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1.
To reconstruct oceanographic variations in the subtropical South Pacific, 271-year long subseasonal time series of Sr/Ca and δ18O were generated from a coral growing at Rarotonga (21.5°S, 159.5°W). In this case, coral Sr/Ca appears to be an excellent proxy for sea surface temperature (SST) and coral δ18O is a function of both SST and seawater δ18O composition (δ18Osw). Here, we focus on extracting the δ18Osw signal from these proxy records. A method is presented assuming that coral Sr/Ca is solely a function of SST and that coral δ18O is a function of both SST and δ18Osw. This method separates the effects of δ18Osw from SST by breaking the instantaneous changes of coral δ18O into separate contributions by instantaneous SST and δ18Osw changes, respectively. The results show that on average δ18Osw at Rarotonga explains ∼39% of the variance in δ18O and that variations in SST explains the remaining ∼61% of δ18O variance. Reconstructed δ18Osw shows systematic increases in summer months (December-February) consistent with the regional pattern of variations in precipitation and evaporation. The δ18Osw also shows a positive linear correlation with satellite-derived estimated salinity for the period 1980 to 1997 (r = 0.72). This linear correlation between reconstructed δ18Osw and salinity makes it possible to use the reconstructed δ18Osw to estimate the past interannual and decadal salinity changes in this region. Comparisons of coral δ18O and δ18Osw at Rarotonga with the Pacific decadal oscillation index suggest that the decadal and interdecadal salinity and SST variability at Rarotonga appears to be related to basin-scale decadal variability in the Pacific.  相似文献   

2.
The build up of the isotopic signal in corals was followed by sampling the newly formed skeleton at a monthly resolution for a period of two years in order to establish the interrelations between the calcification processes and the skeletal isotopic composition. We deployed two underwater sampling schemes, which provide a monitor of the changes in water temperature and δ18O and in the corresponding newly accreted skeleton of undisturbed Porites lutea colonies under natural conditions and four transplanted colonies, which maintained the genetic identity throughout the experiment. The results indicate that δ18O of the newly accreted skeleton does not correlate with ambient temperature although the seasonal temperature variability at the site (winter to summer) is in the order of 6 °C and δ18O of seawater is constant throughout the year. In contrast to the newly formed surface skeleton, the isotopic compositions of the deep and older parts of the skeleton show the predicted annual isotopic pattern with highly significant correlation between δ18Os and SST. The transformation between temperature-independent to temperature-dependent isotopic signal occurs several months after the skeleton was formed at the surface. The position of the skeleton in relation to the open sea may generate the difference between δ18Os of the surface skeleton and that of the skeleton previously accreted further down the tissue layer. Our data support the general model of a multi-step skeletogenesis process, where the temperature independent skeleton is entails the first step, the production of skeletal scaffold, and the environmental temperature signature is captured by the next two other steps: the thickening and the periodic abrupt uplift occurring at the depth of the tissue layer. However, re-examination and development of the current isotopic models for coral calcification are required in order to explain the observed different temperature dependency during the growth’s sequence.  相似文献   

3.
Coupled records of Sr/Ca and oxygen isotope ratios (δ18O) of coral skeletons have been used to produce quantitative estimates of paleo-sea surface temperature (SST) and δ18O of surface seawater that can in some cases be converted to sea surface salinity (SSS). Two fossil corals from Kikai Island in the subtropical northwestern Pacific, a location affected by East Asian summer and winter monsoons, were analyzed to investigate differences between mid-Holocene and present-day SST and SSS. At 6180 cal yr BP, SSTs were roughly the same as today, both in summer and winter; δ18Oseawater and SSS values were higher both in summer (+ 0.5‰, +1.1 psu) and in winter (+ 0.2‰, + 0.6 psu) than modern values. At 7010 cal yr BP, SSTs were slightly cooler both in summer and winter (−0.8 and −0.6 °C), whereas δ18Oseawater and SSS had higher values in summer (+ 0.3‰, + 0.6 psu) and in winter (+ 0.8‰, + 1.9 psu) than present-day values. These results are consistent with other marine records for the mid-Holocene of the low and midlatitudes in the northwestern Pacific. Such regional conditions indicate that the East Asian summer and winter monsoons were more intense in the mid-Holocene, which was likely a function of the mid-Holocene insolation regime.  相似文献   

