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1.
Distinctive lithological associations and geological relationships, and initial geochronological results indicate the presence of an areally extensive region of reworked Archaean basement containing polymetamorphic granulites in the Rauer Group, East Antarctica.
Structurally early metapelites from within this reworked region preserve complex and varied metamorphic histories which largely pre-date and bear no relation to a Late Proterozoic metamorphism generally recognized in this part of East Antarctica. In particular, magnesian metapelite rafts from Long Point record extreme peak P–T conditions of 10–12 kbar and 100–1050°C, and an initial decompression to 8 kbar at temperatures of greater than 900°C. Initial garnet–orthopyroxene–sillimanite assemblages contain the most magnesian (and pyrope-rich) garnets ( X Mg= 0.71) yet found in granulite facies rocks. A high-temperature decompressional P–T history is consistent with reaction textures in which the phase assemblages produced through garnet breakdown vary systematically with the initial garnet X Mg composition, reflecting the intersection of different divariant reactions in rocks of varied composition as pressures decreased. This history is thought to relate to Archaean events, whereas a lower-temperature ( c. 750–800°C) decompression to 5 kbar reflects Late Proterozoic reworking of these relict assemblages.
The major Late Proterozoic ( c. 1000 Ma) granulite facies metamorphism is recorded in a suite of younger Fe-rich metapelites and associated paragneisses in which syn- to post-deformational decompression, through 2–4 kbar from maximum recorded P–T conditions of 7–9 kbar and 800–850°C, is constrained by geothermobarometry and reaction textures. This P–T evolution is thought to reflect rapid tectonic collapse of crust previously thickened through collision.  相似文献   

2.
High-pressure metamorphic rocks exposed in the Bantimala area, c . 40  km north-east of Ujung Pandang, were formed as a Cretaceous subduction complex with fault-bounded slices of melange, chert, basalt, turbidite, shallow-marine sedimentary rocks and ultrabasic rocks. Eclogites, garnet–glaucophane rocks and schists of the Bantimala complex have estimated peak temperatures of T  =580–630 °C at 18  kbar and T  =590–640 °C at 24  kbar, using the garnet–clinopyroxene geothermometer. The garnet–omphacite–phengite equilibrium is used to estimate pressures. The distribution coefficient K D1=[( X pyr)3( X grs)6/( X di)6]/[(Al/Mg)M2,wm (Al/Si)T2,wm]3 among omphacite, garnet and phengite is a good index for metamorphic pressures. The K D1values of the Bantimala eclogites were compared with those of eclogites with reliable P–T  estimates. This comparison suggests that peak pressures of the Bantimala eclogites were P =18–24  kbar at T  =580–640 °C. These results are consistent with the P–T  range calculated using garnet–rutile–epidote–quartz and lawsonite–omphacite–glaucophane–epidote equilibria.  相似文献   

3.
At the eastern margin of the Bohemian Massif (Variscan belt of Central Europe), large bodies of felsic granulite preserve mineral assemblages and structures developed during the early stages of exhumation of the orogenic lower continental crust within the Moldanubian orogenic root. The development of an early steep fabric is associated with east–west-oriented compression and vertical extrusion of the high-grade rocks into higher crustal levels. The high-pressure mineral assemblage Grt-Ky-Kfs-Pl-Qtz-Liq corresponds to metamorphic pressures of ∼18 kbar at ∼850 °C, which are minimum estimates, whereas crystallization of biotite occurred at 13 kbar and ∼790 °C during decompression with slight cooling. The late stages of the granulite exhumation were associated with lateral spreading of associated high-grade rocks over a middle crustal unit at ∼4 kbar and ∼700 °C, as estimated from accompanying cordierite-bearing gneisses. The internal structure of a contemporaneously intruded syenite is coherent with late structures developed in felsic granulites and surrounding gneisses, and the magma only locally explored the early subvertical fabric of the felsic granulite during emplacement. Consequently, the emplacement age of the syenite provides an independent constraint on the timing of the final stages of exhumation and allows calculation of exhumation and cooling rates, which for this part of the Variscan orogenic root are 2.9–3.5 mm yr−1 and 7–9.4 °C Myr−1, respectively. The final part of the temperature evolution shows very rapid cooling, which is interpreted as the result of juxtaposition of hot high-grade rocks with a cold upper-crustal lid.  相似文献   

