共查询到18条相似文献，搜索用时 171 毫秒
1.
采用密度泛函B3LYP理论对氟利昂C2Cl2F4 (F-114)在6-31G++(d,p)基组水平上进行分子结构优化、红外光谱计算,理论计算所得结果与实验结果基本吻合.此外又通过从头算CIS方法计算了C2Cl2F4及其离子的低激发态,将所得分子低激发态的键长、键角及二面角等参数进行了对比分析,并得到了C2Cl2F4分子的UV-Vis光谱和分子前线轨道,最后对C2Cl2F4+离子的低激发态光解离动力学进行了分析. 相似文献
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采用密度泛函（DFT） B3LYP方法在6-311G基组上优化了不同外电场作用下D-甘油酸分子的基态几何结构、电偶极矩和分子的总能量,并在此基础上利用含时密度泛函（TD-DFT）方法在相同基组下探讨了各电场情况下D-甘油酸分子前6个激发态的激发能、波长和振子强度与外电场大小的关系.结果表明：分子的几何构型在外电场F=0.003 a.u.时会发生明显的变化,当外电场强度F=0.003 a.u.时,分子总能量骤然下降,电偶极矩骤然上升,其紫外吸收峰也出现明显的红移.当电场继续增加时,上述指标重新回到正常水平,骤变消失. 相似文献
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采用基于光谱匹配的计算方法开展红外通道模拟仿真,该方法利用高光谱大气探测仪的实际观测数据来模拟气象卫星成像仪红外通道观测目标亮温.利用高光谱大气探测仪(IASI)的实际观测数据,进行了2010年2月14日12:57(UTC)、2010年2月15日00:57(UTC)、2010年5月2日12:57(UTC)MTSAT-1R卫星成像仪(JAMI)红外通道的模拟仿真.结果显示:JAMI 4个红外通道的模拟亮温与观测亮温偏差平均值的绝对值都小于1K,模拟亮温与观测亮温的相关系数都大于0.93,表明这种基于高光谱数据的方法可用于气象卫星成像仪红外通道的模拟仿真.进而利用IASI的观测数据进行了 2010年11月6个时刻FY-2E卫星成像仪(VISSR)红外通道的模拟仿真,并将通道模拟数据与GSICS定标的观测数据以及与业务定标的观测数据相比,结果表明:2010年11月期间,FY-2E卫星成像仪IR2、IR3、IR4通道的GSICS定标比业务定标有明显的改进. 相似文献
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A new two-way land-atmosphere interaction model （R42_AVIM） is fulfilled by coupling the spectral atmospheric model （SAMIL_R42L9） developed at the State Key Laboratory of Numerical Modeling for Atmospheric Sciences and Geophysical Fluid Dynamics, Institute of Atmospheric Physics, Chinese Academy of Sciences （LASG/IAP/CAS） with the land surface model, Atmosphere-Vegetation-Interaction-Model （AVIM）. In this coupled model, physical and biological components of AVIM are both included. Climate base state and land surface physical fluxes simulated by R42_AVIM are analyzed and compared with the results of R42_SSIB [which is coupled by SAMIL_R42L9 and Simplified Simple Biosphere （SSIB） models]. The results show the performance of the new model is closer to the observations. It can basically guarantee that the land surface energy budget is balanced, and can simulate June-July-August （JJA） and December-January- February （DJF） land surface air temperature, sensible heat flux, latent heat flux, precipitation, sea level pressure and other variables reasonably well. Compared with R42_SSIB, there are obvious improvements in the JJA simulations of surface air temperature and surface fluxes. Thus, this land-atmosphere coupled model will offer a good experiment platform for land-atmosphere interaction research. 相似文献
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天山西部地区冰雹云的卫星光谱特征及监测应用 总被引：2，自引：0，他引：2
针对冰雹灾害多发的新疆天山西部地区,利用2007年和2008年5一10月14次MODIS卫星过境资料,选取共计45个云系样本数,进行冰雹云、强对流云团和薄卷云的光谱特征提取和雹暴指数计算与分析。结果表明,冰雹云的热红外亮度温度（CH31、CH32、CH35）均〈240K,中红外波段反射率（CH20）相对较低〈30％,可见光和短红外波段反射率（CH1和CH6）均〉80％,雹暴指数≥0．35,得到了有利于冰雹云的卫星遥感客观判识指标。 相似文献
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基于R语言的NetCDF文件分析和可视化应用 总被引：3，自引：0，他引：3
气象领域目前有多种广泛应用的气象数据分析和可视化工具集,包括GrADS、NCL、CDO和IDL等。R语言是一种由统计学家开发的统计计算和绘图的语言和环境,具有大数据处理的能力。R语言数量众多的扩展包为R语言用于海量气象数据分析和可视化提供了强有力的支持。基于R语言对NCEP发布的数据集进行了统计分析和可视化,展示了R语言在气象数据处理和可视化方面的应用。结合R语言提供的贝叶斯统计扩展包和高性能并行计算扩展包探讨了R语言在气象数据处理和可视化应用方面的广泛前景。 相似文献
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利用MODIS资料对积雪的遥感监测 总被引：7，自引：0，他引：7
通过对遥感卫星资料中云和雪的光谱特征的分析，提出利用中分辨率成像光谱仪（MODIS）红外、可见光谱段数据进行云、雪检测和分离的方法；并提供监测实例来说明利用MODIS数据可进行积雪监测。 相似文献
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在NCEPGDAS中同化MSG和GOES资料 总被引：1，自引：0，他引：1