4.
Coral proxy records of sea surface temperature (SST) and hydrological balance have become important tools in the field of tropical paleoclimatology. However, coral aragonite is subject to post-depositional diagenetic alteration in both the marine and vadose environments. To understand the impact of diagenesis on coral climate proxies, two mid-Holocene Porites corals from raised reefs on Muschu Island, Papua New Guinea, were analysed for Sr/Ca, δ18O, and δ13C along transects from 100% aragonite to 100% calcite. Thin-section analysis showed a characteristic vadose zone diagenetic sequence, beginning with leaching of primary aragonite and fine calcite overgrowths, transitional to calcite void filling and neomorphic, fabric selective replacement of the coral skeleton. Average calcite Sr/Ca and δ18O values were lower than those for coral aragonite, decreasing from 0.0088 to 0.0021 and −5.2 to −8.1‰, respectively. The relatively low Sr/Ca of the secondary calcite reflects the Sr/Ca of dissolving phases and the large difference between aragonite and calcite Sr/Ca partition coefficients. The decrease in δ18O of calcite relative to coral aragonite is a function of the δ18O of precipitation. Carbon-isotope ratios in secondary calcite are variable, though generally lower relative to aragonite, ranging from −2.5 to −10.4%. The variability of δ13C in secondary calcite reflects the amount of soil CO2 contributing 13C-depleted carbon to the precipitating fluids. Diagenesis has a greater impact on Sr/Ca than on δ18O; the calcite compositions reported here convert to SST anomalies of 115°C and 14°C, respectively. Based on calcite Sr/Ca compositions in this study and in the literature, the sensitivity of coral Sr/Ca-SST to vadose-zone calcite diagenesis is 1.1 to 1.5°C per percent calcite. In contrast, the rate of change in coral δ18O-SST is relatively small (−0.2 to 0.2°C per percent calcite). We show that large shifts in δ18O, reported for mid-Holocene and Last Interglacial corals with warmer than present Sr/Ca-SSTs, cannot be caused by calcite diagenesis. Low-level calcite diagenesis can be detected through X-ray diffraction techniques, thin section analysis, and high spatial resolution sampling of the coral skeleton and thus should not impede the production of accurate coral paleoclimate reconstructions.  相似文献   

5.
We tested the effectiveness of stable isotopes as recorders of physiological changes that occur during coral bleaching and recovery. Montipora capitata and Porites compressa fragments were bleached in outdoor tanks with seawater temperature raised to 30 °C (treatment corals) for one month. Additional fragments were maintained at 27 °C in separate tanks (control corals). After one month, (0 months recovery), buoyant weight was measured and a subset of fragments was frozen. Remaining fragments were returned to the reef for recovery. After 1.5, 4, and 8 months, fragments were collected, measured for buoyant weight, and frozen. Fragments were analyzed for stable carbon and oxygen isotopic compositions of the skeleton (δ13Cs; δ18Os) and nitrogen and carbon isotopic compositions of the host tissue (δ15Nh; δ13Ch) and zooxanthellae (δ15Nz; δ13Cz). δ13Cs decreased immediately after bleaching in M. capitata, but not in P. compressa. δ18Os of both species failed to record the warming event. During the remaining months of recovery, δ13Cs and δ18Os were more enriched in treatment than control corals due to decreases in calcification and metabolic fractionation during that time. Increased δ15Nh of treatment P. compressa may be due to expelled zooxanthellae during bleaching and recovery. Increased δ15Nz at 1.5 months in treatment fragments of both species reflects the increased incorporation of dissolved inorganic nitrogen to facilitate mitotic cell division and/or chl a/cell recovery. Changes in δ13Ch and δ13Cz at 1.5 months in treatment M. capitata indicated a large increase in heterotrophically acquired carbon relative to photosynthetically fixed carbon. We experimentally show that isotopes in coral skeleton, host tissue and zooxanthellae can be used to verify physiological changes during bleaching and recovery, but their use as a proxy for past bleaching events in the skeletal record is limited.  相似文献   

