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1.
Calcium-alkalinity relationship in the North Pacific   总被引：3，自引：0，他引：3  
The dissolution of calcium carbonate in deep ocean water causes variation in calcium concentration (Ca) and alkalinity (TA) in the ratio of one to two. The decomposition of organic matter generates nitric acid, phosphoric acid and sulfuric acid. A proton flux which is derived from this process also changes alkalinity. Using the variation in nitrate concentration (NO3) as an index of the proton flux, the relationship betweenCa,TA andNO3 is expressed asCa=0.5TA+0.63NO3 The values of Ca obtained from direct measurements in the North Pacific are in good agreement with the values estimated from this equation.  相似文献   

2.
The maximum uptake rate (max) and affinity constant (K s) for nitrate and ammonium were estimated in the surface water of offshore Oyashio in May (spring) and September (summer), 1990. The average max/Chl.a for ammonium was 2.1 times larger than that of nitrate in both seasons. The average max/Chl.a for both nitrogens were 3.5 times larger in summer than in spring. Water temperature and size composition of phytoplankton population were related to the seasonal difference in the max/Chl.a. Phytoplankton population showed high affinity for both nitrogens in the spring and summer. In addition, the contribution of new production to total production was estimated by max[max–No3/(max–NO3+max–NH4)]. The spring value was in the range of 0.26 to 0.45 (mean±SD=0.35±0.092), and the values in spring bloom were especially a little over 0.4. The summer value was in the range of 0.30 to 0.37 (0.34±0.04).  相似文献   

3.
The downward short- and long-wave radiation fluxes at the sea surface (S, L) were measured aboard the R/VHakuho Maru, University of Tokyo, for the period of 117 days on six cruises from 1981 to 1985 in the western North Pacific near Japan. The upward fluxes of short- and long-wave radiation (S, L) were calculated by Payne's (1972) table and the Stefan-Boltzmann's law, respectively. The sensible and laten heat fluxes (Q h ,Q e ) were also estimated from an aerodynamic bulk method.From April to August, the daily mean value ofS varied with the amplitude of 100200 Wm–2. The value ofS was estimated approximately 6% ofS in all seasons. The difference betweenL andL was so small that the net radiation flux (Q n ) was dominated byS. In addition, the net heat flux at the sea surface was also dominated byS due to small values ofQ h andQ e , and then the ocean was warmed at the rate of 111 Wm–2 in April and 63 Wm–2 in August in the Oyashio Area, and 132 Wm–2 in May and 164 Wm–2 in June in the Kuroshio Area, respectively.From September to March, a remarkable negative correlation between the day to day variation ofS and that ofL was observed except when an intense cold air outbreak occurred. It was found that the correlation was caused by the cloud climatological feature of the western North Pacific in this period.S was not a dominant factor in the net heat flux. The value ofQ h +Q e in the Kuroshio Area ranged from 260 Wm–2 to 630 Wm–2, much larger thanQ n which ranged from –8 Wm–2 to 92 Wm–2 in the leg mean values (each leg period was about 10 days). Then the ocean was cooled at the rate of –160–620 Wm–2 during this period. The net heat flux in the Kuroshio Area averaged over five legs from late November to February was –473 Wm–2. This value is 50100% larger than the climatological values reported so far.The temporal and spatial variability of radiation fluxes and heat fluxes during each leg was also discussed.  相似文献   

4.
Assessment was made of residual ratio of North Pacific Intermediate Water (NPIW) produced in subpolar region of the North Pacific using chlorofluorocarbons, CFC-11 and CFC-12 (CCl3F and CCl2F2), along 175°E. NPIW on density horizons less than 26.80 remained more than 80% north of 30°N. It was suggested that new NPIW laterally spreads over the northern North Pacific without hardly being diluted by the surroundings. For density horizons greater than 26.80 north of 30°N, NPIW remained less than 60%. The difference in the residual ratio between <26.80 and >26.80 north of 30°N suggests that NPIW is produced on density horizons less than 26.80, which contacts the atmosphere in the subpolar region, and that NPIW is diluted by upwelling deep water on density horizons greater than 26.80 in high latitude of the North Pacific. NPIW on a density horizon of 26.80 remained about 50% south of 30°N. The decrease in the horizontal distribution of the residual ratio of NPIW suggests that half the new NPIW produced in the subpolar region is laterally spread over the North Pacific with the southward movement of NPIW.  相似文献   