4.
The high- P , medium- T  Pouébo terrane of the Pam Peninsula, northern New Caledonia includes barroisite- and glaucophane-bearing eclogite and variably rehydrated equivalents. The metamorphic evolution of the Pouébo terrane is inferred from calculated P–T  and P–T  – X H2O pseudosections for bulk compositions appropriate to these rocks in the model system CaO–Na2O–FeO–MgO–Al2O3–SiO2–H2O. The eclogites experienced a clockwise P–T  path that reached P ≈19  kbar and T  ≈600  °C. The eclogitic mineral assemblages are preserved because reaction consequent upon decompression consumed the rocks' fluid. Extensive reaction occurred only in rocks with fluid influx during decompression of the Pouébo terrane.  相似文献   

5.
Petrological and geochronological data of six representative samples of exotic blocks of amphibolite and associated tonalite-trondhjemite from the serpentinitic mélange of the Sierra del Convento (eastern Cuba) indicate counterclockwise P–T paths typical of material subducted in hot and young subduction zones. Peak conditions attained were ∼750 °C and 15 kbar, consistent with the generation of tonalitic partial melts observed in amphibolite. A tonalite boulder provides a U-Pb zircon crystallization age of 112.8 ± 1.1 Ma, and Ar/Ar amphibole dating yielded two groups of cooling ages of 106–97 Ma (interpreted as cooling of metamorphic/magmatic pargasite) and 87–83 Ma (interpreted as growth/cooling of retrograde overprints). These geochronological data, in combination with other published data, allow the following history of subduction and exhumation to be established in the region: (i) a stage of hot subduction 120–115 Ma, developed upon onset of subduction; (ii) relatively fast near-isobaric cooling (25 °C Myr−1) 115–107 Ma, after accretion of the blocks to the upper plate lithospheric mantle; (iii) slow syn-subduction cooling (4 °C Myr−1) and exhumation (0.7 km Myr−1) in the subduction channel 107–70 Ma; and (iv) fast syn-collision cooling (74 °C Myr−1) and exhumation (5 km Myr−1) 70–60 Ma.  相似文献   

6.
Phase analysis in the model K2O-poor aluminous rock system (FMASH) illustrates the following sequence of reactions during retrograde metamorphism in the Botswanan Limpopo Central Zone:
Opx+Sil+Qtz=Crd ,
Opx+Sil=Spr+Crd ,
Grt+Qtz=Opx+Crd ;
Opx+Crd+W=Ged+Qtz ,
Grt+Opx+Crd+W=Ged ;
and
Grt+Qtz+W=Ged+Crd .
A quantitative petrogenetic grid with phase relations shows that sapphirine results from nearly isothermal decompression in the quartz-undersaturated portions of the grid, and that gedrite formation by reactions (4)–(6) records isobaric cooling from high temperature ( c . 800°  C) after the decompression. Conditions for hydration in the western part of the area were 700–800°  C and c . 6  kbar, based on microthermometric data and the available garnet–cordierite geothermometer. On the basis of these conditions and predicted thermodynamic properties of gedrite, phase relations in T–X Mg space were constructed to investigate the isobaric cooling event. The results are in good agreement with the hydration P–T  path. Further, the T–X Mg topologies show that hydration of orthopyroxene in the central part of the area (reaction 4) occurred at about 800°  C and c . 5  kbar. Therefore, we conclude that the Botswanan Limpopo Central Zone has suffered isothermal decompression, similar to the Central Zone in South Africa and Zimbabwe, followed by isobaric cooling. The isobaric cooling event in the western (at c . 6  kbar) and central (at c . 5  kbar) parts of the area commenced at nearly the same temperature ( c . 800°  C), and appear to be consistent with a tectonic model that involved westward movement (thrusting) of the Central Zone.  相似文献   