6.
Understanding the influence of climatic and non-climatic factors on geochemical signals in corals is critical for assessing coral-derived records of tropical climate variability. Porites microatolls form large, disk-shaped colonies constrained in their upward growth by exposure at or close to mean spring low water level, and occur on Indo-Pacific reefs. Microatolls appear suitable for paleoclimate reconstruction, however the systematics of the microatoll chemistry-climate relationship are yet to be characterized. In this study, the δ18O signal in Porites microatolls from well-flushed reef flats on Kiritimati (Christmas) Island, central Pacific was investigated for intra-coral (growth aspect and extension rate effects) and between-coral effects, and to explore the climate signal contained within their skeletons. Samples for δ18O analysis were taken from six individual transects from different positions within Porites microatoll XM22. The results show that: (1) the average standard deviation for the mean δ18O values of transects that represent the same time periods is 0.03‰, and is within measurement error for a single analysis (0.04‰); (2) the average standard deviation for time-equivalent, near-monthly samples along the transects within the same microatoll is 0.07‰ and; (3) comparison of the average δ18O values of records for different microatolls from across Kiritimati Island show only a small between-coral differences of 0.04‰ and 0.11‰ for different time periods. These differences in mean δ18O are within the range for intra- and inter-colony differences in seasonal and interannual δ18O reported for dome-shaped Porites. Based on these results, a stacked microatoll δ18O record was constructed for the period 1978-2007 for comparison with published coral δ18O records for nearby dome-shaped Porites. There is a systematic offset between the two types of records, which is probably due to variations in δ18O seawater across Kiritimati Island. Despite the offset, all records show similar amplitudes for the seasonal-cycle of δ18O, and there is a strong correlation (r = −0.71) between microatoll δ18O and local sea surface temperature (SST). The δ18O-SST slope relationship for microatolls is −0.15‰/°C, very similar to that reported for fast-growing domed corals (−0.18‰ to −0.22‰/°C). Statistical analysis of the stacked microatoll δ18O record shows that it is correlated with both local and large-scale climate variables (primarily SST) at semiannual, annual and interannual timescales. Our results show that the signal reproducibility and fidelity of skeletal δ18O in coral microatolls is comparable to that observed for more conventional coral growth forms. Longer-lived, and fossil, Porites microatolls, where they have grown in suitably flushed environments, are likely to contain δ18O signals that can significantly extend instrumental records of tropical climate variability.  相似文献   

7.
Here we calibrate the carbonate clumped isotope thermometer in modern deep-sea corals. We examined 11 specimens of three species of deep-sea corals and one species of a surface coral spanning a total range in growth temperature of 2-25 °C. External standard errors for individual measurements ranged from 0.005‰ to 0.011‰ (average: 0.0074‰) which corresponds to ∼1-2 °C. External standard errors for replicate measurements of Δ47 in corals ranged from 0.002‰ to 0.014‰ (average: 0.0072‰) which corresponds to 0.4-2.8 °C. We find that skeletal carbonate from deep-sea corals shows the same relationship of Δ47 (the measure of 13C-18O ordering) to temperature as does inorganic calcite. In contrast, the δ13 C and δ18O values of these carbonates (measured simultaneously with Δ47 for every sample) differ markedly from equilibrium with seawater; i.e., these samples exhibit pronounced ‘vital effects’ in their bulk isotopic compositions. We explore several reasons why the clumped isotope compositions of deep-sea coral skeletons exhibit no evidence of a vital effect despite having large conventional isotopic vital effects.  相似文献   