5.
Concentrations of chlorinated hydrocarbons such as HCH isomers and DDT compounds were determined in air and surface water samples taken from the Western Pacific, Eastern Indian and Antarctic Oceans. The most interesting finding was their presence in measurable concentrations in the Antarctic Ocean. Chlorinated hydrocarbon pesticides are widely distributed in the open ocean environment over both the northern and southern hemispheres, and some characteristic distribution patterns of pesticide species in different oceanic regions were observed both in air and water samples. HCH residues found in the northern hemisphere were much higher in concentration than those in the southern hemisphere. On the other hand, higher concentrations of DDT residues were found in the tropical regions, but their levels were not so different between both the northern and southern hemispheres. HCH isomers found in the northern hemisphere had the following order of concentrations:-HCH> HCH>-HCH, while in the southern hemisphere-HCH was apparently dominant. DDT compound compositions were rather uniform in all the oceans surveyed, and more than 50% wasp,p-DDT. These facts can be explained by the world wide situation regarding pesticide use and the physicochemical properties of the pesticides such as their vapor pressures and water solubilities. In addition, the meridional circulation of the atmosphere, particularly the mass flows of the Hadley and Ferrel cells in the troposphere, also contributes to the atmospheric transport and global distribution of these pesticides.  相似文献   

6.
Various wind velocitiesu *,U /2,U andU 10 are correlated to the measured growth rate of water waves , whereu * is the friction velocity of the wind, andU /2,U andU 10 are the wind speeds respectively at the heights /2, and 10m above sea surface (: wave length). It is shown that within a range of the dimensionless wind speed, 0.1<u * /C<0.6, there are no appreciable differences in the correlations, whereC is the phase velocity of water waves. The present relation between andU shows qualitatively similar properties as the one obtained by Al'Zanaidi and Hui (1984); the growth rate for waves with rough surface is larger than that with smooth surface. However, our present relations give, for the both waves with different surface roughness, larger values by factors 1.71.8 than those given by Al'Zanaidi and Hui's relation.  相似文献   

7.
Spectral analysis of the climatic circulation in the upper 10 m layer of the Black Sea has been carried out. The current field was calculated from a three-dimensional baroclinic non-linear model. The mode composition of the circulation was derived. It is shown that the surface climatic circulation can be represented as the superposition of a finite number of elementary currents of two types:n- andm-modes. Only 4n-modes are shown to be energy-dominant throughout the year. A relation is established between the different sources of energy supply of currents and the modes which assimilate this energy. Problems concerning the nature of the classical Black Sea currents such as the main Black Sea current (MBSC) and the Knipovich spectacles are discussed. A scenario of the field large-scale experiment is suggested which allows the reconstruction of the amplitudes of the first 10n- and the first 10m-modes from mooring data.Translated by Mikhail M. Trufanov.  相似文献   

8.
We have investigated the fundamental processes of deep convection in a lake at high latitudes triggered by wind during spring or autumn and the associated deep water formation, executing vertically two-dimensional numerical experiments with a nonhydrostatic model. The water column in which a relatively cold mixed layer overlies a relatively warm layer becomes unstable, when the Ekman convergence on the shore due to along-shore wind deepens the mixed layer below the compensation depth, where water densities in both layers becomes equal to each other because of the thermobaric effect. At the onset of deep convection, the critical Rayleigh number agrees with that predicted by the linear theory. The onset time of deep convection is inversely proportional to the magnitude of wind stress. On the other hand, the onset time is minimal when water temperature in the mixed layer m is 3.1°C because a change of m has two effects oppositely acting on the stability of the water column. After the first onset, deep convection occurs intermittently for a few days. The sinking of the mixed layer water occurs in a thermal-like shape, and its amount is 4184% of the time-integrated Ekman transport when m 3°C while it decreases to less than 10% for m lower than 1.5°C. The present process can explain 30% of the amount of deep water renewal which is expected from the observation in Lake Baikal.  相似文献   

