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《International Journal of Coal Geology》1988,10(4):361-382
The coal deposit of Tibita is located 90 km NNE of Bogotá and is part of the more than 600-km-long coal belt of Colombia's East Cordillera. There are up to 10 mineable coal seams of around 1 m thickness each within the Upper Cretaceous/Early Tertiary Guaduas formation. The coal measures were folded during the Andean orogeny and were preserved in SW-NE-extending synclines. Despite its low rank (35–45% VM) some of the coal possesses good coking properties. The exinite-poor coal shows a number of petrographic pecularities. It largely consists of the rare microlithotype vitrinertite and is lacking in durite and clarodurite. Macroscopically, the coal is mostly homogeneous. Two major lithotypes are described here, i.e. layered and unlayered coal. It was by means of microlithotype analysis, that whole-seam-sample sequences of several boreholes could be correlated successfully. Thus coal reserves could be reliably estimated. 相似文献
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Dams constructed on the seismically active regions have a high-risk potential for downstream life and property. Strong ground
motion can result in instability of the dam and strength loss of foundation. Active faults within the foundation of dam have
the potential to cause damaging displacement of the structures. Appropriate design measures should be considered to obtain
rational solution to the problem of catastrophic release of water from the reservoir, and especially to resist earthquake
loads. Safety concerns for dams under the earthquake loads involve the seismic hazard evaluation of dam site for the overall
stability of structure. Various types of analyses can be used, ranging from a simplified analysis to more complex procedures
based on ground motion parameters and response spectra. This paper briefly evaluates seismic hazard analyses for dam structures,
and introduces the analyses for thirty-six dams with height ranging from 15 to 195 m in Kızılırmak basin, Turkey. The seismic
hazard analyses have indicated that peak ground acceleration varies within a wide range (0.09–0.45 g) for the dam sites of
the basin. 相似文献
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The K?rka borate deposit was deposited in a Miocene lacustrine basin which is closely associated with volcanic activity which lasted from Paleogene to the beginning of Quaternary. Borate mineralization alternates with claystone, mudstone, tuff and fine-layered limestone and mostly shows a lenticular structure. The mineral paragenesis is composed of borax, tincalconite, ulexite, kurnakovite, probertite, tunellite, colemanite, dolomite, smectite group minerals, illite and some firstly reported minerals for the K?rka deposit including hydrochloroborite, brianroulstonite, hilgardite-4M and searlesite minerals. In comparison to average values of earth crust, concentrations of Cs, Sr, Li, As and Se were significantly enriched with respective rates of 21, 15, 14, 3 and 188 folds. Regarding KY, KS1 and KS2 locations, there are differences in both element abundances and their geochemical tendencies which are attributed to variations in discharge regime and physico-chemical conditions of the depositional environment. Independent behaviour of B2O3 might indicate that boron is not associated with clays and carbonates and, therefore, most part of boron must be derived from volcanic activity (hydrothermal solutions, gases). REE data indicate that the K?rka borate deposit was formed in a sedimentary environment where highly alkaline (high pH) hydrothermal solutions also took part in borate precipitation process. 相似文献
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Inductively coupled plasma mass spectrometry, inductively coupled plasma optical emission spectroscopy, hydride generation-atomic fluorescence spectrometry, emission spectrometry, X fluorescence spectrometry, and X-ray diffraction were employed to study the geochemistry and mineralogy of coal gangues from Nos. 2, 3, and 8 coal seams of the Du’erping coal mine, Xishan coalfield, Taiyuan, Shanxi Province. The study revealed that compared with the sedimentary cover, upper continent crust, Carboniferous-Permian coal from North China, as well as most coal in China, coal gangues from Nos. 2 and 3 coal seams are rich in Li, Be, Sc, Cr, Cu, Ga, Ba, Th, Nb, Cd, Pb, Ta and rare-earth elements, and coal gangues from No. 8 coal seam are rich in Li, Sc, V, Cr, Ga, U, and rare-earth elements. Compared with the Carboniferous-Permian coal from North China and most coal in China, coal gangues from Nos. 2, 3 and 8 seams are rich in Rb, V, Cs and Sr. Therefore, The Du’erping coal gangues in the Xishan coalfield are rich in most hazardous trace elements and rare-earth elements, wherein the contents of Ga and Li reach the industrial grade and have