8.
Using the clumped isotope method, the temperature of dolomite and calcite formation and the oxygen isotopic composition (δ18Ow) of the diagenetic fluids have been determined in a core taken from the Arab‐D of the Ghawar field, the largest oil reservoir in the world. These analyses show that while the dolomites and limestones throughout the major zones of the reservoir recrystallized at temperatures between ca 80°C and 100°C, the carbonates near the top of the reservoir formed at significantly lower temperatures (20 to 30°C). Although the δ18O values of the diagenetic fluids show large variations ranging from ca <0‰ to ca +8‰, the variations exhibit consistent downhole changes, with the highest values being associated with the portion of the reservoir with the highest permeability and porosity. Within the limestones, dolomites and dolomites associated with the zone of high permeability, there are statistically significant different trends between the δ18Ow values and recrystallization temperature. These relationships have different intercepts suggesting that fluids with varying δ18Ow values were involved in the formation of dolomite and limestone compared to the formation of dolomite associated with the zone of high permeability. These new data obtained using the clumped isotope technique show how dolomitization and recrystallization by deep‐seated brines with elevated δ18Ow values influence the δ18O values of carbonates, possibly leading to erroneous interpretations unless temperatures can be adequately constrained.  相似文献   

9.
We compare several statistical routines that may be used to calculate δ18Osw and SSS from paired coral Sr/Ca and δ18O measurements. Typically, the δ18Ocoral-SST relationship is estimated by linear regression of coral δ18O vs. SST. If this method is applied, evidence should be given that at a particular site SST and SSS do not co-vary. In the tropical oceans, SST and δ18Osw (SSS) often co-vary, and this will bias the estimate of the regression slope of δ18Ocoral-SST. Using a stochastic model, we show that covariance leads to a bias in the coefficients of the univariate regression equations. As the slope of the δ18Ocoral-SST relationship has known, we propose to insert this value for γ1 in the regression models. This requires that the constants of the regression equations are removed. To omit the constants, we propose to center the regression equations (i.e., to remove the mean values from the variables). The statistical error propagation is calculated to assess our ability to resolve past variations in δ18Osw (SSS). At Tahiti, we find that the combined analytical uncertainties of coral δ18O and Sr/Ca equal the amplitude of the seasonal cycle of δ18Osw (SSS). Therefore, we cannot resolve the seasonal cycle of SSS at Tahiti. At Timor, the error of reconstructed δ18Osw (SSS) is lower than the magnitude of seasonal variations of δ18Osw (SSS), and the seasonal cycle of δ18Osw (SSS) can be resolved.  相似文献   

10.
The oxygen isotope signature (δ18O) of stalagmite SI3 collected from Shizi Cave in north‐east Sichuan Province provides an Asian Summer Monsoon (ASM) record in Central China for the period 54–46 ka. The SI3 δ18O record clearly shows a negative δ18O excursion centred around 49.4 ka, which was reported in Hulu Cave in East China but not identified in the speleothem records from South‐west China. As a whole, this record displays a higher coherence with the two Hulu records from East China than with the speleothem δ18O records from South‐west China, suggesting that at 54–46 ka, Central China was influenced more by the East Asian Summer Monsoon than by the Indian Summer Monsoon. It also displays a significant negative δ18O excursion at 47.5–46.6 ka, which is not clearly documented in two other speleothem δ18O records previously reported from South‐west China. This suggests that details of the Greenland interstadial 12 warrant further investigations in future in monsoonal China. The SI3 δ18O record displays more significant centennial‐scale variations than the other four speleothem δ18O records from East and South‐west China, which may be due to the fact that the study site is closer to the north‐west boundary of the ASM and more sensitive to variations of the ASM than East and South‐west China. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

