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1.
Four bacterial isolates (two resistant and two sensitive to chromium) were isolated from soil contaminated with tannery effluents at Jajmau (Kanpur), India, and were identified by 16S rDNA gene sequencing as Stenotrophomonas maltophilia, Exiguobacterium sp., Pantoea sp., and Aeromonas sp. Biosorption of chromium by dried and living biomasses was determined in the resistant and sensitive isolates. The effect of pH, initial metal concentration, and contact time on biosorption was studied. At pH 2.5 the living biomass of chromium resistant isolate Exiguobacterium sp. ZM‐2 biosorbed maximum amount of Cr6+ (29.8 mg/g) whereas the dried biomass of this isolate biosorbed 20.1 mg/g at an initial concentration of 100 mg/L. In case of chromate sensitive isolates, much difference was not observed in biosorption capacities between their dried and living biomasses. The maximum biosorption of Cr3+ was observed at pH 4.5. However, biosorption was identical in resistant and sensitive isolates. The data on chromium biosorption were analyzed using Langmuir and Freundlich isotherm model. The biosorption data of Cr6+ and Cr3+ from aqueous solution were better fitted in Langmuir isotherm model compared to Freundlich isotherm model. Metal recovery through desorption was observed better with dried biomasses compared to the living biomasses for both types of chromium ions. Bioaccumulation of chromate was found higher in chromate resistant isolates compared to the chromate sensitive isolates. Transmission electron microscopy confirmed the accumulation of chromium in cytoplasm in the resistant isolates.  相似文献   

2.
Cryoturbated Upper Chalk is a dichotomous porous medium wherein the intra‐fragment porosity provides water storage and the inter‐fragment porosity provides potential pathways for relatively rapid flow near saturation. Chloride tracer movement through 43 cm long and 45 cm diameter undisturbed chalk columns was studied at water application rates of 0·3, 1·0, and 1·5 cm h?1. Microscale heterogeneity in effluent was recorded using a grid collection system consisting of 98 funnel‐shaped cells each 3·5 cm in diameter. The total porosity of the columns was 0·47 ± 0·02 m3 m?3, approximately 13% of pores were ≥ 15 µm diameter, and the saturated hydraulic conductivity was 12·66 ± 1·31 m day?1. Although the column remained unsaturated during the leaching even at all application rates, proportionate flow through macropores increased as the application rate decreased. The number of dry cells (with 0 ml of effluent) increased as application rate decreased. Half of the leachate was collected from 15, 19 and 22 cells at 0·3, 1·0, 1·5 cm h?1 application rates respectively. Similar breakthrough curves (BTCs) were obtained at all three application rates when plotted as a function of cumulative drainage, but they were distinctly different when plotted as a function of time. The BTCs indicate that the columns have similar drainage requirement irrespective of application rates, as the rise to the maxima (C/Co) is almost similar. However, the time required to achieve that leaching requirement varies with application rates, and residence time was less in the case of a higher application rate. A two‐region convection–dispersion model was used to describe the BTCs and fitted well (r2 = 0·97–0·99). There was a linear relationship between dispersion coefficient and pore water velocity (correlation coefficient r = 0·95). The results demonstrate the microscale heterogeneity of hydrodynamic properties in the Upper Chalk. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

3.
To study contaminant transport in groundwater, an essential requirement is robust and accurate estimation of the transport parameters such as dispersion coefficient. The commonly used inverse error function method (IEFM) may cause unacceptable errors in dispersion coefficient estimation using the breakthrough curves (BTCs) data. We prove that the random error in the measured concentrations, which might be described by a normal distribution, would no longer follow the normal distribution after the IEFM transformation. In this study, we proposed a new method using the weighted least squares method (WLSM) to estimate the dispersion coefficient and velocity of groundwater. The weights were calculated based on the slope of the observed BTCs. We tested the new method against other methods such as genetic algorithm and CXTFIT program and found great agreement. This new method acknowledged different characteristics of solute transport at early, intermediate, and late time stages and divided BTCs into three sections for analysis. The developed method was applied to interpret three column tracer experiments by introducing continuous, constant‐concentration of sodium chloride (NaCl) into columns filled with sand, gravel, and sand‐gravel media. This study showed that IEFM performed well only when the observed data points were located in the linear (intermediate time) section of BTCs; it performed poorly when data points were in the early and late time stages. The new WLSM method, however, performed well for data points scattering over the entire BTCs and appeared promising in parameter estimation for solute transport in a column.  相似文献   

