共查询到20条相似文献，搜索用时 342 毫秒
1.
铁元素对海相沉积物早期成岩作用的影响 总被引：1，自引：0，他引：1
铁元素是地壳中丰度最高的元素之一,在海相沉积物成岩过程中起着非常重要的作用.铁元素作为海洋初级生产力的微营养元素,影响海相沉积物中有机质的输入,其在早期成岩阶段与硫化物和磷元素的耦合关系,可以促进或者降低有机质的保存;铁元素在海相沉积物早期成岩过程中可以改变孔隙水的化学性质,影响亚稳定碳酸盐矿物的保存,导致碳酸盐沉积物... 相似文献
2.
Carbon mineralization in marine sediments is a key process involved in the cycling of carbon, nutrients and trace metals. However, as marine sediments are usually diffusion dominated, the pace of element and nutrient cycling is slow, because consumption of oxidants and/or nutrients in the pore waters via microbial activity often outpaces resupply. Adding an advective flow component to such a system should change the biogeochemical dynamics considerably. Numerical simulations show that shallow coastal aquifers affected by tidal forces can establish ground water velocities of up to 7 cm h−1, driving a circulation of sea water through the sediments with subsequent discharge. Although known to enhance solute exchange, the impact of advection on early diagenesis has not received much attention.To address this issue we mapped the interstitial water chemistry down to 2.5 m sediment depth along a transect on an intertidal creek bank that is subject to a periodic advective flow. Additionally a recently developed hydrogeological simulation of the creek bank was applied to calculate ages of the sampled pore waters. Sample ages obtained were used to quantify (flow path integrated) production or depletion rates for trace metals, nutrients, and sulphate.We find young sea water percolating relatively fast through sediments close to the creek showing strong signs of alteration, whereas pore waters from diffusion dominated regions are less altered. The increase in inorganic nutrients and some trace elements along the flow path requires high rates of turnover. Sulphate, molybdenum, and uranium are almost completely depleted after 200 days, while dissolved inorganic carbon (DIC), ammonia, and manganese increase. Averaged production rates for DIC appear to be three times higher when advection dominated the subsurface flow regime. Our results demonstrate that sites dominated by advection generally show signs of faster rates of diagenetic reactions. 相似文献
3.
4.
Tirumalesh Keesari U. P. Kulkarni Archana Deodhar P. S. Ramanjaneyulu A. K. Sanjukta U. Saravana Kumar 《Environmental Earth Sciences》2014,71(11):4869-4888
A study on the geochemical processes in arid region of western India (Kachchh district) was carried out using major, minor, trace metal data and isotopic composition (δ2H, δ18O) of groundwaters. Results indicate that the distribution of chemical species in groundwater of this district is controlled by leaching of marine sediments, dissolution of salts in root zone and incongruent dissolution of carbonate minerals. Common inorganic contaminants such as fluoride, nitrate and phosphate are within drinking water permissible limits. However, most of the samples analyzed contain total dissolved salts more than desirable limits and fall in doubtful to unsuitable category with regard to irrigational purpose. Trace metal data indicates no contamination from toxic elements such as arsenic and lead. An increased salt content is observed in groundwater at shallower depths indicating mixing with surface water sources. The chemical characteristics of the groundwater have found to be strongly dependent on the local lithological composition. Environmental isotopic data indicates that the groundwater is of meteoric origin and has undergone limited modification before its recharge. The processes responsible for observed brackishness are identified using chemical and isotope indicators, which are in agreement with subsurface lithology and hydrochemistry. These data though represent hydrochemical scenario of 2001 can still be used for understanding the long-term fluctuations in water chemistry and would be quite useful for the planners in validating groundwater quality models. 相似文献
5.