11.
There has been much recent debate about Holocene climate variation in the monsoon region of China, especially the temporal pattern of variations in precipitation, the time-transgressive nature of the Holocene precipitation maximum, and the extent to which variations in regions influenced by the Indian Summer Monsoon (ISM) and the East Asian Summer Monsoon (EASM) have been synchronous. We summarize and compare carbonate oxygen-isotope records (δ18Ocarb) from ten lakes within the present-day ISM region. We discuss their paleoclimate significance considering the present-day moisture source, isotopic composition of precipitation and the hydrological setting. The δ18Ocarb records are controlled mainly by the isotopic composition of lake water, which in turn is a function of regional Precipitation/Evaporation (P/E) balance and the proportion of precipitation that is monsoon-derived. We normalized the δ18Ocarb data and used these records to generate an integrated moisture index. This index, along with oxygen-isotope records from speleothems and carbon-isotope records (δ13Corg) from peats within the monsoon region, suggests that Holocene climate was broadly synchronous across the monsoon region and, within the limits of accuracy of the existing age models, provides no strong evidence for previously-proposed anti-phasing of the ISM and the EASM. Stable-isotope records from lake sediments and peat bogs have excellent potential for providing high-quality paleoclimate data for monsoon Asia, and complement high-resolution speleothem sequences, which are only found in certain localities.  相似文献   

12.
UWE BRAND 《Sedimentology》1982,29(1):139-147
The aragonitic molluscs and lime-mud of the Pennsylvanian Buckhorn asphalt (Deese Group) of southern Oklahoma precipitated calcium carbonate in oxygen and carbon isotopic equilibrium with ambient sea-water. In addition, δ18O values indicate that the pelecypods precipitated their shells during the warmer months of the year. The coiled nautiloids probably precipitated their shells in the warm surface water and throughout the year. For the orthocone nautiloids, the δ18O values suggest that they precipitated their shells in deeper/cooler water. The low-Mg calcite brachiopods of the Mississippian Lake Valley Formation of New Mexico precipitated shells in oxygen and carbon isotopic equilibrium with ambient sea-water. The δ18O and δ13C values of the Buckhorn and Lake Valley faunas, in conjunction with other published results, suggest that Carboniferous sea-water was, on a average, depleted in δ18O by 1·5 ± 2‰, PDB, relative to Recent sea-water. However, the δ13C value of +2.6 ± 2‰, PDB, for average Carboniferous sea-water is similar to that of Recent ocean water. Early diagenetic alteration of metastable carbonates probably occurs in a meteoric-sea-water mixing zone. In this zone the oxygen and carbon isotopic compositions of these components are increased by about 2-4‰, PDB over their marine composition.  相似文献   

13.
δ18O was determined at high spatial resolution (beam diameter ∼30 μm) by secondary ion mass spectrometry (SIMS) across 1-2 year sections of 2 modern Porites lobata coral skeletons from Hawaii. We observe large (>2‰) cyclical δ18O variations that typically cover skeletal distances equivalent to periods of ∼20-30 days. These variations do not reflect seawater temperature or composition and we conclude that skeletal δ18O is principally controlled by other processes. Calcification site pH in one coral record was estimated from previous SIMS measurements of skeletal δ11B. We model predicted skeletal δ18O as a function of calcification site pH, DIC residence time at the site and DIC source (reflecting the inputs of seawater and molecular CO2 to the site). We assume that oxygen isotopic equilibration proceeds at the rates observed in seawater and that only the aqueous carbonate ion is incorporated into the precipitating aragonite. We reproduce successfully the observed skeletal δ18O range by assuming that DIC is rapidly utilised at the calcification site (within 1 h) and that ∼80% of the skeletal carbonate is derived from seawater. If carbonic anhydrase catalyses the reversible hydration of CO2 at the calcification site, then oxygen isotopic equilibration times may be substantially reduced and a larger proportion of the skeletal carbonate could be derived from molecular CO2. Seasonal skeletal δ18O variations are most pronounced in the skeleton deposited from late autumn to winter (and coincide with the high density skeletal bands) and are dampened in skeleton deposited from spring to summer. We observed no annual pattern in sea surface temperature or photosynthetically active radiation variability which could potentially correlate with the coral δ18O. At present we are unable to resolve an environmental cue to drive seasonal patterns of short term skeletal δ18O heterogeneity.  相似文献   