4.
Sorptive removal of Ni(II) from electroplating rinse wastewaters by cation exchange resin Dueolite C 20 was investigated at the temperature of 30°C under dynamic conditions in a packed bed. The effects of sorbent bed length 0.1–0.2 m, fixed flow rate 6 dm3 min?1, and the initial rinse water concentration (C0) 53.1 mg L?1 on the sorption characteristics of Dueolite C 20 were investigated at an influent pH of 6.5. More than 94.5% of Ni(II) was removed in the column experiments. The column performance was improved with increasing bed height and decreasing the flow rate. The Thomas, Yoon–Nelson, Clark, and Wolborska models were applied to the experimental data to represent the breakthrough curves and determine the characteristic design parameters of the column. The sorption performance of the Ni(II) ions through columns could be well described by the Thomas, Yoon–Nelson, and Wolborska models at effluent‐to‐influent concentration ratios (C/C0) >0.03 and <0.99. Among the all models, the Clark model showed the least average percentage time deviation. The sorptive capacity of electroplating rinse water using Ni(II) was found to be 45.98 mg g?1.  相似文献   

5.
Solute transport experiments using a non-reactive tracer were conducted on short, undisturbed, saturated columns of a sandy loam soil. All columns, 20 cm in diameter and 20 cm long, were collected along a transect of 35 m. Most of the soil columns had pre-existing macropores. The columns were leached at a steady flow-rate under ponding conditions. The resulting breakthrough curves (BTCs) showed a large heterogeneity. Several of the BTCs displayed early breakthrough and long tailing. All the data were interpreted in terms of dimensional time moments, the classical convection-dispersion equation (CDE) and the mobile-immobile transport model (MIM). Experimental time moments were found to vary significantly among the different BTCs. Analysis of the time moments also revealed that the variance of the field-scale BTC was several times larger than the average of the local-scale variance. The pore water velocity v and dispersion coefficient D were obtained by fitting the CDE to the local-scale BTCs, resulting in an average dispersivity of 7·4 cm. Frequency distributions for the CDE parameters v and D were equally well described by a normal or log-normal probability density function (pdf). When a log-normal pdf for D is considered, the variance of the loge transformed D values (σln D2) was found to be 2·1. For the MIM model, two additional parameters were fitted: the fraction of mobile water, θm/θ, and the first-order mass transfer coefficient, α. The MIM was more successful in describing the data than the CDE transport model. For the MIM model, the average dispersivity was about 2 cm. The MIM parameters v, D and θm/θ were best described by a log-normal pdf rather than a normal pdf. Only the parameter α was better described by a normal pdf. Mobile water fractions, θm/θ ranged from 0·01 to 0·98, with a mean of 0·43 (based on a log-normal pdf). When the CDE and MIM were applied to the data, the fitted pore water velocities, v, compared favourably with the effective pore water velocities, veff, obtained from moment analysis.  相似文献   

6.
Hydrocarbon compounds in aquifers are generally known to show a retardation effect due to sorption onto the surfaces of solid particles. In this study, we investigated the effect of sorption on the transport of benzene in sandy aquifer materials by conducting batch and column tests for both sandy aquifer materials and sandy materials to which had been added 0·5% powdered activated carbon. The batch test was conducted by equilibrating dry materials with benzene solutions of various initial concentrations, and by analysing the concentrations of benzene in the initial and equilibrated solutions using high‐performance liquid chromatography (HPLC). The column test was performed to monitor the concentrations of effluent versus time, known as a breakthrough curve (BTC). We injected KCl and benzene solutions as tracers into the inlet boundary as two different types of square pulse and step, and monitored the effluent concentrations at the exit boundary under a steady‐state condition using an electrical conductivity meter and HPLC. Simulation of benzene transport was performed using the convective–dispersive equation model with the distribution coefficients obtained from the batch test and the transport parameters of the conservative solute KCl from the column test. The observed BTCs of KCl and benzene for pulse injection showed that the arrival times of the peaks of both tracers coincided well, but the relative peak concentration of benzene was much lower than that of KCl. Comparison of the simulated and observed BTCs showed a great discrepancy for all cases of injection mode and material texture, indicating the absence of retardation effect. These results reveal that the predominant process affecting the benzene transport in the sandy aquifer materials is an irreversible sorption rather than retardation. This tentative conclusion was verified by simulation of benzene transport using an irreversible sorption parameter that led to a good agreement between the simulated and observed BTCs. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   