9.
Regeneration of silicate in the Japan Sea, an example of semi-closed sea, was studied. In the Japan Sea Proper Water the apparent regenerative ratio of the nutrients was determined to be:O C N P Si=–289 (116)14.3181.It was assumed that the dissolved silicate present in sea water is grouped into three fractions; 1)preformed silicate of conservative nature, 2)oxidative silicate which dissolves in oxidation process of organisms with consumption of oxygen, and 3)non-oxidative silicate which dissolves without oxygen consumption. The dissolution rate ofnon-oxidative silicate in the Japan Sea Proper Water was estimated to be 0.07g-at. Si/l/yr from the data ofAOU values and assumed rates of oxygen consumption. This dissolution rate ofnon-oxidative silicate agreed with that obtained in the deep Pacific by the vertical advection diffusion model byKido andNishimura (1972).  相似文献   

10.
The development process of wind-waves of which spectral peak distributes from 0.6 cps to 9.3 cps will be discussed on the basis of the wind tunnel experiments and of the field observations performed at Lake Biwa. The characteristics of power and slope spectra are here presented. The development process of these wind-waves is characterized by three stages;i.e. initial-wavelets, transition stage and sea-waves. In the wind tunnel experiments, the transition from the stage of the initial-wavelets to the transition stage occurs when the wave spectral peak arrives at the line 6.40×10–4 k –2cm2·sec (wherek is wave number) or when the slope spectral density at the frequencyf max becomes larger than 6.40×10–4 sec. In the stage of sea-waves, the component wave of a wave-spectral peak is steepest in the component waves. And the wave spectral peak develops along the line 1.02×102 f –6 cm2·sec (wheref is the frequency corresponding to the wave numberk) untill it reaches the line 33.3f –4cm2·sec, and thereafter develops along the latter line, which indicates the constant density of slope spectrum. It is suggested that the nonlinearity of wind-waves must become stronger as wind-waves develop. The effective momentum flux ws from the air flow to wind-waves in this stage is evaluated to be about 49% of the total stress 0.  相似文献   

11.
PCBs, DDT compounds and HCH isomers were detected in the air and surface waters of the North Pacific and Indian Oceans, including the Bering Sea, East China Sea, South China Sea, Bay of Bengal and the Arabian Sea. The general concentrations of each chlorinated hydrocarbon were as follows: water PCBs 0.1 to 1.0, DDT 0.01 to 1.0, HCH 1.0 to 10 ngl –1; air DDT 0.01 to 1.0, HCH 0.1 to 10 ng m–3. PCB concentrations in surface waters were slightly lower than those of the North Atlantic and North Sea previously reported, while DDT concentrations in the air and water were higher. Remarkably high concentrations of DDT and HCH were found in the air off the western coast of India. Also in the Pacific site off Central America, a fairly high concentration of DDT was observed in an air sample. These data suggest that large amounts of DDT and HCH are being used in the tropical zone, especially in southern Asia. Furthermore, high concentrations were observed both in the air and water of the Northwest Pacific between 30°N and 40°N latitude. There is a possibility that both pesticides are not only still being used in lower latitude countries but also in the mid-latitude ones of the Asian continent excluding Japan. In addition to this atmospheric circulation may also contribute to the concentration of these pesticides in the mid-latitudinal zone.  相似文献   

12.
Spectral characteristics of rapid-changing random data in the ocean are discussed. Analysis shows that, if records are approximated by saw-toothed random series 1 and step series 2, 1 and 2 generally have spectral ranges of the –4th power and –2nd power, respectively, with respect to frequency (or wave number).  相似文献   

13.
The respiration rates of copepod larvae and a ciliate (Placus sp.) from a tropical sea were measured with an oxygen electrode method. The general range of body size of these animals was 40–161m (diameter equivalent to a sphere), and the respiration rate measured was 0.00076–0.00176l O2 (animal)–1h–1 (or 2.02–9.05l O2 (mg wet weight)–1h–1) at 25.5–29.2C. There was no marked difference observed between the respiration rates of copepod larvae and the ciliate. The respiration rates obtained here are relatively higher than the rates of other similar sized protozoans found in the literature, but lower than the rate extrapolated from larger planktonic copepods in tropical seas.The present results and other information available on microzooplankton biomass suggest that microzooplankton respiration is of near equal importance to that of net zooplankton in the study of energy flow through tropical, pelagic ecosystems.  相似文献   

