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Fulvic acids of different origin, spray deposited on polished silicon after dissolution in high‐purity water without any additives, were analysed by time‐of‐flight secondary ion mass spectrometry (TOF‐SIMS) in combination with oblique 24...36 keV SF5+ ion bombardment. The observed, highly reproducible mass spectra cover more than five orders of magnitude in dynamic range, without background subtraction. Apart from lines due to atomic ions and low‐mass ion fragments, the mass spectra exhibit broad maxima between m/z 200...350, mainly due to a beat‐like superposition of lines at every single mass number, up to at least m/z 400. In the negative ion spectra the beats have a spacing of m/z 14, corresponding to a CH2‐unit. The high‐mass tails of the spectra extend well beyond m/z 5000, with similar slopes in the positive and the negative ion mass spectra. The negative spectra appear to be less affected by fragmentation products than the positive spectra. Fulvic acids (FAs) of different origin show distinctly different spectra, with mean masses ranging between m/z ≈ 450 and 580 (for a low‐mass cut‐off m/z 150). To further verify the ability of TOF‐SIMS to detect molecules and clusters with masses significantly above the maxima of the FA spectra, samples of glycyrrhizic acid (GA, as GA ammonium salt with molecular weight 840) were also analysed. Parent ions as well as multimers (GA)n were observed as positive and negative ions, up to n = 4 (m/z 3320). The results are compared with spectra recently obtained by other mass spectrometric techniques. 相似文献
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Dodecylammonium bentonite (DB) and dodecylammonium sepiolite (DS) were used as sorbents for phenoxyalkanoic acid herbicides 2,4‐D ((2,4‐dichlorophenoxy)acetic acid), 2,4‐DP ((RS)‐2‐(2,4‐dichlorophenoxy)propionic acid), 2,4‐DB (4‐(2,4‐dichlorophenoxy)butyric acid), 2,4,5‐T ((2,4,5‐trichlorophenoxy)acetic acid), and MCPA ((4‐chloro‐2‐methylphenoxy)acetic acid). Langmuir, Freundlich, and the linear Henry’s Law isotherm adsorption parameters were calculated from the adsorption isotherms. Langmuir equation showed poor fit for both adsorbents. According to the evaluation using the Freundlich equation, the DS sample showed much higher and stronger sorption capacity than DB. Similar behaviour was also observed in the case of the linear Henry’s Law isotherm. The adsorption of the herbicides on both DB and DS decreased in the order of 2,4‐DB > 2,4,5‐T > 2,4‐DP > 2,4‐D > MCPA. 相似文献
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Ferrisilicalite‐1 Zeolite Monolith‐Based Affinitive Recognition of Intracellular Phosphorylated Protein Alteration in Tetrahymena thermophila Exposed to Photodegradates of Roxarsone and p‐Arsanilic Acid 
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下载免费PDF全文 Wenzhong Zhang Fang Xu Jingjing Han Jun Yao Deju Wang Kai Yang Ceng Zeng Pengyuan Yang 《洁净——土壤、空气、水》2014,42(12):1798-1807
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Kazuhiko Yamada 《地震工程与结构动力学》2000,29(4):545-554
A simple non‐linear control law is proposed for reducing structural responses against seismic excitations. This law defines control force dynamics by one differential equation involving a non‐linear term that restrains the control force amplitude. If non‐linearity is neglected, the control force becomes the force in a Maxwell element, so it is called the non‐linear‐Maxwell‐element‐type (NMW) control force. The NMW control force vs. deformation relation plots hysteretic curves. The basic performance of an SDOF model with the NMW control force is examined for various conditions by numerical analyses. Furthermore, the control law is extended to fit an MDOF structural model, and an application example is shown. The computational results show that the NMW control force efficiently reduces structural responses. Copyright © 2000 John Wiley & Sons, Ltd. 相似文献
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Major earthquakes (i.e., mainshocks) typically trigger a sequence of lower magnitude events clustered both in time and space. Recent advances of seismic hazard analysis stochastically model aftershock occurrence (given the main event) as a nonhomogeneous Poisson process with rate that decays in time as a negative power law. Risk management in the post‐event emergency phase has to deal with this short‐term seismicity. In fact, because the structural systems of interest might have suffered some damage in the mainshock, possibly worsened by damaging aftershocks, the failure risk may be large until the intensity of the sequence reduces or the structure is repaired. At the state‐of‐the‐art, the quantitative assessment of aftershock risk is aimed at building tagging, that is, to regulate occupancy. The study, on the basis of age‐dependent stochastic processes, derived closed‐form approximations for the aftershock reliability of simple nonevolutionary elastic‐perfectly‐plastic damage‐cumulating systems, conditional on different information about the structure. Results show that, in the case hypotheses apply, the developed models may represent a basis for handy tools enabling risk‐informed tagging by stakeholders and decision makers. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