7.
The Koralpe of the Eastern European Alps experienced high-temperature/low-pressure metamorphism (∼650 °C and 6.5 kbar) during the Permian and eclogite facies metamorphism (∼700 °C and 14 kbar) during the Eo-Alpine (Cretaceous) metamorphic event. In the metapelitic Plattengneiss shear zone that constitutes much of the Koralpe, the second metamorphism caused only partial re-equilibration of the assemblages formed during the first metamorphism. It is shown here that the Eo-Alpine mineral assemblage, garnet + biotite + muscovite + plagioclase + quartz (with or without kyanite), formed under low water activity conditions that are consistent with the level of dehydration that occurred during the Permian event. This implies that the rocks were essentially closed-system from the peak of the Permian metamorphism through the Eo-Alpine event. The evolution of water content of the rocks is traced through time: that prograde dewatering during the Permian metamorphic event terminated at the metamorphic peak with a water content around 3–4 mol.%. The water content remained then constant and led to water-undersaturation during the subsequent Eo-Alpine metamorphism. From the water content and activity evolution a post-peak isothermal decompression path close to the solidus is inferred for the Eo-Alpine event.  相似文献   

8.
Hydration of eclogite, Pam Peninsula, New Caledonia   总被引:2,自引:0,他引:2  
Garnet glaucophanite and greenschist facies assemblages were formed by the recrystallization of barroisite-bearing eclogite facies metabasites in northern New Caledonia. The mineralogical evolution can be modelled by calculated P–T and P–X H2O diagrams for appropriate bulk rock compositions in the model system CaO–Na2O–FeO–MgO–Al2O3–SiO2–H2O. The eclogites, having developed in a clockwise P–T path that reached P ≈19 kbar and T  ≈590 °C, underwent decompression with the consumption of free H2O as the volume of hydrous minerals increased. Eclogite is preserved in domains that experienced no fluid influx following the loss of this fluid. Garnet glaucophanite formed at P ≈16 kbar during semi-pervasive fluid influx. Fluid influx, after further isothermal decompression, was focused in shear zones, and resulted in chlorite–albite-bearing greenschist facies mineral assemblages that reflect P ≈9 kbar.  相似文献   

9.
Magnesian metapelites of probable Archaean age from Forefinger Point, SW Enderby Land, East Antarctica, contain very-high-temperature granulite facies mineral assemblages, which include orthopyroxene (8–9.5 wt% Al2O3)–sillimanite ± garnet ± quartz ± K-feldspar, that formed at 10 ± 1.5 kbar and 950 ± 50°C. These assemblages are overprinted by symplectite and corona reaction textures involving sapphirine, orthopyroxene (6–7 wt% Al2O3), cordierite and sometimes spinel at the expense of porphyroblastic garnet or earlier orthopyroxene–sillimanite. These textures mainly pre-date the development of coarse biotite at the expense of initial mesoperthite, and the subsequent formation of orthopyroxene (4–6 wt% Al2O3)–cordierite–plagioclase rinds on late biotite.
The early reaction textures indicate a period of near-isothermal decompression at temperatures above 900°C. Decompression from 10 ± 1.5 kbar to 7–8 kbar was succeeded by biotite formation at significantly lower temperatures (800–850°C) and further decompression to 4.5 ± 1 kbar at 700–800°C.
The later parts of this P–T evolution can be ascribed to the overprinting and reworking of the Forefinger Point granulites by the Late-Proterozoic ( c . 1000 Ma) Rayner Complex metamorphism, but the age and timing of the early high-temperature decompression is not known. It is speculated that this initial decompression is of Archaean age and therefore records thinning of the crust of the Napier Complex following crustal thickening by tectonic or magmatic mechanisms and preceding the generally wellpreserved post-deformational near-isobaric cooling history of this terrain.  相似文献   

