under the extreme rainfall that occurs in semi‐arid deserts. In combination with rainfall characteristics, connectivity emerges as a useful tool to explain the impact of vegetation change on water, soil and carbon losses across semi‐arid environments. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

3.
During the last 150 years, land degradation across the semi‐arid grasslands of the south‐western United States has been associated with an increase in runoff and erosion. Concurrent with this increase in runoff and erosion is a loss of nitrogen (N) and phosphorus (P), which are plant‐essential nutrients. This study investigates the runoff‐driven redistribution and loss of dissolved and particulate‐bound N and P that occurs during natural runoff events over a trajectory of degradation, from grassland to degraded shrubland, in central New Mexico. Runoff‐driven nutrient dynamics were monitored at four stages over a transition from grassland to shrubland, for naturally occurring rainfall events over 10 × 30 m bounded runoff plots. Results show that particulate‐bound forms of N and P are responsible for most of N and P lost from the plots due to erosion occurring during runoff events. Results suggest that for high‐magnitude rainfall events, the output of N and P from the plots may greatly exceed the amount input into the plots, particularly over shrub‐dominated plots where erosion rates are higher. As these results only become apparent when monitoring these processes over larger hillslope plots, it is important to recognize that processes of nutrient cycling related to the islands of fertility hypothesis may have previously been overstated when observed only at smaller spatial scales. Thus, the progressive degradation of semi‐arid grassland ecosystems across the south‐western United States and other semi‐arid ecosystems worldwide has the potential to affect N and P cycling significantly through an increase in nutrient redistribution and loss in runoff. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

4.
Preferential flow in soils deserves attention due to its potential role in accelerating the movement of contaminants to groundwater. This study investigates the movement of Cd, Cu, and Pb through preferential flow paths under different applied rainfall intensities. Artificial acid rain (pH of 4.1) containing CdCl2, CuCl2, and Pb(NO3)2 was applied to undisturbed soil and repacked sand columns at low and high intensities, and leachate metals and chloride concentrations were measured. Cd was found in the leachate at both low and high rates in all columns, while the increase in Cu concentrations in the leachate was detected only at the high rate of the undisturbed columns. Pb was retained in both columns. For undisturbed columns, the breakthrough curves of Cd and Cu were similar to those of Cl, showing early initial breakthrough by preferential flow and dependency on rainfall intensities. The Cd concentrations were detected in the leachate from repacked columns for high rate rainfall, implying that even homogeneous soil may not be perfectly able to retain metals and the initially wet condition is more harmful for subsurface contaminant transport. In conclusion, the study demonstrated that, despite its highly sorptive nature, the transport of some metals may be as fast as that of a tracer under preferential flow conditions, and the rainfall intensity is a significant factor for the degree of transport.  相似文献   

5.
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6.
Much attention has been given to the surface controls on the generation and transmission of runoff in semi‐arid areas. However, the surface controls form only one part of the system; hence, it is important to consider the effect that the characteristics of the storm event have on the generation of runoff and the transmission of flow across the slope. The impact of storm characteristics has been investigated using the Connectivity of Runoff Model (CRUM). This is a distributed, dynamic hydrology model that considers the hydrological processes relevant to semi‐arid environments at the temporal scale of a single storm event. The key storm characteristics that have been investigated are the storm duration, rainfall intensity, rainfall variability and temporal structure. This has been achieved through the use of a series of defined storm hydrographs and stochastic rainfall. Results show that the temporal fragmentation of high‐intensity rainfall is important for determining the travel distances of overland flow and, hence, the amount of runoff that leaves the slope as discharge. If the high‐intensity rainfall is fragmented, then the runoff infiltrates a short distance downslope. Longer periods of high‐intensity rainfall allow the runoff to travel further and, hence, become discharge. Therefore, storms with similar amounts of high‐intensity rainfall can produce very different amounts of discharge depending on the storm characteristics. The response of the hydrological system to changes in the rainfall characteristics can be explained using a four‐stage model of the runoff generation process. These stages are: (1) all water infiltrating, (2) the surface depression store filling or emptying without runoff occurring, (3) the generation and transmission of runoff and (4) the transmission of runoff without new runoff being generated. The storm event will move the system between the four stages and the nature of the rainfall required to move between the stages is determined by the surface characteristics. This research shows the importance of the variable‐intensity rainfall when modelling semi‐arid runoff generation. The amount of discharge may be greater or less than the amount that would have been produced if constant rainfall intensity is used in the model. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