significance for industrial utilization. On the whole, coal gangues of the Shanxi Formation from the Permian are rich in more trace elements than those of the Carboniferous Taiyuan Formation. The distributions of REE show obviously dipping rightwards with negative Eu anomalies. The contents of rare-earth elements in the three seams are quite different. All of the above indicate that the source of the rare-earth elements is terrigenous debris. Minerals in No. 2 seam identified by X-ray diffraction mainly include quartz, kaolinite, in addition to calcite, pyrite, apatite, epidote, and epsomite. No. 3 seam mainly contains quartz, kaolinite, in addition to a small amount of sodium feldspar, calcium nitrate, iron ore, gypsum, and vivianite. No. 8 seam mainly contains kaolinite, dickite, quartz, illite, and a small amount of hematite and U. The correlations between major elements and trace elements in coal gangues of the Du’erping coal mine analyzed by using SPSS (Statistical Product and Service Solutions) indicate that the trace alkali elements and rare-earth elements occur mainly in such clay minerals as kaolinite. 相似文献
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The research area that is in the north of Istanbul (Turkey) and it is a land of open pit coal mining residuals reclaimed and turned to forest in 1988–1989. The materials that are open pit mine spoils are formed by sandy loam, sandy clay loam, heavy loam and clay (noncalcareous Pliocene I sediments). Pseudoacacia (Robinia pseudoacacia), Maritima Pine (Pinus pinaster) and Stone Pine (Pinus pinea) are planted on these materials. The aims of this research were to determine the strength of the material provided by tree roots and evaluate the performance of the forestation practices at lands especially where open pit coal mining spoil (residual) materials piled up. The research has been performed at two stages. The first one was hydro-mechanical effect concerned about material moisture depletion as a result of transpiration and the second one was bio-mechanical effects due to strength parameters of the roots and their growth pattern within the material. All results were evaluated in relation to tensile strength and displacement curves due to pre and post failure behaviors of materials and root systems. The results showed the increase of the displacement of the material was the significant indicator of the bio-mechanics tensile strength of the material provided by the tree roots. The fast growing type of tree roots have stabilized the material up to a depth for 80–100 cm by covering the coal residual materials within 12 years. 相似文献
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《中国地球化学学报》2006,(Z1)
With increasing use of coal, the growing impact on the environment from potentially hazardous trace elements becomes a great concern. Southwestern Guizhou, China, is a typical area of endemic arsenosis related to coal combustion. The use of locally mined,… 相似文献
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Mining activities impact the nearby environment, causing the so-called mining hazards. The land subsidence phenomena caused by the dewatering of the mines are listed among the mining-induced catastrophic geohazards slowly affecting extensive areas around the opencasts. These large-scale geo-hazards are related to both hydrogeological and geotechnical factors, and they cause irreversible damages. The research presented aims to clarify all the components of the phenomenon and to establish the proper modelling procedure for the study of its mechanism. The site under investigation is the area extending at the west—northwest of the Amyntaio opencast coal mine at Florina Prefecture, Northern Greece. The overexploitation of the aquifers for the protection of the slopes turned the opencast to a large-diameter well, draining the surrounding area. The extensive land subsidence phenomena extend 3–4 km around the mine causing severe damages in two villages. The established results can be used for monitoring and predicting the impact of the particular mining hazard on the natural and human environment, without precluding further exploitation and mining of the energy resources. 相似文献
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《Chemie der Erde / Geochemistry》2021,81(2):125766