7.
One-dimensional flow experiments on biological clogging were carried out by biostimulating columns packed with glass beads, sterilized, and inoculated with toluene-utilizing bacteria. Biostimulation consisted of continuously injecting toluene at four concentrations (3.0 ± 0.9, 6.1 ± 0.8, 8.7 ± 1.6, and 11.3 ± 0.8 mg/L). The results of column flow experiments indicated that a threshold concentration of toluene exists below which the total biomass in the column can be kept at a steady-state level. The column cores were extruded and segmented to determine the biomass distribution throughout the column at clogging. Clogging resulted in a significant buildup of filamentous bacteria close to the inlet end. Based on the nucleotide sequence of 16S rRNA genes, the dominant filamentous bacteria were identified as Nocardia farcinica. A 235-d column experiment demonstrated that the clogging near injection points can be controlled by keeping the influent concentration of toluene below the threshold.  相似文献   

8.
Trivalent chromium in the form of basic chromium sulfate (BCS) is used for tanning hides/skins and is a strong pollutant of the soil and water bodies. Significant quantities of unutilized chemicals, such as sulfates, chlorides, are also discharged, contributing to high levels of total dissolved solids (TDS), biochemical oxygen demand (BOD), chemical oxygen demand (COD), etc. Though many treatment techniques are being practiced, biotechnological methods are gaining importance. Biosorption is recognized as a cost‐effective technology worldwide; one potential sorbent being blue–green algae (BGA), for treating metal‐bearing effluents. This work studies the feasibility of using a species each of Spirulina, Oscillatoria, and Synechocystis, individually and as a consortium, as sorbents to remove Cr3+ from a segregated stream, viz. exhaust chrome liquor (ECL) and synthetic BCS solution. The species studied were found to be effective in removing Cr3+ considerably at varying concentrations, besides reducing sulfates, BOD, COD, etc. The results of ECL experiments were more encouraging than those for BCS solution. The kinetic data on Cr3+ sorption onto algal biomass fit well into the pseudo‐second order model. The equilibrium data were analyzed using the classic Langmuir and Freundlich isotherm models, yielding good fits. The results of the experiments indicate that algal consortia could be good alternatives to the conventional treatment methods for leather and other industrial wastewaters containing chromium.  相似文献   

9.
This study simulates how spatial variations in particle‐size emissions from a playa affect bulk and size‐resolved dust concentration profiles during two contrasting wind erosion events (a small local and a large regional event) in the Channel Country, Lake Eyre Basin, Australia. The regional event had higher dust concentration as a result of stronger frontal winds and higher erodibility across the playa. For each event, two emission scenarios are simulated to determine if measured size‐resolved dust concentration profiles can be explained by spatial variability in source area emissions. The first scenario assumes that particle‐size emissions from source areas occur at a uniform rate, while the second scenario assumes that particle‐size emissions vary between and within source areas. The uniform emission scenario, reproduced measured bulk dust concentration profiles (R2 = 0·93 regional and R2 = 0·81 local), however simulated size‐resolved dust concentration profiles had poor statistical fits to measured size‐resolved profiles for each size class (the highest were R2 = 0·5 regional and R2 = 0·3 local). For the differential particle‐size emission scenario, the fit to the measured bulk dust concentration profiles is improved (R2 = 0·97 regional and R2 = 0·83 local). However, the fit to the size‐resolved profiles improved dramatically, with the lowest being R2 = 0·89 (regional) and R2 = 0·80 (local). Particle‐size emission models should therefore be tested against both bulk and size‐resolved dust concentration profiles, since if only bulk dust concentration profiles are used model performance may be over‐stated. As the source areas in the first 90 m upwind of the tower were similar for both events, the percentage contributions of each particle‐size class to total emissions can be compared. The contribution of each particle‐size class was similar even though the wind speed, turbulence and dust concentrations were significantly different; suggesting that the contribution of each particle‐size to the total emitted dusts is not related to wind speed and turbulence. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