7.
Zekai Şen 《水文研究》2007,21(8):1006-1014
Arid and semi‐arid regions expose special hydrological features that are distinctive from humid areas. Unfortunately, humid‐region hydrological empirical formulations are used directly in the arid and semi‐arid regions without care about the basic assumptions. During any storm rainfall in arid regions, rainfall, infiltration and runoff components of the hydrological cycle have impacts on water resources. The basis of the methodology presented in this paper is the ratio of runoff increment to rainfall increment during an infinitesimally small time duration. This is the definition of runoff coefficient for the same infinitesimal time duration. The ratio is obtained through rational, physical and mathematical combination of hydrological thinking and then integrated with the classical infiltration equation for the hydrograph determination. The parameters of the methodology are explained and their empirical estimations are presented. The methodology works for rainfall and runoff from ungauged watersheds where infiltration measurement can be performed. The comparison of the new approach with different classical approaches, such as the rational formula and Soil Conservation Service method, are presented in detail. Its application is performed for two wadis within the Kingdom of Saudi Arabia. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

8.
Concentrations of ten metals were measured in waters and sediments at 14 sites during four sampling periods (1996–1997). These sites include various marine ecosystems that are highly influenced by industry, tourism and river discharges, nine of which are within the Morrocoy National Park. Spatially, metal concentrations in water were homogenous, whereas in sediments their distributions were related to grain size. Maximum concentrations of cadmium (Cd) and mean concentrations of copper (Cu), nickel (Ni), lead (Pb) and zinc (Zn) in water were above the guideline values proposed by NOAA, indicating the potential of these metals for producing chronic effects in marine biota. Sheltered sites showed the highest metal concentrations in sediments; with Cd and Zn above these guidelines. Enrichment factors and geo-accumulation indexes suggested that metals in sediments were largely of natural origin except for Pb, Cd and vanadium (V), which were apparently associated with industrial effluents. A disruption of the spatial distribution of metals after heavy rainfall, when exposed sites reached concentrations as high as those in sheltered sites, showed the influence of nearby rivers. The potential increase of such climatic events could represent additional stress for natural protected areas in the Caribbean.  相似文献   

9.
In order to investigate the pollution levels, sources and ecological risks of arsenic (As) and heavy metals (Cr, Ni, Cu, Zn, Pb and Cd) in inshore sediments of the Yellow River estuary, the surface sediment in areas of inshore coastal waters were sampled in October 2014 as the flow-sediment regulation project (FSRP) was implemented for 13 years. Results showed that the concentrations of As and heavy metals in inshore sediments of the Yellow River estuary were in the order of Zn?>?Cr?>?Cu?>?Ni?>?Pb?>?As?>?Cd. Higher levels of As, Cr, Ni, Cu, Zn and Pb generally occurred in fine-grained sediments of the Yellow River estuary and the southeast region, which was consistent with the spatial distribution of clay. In contrast, higher concentrations of Cd were generally observed in northwest area of the Yellow River estuary and near the Qingshuigou estuary, which showed similarly spatial distribution with that of sand. The sediment quality guidelines (SQGS) and geoaccumulation indices (Igeo) indicated that the inshore sediments were polluted by Cu, Cd, As, Pb and Zn, and, among them, Cd pollution was more serious. Ecological risk indices (E r i ) demonstrated low risks for Cr, Ni, Cu, Zn, Pb and As, and high potential toxicity by Cd. The integrated ecological risk index implied that 6.8% of stations presented moderate risk, 4.5% of stations exhibited disastrous risk, and 88.7% of stations demonstrated considerable risk. Principal component analysis indicated that Ni, Cu, Zn, Pb and As might originate from common pollution sources, while Cr and Cd might share another similar sources. With the continuous implementation of FSRP, As and heavy metal levels in inshore sediments of the Yellow River estuary could be classified as stage I (2002–2010) and stage II (2010–2014). In the stage I, As, Cr, Ni, Cu, Zn and Pb levels fluctuated but decreased significantly, whereas Cd concentrations showed little variation. In the stage II, As and heavy metal levels significantly increased although some little fluctuations occurred. The continuous accumulation of As and heavy metals (especially for Cd) in inshore sediments of the Yellow River estuary would occur again as the FSRP was implemented for 9 years (since 2010). The ecotoxicological risk of Cd, As, Ni and Cu in inshore sediments might be more serious since the accumulation of the four elements would be continuously occurred in future years. Next step, there will be long-term potential consequences for marine organism if effective measures are not taken to control the loadings of metal pollutants into estuary.  相似文献   