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The phase‐shift‐plus‐interpolation and extended‐split‐step‐Fourier methods are wavefield‐continuation algorithms for seismic migration imaging. These two methods can be applied to regions with complex geological structures. Based on their unified separable formulas, we show that these two methods have the same kinematic characteristics by using the theory of pseudodifferential operators. Numerical tests on a Marmousi model demonstrate this conclusion. Another important aspect of these two methods is the selection of reference velocities and we explore the influence of the selection of reference velocities by comparing the geometric progression method and the statistical method. We show that the geometric progression method is simple but does not take into account the velocity distribution while the statistical approach is relatively complex but reflects the velocity distribution. 相似文献
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Ji Feng Guimin An Biaohua Chen Yingxia Li Kunlun Ding Yun Xie Zhimin Liu 《洁净——土壤、空气、水》2009,37(7):527-533
Ti‐SBA‐15 materials with Ti incorporated into the framework of SBA‐15 and controllable Ti contents were successfully prepared via a post‐treatment route in supercritical CO2‐ethanol solution, followed by calcination. The resultant Ti‐SBA‐15 materials were characterized by means of different techniques including X‐ray diffraction, X‐ray photoelectron spectroscopy, transmission electron microscopy, IR analysis, and N2 sorption analysis. It was demonstrated that the resultant materials retained a structure similar to that of the parent SBA‐15, and Ti was incorporated into the framework of SBA‐15. At high Ti content, i.e, Si/Ti = 5:1, a TiO2 phase formed and was coated onto the inner surface of SBA‐15 in addition to the incorporation of the Ti in the framework. The BET surface areas of the Ti‐SBA‐15 samples decreased with increasing Ti content. The presence of small amounts of H2O in the reaction medium may have resulted in some TiO2 nanoparticles being uniformly distributed in the pores of the SBA‐15 accompanying the incorporation of Ti in the SBA‐15 framework. 相似文献
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Using a large set of rainfall–runoff data from 234 watersheds in the USA, a catchment area‐based evaluation of the modified version of the Mishra and Singh (2002a) model was performed. The model is based on the Soil Conservation Service Curve Number (SCS‐CN) methodology and incorporates the antecedent moisture in computation of direct surface runoff. Comparison with the existing SCS‐CN method showed that the modified version performed better than did the existing one on the data of all seven area‐based groups of watersheds ranging from 0·01 to 310·3 km2. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献
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It is important to include the viscous effect in seismic numerical modelling and seismic migration due to the ubiquitous viscosity in an actual subsurface medium. Prestack reverse‐time migration (RTM) is currently one of the most accurate methods for seismic imaging. One of the key steps of RTM is wavefield forward and backward extrapolation and how to solve the wave equation fast and accurately is the essence of this process. In this paper, we apply the time‐space domain dispersion‐relation‐based finite‐difference (FD) method for visco‐acoustic wave numerical modelling. Dispersion analysis and numerical modelling results demonstrate that the time‐space domain FD method has great accuracy and can effectively suppress numerical dispersion. Also, we use the time‐space domain FD method to solve the visco‐acoustic wave equation in wavefield extrapolation of RTM and apply the source‐normalized cross‐correlation imaging condition in migration. Improved imaging has been obtained in both synthetic and real data tests. The migration result of the visco‐acoustic wave RTM is clearer and more accurate than that of acoustic wave RTM. In addition, in the process of wavefield forward and backward extrapolation, we adopt adaptive variable‐length spatial operators to compute spatial derivatives to significantly decrease computing costs without reducing the accuracy of the numerical solution. 相似文献
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Hussein O. Okail P. Benson Shing William M. McGinley Richard E. Klingner Seongwoo Jo David I. McLean 《地震工程与结构动力学》2011,40(5):509-530