14.
The mechanism of the development of wind-waves will be proposed on the basis of the observed wave spectra in the wind tunnels and at Lake Biwa (Imasato, 1976). It consists of two aspects: One is that the air flow over the wind-waves transfers momentum concentratively to the steepest component waves and the other is that the upper limit of the growth of a wave spectral density is given by the ultimate value in the slope spectral density. The first aspect means that the wave field has the momentum transfer filter on receiving the momentum from the air flow. Wind-waves in the stage of sea-waves receive the necessary amount of momentum by the form drag,e.g. according to the Miles' (1960) inviscid mechanism, through a very narrow frequency region around a dominant spectral peak. On the other hand, wind-waves in the stage of initial-wavelets receive it according to the Miles' (1962a) viscous model through a fairly broad frequency region around the peak. The upper limit ofS max developing according to viscous mechanism is given byS max =6.40×10–4 k max –2cm2s andS max =2.03C(f max )–2cm2s(S max is the power density of the wave spectral peak with the frequencyf max ,k max is the wave number corresponding to the frequencyf max andC is the phase velocity).From the second aspect, the upper limit of the growth of wave spectral density is given by 33.3f –4cm2s in the frequency region of late stage of sea-waves. Therefore, the spectral peak, which has the largest value in the slope spectral density in the component waves of the wave spectrum, rises high over the line 4.15f –5cm2s. The energy is transported from the spectral peak to the high frequency part and to the forward face of a wave spectrum by nonlinear wave-wave interaction. This nonlinearity is confirmed by the bispectra calculated from the observed wind-wave data. In the stage of sea-waves, nonlinear rearrangement of the wave energy comes from a narrow momentum transfer filter, and, in the stage of initial-wavelets, it comes mainly from small corrugations and small steepness of the wave field.  相似文献   

15.
Dependences have been determined which connect the parameters of the dispersion relation of the lowest mode of internal waves with the integral characteristics of the seasonal thermocline when 10 min30 min, 20 mh150 m, and 0·4 m2/s2 Q5·2 m2/s2.Translated by Mikhail M. Trufanov.  相似文献   

16.
Stability constants were determined for60Co (II)-amino acid complexes in sodium perchlorate media at an ionic strength=0.67, using cation exchange resins. Stability constants were, for Co(II)-phenylalanine, log 1=4.4, log 2=8.2, log 3=11.7, for Co(II)-histidine, log 1=7.4. for Co(II)-valine, log 1=4.3, log 2=8.5, for Co(II)-proline, log 1=4.1, and for Co(II)-tyrosine, log 1=7.2, respectively. The abundance of Co(II)-amino acid complexes in seawater was calculated from these stability constants on the basis of chemical equilibrium, assuming the concentration of individual amino acid to be 10–7 to 10–8 mol l–1. It was inferred that the Co(II)-amino acid complexes are probably not formed abundantly in seawater while inorganic species of60Co(II) may still be dominant for a short period of time after discharge into seawater as liquid waste.  相似文献   

17.
Radiocarbon and total carbonate data were obtained near the 1973 GEOSECS stations in the North Pacific along 30°N and along 175°E between 1993 and 1994. In these stations, we estimated radiocarbon originating from atomic bomb tests using tritium, trichlorofluoromethane and silicate contents. The average penetration depth of bomb radiocarbon during the two decades has deepened from 900 m to 1300 m. Bomb radiocarbon inventories above the average value for the whole North Pacific were found widely in the western subtropical region around 30°N both in the 1970s and 1990s, and its area in the 1990s was broader than that in the 1970s. In most of the North Pacific, while the bomb radiocarbon has decreased above 25.4, the bomb radiocarbon flux below 25.4 was over 1 × 1012 atom m-2yr-1 in the subtropical region around 30°N. In the tropical area south of 20°N, the bomb radiocarbon inventory below 25.4 increased from zero to over 10 × 1012 atom m-2 during the last three decades. These distributions suggest that the bomb radiocarbon removed from the surface is currently accumulated with bomb 14C flux of over 1 × 1012 atom m-2yr-1 below 25.4 in the subtropical region, mainly by advection from the higher latitude, and that part of the accumulated bomb 14C gradually spread southward with about 30 years.  相似文献   