10.
Freshwater lakes are one of the most vulnerable ecosystems to environmental contamination. This study was initiated to assess the spatial distribution, fractionation, ecological risk of selected potentially toxic metals (Pb, Zn, Cu, Cr, and Ni) in bottom sediments of the Zarivar lake, the second largest freshwater lake in Iran. The results revealed that Pb, Zn and Cu had the high spatial variability (coefficient of variation >50) across the sampling sites and their maximum concentrations (197.5 for Pb, 198.7 for Zn and 185.6 mg/kg for Cu) were observed in sampling sites from the northern, western and eastern margins of the lake. Cr and Ni with average concentrations of 28.3 and 31.38 mg/kg respectively, exhibited low spatial variability (coefficient of variation <20) and their concentrations did not vary significantly among the sampling sites. Based on the redundancy analysis (RDA), sediment organic matter was strongly correlated with Pb, Zn and Cu while Fe2O3 and Al2O3 showed a positive correlation with Ni and Cr. The calculated average enrichment factor (EF) and geoaccumulation index (Igeo) showed that the contamination level of metals can be arranged in the following order of Pb> Cu > Zn > Cr > Ni. Results from the modified five-step sequential extraction analysis indicated that 40 % of total Pb and Zn were associated with the reducible fraction, 45 % of Cu with the oxidizable fraction and more than 80 % of total Ni and Cr were retrieved from the residual fraction. It was also noticed that Pb, Zn and Cu were more incorporated into the non-residual fractions in the sites with a higher total concentration of these metals, suggesting that both total concentration and fractionation behavior of metals were influenced by their potential sources in the study area. Ecological risk assessment using the potential ecological risk index (PERI) and the modified potential ecological risk index (MPERI) showed that sediments from the eight sampling sites pose a moderate to considerable risk whereas the other sites had low ecological risk level. In comparison to sediment quality guidelines (SQGs), the effects range low (ERL) and probable effect level (PEL) values for Pb, Cu and Zn were exceeded at some sampling sites while Ni and Cr concentrations were found to be below or close to their SQGs values at all the sampling sites. Pb was generally identified as the contaminant of most concern in the study area. Taking into account the results obtained from the fractionation study and the source contribution estimate, it can be inferred that the Pb, Zn and Cu with the average contribution of 79, 54 and 64 % respectively, were mainly derived from anthropogenic sources whereas Ni and Cr with the estimated contribution of 80 and 89 % were predominately from the lithogenic source.  相似文献   