P. K. Govil J. E. Sorlie D. Sujatha A. K. Krishna N. N. Murthy K. Rama Mohan 《Environmental Earth Sciences》2012,66(1):121-128
Spatial distribution and temporal trends studies were carried out at Katedan Industrial Development Area (KIDA) near Hyderabad,
capital of Andhra Pradesh state, India under Indo-Norwegian Institutional Cooperation Program, to find out the extent of contamination
in streams and lake sediments from the discharge of industrial effluents. Stream and lake sediment samples were collected
from the five lakes in the study area and connecting water streams. The samples were analyzed by XRF spectrometer for toxic
elements. The studies reveal that the stream sediments with in the KIDA and the impounded Noor Mohammed Lake down stream have
high concentration of some of the toxic elements like chromium, nickel, lead, arsenic, zinc etc. The geology of the area indicates
that the study area consists of residual soil of acidic rocks, which are predominantly of Archaean gneisses and granites having
low to medium concentrations of chromium and nickel. The source of these high concentration of elements like lead 2,300 mg/kg,
copper 1,500 mg/kg, arsenic 500 mg/kg, chromium 500 mg/kg etc. cannot be derived from the surrounding acidic rocks and may
be attributed to the industrial effluents released in the ditches and random dumping of hazardous solid waste. It was observed
that the metal concentrations increased in the streams during the dry season (pre-monsoon period). After the monsoon rains,
the metal concentrations in the streams were reduced by half which may be due to dilution. The eroded sediments are deposited
in the lake where very high concentrations were encountered. Overflowing of the lake will spread the contamination further
downstream. The lake sediments will remain as a major source of contamination by desorption to the water phase regardless
of what happens to the effluent discharge in the KIDA. However, some samples showed enrichment of lead, arsenic and nickel
during post-monsoon, which were collected near the dumpsite due to the leaching of toxic elements from the dump site to the
lakes. Some of the toxic elements like nickel and copper have not shown any dilution but have increased after the rains, which
could be due to the leaching of arsenic from the dumpsite to the lake along with rainwater. Geochemical maps showing the distribution
of heavy/trace elements in streams and lakes are prepared and presented in this paper. Effect of toxic elements on the health
of the residents in the surrounding residential areas is also discussed. 相似文献
6.
7.
D. T. Jayawardana H. Ishiga H. M. T. G. A. Pitawala 《International Journal of Environmental Science and Technology》2012,9(1):41-55
The December 26, 2004 Indian Ocean tsunami was one of the largest in human history, devastating the coastal wetlands of surrounding countries. This study present the chemical analyses of tsunamigenic and pre-tsunami sediments from Hikkaduwa and Hambantota lagoons in southern Sri Lanka, to assess their geochemical composition, their source, and subsequent environmental impacts. Principal component analysis of the tsunami sediments shows that 42% of the total variance is accounted for calcium oxide and Sr. That is, the tsunami deposits are rich in biogenic phases derived from shallow marine sediments. High organic matter contents of the tsunami sediments of up to 80 wt% also support this interpretation. The association of chlorine (<9.4 wt%), brome (<170?mg/kg), arsenic (<17?mg/kg), iron (III) oxide (<12.9 wt%) and sulfur (<7.6 wt%) accounts for 33% of the variance, reflecting higher salinity. This further suggests that the sediments were mainly derived from a marine environment, rather than from non-marine sands and/or soils. Immobile element contents and relations (thorium, scandium and zirconium) suggest that the tsunami sediment source was mostly felsic in composition, with some mafic component, and mixed with predominantly shallow marine shelf or slope sediments. Additional compositional variations in the tsunami sediments in both lagoons may be associated with variations of wave strength along the coast and by the morphology of the continental shelf. Lower elemental abundances in Hambantota lagoon sediments compared to Hikkaduwa equivalents may thus reflect a greater non-marine component in the former, and greater shelf sediment component in the latter. 相似文献
8.
