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1.
ABSTRACT
Large septarian concretions from the Kimmeridge Clay, up to 1.2 m in diameter, have centres comprising anhedral calcite microspar passing into margins of radiating fibrous calcite microspar, with a pyrite-rich zone at the transition. Septarian veins formed and were lined with brown calcite synchronously with fibrous matrix growth, with white calcite precipitated in septarian cavities after concretion growth ceased. Septarian veins, filled only with white calcite, formed later, at the same time as the outermost calcite microspar crystals were enlarged.
The concretions were buried in the Late Jurassic to about 130 m, and in the Late Cretaceous to about 550 m, with uplift between. Oxygen isotopes show that the concretion grew throughout the first burial, with septarian veins forming from about 30 m depth onwards. Later septarian veins formed between about 200 and 500 m during the second burial.
Carbon isotopes show that the compact inner matrix grew in the sulphate reduction zone, the end of which is marked by the pyrite-enriched zone. Dissolving shells, and possibly minor methanogenic carbonate, slowly diluted sulphate reduction-zone carbonate during deeper burial. During early concretion growth, Mg and Sr were depleted in the pore water. During later stages of the first burial, Mg, Sr, Mn and Fe all increased, especially after concretion growth ceased. During the second burial, Fe, Mn and Mg decreased as calcite precipitated, implying relatively closed systems for these elements.
Synchronous formation of septarian fractures and fibrous calcite matrix shows that the Kimmeridge Clay became overpressured during the later stages of both burials. 相似文献
Large septarian concretions from the Kimmeridge Clay, up to 1.2 m in diameter, have centres comprising anhedral calcite microspar passing into margins of radiating fibrous calcite microspar, with a pyrite-rich zone at the transition. Septarian veins formed and were lined with brown calcite synchronously with fibrous matrix growth, with white calcite precipitated in septarian cavities after concretion growth ceased. Septarian veins, filled only with white calcite, formed later, at the same time as the outermost calcite microspar crystals were enlarged.
The concretions were buried in the Late Jurassic to about 130 m, and in the Late Cretaceous to about 550 m, with uplift between. Oxygen isotopes show that the concretion grew throughout the first burial, with septarian veins forming from about 30 m depth onwards. Later septarian veins formed between about 200 and 500 m during the second burial.
Carbon isotopes show that the compact inner matrix grew in the sulphate reduction zone, the end of which is marked by the pyrite-enriched zone. Dissolving shells, and possibly minor methanogenic carbonate, slowly diluted sulphate reduction-zone carbonate during deeper burial. During early concretion growth, Mg and Sr were depleted in the pore water. During later stages of the first burial, Mg, Sr, Mn and Fe all increased, especially after concretion growth ceased. During the second burial, Fe, Mn and Mg decreased as calcite precipitated, implying relatively closed systems for these elements.
Synchronous formation of septarian fractures and fibrous calcite matrix shows that the Kimmeridge Clay became overpressured during the later stages of both burials. 相似文献
2.
Jurassic septarian concretions from NW Scotland record interdependent bacterial, physical and chemical processes of marine mudrock diagenesis 总被引：3，自引：0，他引：3
JAMES P. HENDRY MICHAEL J. PEARSON† NIGEL H. TREWIN‡ ANTHONY E. FALLICK§ 《Sedimentology》2006,53(3):537-565
Septarian concretions in the Staffin Shales Formation (Kimmeridgian, Isle of Skye) allow controls on concretion rheology and septarian cracking to be investigated. Stratabound concretions consist of anhedral ferroan calcite microspar enclosing clay and minor pyrite. Intergranular volumes range from 77% to 88%, and calcite δ13C and δ18O values in most concretion bodies range from ?10·0‰ to ?17·3‰ and +0·3‰ to ?0·6‰ respectively, consistent with rapid and pervasive cementation in marine pore fluids. Septarian rupture occurred during incipient cementation, with a sediment volume reduction of up to 43%. Crack‐lining brown fibrous calcite records pore fluid re‐oxygenation during a depositional hiatus, followed by increasing Fe content and δ13C related to bacterial methanogenesis. Brown colouration results from an included gel‐like polar organic fraction that probably represents bacterially degraded biomass. A new hypothesis for concretion growth and septarian cracking argues that quasi‐rigid ‘proto‐concretions’ formed via binding of flocculated clays by bacterial extracellular polysaccharide substances (EPS). This provided rheological and chemical conditions for tensional failure, subcritical crack growth, volume contraction, calcite nucleation, and incorporation of degraded products into crack‐lining cements. Bacterial decay of EPS and syneresis of host muds provided internal stresses to initiate rupture at shallow burial. Development of septarian (shrinkage) cracks in muds is envisaged to require pervasive in situ bacterial colonization, and to depend on rates of carbonate precipitation versus EPS degradation and syneresis. Subsequent modification of septarian concretions included envelopment by siderite and calcite microspar, hydraulic fracturing associated with Cretaceous shallow burial or Palaeogene uplift; and cementation by strongly ferroan, yellow sparry calcite that records meteoric water invasion of the host mudrocks. An abundance of fatty acids in these spars indicates aqueous transport of organic breakdown products, and δ13C data suggest a predominantly methanogenic bicarbonate source. However, the wide δ18O range for petrographically identical cement (?1·3‰ to ?15·6‰) is difficult to explain. 相似文献
3.