11.
Sediment from twelve stations was sampled from the Tupilipalem Coast, southeast coast of India, and the presence of a set of heavy metals was established including iron (Fe), manganese (Mn), chromium (Cr), copper (Cu), nickel (Ni), lead (Pb), zinc (Zn) and cadmium (Cd). The heavy metals were assessed by factor analysis, the results of which showed positive and/or negative correlations among Fe, Mn, Cr, Cu, Ni, Pb, Zn, and Cd. Factor analysis also indicated that heavy metals in the sediments of the study area have different natural and anthropogenic sources. Similarly, a sediment pollution assessment was done using the Geoaccumulation Index (Igeo), Enrichment Factor (EF), and Pollution Load Index (PLI). The Geoaccumulation Index indicated that the surface sediment of the Tupilipalem Coast was extremely contaminated with Fe, Mn, Cr, Cu, Ni, Pb, and Zn. The calculation of enrichment factors showed a significant enrichment with respect to Pb, Zn, and Cd and a moderate enrichment with Cr, Cu, and Ni. The falling trend of average contents’ enrichment factors is Cd> Pb> Zn> Cu> Cr> Ni> Mn> Fe. The PLI values of the Cd show higher (>1) values due to the influence of distinct external sources like agricultural runoff, industrial activities, and other anthropogenic inputs. Ninety two percent of heavy metals under study showed the highest concentrations at station TP-5 where the Buckingham Canal and other agricultural and aquacultural effluents connect with the Bay of Bengal. This location is the second inlet which is periodically closed and it seemed that these parts of the study area are heavily affected by anthropogenic pollution.  相似文献   

12.
Data collected in 4 years of field observations were used in conjunction with continuous simulation models to study, at the small‐basin scale, the water balance of a closed catchment‐lake system in a semi‐arid Mediterranean environment. The open water evaporation was computed with the Penman equation, using the data set collected in the middle of the lake. The surface runoff was partly measured at the main tributary and partly simulated using a distributed, catchment, hydrological model, calibrated with the observed discharge. The simplified structure of the developed modelling mainly concerns soil moisture dynamics and bedrock hydraulics, whereas the flow components are physically based. The calibration produced high efficiency coefficients and showed that surface runoff is greatly affected by soil water percolation into fractured bedrock. The bedrock reduces the storm‐flow peaks and the interflow and has important multi‐year effects on the annual runoff coefficients. The net subsurface outflow from the lake was calculated as the residual of the lake water balance. It was almost constant in the dry seasons and increased in the wet seasons, because of the moistening of the unsaturated soil. During the years of observation, rainfall 30% higher than average caused abundant runoff and a continuous rise in the lake water levels. The analysis allows to predict that, in years with lower than the average rainfall, runoff will be drastically reduced and will not be able to compensate for negative balance between precipitation and lake evaporation. Such highly unsteady situations, with great fluctuations in lake levels, are typical of closed catchment‐lake systems in the semi‐arid Mediterranean environment. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

13.
The values for the partition coefficient (Kd) were calculated for Ca, Mg, Cd, Cr, Cu, Fe, Mn, Pb, Ni, and Zn at 19 sites in the Capivara hydroelectric reservoir in Brazil. It was found that the relative values of Kd follow the order: Cr > Mn > Fe > Cu > Zn > Ni > Pb > Ca > Cd, differing from the values reported for Kd in aquatic systems in the northern hemisphere. A hierarchical cluster analysis and linear correlations showed that Cr is strongly associated with Fe and Cu, and that Cd is the only metal found in complexation with organic matter, explaining its higher solubility.  相似文献   

14.
Abstract

The study describes an experimental site installed in an arid region for the study of spatial variations in rainfall, runoff and erosion processes along slopes. Data obtained indicate that despite the frequent development of universal overland flow, due to excess rainfall, runoff generated at the upper part of slopes, 60–70m in length, has little or no chance of reaching the slope base during most rainstorms and thus does not contribute to channel flow. The spatial distribution of areas contributing to channel storm flow was found to be similar to that observed in the humid regions. In both cases the contributing area is limited to a belt extending at the base of the slope area. An analysis of the factors affecting the spatial pattern of runoff development in the arid zone is presented. Suspended sediment data collected indicate that no correlation exists between observed sediment concentrations and runoff rates.  相似文献   