10.
莼菜(Brasenia schreberi)冬芽对Cr6+污染的抗性反应   总被引：3，自引：0，他引：3  
研究了Cr^6 污染对Shun菜冬芽外部形态及过氧化物酶、硝酸还原酶活性,叶绿素、O^-2、MDA的含量等生理指标的影响,结果显示：Cr^6 对Shun菜毒害机制在于 制酶活性和损害细胞膜系统,在培养第三天时叶绿素的含量随着Cr^6 浓度的增加而降低;过化物酶的活性在10mg/L中最高;硝酸还原酶活性除在5mg/L中的略微升高外,在10－40mg/L之间随着Cr^6 培养浓度的升高而降低;O^-2的含量在5mg/L中的最高,在10mg/L中略高于对照,在随后培养中承学度的升高而降低,MDA的含量变化趋势和O^-2相似。  相似文献   

11.
The performance of a constructed wetland for wastewater treatment was examined for four months (December 1995 to March 1996). The study area, hereby referred to as the Splash wetland, is approximately 0·5 ha, and is located in the southern part of Nairobi city. Splash wetland continuously receives domestic sewage from two busy restaurants. Treated wastewater is recycled for re‐use for various purposes in the restaurants. Both wet and dry season data were analysed with a view of determining the impact of seasonal variation on the system performance. The physical and chemical properties of water were measured at a common intake and at series of seven other points established along the wetland gradient and at the outlet where the water is collected and pumped for re‐use at the restaurants. The physico‐chemical characteristics of the wastewater changed significantly as the wastewater flowed through the respective wetland cells. A comparison of wastewater influent versus the effluent from the wetland revealed the system's apparent success in water treatment, especially in pH modification, removal of suspended solids, organic load and nutrients mean influent pH = 5·7 ± 0·5, mean effluent pH 7·7 ± 0·3; mean influent BOD5 = 1603·0 ± 397·6 mg/l, mean effluent BOD5 = 15·1 ± 2·5 mg/l; mean influent COD = 3749·8 ± 206·8 mg/l, mean effluent COD = 95·6 ± 7·2 mg/l; mean influent TSS = 195·4 ± 58·7 mg/l, mean effluent TSS = 4·7 ± 1·9 mg/l. As the wastewater flowed through the wetland system dissolved free and saline ammonia, NH4+, decreased from 14·6 ± 4·1 mg/l to undetectable levels at the outlet. Dissolved oxygen increased progressively through the wetland system. Analysis of the data available did not reveal temporal variation in the system's performance. However, significant spatial variation was evident as the wetland removed most of the common pollutants and considerably improved the quality of the water, making it safe for re‐use at the restaurants. Copyright © 2001 John Wiley & Sons, Ltd.  相似文献   

12.
Large laboratory columns (15.2 cm diameter, 183 cm long) were fed with groundwater containing trichloroethylene (TCE), were biostimulated and bioaugmented, and were monitored for over 7.5 years. The objective of the study was to observe how the selection of the carbon and energy source, i.e., whey, Newman Zone® standard surfactant emulsified oil and Newman Zone nonionic surfactant emulsified oil, affected the rate and extent of dechlorination. Column effluent was monitored for TCE and its degradation products, redox indicators (nitrate‐N, Fe(II), sulfate), and changes in iron mineralogy. Total bacteria and Dehalococcoides mccartyi strains were quantified using q‐PCR. Complete dechlorination was only observed in the whey treated columns, occurring 1 year after bioaugmentation with addition of a culture known to dechlorinate TCE to ethene, and 3 years later in the non‐bioaugmented column. The addition of the emulsified oils with or without bioaugmentation resulted in dechlorination only through cis‐DCE and vinyl chloride. While Dehalococcoides mccartyi strains are the only known bacteria that can fully dechlorinate TCE, their presence, either natural or augmented, was not the sole determiner of complete dechlorination. The establishment of a supporting microbial community and biogeochemistry that developed with continuous feeding of whey, in addition to the presence of D. mccartyi, were necessary to support complete reductive dechlorination. Results confirm that careful selection of a biostimulant is critical to the success of TCE dechlorination in complex soil environments.  相似文献   