Carbonate concretions, lenses and bands in the Pleistocene, Palaeogene and Upper Triassic coalfields of Japan consist of various carbonate minerals with varied chemical compositions. Authigenic carbonates in freshwater sediments are siderite > calcite > ankerite > dolomite >> ferroan magnesite; in brackish water to marine sediments in the coal measures, calcite > dolomite > ankerite > siderite >> ferroan magnesite; and in the overlying marine deposits, calcite > dolomite >> siderite. Most carbonates were formed progressively during burial within a range of depths between the sediment-water interface and approximately 3 km. The mineral species and the chemical composition of the carbonates are controlled primarily by the initial sedimentary facies of the host sediments and secondarily by the diagenetic evolution of pore water during burial. Based on the regular sequence and burial depth of precipitation of authigenic carbonates in a specific sedimentary facies, three diagenetic stages of carbonates are proposed. Carbonates formed during Stage I (< 500 m) strongly reflect the initial sedimentary facies, e.g. low Ca-Mg siderite in freshwater sediments which are initially rich in iron derived from lateritic soil on the nearby landmass, and Mg calcite and dolomite in brackish-marine sediments whose pore waters abound in Ca2+ and Mg2+ originating in seawater and calcareous shells. Carbonates formed during Stage II (500–2000 m) include high Ca-Mg siderite, ankerite, Fe dolomite and Fe–Mg calcite in freshwater sediments. The assemblage of Stage II carbonates in brackish-marine sediments in the coal measures is similar to that in freshwater sediments. This suggests similar diagenetic environments owing to an effective migration and mixing of pore water due to the compaction of host sediments. Carbonates formed during Stage III (> 2000 m) are Fe calcite and extremely high Ca-Mg siderite; the latter is exclusively in marine mudstones. The supply of Ca is partly from the alteration of silicates in the sediments at elevated burial temperatures. After uplift, calcite with low Mg content precipitates from percolating groundwater and fills extensional cracks. 相似文献
4.
A study of septarian concretions from late Cretaceous shale sequences of Texas and northern Mexico reveals complex burial-exhumation histories. First generation concretions and pre-fossilized moulds formed in silty clays before significant compaction occurred. Syneresis cracks developed and were filled by length slow fibrous calcite with a decrease in iron content toward the centre of each vein; in some cases this was succeeded by growth of equant or bladed calcite. Subsequent erosion of enclosing sediment caused collapse and break up of concretions, leaving fragments and some unbroken concretions exposed to encrustation and boring on the sea floor. These were subsequently buried and enclosed in a second generation of concretions, which also developed syneresis cracks. The calcite that filled these latter cracks was generally bladed (sometimes followed by equant calcite) and contains more iron toward the centre of the vein. Differences between the calcite filling first and second generation septarian veins indicates changing diagenetic regimes during burial in the marine environment, without a major shift in diagenetic conditions, such as the introduction of meteoric waters. These conclusions have significant implications to cementation in ancient limestones, which show textural and chemical sequences similar to those present in the septarian concretions described. 相似文献
5.