10.
Abstract Fluids with compositions in the system CO2-H2O-NaCl were trapped in quartz veins enclosed in low-grade metamorphic rocks (chlorite zone) on the southern flank of the Canigó Massif, eastern Pyrenees. The veins, which also contain arsenopyrite crystals, were formed contemporaneously with the main Hercynian foliation and metamorphism. Volumetric properties of the fluid and the results of arsenopyrite geothermometry suggest P-T trapping conditions of 4.6–6 kbar and 450–530° C. This implies that an episode of metamorphism with an average geothermal gradient of 25° C km−1 occurred during the main deformation event. This episode preceded the low- P /high- T metamorphism described around domes and to date considered as characteristic of the Hercynian orogeny in the Pyrenees.  相似文献   

11.
The Tormes Gneissic Dome (TGD, NW sector of the Iberian Massif, Spain) is a high-grade metamorphic complex affected by a major episode of extensional deformation (D2). The syn-D2 P–T  path of the Lower Unit of the TGD was deduced from the analysis of reaction textures related to superimposed fabrics developed during exhumation, analysis of mineral zoning and thermobarometric calculations. It comprises an initial phase of decompression, determined using the tweequ thermobarometric technique, from 6.4–8.1 kbar at 735–750 °C (upper structural levels) and 7.2 kbar at 770 °C (lower structural levels) to 3.3–3.9 kbar and 645–680 °C. This evolution is consistent with the observed sequence of melting reactions and the generation of garnet- and cordierite-bearing anatectic granitoids. The later part of the syn-D2 P–T  path consisted of almost isobaric cooling associated with the thermal re-equilibration of the unit in the new structural position. This segment of the P–T  path is recorded by assemblages with And +Bt+Ms and Ms+ Chl +Ab related to the later mylonitic S2 fabrics, which indicate retrogression to low-amphibolite and greenschist facies conditions.  相似文献   

12.
In this work, the factors controlling the formation and preservation of high-pressure mineral assemblages in the metamorphosed orthopyroxene-bearing metagranitoids of the Sandmata Complex, Aravalli-Delhi Mobile Belt (ADMB), northwestern India have been modelled. The rocks range in composition from farsundite through quartz mangerite to opdalite, and with varying K2O, Ca/(Ca + Na)rock and FeOtot + MgO contents. A two stage metamorphic evolution has been recorded in these rocks.
An early hydration event stabilized biotite with or without epidote at the expense of magmatic orthopyroxene and plagioclase. Subsequent high-pressure granulite facies metamorphism (∼15 kbar, ∼800 °C) of these hydrated rocks produced two rock types with contrasting mineralogy and textures. In the non-migmatitic metagranitoids, spectacular garnet ± K-feldspar ± quartz corona was formed around reacting biotite, plagioclase, quartz and/or pyroxene. In contrast, biotite ± epidote melting produced migmatites, containing porphyroblastic garnet incongruent solids and leucosomes.
Applying NCKFMASHTO T–M (H2O) and P–T pseudosection modelling techniques, it is demonstrated that the differential response of these magmatic rocks to high-pressure metamorphism is primarily controlled by the scale of initial hydration. Rocks, which were pervasively hydrated, produced garnetiferous migmatites, while for limited hydration, the same metamorphism formed sub-solidus garnet-bearing coronae. Based on the sequence of mineral assemblage evolution and the mineral compositional zoning features in the two metagranitoids, a clockwise metamorphic P–T path is constrained for the high-pressure metamorphic event. The finding has major implications in formulating geodynamic model of crustal amalgamation in the ADMB.  相似文献   