13.
Surface waters associated with peatlands, supersaturated with CO2 and CH4 with respect to the atmosphere, act as important pathways linking a large and potentially unstable global repository of C to the atmosphere. Understanding the drivers and mechanisms which control C release from peatland systems to the atmosphere will contribute to better management and modelling of terrestrial C pools. We used non‐dispersive infra‐red (NDIR) CO2 sensors to continuously measure gas concentrations in a beaver pond at Mer Bleue peatland (Canada); measurements were made between July and August 2007. Concentrations of CO2 in the surface water (10 cm) reached 13 mg C l?1 (epCO2 72), and 26 mg C l?1 (epCO2 133) at depth (60 cm). The study also showed large diurnal fluctuations in dissolved CO2 which ranged in amplitude from ～1·6 mg C l?1 at 10 cm to ～0·2 mg C l?1 at 60 cm depth. CH4 concentration and supersaturation (epCH4) measured using headspace analysis averaged 1·47 mg C l?1 and 3252, respectively; diurnal cycling was also evident in CH4 concentrations. Mean estimated evasion rates of CO2 and CH4 over the summer period were 44·92 ± 7·86 and 0·44 ± 0·25 µg C m?2s?1, respectively. Open water at Mer Bleue is a significant summer hotspot for greenhouse gas emissions within the catchment. Our results suggest that CO2 concentrations during the summer in beaver ponds at Mer Bleue are strongly influenced by biological processes within the water column involving aquatic plants and algae (in situ photosynthesis and respiration). In terms of carbon cycling, soil‐stream connectivity at this time of year is therefore relatively weak. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   

14.
Excessive terrestrial nutrient loadings adversely impact coral reefs by primarily enhancing growth of macroalgae, potentially leading to a phase‐shift phenomenon. Hydrological processes and other spatial and temporal factors affecting nutrient discharge must be examined to be able to formulate effective measures for reducing nutrient export to adjacent reefs. During storm events and baseflow periods, water samples were obtained from the tropical Todoroki River, which drains an intensively agricultural watershed into Shiraho coral reef. In situ nutrient analyzers were deployed for 6 months to hourly measure dissolved nutrient (NO3−‐N and PO43−‐P) concentrations. Total phosphorus (TP) and suspended solid concentration (TSS) were increased by higher rainfall intensity (r = 0·94, p < 0·01) and river discharge Q (r = 0·88, p < 0·01). In contrast, NO3−‐N concentration tends to decrease drastically (e.g. from 3 to 1 mg l−1) during flood events. When base flow starts to dominate afterwards, NO3−‐N manifested an increasing trend, but decreases when baseflow discharge becomes low. This counter‐clockwise hysteresis for NO3−‐N highlights the significant influence of groundwater discharge. N delivery can therefore be considered a persistent process compared to sediment and P discharge, which are highly episodic in nature. Based on GIS analysis, nutrient concentration along the Todoroki River was largely affected by the percentage of sugarcane/bare areas and bedrock type. The spatial distribution of N concentration in the river reflects the considerable influence of subsurface geology—higher N levels in limestone‐dominated areas. P concentrations were directly related to the total length of artificial drainage, which enhances sediment transport. The use of high‐resolution monitoring data coupled with GIS‐based spatial analysis therefore enabled the clarification of control factors and the difference in the spatio‐temporal discharge characteristics between N and P. Thus, although erosion‐reduction schemes would reduce P discharge, other approaches (e.g. minimize fertilizer) are needed to reduce N discharge. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