首次将MSG-2（Meteosat Second Generation-2）卫星上的旋转增强可见光及红外成像仪（Spin—ning Enhanced Visibleand Infrared Imager,SEVIRI）的观测资料同化到美国国家环境预报中心（Na—tional Centers for Environmental Prediction,NCEP）全球资料同化系统（globaldataassimilationsys—tern,GDAS）中。对当前的地球静止业务环境卫星（Geostationary Operational Environmental Satel—lite,GOES）成像仪资料的同化问题也进行了进一步探讨。利用CRTM（The Community Radiative Transfer Model）模式,对SEVIRI辐射率观测资料进行了模拟。为了对红外辐射率资料进行模拟,CRTM模式中的几个关键部分得到改进,例如：动态更新地面发射率资料以及采用了快速精确的气体吸收模块。为了改进对SEVIRI和GOES成像仪辐射率资料的模拟效果,采用了GSICS（The Global Space—Based Inter—Calibration System）标定订正。初步研究结果表明,包含对SEVIRI辐射率资料的水汽通道（6．25和7．35μm）和二氧化碳通道（13．40μm）的同化对GFS（Global Forecast System）6d预报具有显著的正影响;而对其他5个SEVIRI红外窗口通道资料的同化则减小了这种正影响。通过应用GSICS标定算法,订正了SEVIRI和GOES-12成像仪观测资料的偏差,提高了对GFS预报的影响。此外,还需作进一步研究来提高对SEVIRI红外窗口通道辐射率资料同化的有效性。 相似文献
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Cospectra and quadrature spectra are calculated for six pairs of tall offshore measurement masts near the Horns Rev I wind farm in the Danish North Sea and the Nysted wind farm in the Baltic sea. The mast-pairs are separated from one another by horizontal distances of 2.13–12.4 km. Cospectra and quadrature spectra for the two sites are classified in terms of the angle between the mean wind direction and the line connecting each pair of masts. The frequency axes of the spectra are normalized to remove the effect of mean wind speed and separation distance. Results indicate a larger contribution to the quadrature spectrum for flow from the sea than for flow from the land, and the patterns in the spectra are clearer and better defined for Horns Rev I (which has a long uninterrupted sea-fetch from the west) than for Nysted (which is surrounded by a more complicated coastline). The analysis is replicated based on 3-month simulations using the weather research and forecasting (WRF) numerical model with a horizontal grid spacing of 2 km. For the sea-fetch directions, good agreement in spectral properties between the model and observations is found. Analytical expressions based on the properties of the cross-correlation function and an exponentially decaying coherence function are fitted to the normalized cospectra and quadrature spectra. The expressions are shown to be a good fit to the spectra calculated from the WRF simulations and to the observed spectra for directions with a long sea-fetch, which suggests that to a good approximation, the average cospectra and quadrature spectra over the sea can be written as functions of frequency, mean wind speed, separation distance and the angle between the wind direction and the orientation of the masts. 相似文献
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文章介绍了一种比较简单实用的地球大气的光谱透过率和到达大气层顶的红外辐射率的计算模型,光谱波长从4 μm到∞ μm,吸收气体H2O、CO2、O3的吸收计算采用Elsasser带模式及其经验参数,H2O的连续吸收公式是美国LOWTRAN-6计算程序的水汽连续吸收经验公式。透过率的计算结果与LOWTRAN计算结果相一致。以这种透过率简化模型为基础,建立了辐射传递正演计算模型,开发了相应软件,并用于卫星遥感射出长波辐射的资料处理中,取得了良好结果。 相似文献
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E. Mahieu C. P. Rinsland R. Zander P. Demoulin L. Delbouille G. Roland 《Journal of Atmospheric Chemistry》1995,20(3):299-310
