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1.
海水温盐深剖面测量技术综述 总被引:1,自引:0,他引:1
温盐深是反应海洋物理学特性的重要参数,是海洋水文观测的基本要素。CTD剖面仪(Conductivity-Temperature-Depth profiler)是进行海水温盐剖面观测的主要仪器,利用CTD剖面仪可精确测得水下不同深度上海水的温度和电导率参数,进而能够推算出海水盐度、密度、声速等相关信息,对于海洋经济开发、海上国防建设、海洋环境保护等都具有非常重要的意义。本文介绍了温盐深剖面测量技术的基本原理与发展现状,对几种典型的温盐深测量设备及各种海洋观测平台中搭载的CTD传感器进行了介绍,论述了CTD传感器的标定和测试技术,并对其发展趋势进行了分析。 相似文献
2.
盐度定义狭义性与广义性 总被引:2,自引:0,他引:2
通过理论分析和实验验证,论述了“实用盐标”、“氯度盐标”定义的狭义性及应用范围,指出电导法和氯度法测定保守性质样品,数据正确;而测定非保守性质样品,测定值偏离绝对盐度Sa.笔者建议的“密度盐标”属于广义性质,可广泛应用于保守和非保守性质样品.密度盐标具有的优点是:(1)不受样品组成变化影响,只与溶液质量和浮力有关,测定值有高度可靠性与重现性;(2)测定大洋水盐度与现有实用盐度值相同,测定工业水盐度较实用盐度、氯度盐度值更接近绝对盐度Sa;(3)在已知溶质情况下,应用溶液膨胀系数和物质偏摩尔体积校正系数可统一溶质浓度与盐度的换算关系. 相似文献
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INTRODUCTIONBecausesalinityisanessentialfactorinoceanographicstudies ,andanimportantparameterinsaltchemicalindustriesandmaricultureaswellasecosystem ,thesalinitydefinitionanditsmeasurementarebeingcontinuouslystudied .Researchershavebeenconstantlyworking… 相似文献
4.
J.V. Leyendekkers 《Marine Chemistry》1977,5(1):29-42
An equation is given for predicting the absolute refractive index of seawater as a function of wavelength (in the visible region), temperature, pressure and salinity. This equation is based on the pure-water equation of H. Eisenberg, on the Tammann hypothesis and the Tait-Gibson equation of state for seawater. Comparison with experimental results (to 1380 bars) indicate an accuracy of ca. 0.0001 or better is achieved in the range of oceanographic interest. 相似文献
5.
The practical (Sp) and reference (SR) salinities do not account for variations in physical properties such as density and enthalpy. Trace and minor components of seawater, such as nutrients or inorganic carbon affect these properties. This limitation has been recognized and several studies have been made to estimate the effect of these compositional changes on the conductivity–density relationship. These studies have been limited in number and geographic scope. Here, we combine the measurements of previous studies with new measurements for a total of 2857 conductivity–density measurements, covering all of the world׳s major oceans, to derive empirical equations for the effect of silica and total alkalinity on the density and absolute salinity of the global oceans and to recommend an equation applicable to most of the world׳s oceans. The potential impact on salinity as a result of uptake of anthropogenic CO2 is also discussed. 相似文献
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The conductivity ratio of diluted and concentrated standard seawater has been measured very accurately in a salinity range from 0 to42permil and at temperature from -1 to30deg C. All the data have been fitted into polynomials which are compared with previous data. The specific conductance of seawater is deduced and a polynomial for the full range of salinity and temperature is proposed. Data presented in this paper have been used, with those of Dauphinee presented in this issue, to elaborate the new "Practical Salinity Scale 1978." 相似文献
7.
《Deep Sea Research Part I: Oceanographic Research Papers》2000,47(8):1583-1590
Over the next 5–10 years, the WOCE hydrographic program will generate reliable hydrographic data for the world oceans. The resultant conductivity salinity, temperature, and pressure data will generate calculated densities that will be used to examine mixing along constant density surfaces. Changes in the composition of deep waters due to the breakdown of plant material can effect the calculated densities at a given conductivity salinity. The increases in SiO2, nitrate, alkalinity, and TCO2 (or pH) can change the density of seawater as well as the conductivity. For studies of the salinity and density fields over small spatial scales, these changes will be small, but for large scale and ocean to ocean studies the differences can be significant. The density calculations based on the salinity determined from conductivity need to be adjusted for the offsets due to changes in the composition of seawater. This report describes how this correction should be made using existing information. 相似文献
8.