15.
The effects of depuration, size and sex on the concentrations of Mn, Ni, Cu, Zn and Cd were determined for gonadal and somatic tissues of Mytilus edulis from Yaquina Bay, Oregon. After depuration, Mn levels decreased significantly in both tissues while Cu and Ni concentrations increased in somatic tissues. The latter finding may have been associated with a stress response manifested by the appearance of new byssal threads and attachment to the vessel. Larger, and presumably older, mussels contained higher concentrations of Ni, Cu and Cd in their somatic tissues while smaller animals had greater somatic levels of Mn. There were no significant differences in gonad concentrations between the two size groups. Manganese and Zn levels were greater in the gonads of female mussels and Cd was more concentrated in the somatic tissues of females.  相似文献   

16.
Surface sediment samples were collected at 21 offshore sites in western Xiamen Bay, Southeast China.Total concentrations of Li, V, Cr, Co, Ni, Cu, Zn, Sr, Mn,Pb, Ba, Fe, and Ti were determined by inductively coupled plasma-optical emission spectrometry; Hg was determined by atomic fluorescence spectrometry. A modified BCR sequential extraction procedure was used to extract fractions of the above elements. Concentrations of Pb, Cr, and Hg at most sites met the primary standard criteria of Marine Sediment Quality except site S12 for Pb and S7 for Cr, while concentrations of Zn at 17 sites and Cu at seven sites exceeded the criteria. The mean concentration of Hg was three times higher than the background, with a possible source being the Jiulong River. Fe, Ti, Ba, Co, V, and Li dominated the residual phase, mainly from terrestrial input.Ni, Cr, Pb, and Hg in the non-residual phase varied largely between sites. Sr, Mn, Cu, and Zn were mainly in the nonresidual fraction. Most sites showed considerable ecological risk; exceptions were site S7(very high) and sites S10,S11, and S14(moderate). Cu showed moderate-to-high pollution and Pb exhibited no-to-low pollution, while other metals had a non-pollution status according to their ratios of secondary phase to primary phase(RSP). Results of two assessment methods showed moderate pollution and a veryhigh ecological risk for Cu, Zn, Ni, and Cr at site S7, which might be due to the local sewage treatment plant.  相似文献   

17.
Levels of heavy metals along the Libyan coastline   总被引：1，自引：0，他引：1  
A coastal survey off the east part of the Libyan coastline which has no river inputs was initiated to measure the existing level and distribution of selected heavy metals (Cu, Zn, Cd, Ni, and Mn) in surface sediments along Benghazi Bay. In order to place the finding of this survey in proper perspective and for practical terms a Pollution Load Index (PLI) was used. The results establish that of the sites examined only the harbour site exhibited relatively high levels particularly in the cases of cadmium and copper indicating a detectable anthropogenic input. The range of concentrations were 1.03%–1.96% μg g−1 (dry wt) for organic content and 64.7%–93% for calcium carbonate while the range of heavy metals concentrations (μg g−1 dry wt) were 8.7–42 for Cu, 2.3–27.3 for Zn, 5.7–19 for Ni, 37–76.7 for Mn, and below the detection limit-1.73 for Cd. A PLI score of 2.93 was obtained at the harbour site and a range of 6.11–7.63 for the other sites. The PLI score for the control site was 9.51 and the score for the overall studied area was 7.51 indicating a very clean environment. The index would be, with some modification, a step in the right direction from the management point of view in Libya due to the absence of environmental expertise.  相似文献   