18.
Ishiwatari  R.  Hirakawa  Y.  Uzaki  M.  Yamada  K.  Yada  T. 《Journal of Oceanography》1994,50(2):179-195
Organic geochemical study of bulk organic matter (OM), hopanoid hydrocarbon and normal hydrocarbon (C23C35) was conducted for a 936-cm-long sediment core sample from the Oki Ridge of the Japan Sea (Core KH-79-3, C-3; 37°03.5 N, 134°42.6E, water depth 935 m). Stable carbon isotopic ratios were also measured for both bulk OM and individual hydrocarbons. The following results were obtained: (1) The weight ratios of total organic carbon to total nitrogen range from 6.2 to 9.4 in the core. The 13C values of bulk OM range from –25.1–20.7%.. The 13C values of OM in the sections of 140190 cm are lower (–25–24) than those in the other sections (–23–21). This result indicates that OM in the core except for the 140190 cm sections is essentially of marine origin. (2) The 13C value of diploptene (a hopanoid hydrocarbon) in the last glacial maximum (LGM), is –66.3 (vs. PDB), which indicates it originating in methanotrophic bacteria. This result provides evidence to support for the previous ideas (Oba et al., 1980, 1984; Masuzawa and Kitano, 1984) that the bottom waters in the Japan Sea were anoxic in LGM. (3) Long chain (C23C35) n-alkanes of higher-plant wax origin were found throughout the core. Their concentration is high in 140190 cm in depth, suggesting that eolian dust load was high in LGM. (4) The n-alkane/TOC ratio increases with decreasing 13C values of bulk OM. This result indicates that the load of terrestrial (probably eolian dust-derived) OM to the Japan Sea became higher in colder climates. (5) The CPI values of long-chain n-alkanes are different in different 13O stages of paleoclimate, probably reflecting variations in species of terrestrial higher plants as a result of climatological adaptations.  相似文献   

19.
Observational data on air-sea boundary processes at the Shirahama Oceanographic Tower Station, Kyoto University, obtained in November, 1969, was analyzed and presented as an example representing the structure of growing wind-wave field. The condition was an ideal onshore wind, and the data contained continuous records of the wind speed at four heights, the wind direction, the air and water temperatures, the tides, and the growing wind waves, for more than six hours. The main results are as follows. Firstly, in both of the wind speed and the sea surface wind stress, rather conspicuous variations of about six-minute period were appreciable. Secondly, the three-seconds power law and its lemma expressed byH *=BT *3/2 and=2BT *–1/2, respectively, are very well supported by the data, whereH *(gH/u * 2) andT *(gT/u *) are the dimensionless significant wave height and period, respectively, the wave steepness,u * the friction velocity of air,g the acceleration of gravity, andB=0.062 is a universal constant. Thirdly, the spectral form for the high-frequency side of the spectral maximum is well expressed by the form of()= sgu*–4, where is the angular frequency and() the spectral density. The value of s is determined as 0.062±0.010 from the observational data. There is a conspicuous discrepancy between the spectral shape of wind waves obtained in wind-wave tunnels and those in the sea, the former containing well-defined higher harmonics of the spectral peak, and consequently there is an apparent difference in the values of s also. However, it is shown that the discrepancy of s may be eliminated by evaluating properly the energy level of the spectral form containing higher harmonics.  相似文献   

20.
The present study deals with the elucidation of sterol composition of the marine sediments in Kagoshima Bay. The identification of each sterol was performed by gas-liquid chromatography, Ag+ impregnated column chromatography, mass spectrometry, and nuclear magnetic resonance spectrometry. The sediment obtained near the estuary of River Koutsuki contained large portions of 5-stanols such as coprostanol and 24-ethylcoprostanol basides 5-stanols such as cholestanol, 24-methylcholestanol, and 24-ethylcholestanol in the sterol fraction. These 5-stanols in the marine sediment may be derived from the fecal contamination by domestic sewages.  相似文献   

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