A. B. Kuznetsov I. M. Gorokhov V. A. Melezhik N. N. Mel’nikov G. V. Konstantinova T. L. Turchenko 《Lithology and Mineral Resources》2012,47(4):319-333
The middle part of the volcanosedimentary Zaonega Formation of the Ludikovian Suprahorizon (approximately 2.0 Ga) includes large carbonates concretions and lenses in shungite layers. Carbonate lenses and concretions are primarily elongated and flattened, and their thickness varies from tens of centimeters to a few meters. Some lenses retain relicts of lamination. Concretions are composed of calcite or dolomite. They contain abundant organic matter, as well as mica, talc, chlorite, quartz, and pyrite crystals. The calcite concretions contain some dolomite admixture (Mg/Ca = 0.011?0.045) and differ from sedimentary limestones by a low Fe/Mn value (0.3–2.1). The Sr content is as much as 385–505 μg/g in most samples and is low (86 μg/g) only in one sample. The Rb-Sr systematics of carbonate concretions was studied with the stepwise dissolution procedure, which included processing with the ammonium acetate solution (AMA fraction) to partially remove the secondary carbonate material, with dissolution of the residue in acetic acid (ACA fraction). In individual calcite samples, discrepancy between the measured 87Sr/86Sr values in the AMA and ACA calcite fractions shows a variation range of 0.0008–0.0033. The initial 87Sr/86Sr ratio in the ACA fractions of the studied samples varies from 0.7053 to 0.7162. The ratio shows a positive correlation with Mg/Ca and the proportion of siliciclastic admixture and negative correlation with the Mn content. The concretions were formed when the sediments subsided, probably, during the transition from a zone with “mild” reductive conditions to zones with active sulfate reduction and methanogenesis. In the sulfate reduction zone, where most pyrite-bearing concretions were formed, the sediment was not geochemically exchaged with the bottom water and was evolved into a closed or semiclosed system. Processes of diagenesis in this zone promoted the release of the radiogenic 87Sr from the associated siliciclastic minerals, resulting in growth of the initial 87Sr/86Sr in concretions up to 0.7108–0.7162. Some calcite concretions, which lacked pyrite (or contained its minimal amount) were likely formed in a thin surficial sediment layer located above the sulfate reduction zone. Therefore, they precipitated Sr in isotope equilibrium with Sr of the bottom water. However, large concretions and carbonate lenses with an insignificant siliciclastic admixture could retain the signature of early diagenesis or even sedimentation. The initial 87Sr/86Sr ratio in one of such samples with the siliciclastic admixture of 6.2% makes it possible to estimate the maximal value of this ratio (0.7053) in the Ludikovian paleobasin. 相似文献
6.
The septarian carbonate concretions from the Boom Clay (Belgium) consist mainly of authigenic minerals such as micrite ( 70% bulk volume) and pyrite framboids ( 3%). These mineral phases occur between detrital grains and fossils. The septarian cracks are lined with calcite, which is sometimes covered with pyrite. The preservation of delicate sedimentological features in the concretion matrix (hardly compacted faecal pellets, burrows and uncrushed shells) points to an early origin of the concretions. Systematic geochemical variations from concretion centre to edge suggest that growth continued during shallow burial. The13C values (–17.5 to –20.5) of the concretionary carbonate show that bacterial sulphate-reduction processes were dominant. Sulphate-reduction-derived HCO3- was diluted by marine-related HCO3-, derived from dissolved bioclasts. A slight enrichment in 13C during growth is caused by the decreasing influence of sulphate reduction because of the progressive closure of the diagenetic system due to shallow-burial compaction. The 18O values (–0.5 to +1.0) of the concretionary carbonate point to a marine origin. The slightly 18O-depleted signature with respect to time-equivalent marine-derived carbonate relates to the incorporation of an 18O-depleted component, originating from sulphate and organic matter. The slight decrease in 18O during growth relates to an increasing influence of this component and to a decreasing influence of seawater-derived oxygen during early diagenesis. 相似文献
7.
Three silicified limestone horizons of D1 age from the Visean of the Isle of Man contain calcitic concretions with peripheral silica crusts, occasionally surrounded by a further calcitic layer. Components of the original sediment include carbonate skeletons, carbonaceous grains, sponge spicules and muscovite. Diagenetic products include calcite, dolomite, pyrite, sphalerite, clays, feldspar and quartz. The concretions are composed of neomorphic calcite. The time of recrystallization and the identity of the neomorphic precurosor are both unknown. Displacive, fibrous calcite is chemically similar to neomorphic calcite and both are of early diagenetic age. Granular and rhombic ferroan calcites are of late diagenetic age and were precipitated from pore-waters with Sr/Ca, Mg/Ca and Fe/Ca ratios unlike those of seawater. The difference between early silicification which produced silica crusts and later diffuse silicification of the host sediment is related to a change in sediment transmissivity between the two silicification periods. A four-fold scheme of concretionary growth is proposed. The supply of silica is from sponge spicules and that of carbonate from seawater via porewater. The distribution of organic matter, either as sporadic large carcasses or as small carcasses concentrated in particular horizons, is believed to be vital for carbonate precipitation and controls the distribution of concretions. Awareness of the multiplicity of diagenetic changes is essential in interpretation of early porewater systems and in the origin of products which are often metastable and destined to subsequent changes. No single model is an explanation for all types of concretionary growth. 相似文献
8.