David Alan Spears 《Geochimica et cosmochimica acta》1974,38(4):567-575
Finely ground shale samples from a Carboniferous borehole sequence were shaken in water and the concentration of the water-soluble Na, K, Ca and Mg determined. The marine shales in the sequence were characterized by low concentrations of Na and K, and high concentrations of Ca and Mg. The reverse situation was found for the non-marine and brackish shales. The electrical conductivity of the water extract was higher for the marine shales than for the non-marine/brackish shales. It is suggested that the water-soluble cations were present in the sediment at the time of deposition as exchangeable cations which were released into the pore water during diagenesis as some of the exchange sites were eliminated. 相似文献
9.
D. M. Polyakov 《Geochemistry International》2009,47(1):58-66
The composition of clay minerals in the subcolloid fraction from the uppermost layer of bottom sediments in the northern part of Amur Bay was determined by X-ray powder diffraction analysis, and the enrichment of 33 elements in the subcolloid and pelite fractions of the surface deposits from a number of sites at the marginal filter of the Razdol’naya River was studied by ICP-MS.Fe, U, and chalcophile elements are contained in the highest concentrations in sediments from all sampling sites within the filter. The bottom sediments are not enriched in trace, alkali, and alkali-earth elements. The maximum concentrations of chemical elements were found in deposits from the brackish part of the marginal filter, perhaps, because of the formation of Fe and Mn (Al) hydroxides. Bottom sediment at the boundary between the brackish and marine parts of the filter contain the lowest concentrations of the examined elements. 相似文献
10.
太湖全新世沉积物的古盐度指标及其环境意义 总被引：5，自引：0，他引：5
沉积物中的Ｃａ／（Ｆｅ＋Ｃａ）比值和硼含量随水体含盐度的高低而相应增减，它们都是较好的古盐度指标。本文对太湖全新世的沉积物进行了古盐度指标的分析。并与现代湖泊和海洋沉积物作了对比，结果反映东太湖为陆相沉积环境，而西太湖则主要为海相沉积环境。此结论与古生物化石的结论一致，从而证明了太湖地区于全新世期间经历了大规模的海侵，并形成海湾－湖环境。同时也证明了这些古盐度指标是行之有效的。 相似文献
11.
Olga V. Shuvaeva Svetlana B. Bortnikova Tamara M. Korda Elena V. Lazareva 《Geostandards and Geoanalytical Research》2000,24(2):247-252
Gold recovery in ores containing arsenopyrite releases significant amounts of arsenic into the environment due to mineral processing and oxidation during storage. The extent of arsenic weathering in a tailings dam has been investigated. Speciation of As in surface and pore waters and pond sediments showed that for gold tailings in the dam, As enrichment took place in the pore water relative to the surface water. In pond sediments As was predominantly present as residual arsenopyrite and partly as a substance co-precipitated with iron hydroxide. The arsenic release from the sediment results from a reductive dissolution of the arsenopyrite and Fe oxides. In the surface water, arsenate and arsenite are the main arsenic species (arsenate is dominant), but in the pore waters methylation processes play a significant role. Arsenic transport is accompanied by the transformation of As into the less toxic compounds (methylated species) co-existing with the most toxic species (arsenite). 相似文献
12.
海相沉积物中自生沉积碳酸盐相的微量元素携带极为丰富的原始地质信息,然而海相沉积物中碳酸盐相的测定还没有建立统一的标准方法.本文以修正的Tessier七步提取流程为基础,以电感耦合等离子体质谱法(ICP-MS)为检测手段,针对海相沉积物碳酸盐相组分中V、Cr、Co、Ni、Sr五种微量元素建立了分级提取方法.实验以海相沉积物样品和标准物质作为参考样品,对比了NaAc和EDTA提取碳酸盐相的效果.结果表明,NaAc不能完全提取出沉积物碳酸盐相中的微量元素;EDTA可以较好地提取自生海相沉积物碳酸盐相中的微量元素,但是由于其络合能力太强还会提取有机物结合态的金属元素.本研究确定的分级提取方法是:首先用中性盐NaC1去除离子交换态,然后用提取专一性较强的焦磷酸钠(pH =10)去除有机态,再用EDTA提取仅自生海相沉积物的碳酸盐相.方法精密度(RSD)均＜5％,各元素的检出限在0.5～ 4.3 ng/g之间,回收率在88.0％ ～ 101.6％之间,方法的选择性和稳定性能够满足地球化学样品形态分析的要求. 相似文献
13.