Early Cenozoic magmatism in the eastern Sakarya Zone (NE Turkey) provides an important constraint on the regional tectono-magmatic evolution of the region. Early Eocene syn-collisional adakitic rocks are observed as small stocks with outcropping areas commonly less than 10 km2. This study presents petrography, whole-rock geochemistry and Sr-Nd-Pb isotope data, as well as in-situ 40Ar/39Ar age constraints on one of these adakitic andesites in the Altınpınar area of Gümüşhane, and discusses source region, petrological processes and geodynamic setting prevailed during their genesis. Andesites commonly show microlitic porphyric and vitrophyric porphyric textures, and include significant amounts of mafic microgranular enclaves (MMEs). Plagioclase, hornblende, Fe-Ti oxides and minor pyroxene are the main mineral phases. In-situ 40Ar-39Ar amphibole dating constrains the cooling age of andesites into a time span from 52.8 ± 1.3–48.8 ± 1.9 Ma. Andesites are medium to high-K calc-alkaline and display most of the signatures typical of those of the adakites. They are characterized by moderate MgO (1.7–4.1 wt%), low Y (9−14 ppm), Yb (0.9–1.5 ppm), and HREE and high Sr (325−964 ppm) contents, and high Sr/Y (36–76) ratios. 87Sr/86Sr(t) (0.704948−0.705100) and 143Nd/144Nd(t) (0.512588−0.512628) ratios are in the isotopic range of the adakites. All these geochemical and isotopic data suggest that the parental magma of adakitic andesites has been produced by partial melting of oceanic basalts under amphibole-eclogite facies conditions during the breakoff of the northern Neotethyan oceanic slab. 相似文献
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It is important to know the distribution and transfer of radionuclides such as uranium, thorium, and potassium, which exist naturally in the environment we live in. For this reason, measurements of these natural radionuclides have been carried out for 15 gravel samples collected from Konyaalt? Beach, Antalya. In order to measure the natural activity concentrations of potassium-40, uranium-238, and thorium-232 radionuclides, we performed the measurements by applying a gamma spectrometry method with a “3?×?3” NaI(Tl) detector, which is a multichannel analytical detector in the Suleyman Demirel University gamma spectrometry laboratory. The minimum, maximum, and mean values for the 226Ra activity concentration were measured as 19.74 Bq/kg, 37.03 Bq/kg, and 31.64 Bq/kg, respectively. The minimum, maximum, and mean values for the 232Th activity concentration were measured as 12.76 Bq/kg, 34.32 Bq/kg, and 26.67 Bq/kg, respectively. The minimum, maximum, and mean values for the 40K activity concentration were measured as 196.37 Bq/kg, 421.13 Bq/kg, and 350.42 Bq/kg, respectively. Dose parameters and radiation damage indices were calculated using experimentally measured activity results and the resulting dose and hazard index values were compared with the determined limit values. It can be concluded that no risk may threat in terms of the hazard index values. In addition, all results obtained in terms of calculated dose values except for annual gonadal dose are below the recommended limit values. 相似文献
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Lake Seyfe is located in a closed basin near K?r?ehir in the central Anatolian region, Turkey. The aim of this study is to evaluate the groundwater quality and effects of lithogenic contamination carried out in the Lake Seyfe basin, which is represented by various lithologies and groundwater types. Seyfe, Horla and Akp?nar springs are recharged through marbles at the western and southwestern of the basin are ultimately and discharged into the K?z?l?rmak Formation and Lake Seyfe. The waters of deep wells drilled into the marbles are of bicarbonate type (type I) in the Ca2+–Mg2+–HCO3 ? and Ca2+–HCO3 ? facies. Özlühüyük spring and waters from most of trenches and shallow wells, which are fed by the K?z?l?rmak Formation, have a mixed (type II) composition in the Ca2+–Mg2+–HCO3 ?–Cl? facies. Groundwater in the alluvium and K?z?l?rmak Formation along Lake Seyfe has a salty (type III) character in the Na+–Cl? facies. The main reasons of formation and change of the groundwater salinity and hydrochemical facies in the Seyfe basin are causing the various (a) lithogenic pollution and heterogeneity of the K?z?l?rmak Formation, (b) salinity of the upper soil zones, and (c) evaporation of the trench and channel waters open to the atmosphere. Considering parameters such as sodium hazard, specific conductivity, bicarbonate and carbonate hazards, waters in the study area are generally suitable for agricultural usage. 相似文献
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Radioactivity in sediments and gross alpha–beta activities in surface water of Fırtına River, Turkey
B. Kücükömeroglu A. Kurnaz R. Keser F. Korkmaz N. T. Okumusoglu G. Karahan C. Sen U. Cevik 《Environmental Geology》2008,55(7):1483-1491
The concentrations and distribution of natural and artificial radionuclides in sediment and water samples collected from Fırtına
River in the Eastern Black Sea region of Turkey were investigated with an aim of evaluating the environmental radioactivity
and radiation hazard. Natural gross α and gross β activities were determined for 21 different water samples, and the activity
concentrations were obtained for 226Ra, 214Pb, 214Bi, 228Ac, 208Tl, 40K and 137Cs in 20 different sediment samples. The obtained results showed that natural gross α and gross β activity concentrations