Reworked early diagenetic concretions and the bioerosional origin of a regional discontinuity within British Jurassic marine mudstones 总被引：1，自引：0，他引：1
The Coinstone is a well known hiatus-concretion level in the Lower Lias (Lower Jurassic, Upper Sinemurian) of Dorset, southern England. It has long been recognized as a layer of bored and encrusted, early diagenetic, clay-hosted septarian concretions coincident with a biostratigraphic gap of three ammonite subzones. Several different types of concretion of variable complexity can be distinguished, of which two, probably derived from slightly different stratigraphic levels, have been juxtaposed by condensation at the erosion surface. Diagenetic and biological processes occurring before, during and after exhumation on the Jurassic sea-floor can be recognized. The relative timing of these events can be distinguished, suggesting that initial concretion consolidation, the first generation of septarian cracking, and the precipitation of the first generation of crack-lining calcite preceded exhumation. These, therefore, probably took place at an early stage, at shallow burial depths within the accumulating sediment pile. The early calcite is brown, UV-fluorescent and inclusion-rich, and is similar to the first calcite generations seen in many other clay-hosted septarian concretions. A generally early diagnetic origin of this material is thus inferred. Observations on crack textures and geometries and the interactions of the post-exhumation fauna of encrusters, borers and burrowers lend support to previous suggestions that initial cracking in some septarian concretions took place in a stiff rather than a fully rigid concretion body, possibly given coherence by initial growth of some organic substance that was only later replaced by the calcite cements seen in most such concretions today. The burrowing activities of a benthic fauna in muds cause resuspension of sediment and facilitate erosion, even in the absence of high energy physical processes. Regional stratigraphic gaps may be formed as a consequence of sea level rises or falls, or as a response to sediment supply reduction independent of sea level change. Such major episodes of biologically mediated erosion in mudstone sequences may be of more general importance than has hitherto been recognized. 相似文献
9.
Carbonate concretions formed in bathyal and deeper settings have been studied less frequently than those formed in shallow‐marine deposits. Similarly, concretions affected by catagenetic conditions have rarely been reported. Calcite concretions in deep‐marine mudstones and greywackes of the Bardo Unit (Sudetes Mountains, Poland) formed during early diagenesis and were buried to significant depths. Petrographic and geochemical (elemental and stable C and O isotopic) analyses document their formation close to the sediment–water interface, prior to mechanical compaction within the sulphate reduction zone and their later burial below the oil window. Although the concretions were fully formed during early diagenesis, the effects of increased temperature and interaction with late‐diagenetic interstitial fluids can be discerned. During maximum burial, the concretions underwent thorough recrystallization that caused alteration of fabric and elemental and O isotope composition. The initial finely crystalline cement was replaced by more coarsely crystalline, sheaf‐like, poikilotopic calcite in the concretions. These large calcite crystals engulf and partially replace unstable detrital constituents. The extremely low δ18O values (down to ?21·2‰ Vienna Pee Dee Belemnite) in the concretions are the result of the increased temperature in combination with alteration of volcanic glass, both causing a significant 18O‐depletion of bicarbonate dissolved in the interstitial fluids. Recrystallization led to uniform O isotope ratios in the concretions, but did not affect the C isotope signature. The δ13C values of the late‐diagenetic cements precipitated in the greywacke and in cracks cutting through concretions imply crystallization in the catagenetic zone and decarboxylation as a source of the bicarbonate. These late‐diagenetic processes took place in a supposedly overpressured setting, as suggested by clastic dykes and hydrofractures that cut through both concretions and host rock. All of these features show how the effects of early and late diagenesis can be distinguished in such rocks. 相似文献
10.
S. Anne Reeckmann 《Sedimentary Geology》1988,60(1-4):209-219
Temperate shelf carbonates form in cool marine waters and have skeletal and mineralogical compositions which are different from their tropical counterparts. They commonly lack non-skeletal grains and are often composed of low- and high-magnesium calcite with subordinate aragonite. Many of the aragonitic components found in tropical carbonates, such as corals, ooids, blue-green algae and lime mud, are absent.