Wang Yue Wang Jing CHEN Jun WANG Weijie Shen Shuzhong Charles M. HENDERSON 《《地质学报》英文版》2011,85(2):387-398
The Kungurian Stage is one of the three remaining stages of the Permian that is not yet defined at the base by a Global Stratotype Section and Point (GSSP). The candidate section at the Yuryuzan’River in the Urals yields few conodonts, and contains non-marine sediments near the boundary. The search for a suitable, continuous marine succession is a principal task for the Subcommission on Permian Stratigraphy. The Leonardian, with its type area in the southwest United States, and in objective stratigraphic succession directly beneath the basal Guadalupian Roadian Stage, has priority to serve as a subseries of the Lower Permian. However, distinct provincialism limits the correlation of Leonardian fossil zones with the fusuline-based Tethyan timescale. Conodonts can be correlated in many important regions on opposite sides of Pangea, yet contradictions arise when relating conodont zones with fusuline and ammonoid zones. The different taxonomic philosophies are highly suspected for the cause of the conflicts, but also there are different conodonts from the type Roadian in West Texas. Given that the Pamir and Darvaz in central Asia are difficult to access, further investigations should focus on South China, where abundant fusulines and ammonoids facilitate correlation throughout the Tethyan region, and where conodonts permit correlation with North America. 相似文献
14.
Thirty-four chemical elements, pH, total nitrogen, and total organic carbon were determined in 49 bottom sediment samples from the whole High Dam Lake in order to improve our understanding of geochemical characteristics of these sediments and geochemical patterns of trace elements and related feeding sources. The present study revealed that the lake were clearly discriminated into three portions in accordance with the sediment geochemistry and geographic position. Likewise, the analyzed elements in the entire lake sediments were classified into six geochemical association patterns that are indicative of the contributing geogenic and anthropogenic sources. As has been noted here, mineralogy, anthropogenic inputs, pH, and organic matter had significant roles in controlling the behavior, concentration, dispersion, and geochemical patterns of the trace elements in the lake sediments. Consequently, the elevated concentration of Bi, Cd, Co, Cr, Cu, Fe, Ga, Mn, Mo, Ni, Sc, V, Y, and Zn posed moderate contamination level in the sediments. At the same time, the enhancement of Ag, Se, and Te levels caused contamination up to very high levels. Admittedly, the contamination levels were generated by natural and human activities that are coming from the Nile basin countries. Despite progressive deterioration of these sediments, they still have economic applications. 相似文献
15.
G. Panagopoulos 《Environmental Geology》2009,58(5):1067-1082
The Trifilia karst aquifer presents a complex hydrochemical character due to the intricate geochemical processes that take
place in the area. Their discernment was achieved by using the chemical analyses of major, trace elements and boron isotopes.
Major ion composition indicates mixing between seawater and freshwater is occurring. Five hydrochemical zones corresponding
to five respective groundwater types were distinguished, in which the chemical composition of groundwater is influenced mainly
due to the different salinization grade of the aquifer. The relatively increased temperature of the aquifer indicates the
presence of hydrothermal waters. Boron isotopes and trace elements indicate that the intruding seawater has been hydrothermally
altered, as it is shown by the δ11B depleted signature and the increased concentrations of Li and Sr. Trace elements analyses showed that the groundwater is
enriched in various metallic elements, which derive from the solid hydrocarbons (bitumens), contained in the carbonate sediments
of the Tripolis zone. The concentration of these trace elements depends on the redox environment. Thus, in reductive conditions
As, Mn, Co and NH4 concentrations are high, in oxidized conditions the V, Se, Mo, Tl and U concentration increases while Ni is not redox sensitive
and present high concentration in both environments. 相似文献
16.
