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1.
《Journal of Hydrology》2006,316(1-4):84-97
Dyes are important hydrological tracers. Many different dyes have been proposed as optimal tracers, but none of these dyes can be considered an ideal water tracer. Some dyes are toxic and most sorb to subsurface materials. The objective of this study was to find the molecular structure of an optimal water tracer. We used QSAR to screen a large number of hypothetical molecules, belonging to the class of triarylmethane dyes, in regard to their sorption characteristics to a sandy soil. The QSAR model was based on experimental sorption data obtained from four triarylmethane dyes: C.I. Food Blue 2 (C.I. 42090; Brilliant Blue FCF), C.I. Food Green 3 (C.I. 42053; FD&C Green No. 3), C.I. Acid Blue 7 (C.I. 42080; ORCOacid Blue A 150%), and C.I. Acid Green 9 (C.I. 42100; ORCOacid Fast Green B). Sorption characteristics of the dyes to the sandy soil were expressed with the Langmuir isotherm. Our premise was that dye sorption can be reduced by attachment of sulfonic acid (SO3) groups to the triarylmethane template. About 70 hypothetical dyes were created and QSAR were used to estimate sorption characteristics. The results indicated that both the position and the number of SO3 groups affected dye sorption. Sorption decreased with increasing number of SO3 groups attached to the molecule. Increasing the number of sulfonic acid groups also decreases the toxicity of the compounds. An optimal triarylmethane water tracer contains 4 to 6 SO3 groups.  相似文献   

2.
Textile wastewater contains huge quantities of nitrogen (N)‐containing azo‐dyes. Irrigation of crops with such wastewater adds toxic dyes into our healthy soils. One of the ways to prevent their entry to soils could be these waters after the dyes' biodegradation. Therefore, the present study was conducted to evaluate the impact of textile dyes on wheat growth, dye degradation efficiency of bacteria‐fungi consortium, and alleviation of dye toxicity in wheat by treatment with microbial consortium. Among dyes, Red‐S3B (3.19% N) was found to be the most toxic to germination and growth of seven‐day‐old wheat seedlings. Shewanella sp. NIAB‐BM15 and Aspergillus terreus NIAB‐FM10 were found to be efficient degraders of Red‐S3B. Their consortium completely decolorized 500 mg L?1 Red‐S3B within 4 h. Irrigation with Red‐S3B‐contaminated water after treatment with developed consortium increased root length, shoot length, root biomass, and shoot biomass of 30‐day‐old wheat seedlings by 47, 18, 6, and 25%, respectively, than untreated water. Moreover, irrigation after microbial treatment of dye‐contaminated water resulted in 20 and 51% increase in shoot N content and N uptake, respectively, than untreated water. Thus, co‐inoculation of bacteria and fungi could be a useful bioremediation strategy for the treatment of azo‐dye‐polluted water.  相似文献   

3.
This paper discusses the possibility of immobilization of TiO2 nanoparticles onto recycled wool‐based nonwoven material, which can be utilized for removal of dyes from wastewater. The photocatalytic activity of TiO2 nanoparticles deposited on the nonwoven material was evaluated in the aqueous solution of direct dye C.I. Direct Blue 78 under the UV illumination. Nonwoven material modified with TiO2 nanoparticles provides complete removal of dye from the solution already after 4–6 h of UV illumination. However, photodegradation of the dye adsorbed on the nonwoven material was obtained within 24 h of UV illumination. The rate of dye adsorption and photodegradation depends on the amount of deposited TiO2 nanoparticles. The increase of initial dye concentration induced decrease in photocatalytic efficiency of immobilized TiO2 nanoparticles. The highest photodegradation rate was achieved in acidic conditions. Elevated temperatures positively affected the removal of dye from solution. Photocatalytic activity of TiO2 nanoparticles deposited on nonwoven material was preserved after three photodegradation cycles.  相似文献   