This paper presents the findings of shaking‐table experiments conducted to examine the seismic performance of a full‐scale, one‐story, wood‐framed structure with masonry veneer. The structure was designed and constructed in accordance with current U.S. code provisions. The veneer was attached to the wood backing with two kinds of metal anchors, corrugated ties fastened with 8d nails and rigid ties fastened with #8 screws. The tests have shown that the use of nails to fasten veneer anchors to the wood studs is highly unreliable due to the high variation of the nail extraction capacity, which can be influenced by the moisture content of the wood. Other than this, both the wood frame and the masonry veneer performed well under severe ground motions far exceeding a design level earthquake for Seismic Design Category D. Good performance was observed for the rigid veneer ties, which were attached to the wood studs with screws. The results have shown that the veneer walls parallel to the direction of shaking helped to restrain the motion of the wood structure and therefore should not be simply treated as added mass. The detailing of wood roof diaphragms requires special attention in consideration of the out‐of‐plane inertia force of the veneer that can be transmitted through the top plate of the wood‐stud wall to the rim joist. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
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This paper describes least‐squares reverse‐time migration. The method provides the exact adjoint operator pair for solving the linear inverse problem, thereby enhancing the convergence of gradient‐based iterative linear inversion methods. In this formulation, modified source wavelets are used to correct the source signature imprint in the predicted data. Moreover, a roughness constraint is applied to stabilise the inversion and reduce high‐wavenumber artefacts. It is also shown that least‐squares migration implicitly applies a deconvolution imaging condition. Three numerical experiments illustrate that this method is able to produce seismic reflectivity images with higher resolution, more accurate amplitudes, and fewer artefacts than conventional reverse‐time migration. The methodology is currently feasible in 2‐D and can naturally be extended to 3‐D when computational resources become more powerful. 相似文献
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Reliable estimation of the volume and timing of snowmelt runoff is vital for water supply and flood forecasting in snow‐dominated regions. Snowmelt is often simulated using temperature‐index (TI) models due to their applicability in data‐sparse environments. Previous research has shown that a modified‐TI model, which uses a radiation‐derived proxy temperature instead of air temperature as its surrogate for available energy, can produce more accurate snow‐covered area (SCA) maps than a traditional TI model. However, it is unclear whether the improved SCA maps are associated with improved snow water equivalent (SWE) estimation across the watershed or improved snowmelt‐derived streamflow simulation. This paper evaluates whether a modified‐TI model produces better streamflow estimates than a TI model when they are used within a fully distributed hydrologic model. It further evaluates the performance of the two models when they are calibrated using either point SWE measurements or SCA maps. The Senator Beck Basin in Colorado is used as the study site because its surface is largely bedrock, which reduces the role of infiltration and emphasizes the role of the SWE pattern on streamflow generation. Streamflow is simulated using both models for 6 years. The modified‐TI model produces more accurate streamflow estimates (including flow volume and peak flow rate) than the TI model, likely because the modified‐TI model better reproduces the SWE pattern across the watershed. Both models also produce better performance when calibrated with SCA maps instead of point SWE data, likely because the SCA maps better constrain the space‐time pattern of SWE. 相似文献
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Paul Sava 《Geophysical Prospecting》2015,63(5):1086-1096
Waveform inversion is a velocity‐model‐building technique based on full waveforms as the input and seismic wavefields as the information carrier. Conventional waveform inversion is implemented in the data domain. However, similar techniques referred to as image‐domain wavefield tomography can be formulated in the image domain and use a seismic image as the input and seismic wavefields as the information carrier. The objective function for the image‐domain approach is designed to optimize the coherency of reflections in extended common‐image gathers. The function applies a penalty operator to the gathers, thus highlighting image inaccuracies arising from the velocity model error. Minimizing the objective function optimizes the model and improves the image quality. The gradient of the objective function is computed using the adjoint state method in a way similar to that in the analogous data‐domain implementation. We propose an image‐domain velocity‐model building method using extended common‐image‐point space‐ and time‐lag gathers constructed sparsely at reflections in the image. The gathers are effective in reconstructing the velocity model in complex geologic environments and can be used as an economical replacement for conventional common‐image gathers in wave‐equation tomography. A test on the Marmousi model illustrates successful updating of the velocity model using common‐image‐point gathers and resulting improved image quality. 相似文献