A set of high-resolution IR solar spectra recorded at the International Scientific Station of the Jungfraujoch, Switzerland, from 84/06 to 93/06, and at the National Solar Observatory McMath-Pierce solar telescope facility on Kitt Peak, Arizona, U.S.A. from 78/05 to 92/07 have been analyzed to determine the vertical column abundances of hydrogen cyanide, HCN, above the two stations. The analysis was based on least-squares curve fitting of calculated spectra to the observations encompassing the P4 and the P8 lines of HCN respectively located at 3299.5273 and 3287.2483 cm–1. The results obtained for the two stations indicate that no significant long-term trend affects either of the two databases; however, this analysis reveals variable increases during springtime of up to a factor of 2 in the HCN total column above the Jungfraujoch and even up to 3 above Kitt Peak. The calculated mean vertical column abundances, excluding the spring observations, are equal to (2.55±0.30)×1015 molec./cm2 (S.D.) and (2.75±0.30)×1015 molec./cm2 respectively above the Jungfraujoch and the Kitt Peak observatories. Based on a realistic volume mixing ratio profile, these columns translate into mean volume mixing ratios equal to 190×10–12 ppv at the respective altitudes of the stations. 相似文献
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FY-2和GMS-5红外通道遥感图像质量的功率谱分析 总被引：3，自引：0，他引：3
根据遥感图像功率谱的性质,对比分析了FY-2和GMS-5扫描辐射计红外通道的图像质量。计算结果表明,FY-2红外通道遥感图像功率谱各分量之和不高于GMS-5红外A通道遥感图像的功率谱各分量之和。数值模拟试验的结果表明,FY-2红外通道的图像质量大体上与GMS-5红外A通道的图像质量相当。 相似文献
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A systematic evaluation is conducted of the smoothed spectrum, which is a spectral estimate obtained by averaging over a window of contiguous frequencies. The technique is extended to the ogive, as well as to the cross-spectrum. It is shown that, combined with existing variance estimates for the periodogram, the variance—and therefore the random error—associated with these estimates can be calculated in a straightforward way. The smoothed spectra and ogives are biased estimates; with simple power-law analytical models, correction procedures are devised, as well as a global constraint that enforces Parseval’s identity. Several new results are thus obtained: (1) The analytical variance estimates compare well with the sample variance calculated for the Bartlett spectrum and the variance of the inertial subrange of the cospectrum is shown to be relatively much larger than that of the spectrum. (2) Ogives and spectra estimates with reduced bias are calculated. (3) The bias of the smoothed spectrum and ogive is shown to be negligible at the higher frequencies. (4) The ogives and spectra thus calculated have better frequency resolution than the Bartlett spectrum, with (5) gradually increasing variance and relative error towards the low frequencies. (6) Power-law identification and extraction of the rate of dissipation of turbulence kinetic energy are possible directly from the ogive. (7) The smoothed cross-spectrum is a valid inner product and therefore an acceptable candidate for coherence and spectral correlation coefficient estimation by means of the Cauchy–Schwarz inequality. The quadrature, phase function, coherence function and spectral correlation function obtained from the smoothed spectral estimates compare well with the classical ones derived from the Bartlett spectrum. 相似文献
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CHARACTERISTICS OF TURBULENCE SPECTRA IN DIFFERENT WEATHER PROCESSES UNDER UNSTABLE CONDITIONS 