Temperate shelf carbonates undergo diagenesis in marine waters with lower carbonate saturation than do tropical carbonates, and are exposed to cool climates with moderate to low rainfall. Marine cementation is rare because of low carbonate saturations in the surrounding waters. However, aragonite and high-magnesium calcite cements have been reported forming under specialized conditions associated with biogenic precipitation, submarine methane and sulphate-reducing bacteria, and more commonly in the intertidal environment where evaporation has increased carbonate concentrations.
In Pleistocene and Tertiary temperate shelf carbonates from southeastern Australia, evidence of marine diagenesis is rare to absent. Diagenetic stabilization of aragonite and high-magnesium calcite has taken from 80,000 y to 1 My, or longer, during subaerial exposure. This is slower than rates reported from tropical climates. A general lack of aragonite in some facies within these temperate carbonates leads to a lack of secondary porosity and only sparse low-magnesium calcite cement, even after prolonged fresh-water diagenesis. However, with lengthy exposure and under the right climatic conditions, karstic solution and calcrete precipitation can occur.
In sequences containing siliciclastic clays, pyrite and glauconite, abundant iron is present in interstitial waters leading to the precipitation of ferroan calcite cements in the phreatic and shallow burial environments, and to the substitution of iron for magnesium in stabilizing high-magnesium calcite skeletal material.
A unique void-filling, micritic internal sediment occurs in discrete layers in many of the Tertiary temperate shelf carbonate sequences in southeastern Australia. This internal sediment is localized as a pore-filling material above permeability barriers such as fine-grained sediments or volcanics, and above paleo-water tables which formed during periods of subaerial exposure. It is a feature of the vadose zone and lithifies to form a dense micritic low-magnesium calcite cement with characteristic pink/brown coloration, often associated with erosion surfaces and nodule beds.
Dolomite is uncommon in the southeastern Australian temperate shelf carbonates. It forms associated with preferential fluid pathways or mixing zones. Ferroan dolomite forms in siliciclastic clay-rich carbonates in the shallow burial environment. The ubiquitous fine, evaporite-related dolomite so common in tropical carbonates is absent. 相似文献
11.
MARK WILKINSON 《Sedimentology》1991,38(5):899-912
The sandbodies of the Bearreraig Sandstone Formation (Inner Hebrides, UK) are cemented by two generations of calcite. The first generation, an inhomogeneous ferroan calcite (0.05?3.28 mol% FeCo3) formed during sulphate reduction (δ13C =?24 to ?32%o PDB) in marine porewaters (δ18O of cement from ?1 to ?4%o PDB) at very shallow burial depths (a few centimetres). These cements are rare but form millimetre-scale clusters of crystals which acted as nuclei to the later, concretionary cements. The second generation of cements are more homogeneous ferroan calcites (mean 1?58% mol% FeCo3) which evolve to progressively higher Fe/Mg ratios. They are sourced by shell dissolution (δ13C of cement from +1 to ?3%o PDB) into meteoric (δ18O of cement from ?6 to ?10%o PDB) or mixed marine meteoric waters (δ18O of cement from ?4 to ?6%o SMOW). These were introduced into the formation either during Bathonian times as a freshwater lens, or, subsequent to partial inversion, by confined aquifer flow. Corroded feldspars within the concretions suggest that an interval of at least 8 Ma separated the deposition of the sediments from the onset of concretion growth. Abundant concretions are preferentially developed at certain horizons within the sandbodies, where the early generation of ferroan calcite cements provided nuclei. The latter formed close to the sediment-water interface, the concentration of cement within the sediment being related to sedimentation rate. The relatively high concentrations of the first generation of cement, upon which the concretionary horizons are nucleated, formed during periods of minimal sedimentation. 相似文献
12.
Peter J. Davies 《Australian Journal of Earth Sciences》2013,60(3):279-292
Many fabrics in Corallian (Upper Jurassic) carbonates in England, France and Switzerland are bigenetic, forming by solution/precipitation and recrystallization processes. Early precipitated cements are non‐ferroan, whereas those formed later are decidedly ferroan. Mossbauer spectroscopy has shown that the iron in the carbonates is largely divalent, substituting for calcium in the calcite lattice. The cements may be subdivided into those forming in an oxidizing environment, and those forming in a reducing environment. Fabric evidence indicates that a solution period separates the two cement phases. The diagenetic history is linked with the sedimentation pattern. Thus, under progressive build up of sediments into shallow‐water or supratidal conditions, the first‐phase cement probably precipitated from non‐marine, partially oxygenated vadose water. Subsequent subsidence and sedimentation resulted in the depression of partially cemented sediments into zones within the sedimentary pile conducive first to pyrite precipitation, and then to ferroan calcite precipitation. Fabrics can therefore be used to interpret the diagenetic environment of regressive sedimentary associations. 相似文献
13.