15.
Retardation of organic contaminants in natural fractures in chalk   总被引：1，自引：0，他引：1  
Transport of a conservative compound and two sorbing compounds through fractured chalk was studied using flow-through columns consisting of chalk cores with a single subvertical fracture. Two types of chalk matrix were compared, an oxidized white chalk with low organic carbon content (0.2%), and a gray chalk with a higher organic carbon content (1.3%). Initial rapid breakthrough followed by a delayed approach to a relative concentration of unity for the conservative compound (2,6–difluorobenzoic acid [DFBA]) was clear evidence for diffusion into the porous chalk matrix. Matrix diffusion of DFBA was apparently much greater in the gray chalk columns than in the white chalk columns. Breakthrough curves (BTCs) of the sorbing compounds (2,4,6–tri-bromophenol [TBP] and ametryn [AME]) were retarded in all cases as compared to the conservative compound. Sorption retardation was far greater in the gray chalk as compared with the white chalk, in good agreement with results from batch sorption experiments. BTCs for the conservative compound were relatively nonhysteretic for both white and gray chalk columns. In contrast, BTCs for the sorbing compounds were hysteretic in all cases, demonstrating that sorption was not at equilibrium before desorp-tion began. These experiments suggest that on a field scale, transport of contaminants through fractures in chalk and other fractured porous media will be attenuated by diffusion and sorption into the matrix.  相似文献   

16.
Batch and continuous flow adsorption experiments are carried out and the design of a full‐scale facility for removing dissolved natural organic matter (DNOM) from Catalan Lakewater is demonstrated. The adsorption efficiency is proportional to the temperature and the amount of adsorbent unlike pH increase. The highest DNOM removal rate is obtained at 35 °C, pH 4, and an adsorbent amount of 0.8 g L?1. Optimum contact time for batch studies is 60 min at equilibrium. Correlation constants (r) of Langmuir and Freundlich isotherms are 0.8905 and 0.9739, respectively. Based on the Freundlich isotherm, the highest adsorption capacity (qmax) obtained is 2.44 and 6.01 mg DNOM/g granulated activated carbon (GAC) for raw and enriched water, respectively. Consequently, the effects of adsorbent amount, bed depth, empty bed contact time, and organic loading on removal performance are investigated in the rapid small‐scale column test (RSSCT) columns. The targeted effluent concentration of 1 mg DNOM/L can easily be achieved in the columns. At the design capacity of the facility, 15 adsorption columns with dimensions of 7 m height, 4.33 m diameter, and 22 days of operation cycle are required to remove DNOM from raw water.  相似文献   

17.
Z. Shi  H. J. Zhou 《水文研究》2004,18(15):2877-2892
Theoretical and experimental studies were undertaken to gain insight into physical parameters controlling the flocculation and settling properties of mud flocs in the Changjiang Estuary, China. The Rouse equation is applied to vertical profiles of suspended sediment concentration to determine the bulk mean settling velocity (ws) of sediment suspended in the Changjiang Estuary. Both in situ point‐sampled and acoustically measured profiles of suspended mud concentrations were fit selectively. The calculated settling velocities ws mainly ranged from 0·4 to 4·1 mm s?1 for the point‐sampled data set, and from 1·0 to 3·0 mm s?1 for the acoustically measured data set. Furthermore, the settling velocities of mud flocs increased with mean concentration (C?) of mud flocs in suspension and were proportional to increasing bottom shear stress (τb) of tidal flow. The best equation for the field settling velocity of mud flocs in the Changjiang Estuary can be expressed by the power law: ws = mC?n (m, 1·14–2·37; n, 0·84–1·03). It is suggested that C? and τb were the dominant physical parameters controlling the flocculation and ws of mud flocs in suspension. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