4.
In the present study, Oreganum onites L. stalks in natural and chemically modified with HNO3 and H3PO4 used as adsorbent for removal of both acidic and basic dyes from waters. The adsorption was studied as a function of pH and contact time by batch method. All tested biosorbents were characterized by FT‐IR, scanning electron microscopy, and measuring the pH dependence of the zeta potential. The adsorption isotherms were fitted to Langmuir isotherm. The maximum adsorption capacity of dyes was 280.73 mg g?1 for Basic Red 18, 147.06 mg g?1 for methylene blue and 112.36 for Acid Red 111, which is comparable to that of other lignocellulosic materials. The modification process was considerably increased the biosorption capacity of lignocellulosic material, resulting in a 56–63% increase in the biosorption capacity of basic dyes and a 125% increase in the biosorption capacity of acidic dye. The present study illustrated that the most effective factors in the adsorption of basic dye were surface charge and acidic groups on lignocellulosic biosorbents, while non‐electrostatic forces as well as electrostatic forces were also effective in the adsorption of acidic dye. In conclusion, Oreganum stalks can be considered as a very prospective adsorbent for the removal of tested basic and acidic dyes.  相似文献   

5.
Acid violet 19 (AV) belongs to the triphenylmethane (TPM) class of dyes which are potentially mutagenic or carcinogenic. However, very little studies on biodegradation of AV were reported as compared to other TPM dyes such as malachite green and crystal violet. In this study, AV was decolorized up to 98% within 30 min by Pseudomonas aeruginosa BCH. The decolorization depends on the initial dye concentration, pH, and temperature. However, the dye was decolorized under wide pH and temperature ranges with an optimum of pH 7 and 30°C. Up to 250 mg L?1 of dye was found to be tolerated and decolorized by this strain. It showed decolorization ability for seven repeated dye addition cycles. The effect of additional carbon sources on dye decolorization was studied in which mannitol containing medium showed decolorization in 15 min. Induction in the enzyme activities of laccase, NADH‐DCIP reductase, and veratryl alcohol oxidase (VAO) indicates their involvement in AV degradation. Various analytical studies viz. UV–VIS, HPTLC, HPLC, and FTIR confirmed the biodegradation of AV by the bacterium. Based on GC‐MS analysis, a possible degradation pathway for AV was proposed. The phytotoxicity studies using Phaseolus mungo and Sorghum vulgare revealed the less toxic nature of metabolites formed after AV degradation.  相似文献   

6.
The decolorization of some of azo‐metal complex dyes used in textile industry was investigated in this study. The halophilic prokaryotes isolated from a solar sea‐saltern (Çamalt?) in Turkey were screened for resistance to five commercial azo and mixture of azo‐metal complex dyes. Only one bacterium was found to be resistant against two of dyes, namely Lanaset Navy R and Lanaset Brown B. The bacterium was identified as Halobacillus sp. C‐22 according to 16S rRNA gene sequence analyses. Decolorization experiments were carried out at 120 mg/L concentration of both dyes, at room temperature, and with an acidic pH of 4.5. Lanaset Brown B was decolorized at a high adsorbance ratio (96.12%) at the 78th hour. However, Lanaset Navy R was rapidly decolorized in 10 min (46.67%) and showed the highest adsorbance ratio (60.66%) at the third hour. Freundlich and Langmuir equilibrium isotherm models were used to evaluate the adsorption of dyes and Freundlich isoterm was more suitable for biosorpsiyon of both azo dyes. The functional groups on Halobacillus sp. C‐22 for decolorization were characterized by FT‐IR. This is the first study to reveal potential of Halobacillus sp. for decolorization of textile azo‐metal complex dyes.  相似文献   

7.
The relative advantages of fluorescent dyes and Lycopodium spores as tracers are discussed. The major advantage of fluorescent dyes is that they may be detected quantitatively. Thus, in combination with discharge measurements, a dye mass balance can be prepared for tracer tests in karst conduits, which permits elucidation of the underground network. The advantages of this procedure are illustrated by comparison of the networks derived from non-quantitative (Lycopodium and dye) and quantitative (fluorescent dye) tracer methods in the Traligill Basin, Scotland. These tests also suggest that Lycopodium does not give a true indication of travel time, due to sedimentation underground. This could also cause contamination problems in later tests. For non-quantitative tracer tests, sensitive methods are necessary if incorrect inferences on conduit networks are to be avoided. In general, however, quantitative tests give much less ambiguous results, and are therefore to be preferred.  相似文献   