13.
Abstract Petrological data from intercalated pelitic schists and greenstones are used to construct a pressure–temperature path followed by the Upper Schieferhülle (USH) series during progressive metamorphism and uplift in the south-west Tauern Window, Italy. Pseudomorphs of Al–epidote + Fe-epidote + albite + oligoclase + chlorite after lawsonite and data on amphibole crystal chemistry indicate early metamorphism in the lawsonite-albite-chlorite subfacies of the blueschist facies at P ± 7–8 kbar. Geothermometry and geobarometry yield conditions of final equilibration of the matrix assemblage of 475±25°C, 5–6 kbar; calculations with plagioclase and phengite inclusions in garnet indicate early garnet growth at pressures of ∼ 7.5 kbar. Garnet zoning patterns are complex and reversals in zoning can be correlated between samples. Thermodynamic modelling of these zoning profiles implies garnet growth in response to four distinct phases of tectonic activity. Fluid inclusion data from coexisting immiscible H2O–CO2–NaCl fluids constrain the uplift path to have passed through temperatures of 380 + 30°C at 1.3 + 0.2 kbar.
There is no evidence for metamorphism of USH at pressures greater than ∼ 7.5 kbar in this area of the Tauern Window. This is in contrast to pressures of ± 10 kbar recorded in the Lower Schieferhülle only 2–3 km across strike. A history of differential uplift and thinning of the intervening section during metamorphism is necessary to reconcile the P–T data obtained from these adjacent tectonic units.  相似文献   

14.
The Mallee Bore area in the northern Harts Range of central Australia underwent high-temperature, medium- to high-pressure granulite facies metamorphism. Individual geothermometers and geobarometers and average P–T  calculations using the program Thermocalc suggest that peak metamorphic conditions were 705–810 °C and 8–12 kbar. Partial melting of both metasedimentary and meta-igneous rocks, forming garnet-bearing restites, occurred under peak metamorphic conditions. Comparison with partial melting experiments suggests that vapour-absent melting in metabasic and metapelitic rocks with compositions close to those of rocks in the Mallee Bore area occurs at 800–875 °C and >9–10 kbar. The lower temperatures obtained from geothermometry imply that mineral compositions were reset during cooling. Following the metamorphic peak, the rocks underwent local mylonitization at 680–730 °C and 5.8–7.7 kbar. After mylonitization ceased, garnet retrogressed locally to biotite, which was probably caused by fluids exsolving from crystallizing melts. These three events are interpreted as different stages of a single, continuous, clockwise P–T  path. The metamorphism at Mallee Bore probably occurred during the 1745–1730 Ma Late Strangways Orogeny, and the area escaped significant crustal reworking during the Anmatjira and Alice Springs events that locally reached amphibolite facies conditions elsewhere in the Harts Ranges.  相似文献   

15.
Abstract Two blueschist belts in the North Qilian Mountains occur in Middle Cambrian and Lower Ordovician strata and strike N30–35°W for about 500 km along the Caledonian fold belt on the south-west margin of the Sino-Korean plate. The styles of metamorphism and deformation are quite different in the two belts. The Middle Cambrian to Ordovician rocks in the high-grade belt are mainly blueschists and C-type eclogites in which six phases of lower and upper crustal deformation have been recognized. The rocks contain glaucophane, phengite, epidote, clinozoisite, chlorite, garnet, stilpnomelane, piedmontite, albite, titanite and quartz. The estimated P–T conditions of eclogites are 340 ± 10°C, 8 ± 1 kbar and, of blueschist, >380°C, 6–7 kbar. The Ordovician rocks in the low-grade belt are characterized by ductile to brittle deformation in the middle to upper crust. The low-grade blueschists contain glaucophane, lawsonite, pumpellyite, aragonite, albite and chlorite. The estimated P–T conditions are 150–250°C and 4–7 kbar.
K–Ar and 39Ar/40Ar geochronology on glaucophane and phengite from the high-grade blueschist belt suggest two stages of metamorphism at 460–440 and 400–380 Ma, which may represent the times of subduction and orogeny. The subduction metamorphism of the northern low-grade blueschist belt took place approximately at the end of the Ordovician.  相似文献   