James P. Hendry Mark Wilkinson Anthony E. Fallick & Nigel H. Trewin 《Sedimentology》2000,47(3):631-644
Unusual textural and chemical characteristics of disseminated dolomite in Upper Jurassic shelf sediments of the North Sea have provided the basis for a proposed new interpretation of early diagenetic dolomite authigenesis in highly bioturbated marine sandstones. The dolomite is present throughout the Franklin Sandstone Formation of the Franklin and Elgin Fields as discrete, non‐ferroan, generally unzoned, subhedral to highly anhedral ‘jigsaw piece’ crystals. These are of a similar size to the detrital silicate grains and typically account for ≈5% of the rock volume. The dolomite crystals are never seen to form polycrystalline aggregates or concretions, or ever to envelop the adjacent silicate grains. They are uniformly dispersed throughout the sandstones, irrespective of detrital grain size or clay content. Dolomite authigenesis predated all the other significant diagenetic events visible in thin section. The dolomite is overgrown by late diagenetic ankerite, and bulk samples display stable isotope compositions that lie on a mixing trend between these components. Extrapolation of this trend suggests that the dolomite has near‐marine δ18O values and low, positive δ13C values. The unusual textural and chemical characteristics of this dolomite can all be reconciled if it formed in the near‐surface zone of active bioturbation. Sea water provided a plentiful reservoir of Mg and a pore fluid of regionally consistent δ18O. Labile bioclastic debris (e.g. aragonite, Mg‐calcite) supplied isotopically positive carbon to the pore fluids during shallow‐burial dissolution. Such dissolution took place in response to the ambient ‘calcite sea’ conditions, but may have been catalysed by organic matter oxidation reactions. Bioturbation not only ensured that the dissolving carbonate was dispersed throughout the sandstones, but also prohibited coalescence of the dolomite crystals and consequent cementation of the grain framework. Continued exchange of Mg2+ and Ca2+ with the sea‐water reservoir maintained a sufficient Mg/Ca ratio for dolomite (rather than calcite) to form. Irregular crystal shapes resulted from dissolution, of both the dolomite and the enclosed fine calcitic shell debris, before ankerite precipitation during deep‐burial diagenesis. 相似文献
14.
A.E.KELEPERTSIS E.KONTIS 《中国地球化学学报》1997,16(1):8-19
The mineralogy and geochemistry data are presented for thirty-seven shales,four concretions,two carbonate sediments and seven lignites from the Marathousa coal field of the Megalopolis Basin in Greece.The argillaceous rocks consist of chlorite,illite,kaolinte,albite,quartz.opal-A,calcite and dolomite;the concretions of aragonite,gypsum and pyrite;and the carbonate rocks of calcite,quartz and illite.The mineral matter in the lignites consists of gypsum,quartz,albite,chlorite,illite,opal-A,dolomite,pyrite,and rarely calcite and kaolinite Athree-factor model explains the total variaition of major and trace elements in the argillaceous sediments.The first factor is an aluminosilicate factor and involves the following elements:Al,Si,Mg,Na,K,Ti,Mn,Nb,Y,Rb,Zn,Cu,Ni,Cr,Nband V,associated with chlorite,albite and illite.The second factor involves the elements Ca,Sr,Ba,Znand Sc and is related to carbonate lithology and mainly the carbonate concretions with gypsum.The third factor involves Fe and Ce with a weak association with Mn.The diagenesis of the Marathousa sediments and lignites was not very advanced as indicated by (a) the total thickness of the sequence (500m),(b) the presence of biogenic silica(opal-A) and (c) the age of the deposit(Pleistocene).FOr these reasons the rpresence of chlorite,illite and kaolinite in the sediments and lignite is due not to diagenetic reactions but to weathering of the flysch and metamorphic rocks at the edges of the Megalopolis Basin and transport of the weathering products(illite,chlorite,kaolinite)into the basin of deposition.The diagenetic minerals of the Marathousa sequence include pyrite,gypsum,dolomite and aragonite. 相似文献
15.