14.
Offsets from isotopic equilibrium in biogenic carbonates have complicated paleoclimate reconstructions for decades. A new archive of climate, deep-sea corals, is used to evaluate the calcification processes, independent of photosynthesis, that contribute to these offsets. Carbon and oxygen stable isotope data from six modern deep-sea corals show strong linear trends between δ13C and δ18O. Slopes of these trends between samples are similar and range between 1.9 to 2.6 for Δδ13C/Δδ18O. Linear trends intersect isotopic equilibrium for δ18O and are slightly depleted for δ13C. Variations in the isotopic ratios are strongly correlated with the density banding structure. Isotopically depleted aragonite is associated with light, quickly precipitating bands, whereas isotopically enriched points correspond to slowly accumulating, less dense aragonite. The densest white band at the trabecular center is furthest from isotopic equilibrium for both carbon and oxygen. Data from this region fall off the linear trend between δ18O and δ13C. This deviation, where δ13C remains constant while the δ18O continues to decrease, does not support “vital effect” mechanisms that call upon kinetic fractionation to explain offsets from isotopic equilibrium. We propose a new mechanism for vital effects in these deep-sea corals that is based on a thermodynamic response to a biologically induced pH gradient in the calcifying region.  相似文献   

15.
Laboratory experiments on the branching, symbiont-bearing coral genus Porites and Acropora have been carried out to determine the dependence of the skeletal boron isotopic composition (δ11B) on the pH of seawater. The results show a clear relationship similar to previously established empirical calibrations for planktonic foraminifera and inorganic calcite. A −0.6‰ offset exists between P. cylindrica and A. nobilis which is systematic over the pH range of 7.7-8.2. To test whether the δ11B of coral skeletons changes with physiological processes such as photosynthesis and respiration, corals were grown along a depth transect in their natural environment and under controlled conditions in the laboratory at varying light intensities and food supply. Although we also observe an isotopic offset between P. compressa and Montipora verrucosa, neither experimental treatment systematically changed the δ11B of the two species. These findings are encouraging for using the boron isotope paleo-pH proxy in corals, because it appears that seawater pH is the dominant control on the boron isotopic composition in corals.  相似文献   

16.
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17.
We investigate Pacific Decadal Oscillation (PDO) signals recorded by two bimonthly resolved coral δ18O series from La Réunion and Ifaty (West Madagascar), Indian Ocean from 1882 to 1993. To isolate the main PDO frequencies, we apply a band pass filter to the time series passing only periodicities from 16 to 28 years. We investigate the covariance patterns of the coral time series with sea surface temperature (SST) and sea level pressure (SLP) of the Indian and Pacific Oceans. In addition, the empirical orthogonal functions of the filtered SST and SLP fields (single and coupled) are related to the filtered coral times series. The covariance maps show the typical PDO pattern for SST and SLP, confirming the coupling between the Indian and Pacific Oceans. Both corals show the strongest signal in boreal summer. The La Réunion (Ifaty) coral better records SST (SLP) than SLP (SST) pattern variability. We suggest that the filtered La Réunion coral δ18O represents δ18O of seawater that varies with the South Equatorial Current, which, in turn, is linked with the SST PDO. The filtered Ifaty coral δ18O represents SST and is remotely linked with the SLP PDO variability. A combined coral record of the Ifaty and La Réunion boreal summer δ18O series explains about 64% of the variance of the coupled SST/SLP PDO time series. AGU OS06 special issue “Ocean’s role in climate change—a paleo perspective”.  相似文献   

18.
We have analyzed the stable oxygen isotopic composition of two Porites corals from the Chagos Archipelago, which is situated in the geographical center of the Indian Ocean. Coral δ18O at this site reliably records temporal variations in precipitation associated with the Intertropical Convergence Zone (ITCZ). Precipitation maxima occur in boreal winter, when the ITCZ forms a narrow band across the Indian Ocean. The Chagos then lies within the center of the ITCZ, and rainfall is strongly depleted in δ18O. A 120-yr coral isotopic record indicates an alternation of wet and dry intervals lasting 15 to 20 yr. The most recent 2 decades are dominated by interannual variability, which is tightly coupled to the El Niño-Southern Oscillation (ENSO). This is unprecedented in the 120 yr of coral record. As the ITCZ is governed by atmospheric dynamics, this provides evidence of a major change in the coupled ENSO-monsoon system.  相似文献   