in water samples range from 12.4 ± 3.4 to 66.2 ± 9.2 mBq l−1 and from 27.9 ± 3.3 to 133.3 ± 4.1 mBq l−1, respectively. The mean activity concentrations were 32.6 ± 3.8 mBq l−1 for gross α and 69.9 ± 4.4 mBq l−1 for gross β. Generally, the gross β activities were higher than the corresponding gross α activities. The average concentrations
of 238U and 232Th daughter products vary from 11 to 167 Bq kg−1 and from 16 to 107 Bq kg−1, respectively. The concentrations of 40K and 137Cs vary from 51 to 1,605 Bq kg−1 and from 0.8 to 42 Bq kg−1, respectively. Sediment characterization was also investigated using grain size, thin section and XRD analysis. 相似文献
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Characterization of coal reservoirs and determination of in-situ physical coal properties related to transport mechanism are complicated due to having lack of standard procedures in the literature. By considering these difficulties, a new approach has been developed proposing the usage of relationships between coal rank and physical coal properties. In this study, effects of shrinkage and swelling (SS) on total methane recovery at CO2 breakthrough (TMRB), which includes ten-year primary methane recovery and succeeding enhanced coalbed methane (ECBM) recovery up to CO2 breakthrough, and CO2 sequestration have been investigated by using rank-dependent coal properties. In addition to coal rank, different coal reservoir types, molar compositions of injected fluid, and parameters within the extended Palmer & Mansoori (P&M) permeability model were considered. As a result of this study, shrinkage and swelling lead to an increase in TMRB. Moreover, swelling increased CO2 breakthrough time and decreased displacement ratio and CO2 storage for all ranks of coal. Low-rank coals are affected more negatively than high-rank coals by swelling. Furthermore, it was realized that dry coal reservoirs are more influenced by swelling than others and saturated wet coals are more suitable for eliminating the negative effects of CO2 injection. In addition, it was understood that it is possible to reduce swelling effect of CO2 on cleat permeability by mixing it with N2 before injection. However, an economical optimization is required for the selection of proper gas mixture. Finally, it is concluded from sensitivity analysis that elastic modulus is the most important parameter, except the initial cleat porosity, controlling SS in the extended P&M model by highly affecting TMRB. 相似文献
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Hydrochemical analysis results suggest four different water types: bicarbonate dominant water (facies-I), sulfate dominant cold brine water (facies-II), sodium-bicarbonate dominant thermal water and thermal and mineralized water (facies-III), and sulfate–chloride dominant thermal and mineralized water (facies-IV). The mineral content/salinity of the water is related to the ions that these waters dissolve from the minerals on the rocks during infiltration and circulation in the saturated zone. Gypsum cover units that exist on the granitoids in the region is the main factor for the ion increase in the facies III geothermal water similar to the cold brine water (facies II). Isotopic analyses indicate that the thermal springs (Dutlu bath spring, Aya? bath well, Çoban bath well and Kapullu bath spring) are of meteoric origin and receive recharge from precipitation in the Beypazar? granitoids and around gypseous formations with elevations of about 950–1,150 m. Karakaya bath well and Il?ca bath spring thermal water points are recharged from the Bilecik limestone hills, Tekke volcanics and ?ncedoruk Formations. Karakoca mineral spring of thermal and mineralized water is recharged from out of the study area. According to oxygen-18 (SO42?) and sulfur-34 (SO42?) contents, sulfate in water samples from Aya? and Dutlu resorts as well as Çoban bath is derived from the gypsum of Kirmir Formation as the primary source. Sulfates of the Kapullu bath water and Karakoca mineral water originate from secondary sources such as pyrite oxidation and bacteriological reduction. 相似文献
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Finite element simulation of seawater intrusion into a quarry-site coastal aquifer,Kocaeli-Darıca,Turkey 总被引：1，自引：0，他引：1