R. Raiswell S. H. Bottrell S. P. Dean J. D. Marshall† A. Carr‡ & D. Hatfield 《Sedimentology》2002,49(2):237-254
Carbonate concretions in the Lower Carboniferous Caton Shale Formation contain diagenetic pyrite, calcite and barite in the concretion matrix or in different generations of septarian fissures. Pyrite was formed by sulphate reduction throughout the sediment before concretionary growth, then continued to form mainly in the concretion centres. The septarian calcites show a continuous isotopic trend from δ13C=?28·7‰ PDB and δ18O=?1·6‰ PDB through to δ13C=?6·9‰ PDB and δ18O=?14·6‰ PDB. This trend arises from (1) a carbonate source initially from sulphate reduction, to which was added increasing contributions of methanogenic carbonate; and (2) burial/temperature effects or the addition of isotopically light oxygen from meteoric water. The concretionary matrix carbonates must have at least partially predated the earliest septarian cements, and thus used the same carbonate sources. Consequently, their isotopic composition (δ13C=?12·0 to ?10·1‰ PDB and δ18O=?5·7 to ?5·6‰ PDB) can only result from mixing a carbonate cement derived from sulphate reduction with cements containing increasing proportions of carbonate from methanogenesis and, directly or indirectly, also from skeletal carbonate. Concretionary growth was therefore pervasive, with cements being added progressively throughout the concretion body during growth. The concretions contain barite in the concretion matrix and in septarian fissures. Barite in the earlier matrix phase has an isotopic composition (δ34S=+24·8‰ CDT and δ18O=+16·4‰ SMOW), indicating formation from near‐surface, sulphate‐depleted porewaters. Barites in the later septarian phase have unusual isotopic compositions (δ34S=+6 to +11‰ CDT and δ18O=+8 to +11‰ SMOW), which require the late addition of isotopically light sulphate to the porewaters, either from anoxic sulphide oxidation (using ferric iron) or from sulphate dissolved in meteoric water. Carbon isotope and biomarker data indicate that oil trapped within septarian fissures was derived from the maturation of kerogen in the enclosing sediments. 相似文献
16.
早期形成的碳酸盐结核在埋藏期间会经历多种碳酸盐矿物相沉淀的复杂胶结作用,岩石学研究是探究结核成因的关键。通过野外剖面观察、岩石学观察和阴极发光技术,分析了鄂尔多斯盆地渭北地区上三叠统延长组长7油层组泥页岩中各种形状的方解石和白云石结核中自生碳酸盐矿物的特征。这些结核为成岩早期的产物,构成结核的自生碳酸盐矿物特征显著:(1)球粒方解石结核中,方解石呈纤维状或刃片状,球粒间充填晶粒方解石或因压实呈贴面结合,纤维状方解石发桔红色和暗红色2种光,刃片状方解石发暗红色光;(2)粉晶方解石结核中,方解石呈他形粒状,含有机质包裹体或纤维状晶形残余,晶间含沥青和纤维状方解石残余,主要发暗红色光;(3)白云石结核有泥晶和粉晶2种晶体类型,粉晶白云石结核含较多泥质,泥质条带或有机质条带处常见纤柱状白云石;(4)沿裂缝充填的方解石和白云石常呈纤维状或纤柱状结构,发暗红色光或不发光。研究区长7油层组碳酸盐结核中的方解石和白云石具有不同的成因类型和复杂的胶结作用:球粒方解石和泥晶白云石代表了结核开始形成时的胶结作用,可以准确地反映结核的成因;粉晶方解石、粉晶白云石反映了交代成因;裂缝中纤维状、纤柱状方解石和白云石集合体则为结核经历了较强压实作用之后充填裂缝而成。 相似文献
17.
酒西盆地下白垩统陆相碎屑岩胶结物的形成关系到油气储集的重要问题,富铁的洪积扇沉积体系和非富铁的河流一湖泊沉积体系形成两种不同的胶结物组合类型,平面上可分为三带胶结物:混合胶结带、铁镁胶结带和浓聚成岩带。盆地边缘带是以铁、泥、钙为主的混合胶结物,中间为以碳酸铁镁矿物的白云石、铁白云石为主的胶结物,盆中带形成胶结物的浓聚成岩层,事实证明过渡的铁镁胶结带是最富于聚集油气的地带。本文还在纵向上探讨了泥质粘土矿物和碳酸盐胶结物的成岩变化。 相似文献
18.