16.
Abstract Ganguvarpatti is part of a Precambrian terrane characterized by granulite facies rocks, including charnockites, mafic granulites, sapphirine-bearing granulites, leptynites and gneisses. A sequence of reactions deduced from the multiphase reaction textures provide information on the metamorphic history of this area, as they formed in response to decompression during uplift. Geothermobarometry and constraints from reaction textures define a segment of a P–T path traversed by the granulites of Ganguvarpatti. Near-peak metamorphic conditions of c. 800°C and 8 kbar were succeeded by a symplectitic stage at a significantly lower pressure ( c. 700°C and 4.5 kbar), documenting a nearly isothermal decompression P–T path and rapid uplift ( c. 12 km) followed by cooling. The presence of many fluid inclusions of extremely low density in the charnockites is consistent with a nearly isothermal uplift path. Attainment of a maximum pressure of c. 8 kbar indicates c. 27 km depth of burial during metamorphism. This would imply a total crustal thickness of c. 65–70 km at 2.6–2.5 Ga. Such a profound crustal thickness and a clockwise decompressive P–T path is interpreted as a consequence of tectonic thickening of crust, accomplished by collision tectonics of the southern granulite terrane against the Dharwar craton along the Palghat–Cauvery shear zone via northward subduction.  相似文献   

17.
Abstract Garnet granulites from Sri Lanka preserve textural and chemical evidence for prograde equilibration at temperatures of at least 700–750°C and pressures in the vicinity of 6–8 kbar. Associated strain patterns suggest prograde metamorphism occurred during and immediately following an episode of crustal thickening, with the prograde P–T conditions probably reflecting a combination of the conductive and advective transport of heat at the mid-levels of tectonically thickened crust. The occurrence of prograde wollastonite provides evidence for internally buffered fluid compositions, or fluid absent conditions, during peak metamorphism and precludes pervasive advection of a CO2-rich fluid. The advective heat component is therefore likely to have been provided by the transport of silicate melt. Intricate symplectitic textures record partial re-equilibration of the garnet granulites to lower pressures (˜ 4–6 kbar) at high temperatures (600–750°C), and testify either to the erosional denudation of the overthick crust prior to significant cooling (i.e. quasi-isothermal decompression) or to a subsequent static heating possibly of early Palaeozoic age (Pan-African). The metamorphic history of the Sri Lankan granulites is compared with high grade terrains in the neighbouring fragments of Gondwana, with the emphasis on similarities with Proterozoic granulites of the East Antarctic craton.  相似文献   

18.
In the Shackleton Range of East Antarctica, garnet-bearing ultramafic rocks occur as lenses in supracrustal high-grade gneisses. In the presence of olivine, garnet is an unmistakable indicator of eclogite facies metamorphic conditions. The eclogite facies assemblages are only present in ultramafic rocks, particularly in pyroxenites, whereas other lithologies – including metabasites – lack such assemblages. We conclude that under high-temperature conditions, pyroxenites preserve high-pressure assemblages better than isofacial metabasites, provided the pressure is high enough to stabilize garnet–olivine assemblages (i.e. ≥18–20 kbar). The Shackleton Range ultramafic rocks experienced a clockwise P–T path and peak conditions of 800–850 °C and 23–25 kbar. These conditions correspond to ∼70 km depth of burial and a metamorphic gradient of 11–12 °C km−1 that is typical of a convergent plate-margin setting. The age of metamorphism is defined by two garnet–whole-rock Sm–Nd isochrons that give ages of 525 ± 5 and 520 ± 14 Ma corresponding to the time of the Pan-African orogeny. These results are evidence of a Pan-African suture zone within the northern Shackleton Range. This suture marks the site of a palaeo-subduction zone that likely continues to the Herbert Mountains, where ophiolitic rocks of Neoproterozoic age testify to an ocean basin that was closed during Pan-African collision. The garnet-bearing ultramafic rocks in the Shackleton Range are the first known example of eclogite facies metamorphism in Antarctica that is related to the collision of East and West Gondwana and the first example of Pan-African eclogite facies ultramafic rocks worldwide. Eclogites in the Lanterman Range of the Transantarctic Mountains formed during subduction of the palaeo-Pacific beneath the East Antarctic craton.  相似文献   