A numerical simulation has been carried out to investigate the effects of below-sea-level (b.s.l.) excavation on the raw material quality of a cement quarry in Turkey. The model simulates variations in the hydrodynamic and hydrogeochemical mechanisms in the coastal aquifer upon BSL excavation. In this context, behavior of the seawater intrusion zone, changes in water levels, and salt concentrations have been simulated. In the development of the model, previous geological and hydrogeological reports of the quarry site and the near vicinity have been considered. Eleven new wells (BH-1,...BH-11) have been drilled to reveal hydrogeological features of the area and also for periodical observations of the water levels and hydrogeochemical monitoring. These wells were utilized to develop and calibrate the model to the field conditions. Physical and hydrogeochemical parameters used in the model have been evaluated using available hydrogeological data, the field test results and the related literature. The model has been verified using the field observations. It is based on the virgin conditions of the aquifer as well as on the data for years 1990 and 2001. An average raw material production rate for the cement factory was considered during development of the model, and for making future predictions. Two alternative production scenarios have been considered and probable effects of above-sea-level (a.s.l.) and b.s.l. excavations on seawater intrusion into the aquifer have been studied. Future prediction studies are based on these two production scenarios that assume 43 years of total production (30 years of a.s.l. and 13 years of b.s.l. production) in the quarry. The first scenario, Scenario I, assumes that starting from 2001, the next 30 years would be devoted only to ASL and then the remaining 13 years would be used for b.s.l. production. Scenario II, on the other hand, assumes simultaneous operations both at a.s.l. and b.s.l. levels for the next 43 years after 2001. Effects of b.s.l. production in the quarry site have been simulated accordingly, and seawater intrusion into the aquifer as well as water discharge rates have been predicted for –10, –20 and –30 m production levels. 相似文献
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Influences of human activities and agriculture on groundwater quality of Kayseri-Incesu-Dokuzpınar springs,central Anatolian part of Turkey 总被引：3，自引：0，他引：3
Human activities and agriculture have had direct and indirect effects on the rates of contamination of groundwater in the Incesu-Dokuzp inar spring area. Direct effects include dissolution and transport of excess quantities of fertilizers with associated materials and hydrological alterations related to irrigation and drainage. Indirect effects may include changes in water–rock reactions in soils and aquifers caused by increased concentrations of dissolved oxidants, protons, and major ions. Agricultural activities have directly or indirectly affected the concentrations of a large number of inorganic chemicals in groundwater, for example NO 3, N 2, Cl, SO 4 2, H +, K, Mg, Ca, Fe, Cu, B, Pb, and Zn, as well as a wide variety of pesticides and other organic compounds. For reactive contaminants like NO 3, it is recommended that a combination of hydrochemical and environmental-tracer analytical approaches might be required to resolve changing inputs from subsequent alterations as causes of concentration gradients in groundwater. The water type of Dokuzp inar springs is mainly Na–Mg–Ca–Cl–HCO 3. Note that the water types of the springs were directly related to the hydrogeochemical properties of outcrops at the study area. Thus, the high concentration of Ca 2+ and HCO 3 is mainly related to the high CO 2 contents in the marbles, whereas the high Na concentration arises from the existing syenite, volcanic ash, basalt, and clay units, although the Incesu-Dokuzp inar springs cover most of the drinking and irrigation water demands of this area. The high concentrations of NO 3 and NaCl show that the area around the springs is continuously being contaminated by untreated sewage and agricultural wastes, especially during dry periods. Therefore, this approach is based on the vulnerability studies of the catchment area, determination of the transfer time of the pollutant, and the water-bearing formations of Incesu-Dokuzp inar springs. Vulnerability in this study is defined as the intrinsic hydrogeochemical characteristics of an aquifer, which may show the sensitivity of groundwater to be contaminated by different human activities. 相似文献
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Hongfu SUN Fenghua ZHAO 《中国地球化学学报》2006,25(B08):26-27
In this study, geochemical characteristics of acid mine drainage （AMD） and its sediments from the Malan and Sitai coalmines, Shanxi Province, China, were investigated. Many analytical approaches such as IC, ICP-MS, XRD, XRF, and modeling calculation of hydrogeochemistry using PHREEQCI software were employed. The AMD is characterized by higher concentrations of iron and sulfate, a low pH, and elevated concentrations of a wide variety of heavy metals. The results of modeling calculation by PHREEQCI software demonstrate the metals in AMD are present mainly as Me^n＋ and MeSO4^n-2 species. The sediments of AMD are composed mainly of iron-beating minerals such as goethite and schwertmannite, which are controlled by pH, Fe and SO4^2- concentrations. The schwertmannite mineral has been found for the first time in China. 相似文献