Xiang Gao Pingkang Wang Dairong Li Qiang Peng Chengshan Wang Hongwen Ma 《地学前缘(英文版)》2012,3(5):669-680
The well SK-I in the Songliao Basin is the first scientific borehole targeting the continental Cretaceous strata in China.Oval concretions,thin laminae and beds of dolostone are found intercalated within mudstone and organic-rich black shale in the Nenjiang Formation of Campanian age.Low ordered ferruginous dolomite is composed of euhedral-subhedral rhombs with cloudy nucleus and light rims formed during the diagenesis.which are typical features of replacement.The heavy carbon isotopes (δ13CPDB-1.16-16.0) are results of both the fermentation of organic matter by microbes and degassing of carbon dioxide during the period of diagenesis,and the presence of light oxygen isotopes(δ18OPdb- 18.53～-5.1) is a characteristic feature of fresh water influence which means the carbonate may have been altered by ground water or rainwater in the late diagenesis.Marine water incursions into the normally lacustrine basin have been proved by both the salinity of Z value and the occurrence of foraminifera in the same strata where dolomite occurs.Pyrite framboids observed by SEM are usually enclosed in the dolomite crystals or in the mudstones,supporting the sulfate reducing bacteria（SRB）.The formation of both dolomite and pyrite are associated with marine water incursions,which not only supply magnesium ion for dolomite,but also result in limited carbonate precipitation in the basin.The presence of pyrite tramboids indicates the development of an anoxic environment associated with salinity stratification in the lake.The dolomite in the Nenjiang Formation is the results of marine water incursions,diagenetic replacement of calcareous carbonate and sulfate reducing bacteria（SRB）. 相似文献
19.
SARAH ANNE REECKMANN 《Sedimentology》1981,28(5):643-652
A 3 km long lateral facies transition from Oligo-Miocene skeletal grainstones into packstones and mudstones displays systematic variation in carbonate skeletal fragment alteration and secondary carbonate mineral composition. Within the skeletal grainstone end-member all aragonitic grains have dissolved, all Mg-calcite skeletal fragments have altered to calcite, and calcite has been precipitated as both void-filling spar and as syntaxial overgrowths on echinoid fragments. Within the transitional grainstone-packstone lithologies some skeletal fragments show preservation of their original mineralogy, while calcite, ferroan calcite spar and dolomite have precipitated in void spaces. Within the packstone-mudstone end-member of the transition, aragonitic grains have been preserved and Mg-calcite skeletal fragments have retained most of their magnesium. Thin, originally porous grainstone layers within the pack-stone-mudstones contain sideroplesite and ferroan calcite spar in void spaces, and iron has been incorporated in skeletal fragments which were originally Mg-calcite. In these grains iron has been incorporated at the expense of magnesium until the grains approach the composition of the surrounding ferroan calcite cement. The lateral variation in diagenetic alteration across this facies transition is a function of differing groundwater movement and composition, controlled ultimately by the composition, porosity and permeability of the host lithologies. 相似文献
20.
The question of a primary versus diagenetic origin for the limestone-shale rhythms of the Blue Lias has been addressed through a study of pyrite abundance and isotopic composition. Pyrite is relatively abundant and isotopically light in the central portions of the bioturbated limestones as compared to adjacent, less calcareous, sediment. The abundance of pyrite shows that the limestones were a focus for prolonged sulphate reduction and pyrite formation. The isotopic data indicate that bioturbation oxidized some pyrite to produce isotopically light sulphate, part of which was subsequently reduced back to pyrite before preservation by burial. Acidity generated by pyrite oxidation was buffered in the limestones by carbonate dissolution, hence supersaturation of sulphides could be maintained. By contrast, in adjacent less calcareous sediments, carbonate dissolution was unable to buffer acidity and bioturbational oxidation of pyrite formed iron-rich pore solutions. Continued sulphate reduction in the limestones acted as a sink for iron from the adjacent sediments and, with burial below the zone of bioturbation, the alkalinity so generated caused cementation of the limestones. Diagenetic cementation would be enhanced during an hiatus in sedimentation, an event which might be related to a Milankovitch forcing mechanism, but which would not be recorded in bioturbated, less calcareous sediment, thus leaving an imperfect record. Only cyclicity in pre-diagenetic sedimentation patterns may be safely related to a Milankovitch forcing mechanism as proposed by Weedon. 相似文献