中国系列标准海水制备与质量评价 总被引:1,自引:1,他引:1
中国系列标准海水是国家二级标准物质 [GBW (E) 130 0 11],在盐度或电导率传感器的现场检定 ,实验室盐度计的检定和校准中应用广泛。主要介绍中国系列标准海水的制备和不确定度分析。 相似文献
9.
走航式海洋多参数剖面测量系统(MVP)是一种集成程度和自动化程度都较高的海洋调查设备,能对多要素进行同时观测,获得高水平空间分辨率的数据资料。MVP由于温度和电导率传感器响应时间的不匹配,下放速度过快(峰值速度4m/s)而造成非常严重的盐度尖峰现象。本研究通过结合F法、GM法和Grose法提出的盐度尖峰订正方案,提出了一种新的方法Match conductivity and temperature response times法,对压力、温度和电导率传感器三者进行响应时间的匹配来减弱盐度尖峰。与SBE-9型CTD资料进行对比发现订正后的资料误差比订正前减小80%,与CTD盐度曲线互相关程度为0.917。对比35N断面修正前后的盐度资料发现订正后温盐跃层处出现的低盐区域消失,与CTD断面资料对比结果显示MVP资料比CTD资料在细结构上更具有优势。 相似文献
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We study the procedures aimed at decreasing the dynamic errors of the evaluation of salinity with the help ofCTD-probes by reducing the difference between the amplitude-phase characteristics of temperature and conductivity sensors. This
is attained by introducing a delay between the times of scanning the sensors. To make the amplitude characteristics as close
as possible, we propose to use temperature sensors distributed in the direction of probing. We present the procedures used
to determine the optimal parameters of temperature sensors and the length of time delay. The advantages of the proposed method
are demonstrated by analyzing a numerical example.
Translated by Peter V. Malyshev and Dmitry V. Malyshev 相似文献
12.
The ratiosR_{s,t,o} of electrical conductivity of seawater samples of precisely known salinity to standard seawater at the same temperature have been measured over a wide range of salinities from 0 to42permil S and over the full range of oceanic temperatures from -2 to35deg C. The samples withS<35permil were prepared by accurate weight dilution of standard seawater with distilled water. High salinity samples were prepared by fast evaporation of standard seawater and subsequent weight dilution into the already determined <35permil range. An equation was derived which expresses the S versusR_{s,t,o} relationship very precisely from1-42permil and at all temperatures, i.e.,S = f_{1}(R_{s,t,o}) + f_{2}(R_{s, t,o},t) =Sigma_{n=0}^{5} a_{n}R^{n/2}+ frac{Delta t}{1+kDelta t} Sigma_{n=0}^{5} b_{n}R^{n/2} whereDelta t = t-15deg C,R = R_{s, t.o} ; only the first termf_{1} is required at15deg C. The effeet of temperature on the electrical conductivity of standard seawater was also measured. The ratior_{t} of the conductivity at temperaturet to the conductivity at15deg C (C_{35,t, o}/C_{35,15,o} ) is very aeenrately expressed by a fourth degree equation int . i.e,r_{t}=Sigma_{n=0}^{4} c_{n}t^{n} These two equations are sufficient for all salinity determinations at normal atmospheric pressure. 相似文献
13.
叶绿素浓度是衡量海洋浮游植物丰度的重要指标,快速准确地测定海水中的叶绿素含量,对于业务化监测和科学研究都具有重要的现实意义。基于活体荧光法的叶绿素传感器操作简便,可长期原位在线监测,能轻易获取大量实测数据,是当前海水叶绿素高精度测量手段的主要发展趋势。由于在海上应用时受到多种环境因素的影响,叶绿素传感器数据与实验室萃取法数值之间存在较大偏差。作者综述了科学界在浊度、光照、温度、盐度等海洋环境因素及藻类生理因素对叶绿素传感器测量的影响规律、影响机理和数据校正方法的研究进展,并对活体荧光法叶绿素传感器海上应用数据质量控制方法的研究思路进行了展望。 相似文献
14.