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下载免费PDF全文 In this paper,the data chosen from measurements by supersonic anemometers in Tongxian County of Beijing in1990 are used to study characteristics of turbulence spectra in precipitation weather.Some turbulence parameters such asturbulence intensity,heat and momentum fluxes,friction velocity,M-O length and stability parameter are calculatedand their dependence on turbulence spectra in different stability conditions are analyzed.Some encouraging results areobtained and compared with others' results. 相似文献
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R. Zander E. Mahieu Ph. Demoulin C. P. Rinsland D. K. Weisenstein M. K. W. Ko N. D. Sze M. R. Gunson 《Journal of Atmospheric Chemistry》1994,18(2):129-148
Series of high-resolution infrared solar spectra recorded at the International Scientific Station of the Jungfraujoch, Switzerland, between 06/1986 and 11/1992, and at Kitt Peak National Observatory, Tucson, Arizona (U.S.A.), from 12/1980 to 04/1992, have been analyzed to provide a comprehensive ensemble of vertical column abundances of CHCIF2 (HCFC-22; Freon-22) above the European and the North American continents. The columns were derived from nonlinear least-squares curve fittings between synthetic spectra and the observations containing the unresolved 2v
6 Q-branch absorption of CHCIF2 at 829.05 cm–1. The changes versus time observed in these columns were modeled assuming both an exponential and a linear increase with time. The exponential rates of increase at one-sigma uncertainties were found equal to (7.0±0.35)%/yr for the Junfraujoch data and (7.0±0.23)%/yr for the Kitt Peak data. The exponential trend of 7.0%/yr found at both stations widely separated in location can be considered as representative of the global increase of the CHCIF2 burden in the Earth's atmosphere during the period 1980 to 1992. When assuming two realistic vertical volume mixing ratio profiles for CHCIF2 in the troposphere, one quasi constant and the other decreasing by about 13% from the ground to the tropopause, the concentrations for mid-1990 were found to lie between 97 and 111 pptv (parts per trillion by volume) at the 3.58 km altitude of the Jungfraujoch and between 97 and 103 pptv at Kitt Peak, 2.09 km above sea level. Corresponding values derived from calculations using a high vertical resolution-2D model and recently compiled HCFC-22 releases to the atmosphere, were equal to 107 and 105 pptv, respectively, in excellent agreement with the measurements. The model calculated lifetime of CHCIF2 was found equal to 15.6 years. The present results are compared critically with similar data found in the literature. On average, the concentrations found here are lower by 15–20% than those derived from in situ investigations; this difference cannot be explained by the absolute uncertainty of ±11% assigned presently to the infrared remote measurements. 相似文献
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CHARACTERISTICS OF TURBULENCE SPECTRA IN DIFFERENT WEATHER PROCESSES UNDER UNSTABLE CONDITIONS* 下载免费PDF全文
下载免费PDF全文 In this paper,the data chosen from measurements by supersonic anemometers in Tongxian County of Beijing in 1990 are used to study characteristics of turbulence spectra in precipitation weather.Some turbulence parameters such as turbulence intensity,heat and momentum fluxes,friction velocity,M-O length and stability parameter are calculated and their dependence on turbulence spectra in different stability conditions are analyzed.Some encouraging results are obtained and compared with others' results. 相似文献