18.
Post‐wildfire runoff and erosion are major concerns in fire‐prone landscapes around the world, but these hydro‐geomorphic responses have been found to be highly variable and difficult to predict. Some variations have been observed to be associated with landscape aridity, which in turn can influence soil hydraulic properties. However, to date there has been no attempt to systematically evaluate the apparent relations between aridity and post‐wildfire runoff. In this study, five sites in a wildfire burnt area were instrumented with rainfall‐runoff plots across an aridity index (AI) gradient. Surface runoff and effective rainfall were measured over 10 months to allow investigation of short‐ (peak runoff) and longer‐term (runoff ratio) runoff characteristics over the recovery period. The results show a systematic and strong relation between aridity and post‐wildfire runoff. The average runoff ratio at the driest AI site (33.6%) was two orders of magnitude higher than at the wettest AI site (0.3%). Peak runoff also increased with AI, with up to a thousand‐fold difference observed during one event between the driest and wettest sites. The relation between AI, peak 15‐min runoff (Q15) and peak 15‐min rainfall intensity (I15) (both in mm h‐1) could be quantified by the equation: Q15 = 0.1086I15 × AI 2.691 (0.65<AI<1.80, 0<I15<45) (adjusted r2 = 0.84). The runoff ratios remained higher at drier AI sites (AI 1.24 and 1.80) throughout the monitoring period, suggesting higher AI also lengthens the window of disturbance after wildfire. The strong quantifiable link which this study has determined between AI and post‐wildfire surface runoff could greatly improve our capacity to predict the magnitude and location of hydro‐geomorphic processes such as flash floods and debris flows following wildfire, and may help explain aridity‐related patterns of soil properties in complex upland landscapes. Copyright © 2018 John Wiley & Sons, Ltd.  相似文献   

19.
In semi‐arid environments, the characteristics of the land surface determine how rainfall is transformed into surface runoff and influences how this runoff moves from the hillslopes into river channels. Whether or not water reaches the river channel is determined by the hydrological connectivity. This paper uses a numerical experiment‐based approach to systematically assess the effects of slope length, gradient, flow path convergence, infiltration rates and vegetation patterns on the generation and connectivity of runoff. The experiments were performed with the Connectivity of Runoff Model, 2D version distributed, physically based, hydrological model. The experiments presented are set within a semi‐arid environment, characteristic of south‐eastern Spain, which is subject to low frequency high rainfall intensity storm events. As a result, the dominant hydrological processes are infiltration excess runoff generation and surface flow dynamics. The results from the modelling experiments demonstrate that three surface factors are important in determining the form of the discharge hydrograph: the slope length, the slope gradient and the infiltration characteristics at the hillslope‐channel connection. These factors are all related to the time required for generated runoff to reach an efficient flow channel, because once in this channel, the transmission losses significantly decrease. Because these factors are distributed across the landscape, they have a fundamental role in controlling the landscape hydrological response to storm events. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

20.
Concentrations of dissolved metals (Cd, Cu, Ni, Mn and Zn) were determined for summer and winter, under low-flow conditions in Port Jackson, a microtidal, well-mixed estuary in south-east Australia. Mean concentrations of Cd (0.04+/-0.02 microg/l), Ni (0.86+/-0.40 microg/l), Mn (20.0+/-25 microg/l) and Zn (6.47+/-2.0 microg/l) were below water quality guidelines. Concentrations of Cu (1.68+/-0.37 microg/l), however, slightly exceeded recommended values. Dissolved Ni and Mn behaved mostly conservatively, whereas Cd, Cu and Zn showed mid-estuarine maxima. Peaks in Cd, Cu and Zn concentrations were located in the upper estuary, independent of the salinity and suspended particulate matter loading, and were consistent with anthropogenic inputs of metals in the estuary. Concentrations of dissolved Cu were highest in summer, whereas concentrations of Cd, Ni and Mn were significantly lower in summer than winter (P< or =0.05). The increase in temperature and biological activity during summer explained the seasonal variation. The sequence of log K(d) values (20-30 salinity) was Mn>Zn>Cu>Ni. These results give unique information concerning the contemporaneous distribution of dissolved trace metals in the Port Jackson estuary and they provide a data set against which the long-term contamination may be assessed.  相似文献   

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