19.
Geochemical and petrographic data suggest early submarine cementation of hardgrounds from the Lincolnshire Limestone Formation, Middle Jurassic, England. The three hardgrounds, from Cowthick, Castle Bytham and Leadenham quarries, developed in tidal-inlet, on-barrier and lagoonal sub-environments of a carbonate barrier-island complex. At Cowthick early composite (acicular-bladed) radial-fibrous cements, which pre-date aragonite dissolution, completely fill intergranular pore-space at the hardground surface; away from it isopachous fringing cements decrease in thickness. Microprobe analyses demonstrate zoning within the fringes with magnesium concentrations (> 2 wt % MgCO3) higher than those in allochems or later, ferroan cement (?0.5 wt % MgCO3, 1.7 wt % FeCO3). At Castle Bytham early granular isopachous cements, which post-date aragonite dissolution, occur within 5 cm of the surface. At Leadenham early lithification is superficial and represented by ferruginous crusts and micritic internal sediment. Late blocky cement fills residual pore-space in all three examples. Carbon and oxygen isotopic composition of whole-rock samples taken at intervals away from each hardground surface demonstrate the increasing proportion of late 18O depleted cements (δ18O – 8 to – 10). Early cements must have a marine isotopic composition; different δ18O values from each hardground reflect the intensity of early lithification and exclusion of late cements at the hardened surface. There is no isotopic evidence for subaerial cement precipitation during possible emergence at Castle Bytham. Oyster samples (with δ18O, – 2.9 and δ13C, 2.4) give estimated palaeotemperatures of 22–25°C. Early cements from Cowthick are enriched in 18O and 13C (δ18O = 0 δ13C ? 3‰) compared to the oyster values. In conjunction with trace element data this is interpreted as evidence for high-magnesium calcite precursor cements which underwent replacement in a system with a low water: rock ratio. The intensity of early lithification is related to depositional environment: maximum circulation of sea-water producing the most lithified hardground (Cowthick). This is directly analogous to the formation of Recent hardgrounds.  相似文献   

20.
We have used correlative analysis between mean December-January-February winter wind velocities, measured at the Xisha Meteorological Observatory (16°50′N, 112°20′E) in the middle of the South China Sea, and mean δ18O data for the corresponding month from Porites lutea coral, collected in Longwan waters (19°20′N, 110°39′E), to obtain a linear equation relating the two datasets. This winter wind velocity for the South China Sea (WMIIscs) can then be correlated to the coral δ18O by the equation WMIIscs = −1.213-1.351 δ18O (‰ PDB), r = −0.60, n = 40, P = 0.01. From this, the calculated WMIIscs-δ18O series from 1944 to 1997 tends to decrease during the 1940s to the 1960s; it increases slightly during the 1970s and then decreases again in the 1980s and 1990s. The calculated decadal mean WMIIscs-δ18O series had a obvious decrease from 5.92 to 4.63 m/s during the period of 1944-1997. The calculated yearly mean WMIIscs-δ18O value is 5.58 m/s from 1944 to 1976 and this decreases to 4.85 m/s from 1977 to 1998. That is the opposite trend to the observed yearly mean SST variation. The yearly mean SST anomaly is −0.27° from 1943 to 1976 and this increases to +0.16° from 1977 to 1998. Spectral analysis used on a 54-year-long calculated WMIIscs-δ18O series produces spectral peaks at 2.4-7 yr, which can be closely correlated with the quasibiennial oscillation band (QBO band, 2-2.4 yr) and the El Ñino southern oscillation band (ENSO band, 3-8 yr). Hence most of the variability of the winter monsoon intensity in the middle of the South China Sea is mainly constrained by changes in the thermal difference between the land and the adjoining sea area, perhaps due to global warming.  相似文献   

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