19.
Continental crust is displaced in strike-slip fault zones through lateral and vertical movement that together drive burial and exhumation. Pressure – temperature–deformation ( P–T–d ) histories of orogenic crust exhumed in transcurrent zones record the mechanisms and conditions of these processes. The Skagit Gneiss Complex, a migmatitic unit of the North Cascades, Washington (USA), was metamorphosed at depths of ∼25–30 km in a continental arc under contraction, and is bounded on its eastern side by the long-lived transcurrent Ross Lake fault zone (RLFZ). The P–T–d conditions recorded by rocks on either side of the RLFZ vary along the length of the fault zone, but most typically the fault separates high-grade gneiss and plutons from lower-grade rocks. The Ruby Mt–Elijah Ridge area at the eastern margin of the Skagit Gneiss exposes tectonic contacts between gneiss and overlying rocks; the latter rocks, including slivers of Methow basin deposits, are metamorphosed and record higher-grade metamorphism than in correlative rocks along strike along the RLFZ. In this area, the Skagit Gneiss and overlying units all yield maximum P–T conditions of 8–10 kbar at >650 °C, indicating that slices of basin rocks were buried to similar mid-crustal depths as the gneiss. After exhumation of fault zone rocks to <15 km depth, intrusion of granitoid plutons drove contact metamorphism, resulting in texturally late andalusite–cordierite in garnet schist. In the Elijah Ridge area of the RLFZ, an overlapping step-over or series of step-overs that evolved through time may have facilitated burial and exhumation of a deep slice of the Methow basin, indicating that strike-slip faults can have major vertical displacement (tens of kilometres) that is significant during the crustal thickening and exhumation stages of orogeny.  相似文献   

20.
The upper pressure limit of pyrophyllite is given by the equilibria (i) pyrophyllite=diaspore+quartz and (ii) pyrophyllite=diaspore+coesite. High- P experimental investigations carried out to locate equilibrium (i) yield brackets between 497 °C/24.8  kbar and 535 °C/25.1  kbar, and between 500 °C/23  kbar and 540 °C/23  kbar. Equilibrium (ii) was bracketed at 550 °C between 26.0 and 28.3  kbar. In the experimental P–T  range, equilibria (i) and (ii) are metastable with respect to kyanite. A stable P–T  grid is calculated using thermodynamic data derived under consideration of the present experimental results. According to these data, the lower pressure limit of the assemblage diaspore+quartz according to equilibrium (i) range from about 12  kbar/300 °C to 20  kbar/430 °C (in the presence of pure water). The upper stability of diaspore+quartz is limited by the reaction diaspore+quartz=kyanite+H2O at about 450 °C (nearly independent of pressure) and, to higher pressure, by the quartz=coesite transition. Equilibrium (ii) is metastable over the whole P–T  range.
Natural occurrences600.S of the diaspore–quartz assemblage in metamorphic rocks in Sulawesi, New Caledonia, Amorgos and the Vanoise are characterized by minerals indicative of high- P such as ferro-magnesiocarpholite, glaucophane, sodic pyroxene and lawsonite. The metamorphic P–T  conditions of these rocks are estimated to be in the range 300–400 °C, >8  kbar. These data are compatible with the derived P–T  stability field of the diaspore+quartz assemblage. We conclude that, in metamorphic rocks, diaspore+quartz is, as ferrocarpholite, an indicator for unusual low- T  /very high- P settings.  相似文献   

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