非海相白垩系年代学和对比 总被引：1，自引：0，他引：1
从1800年代初最早确定的白垩系定义起,白垩系就包括了海相和非海相白垩纪的地层和化石。白垩纪是一个全球性气候温暖、海平面高、构造和火山活动强烈的世界。此时,多块大陆分解,几乎所有海洋都已打开,形成了与现代相近的海陆分布的地理图案。这一变革导致了全球生物群的区域化,给全球对比带来了困难。白垩纪的全球年代地层表是主要依据菊石和微体生物(有孔虫和钙质超微浮游生物)化石,并与已完整建立的全球极性倒转年表和很多放射性同位素年龄相结合的产物。从孢粉到恐龙等各类非海相化石均已用于白垩纪生物地层学。此期专刊的特色是聚焦于区域或全球的孢粉(包括沟鞭藻)、大植物、甲壳类(包括叶肢介和介形类)、软体动物(包括腹足类和双壳类)和脊椎动物(包括硬躯体和足印)非海相白垩纪生物地层学和生物年代学。这些研究大大扩展了非海相白垩系对比的内容,并强调了将能取得更多进展的研究方向。非海相地层和化石群中直接夹有海相地层和化石的剖面/地区的非海相生物地层学更精确的研究,高分辨率的微体化石,特别是既出现于非海相又见于海相地层中的微体化石的微体生物地层学的进展,更多的直接与非海相生物地层学相关的放射性同位素和古地磁年龄的测试,非海相地层的高分辨率层序和旋回地层学分析及与非海相生物地层学对比的化学地层学的发展等,均将促进全球非海相白垩纪地层时代和对比,甚至以国际地质时标为准绳的全球非海相白垩纪地层对比框架表的建立。 相似文献
17.
南极普里兹湾表层沉积物微量元素分布特征及其物源指示意义 总被引：1，自引：0，他引：1
利用电感耦合等离子体质谱仪测定了中国南极科考21~27航次期间获取的普里兹湾表层沉积物中Cu、Pb、Zn、Cd、Cr、Co、Al、Fe、Mn的含量,分析了普里兹湾微量元素的分布特征,结合沉积物粒度分布、生物硅含量,并利用富集系数和主成分分析的方法,探讨了微量元素的物源指示意义。研究结果表明:普里兹湾沉积物中的微量元素含量与南大洋其他海域具有很好的可比性。Cu、Zn、Cr、Co、Fe、Mn含量在陆坡深海区明显高于冰架边缘区和陆架区;Al、Pb含量在冰架边缘区较高;而Cd含量在陆架区相对较高。人类活动对普里兹湾沉积物中的微量元素没有明显的影响,南极大陆岩石风化产物和海洋生物源性沉降是其主要来源。冰架边缘区及陆架破折处P2-9站位的微量元素主要为岩源性输入。陆架区、陆坡深海区的微量元素Cu、Zn、Cr、Co、Fe、Mn明显受到生源性物质输入的影响。而普里兹湾沉积物中Cd则主要来源于硅藻的吸收利用及硅质软泥的富集。 相似文献
18.