18.
Measurements of sap flow, meteorological parameters, soil water content and tension were made for 4 months in a young cashew (Anacardium occidentale L.) plantation during the 2002 rainy season in Ejura, Ghana. This experiment was part of a sustainable water management project in West Africa. The Granier system was used to measure half‐hourly whole‐tree sap flow. Weather variables were observed with an automatic weather station, whereas soil moisture and tension were measured with a Delta‐T profile probe and tensiometers respectively. Clearness index (CI), a measure of the sky condition, was significantly correlated with tree transpiration (r2 = 0·73) and potential evaporation (r2 = 0·86). Both diurnal and daily stomata conductance were poorly correlated with the climatic variables. Estimated daily canopy conductance gc ranged from 4·0 to 21·2 mm s−1, with a mean value of 8·0 ± 3·3 mm s−1. Water flux variation was related to a range of environmental variables: soil water content, air temperature, solar radiation, relative humidity and vapour pressure deficit. Linear and non‐linear regression models, as well as a modified Priestley–Taylor formula, were fitted with transpiration, and the well‐correlated variables, using half‐hourly measurements. Measured and predicted transpiration using these regression models were in good agreement, with r2 ranging from 0·71 to 0·84. The computed measure of accuracy δ indicated that a non‐linear model is better than its corresponding linear one. Furthermore, solar radiation, CI, clouds and rain were found to influence tree water flux. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

19.
Here we characterize the nutrient content in the outflow of the Green Lake 5 rock glacier, located in the Green Lakes Valley of the Colorado Front Range. Dissolved organic carbon (DOC) was present in all samples with a mean concentration of 0·85 mg L?1 . A one‐way analysis of variance test shows no statistical difference in DOC amounts among surface waters (p = 0·42). Average nitrate concentrations were 69 µmoles L?1 in the outflow of the rock glacier, compared to 7 µmoles L?1 in snow and 25 µmoles L?1 in rain. Nitrate concentrations from the rock glacier generally increased with time, with maximum concentrations of 135 µmoles L?1 in October, among the highest nitrate concentrations reported for high‐elevation surface waters. These high nitrate concentrations appear to be characteristic of rock glacier outflow in the Rocky Mountains, as a paired‐difference t‐test shows that nitrate concentrations from the outflow of 7 additional rock glaciers were significantly greater compared to their reference streams (p = 0·003). End‐member mixing analysis suggest that snow was the dominant source of nitrate in June, ‘soil’ solution was the dominant nitrate source in July, and base flow was the dominant source in September. Fluoresence index values and PARAFAC analyses of dissolved organic matter (DOM) are also consistent with a switch from terrestrial DOM in the summer time period to an increasing aquatic‐like microbial source during the autumn months. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

20.
Hydrological processes of lowland watersheds of the southern USA are not well understood compared to a hilly landscape due to their unique topography, soil compositions, and climate. This study describes the seasonal relationships between rainfall patterns and runoff (sum of storm flow and base flow) using 13 years (1964–1976) of rainfall and stream flow data for a low‐gradient, third‐order forested watershed. It was hypothesized that runoff–rainfall ratios (R/P) are smaller during the dry periods (summer and fall) and greater during the wet periods (winter and spring). We found a large seasonal variability in event R/P potentially due to differences in forest evapotranspiration that affected seasonal soil moisture conditions. Linear regression analysis results revealed a significant relationship between rainfall and runoff for wet (r2 = 0·68; p < 0·01) and dry (r2 = 0·19; p = 0·02) periods. Rainfall‐runoff relationships based on a 5‐day antecedent precipitation index (API) showed significant (r2 = 0·39; p < 0·01) correspondence for wet but not (r2 = 0·02; p = 0·56) for dry conditions. The same was true for rainfall‐runoff relationships based on 30‐day API (r2 = 0·39; p < 0·01 for wet and r2 = 0·00; p = 0·79 for dry). Stepwise regression analyses suggested that runoff was controlled mainly by rainfall amount and initial soil moisture conditions as represented by the initial flow rate of a storm event. Mean event R/P were higher for the wet period (R/P = 0·33), and the wet antecedent soil moisture condition based on 5‐day (R/P = 0·25) and 30‐day (R/P = 0·26) prior API than those for the dry period conditions. This study suggests that soil water status, i.e. antecedent soil moisture and groundwater table level, is important besides the rainfall to seasonal runoff generation in the coastal plain region with shallow soil argillic horizons. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

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