The history of the definition of salinity and the methods of computing It are traced from the beginning of the twentieth century until the present. Difficulties that have arisen in existing practices are discussed, in particular, the situation regarding reduction of in-situ CTD observations. The Practical Salinity Scale 1978 is an attempt to remove the shortcomings; it has been recommended for international acceptance. The basis for this new scale is an equation relating the ratio of the electrical conductivity of the seawater sample to that of a standard potassium chloride solution (KCI) at15deg C atmospheric pressure. The samples used were prepared from standard seawater diluted with distilled water or evaporated by weight. Finally, the set of new equations for CTD data reduction is given, based upon the work of authors whose papers are appearing elsewhere in this volume. 相似文献
15.
为了寻求一种简单、快速、连续测定悬浮泥沙含量的方法,以高含沙量海区黄河口泥沙为研究对象,利用电导率仪测定了不同悬浮泥沙含量水体的电导率。前期实验结果已经证明悬浮泥沙含量与电导率之间有很好的线性关系。在此基础上扩大研究范围,并对影响悬浮泥沙含量与电导率关系的因素进行定量分析,结果表明,盐度、温度、颗粒粒径对电导率具有一定的影响,其中盐度的影响最大,颗粒粒径的影响最小,几乎可以忽略。在此基础上通过大量的实验数据初步建立起在盐度、温度较大变化范围内电导率与泥沙含量的一般函数关系,为实现海水悬浮泥沙含量的现场电导率原位监测系统提供可靠的数据支持。 相似文献
16.
Yubin Hu 《海洋学报(英文版)》2022,41(6):114-118
pH is a measure of the hydrogen ion activity in a solution, which is a function of temperature. Under normal seawater conditions, it is well constrained. Nowadays, with an increasing interest in complex environments(e.g.,sea ice), a better understanding of the temperature change on pH under extreme conditions is needed. The objective of this paper was to investigate the temperature coefficient of the seawater pH(?pH/?T) over a wide range of temperature, pH, dissolved inorganic carbon(DIC) and sa... 相似文献
17.
《Deep Sea Research Part I: Oceanographic Research Papers》2005,52(2):389-396
The salinity of seawater has been defined in terms of the ratio of its electrical conductivity to that of a standard potassium chloride solution. The potassium chloride solution is obtained by dissolution of high-purity potassium chloride in ultrapure water. However, even high-purity potassium chloride is not 100% pure, and suppliers do not certify it, as the standard for electrical conductivity. We prepared defined solutions using several kinds of high-purity potassium chloride and examined the difference between the measured electrical conductivity ratio and the value calculated from the experimental equation given in the UNESCO background papers. The differences between the electrical conductivity ratios of the solutions made from the various potassium chloride reagents were equivalent to about 0.0012 in salinity. The solution may not actually become a standard for salinity measurements even if it is prepared exactly according to the present definition. The lot dependency of the electrical conductivity ratio of the potassium chloride solutions may result in a systematic error in the measurement of salinity. 相似文献
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Variability in water temperature, salinity and density was investigated based on field measurements near Anzali Port, in the
Southern Caspian Sea in 2008. Seasonal changes of seawater properties were mainly observed through the upper 100 m layer,
while below this layer seasonal variations of the parameters were minor. Vertical structure of the temperature in the southern
coastal waters of the Caspian Sea is characterized by a significant seasonal thermocline between 20–50 m depths with vertical
variation in temperature about 16°C in midsummer (August). Decrease of the thermocline occurs with the general cooling of
the air and sea surface water, and deepening of the mixed layer during late of autumn and winter. Seasonal averages of the
salinity were estimated in a range of 12.27–12.37 PSU. The structure of thermocline and pycnocline indicated agreement between
changes of temperature and density of seawater. Seasonal pycnocline was observed in position of the thermocline layer. 相似文献