Bulk rock geochemistry of 169 fine-grained sediment samples of the upper Cretaceous to Paleogene Gosau Group（Northern Calcareous Alps,Austria and Slovakia） from borehole and outcrop localities was performed to separate non-marine and marine deposits.Geochemical characteristics of different Gosau depositional systems,basins and sediment provenance using major-,trace-,and rare earth elements were also investigated.Geochemical proxies such as boron concentrations were tested for seeking the possibilities of paleosalinity indicators.Due to the fact that several pelagic sections are represented by extremely low boron contents.B/Al* ratios are recognized as more robust and differentiate reliably between marine（mean:160±34） and non-marine（mean:133±33） samples.Using statistical factor analysis,hemipelagic to pelagic samples from the Gieβhbl Syncline and Slovakian equivalents can be differentiated from marginal-marine to non-marine samples from the Grnbach and Glinzendorf Syncline related to terrigenous（SiCh.Al2O3,K2O,Th,Rb,Zr and others） and pelagic indicative elements （CaO,Sr,TOT/C and B/Al*）.A clear indication for ophiolitic provenance is traced by high amounts of chromium and nickel.Only non-marine successions of the Glinzendorf Syncline show higher Cr and Ni concentrations（up to 250 and 400 ppm,respectively） and enriched Cr/V and Y/Ni ratios trending to an ultramafic source. 相似文献
19.
Groundwater contamination with arsenic and other trace elements in an area of the pampa,province of Córdoba,Argentina 总被引：1，自引：0，他引：1
Hugo B. Nicolli Jose M. Suriano Miguel A. Gomez Peral Luis H. Ferpozzi Omar A. Baleani 《Environmental Geology》1989,14(1):3-16
A geochemical study of groundwater of the pampa in the province of Córdoba, Argentina, was performed; the area covered approximately 10,000 km2.Physical-chemical parameters, dissolved solids, and seven trace elements were determined in 60 selected water samples. Systematic and accurate measurements of arsenic, flourine, and vanadium were performed for the first time. Three trace element contaminants not reported earlier were found: an important one, selenium, and two others of less known effects, uranium and molybdenum.Eighty-four percent of the water analyzed showed arsenic contents over 0.05 mg/L, maximum contaminant level established by the U.S. Environmental Protection Agency (1982). The frequency distribution of trace elements was analyzed, and its fit to the lognormal distribution was proved by means of the Pearson and Kolmogorov-Smirnov test; the geographic distribution of the seven trace elements was mapped and its correlation with the anion-cation composition of the water was studied.The maximum arsenic, fluorine, vanadium, and uranium contents were found in the western part of the area under study, in waters containing dominant alkali metals in the cation composition. Maximum selenium and antimony contents were found in the eastern part of the area, while molybdenum distribution does not show any relationship with the other two groups. In addition, the geographic distribution of the trace elements seems to be related to the subsurface structure, which has been inferred using interactive digital analysis of Landsat imagery. The movements of the subsoil have disturbed surface and subsurface drainage influencing the water salinity and trace element contents.In order to investigate the origin of the contamination, 54 loess samples were collected in wells at depths ranging from the surface down to the water table. This loess, which has a high proportion of volcanic components, mainly rhyolitic glass, exhibits a chemical composition corresponding to that of a dacite.The loess and the volcanic glass show anomalous contents of all contaminant trace elements, mainly arsenic and selenium. For this reason loess is considered the most important contamination source in the groundwater under study. 相似文献
20.
MARIT-SOLVEIG SEIDENKRANTZ 《Boreas: An International Journal of Quaternary Research》1993,22(4):283-290
The Quaternary sequence of a boring from the island of Anholt, Denmark, comprises both marine and non-marine sediments spanning a time interval from the Holocene to at least as far back as the Saalian. The oldest Quaternary sediments consist of a till and a glaciofluvial sand sequence. These are overlain by marine silty clays of Saalian to Eemian age. An interstadial (Flakket Interstadial) and a stadial (Kattegat Stadial) are identified in the late Saalian. This climatic fluctuation has been compared to the Allerød and Younger Dryas events at the Weichselian–Holocene transition. The Eemian sediments are followed by sand and non-marine, varved clay overlain by 2 m of marine clay, which is correlated with the Middle Weichselian of the Skærumhede series. The marine clay is covered by silty clay and a thick sand sequence of non-marine origin. The uppermost 2 m sediments may represent the Holocene coastal accretion on Anholt. 相似文献