8.
The percentage removal and uptake capacity of Basic Violet 14 using Hydrilla verticillata with living biomass was studied under batch conditions. The survival of H. verticillata was studied using the chlorophyll content in the living biomass. Bioaccumulation of Basic Violet 14 using H. verticillata was tested by varying the wet sorbent dosage (0.5–2.5 g), initial pH (3–8), and initial dye concentrations (5–25 mg L?1). The results show that the plant was effectively accumulating the Basic Violet 14 dye. The uptake capacity of Basic Violet 14 dye was observed as 5.9 and 21.3 mg g?1 at the initial dye concentration of 5 and 25 mg L?1, respectively, for a biomass of 5 g L?1 (wet weight) at pH 7.0 for 144 h. In general, the plant growth was found to be normal at lower concentrations and showed higher removal efficiency. It was also observed that removal efficiency of H. verticillata was found to decrease with increase in initial dye concentration. The biomass sample surface was analyzed using SEM imaging and functional groups present in the biomass were analyzed using FTIR. The equilibrium uptake capacity was analyzed by Langmuir and Freundlich isotherms. The equilibrium data was found to be fit well to both Langmuir and Freundlich isotherm models with higher coefficient of determination.  相似文献   

9.
This study investigates structural and adsorption properties of the powdered waste shells of Rapana gastropod and their use as a new cheap adsorbent to remove reactive dye Brilliant Red HE‐3B from aqueous solutions under batch conditions. For the powder shells characterization, solubility tests in acidic solutions and X‐ray diffraction (XRD), scanning electron microscopy (SEM), energy‐dispersive X‐ray spectroscopy (EDX), Fourier transform IR spectroscopy (FT‐IR) and thermogravimetric analyses were performed. The results revealed that the adsorbent surface is heterogeneous consisting mainly from calcium carbonate layers (either calcite or aragonite) and a small amount of organic macromolecules (proteins and polysaccharides). The dye adsorptive potential of gastropod shells powder was evaluated as function of initial solution pH (1–5), adsorbent dose (6–40 g L?1), dye concentration (50–300 mg L?1), temperature (5–60°C), and contact time (0–24 h). It was observed that the maximum values of dye percentage removal were obtained at the initial pH of solution 1.2, shells dose of 40 g L?1, dye initial concentration of 50–50 mg L?1 and higher temperatures; the equilibrium time decreases with increasing of dye concentration. It is proved that the waste seashell powder can be used as low cost bioinorganic adsorbent for dyes removal from textile wastewaters.  相似文献   

10.
Batch biosorption experiments were carried out for the removal of Congo red from aqueous solution using native and pretreated mycelial pellets/biomass of Trametes versicolor. The effect of process parameters such as contact time, dye concentration, and pH on the extent of Congo red biosorption has been investigated. Higher dye concentrations resulted in lower biosorption. Increases in biomass dosage led to increases in the levels of biosorption. Biosorption kinetics and equilibrium data are essential basic requirements to develop an effective and accurate design model for the removal of the dye. A kinetic study showed that the biosorption of the dye on fungal biomass was a gradual process. Pseudo‐first‐order, pseudo‐second‐order, and Bangham's model were used to fit the experimental data. The results of the kinetic studies showed that the second‐order kinetic model fitted well for the present experimental data. Equilibrium isotherms were analyzed by Langmuir, Freundlich, Dubnin‐Radushkevich, and Temkin isotherms. The biosorption equilibrium data obeyed the Langmuir and Temkin isotherms well. Acidic pH was favorable for the biosorption of the dye. Studies on the pH effect and desorption show that chemisorption seems to play a major role in the biosorption process. Among the native and pretreated biomass studied, autoclaved biomass showed a better biosorption capacity.  相似文献   

11.
This paper deals with the removal of textile dyes from aqueous solutions by poly(propylene imine) dendrimer (PPI). Direct red 80 (DR80), Acid Green 25 (AG25), Acid Blue 7 (AB7), and Direct Red 23 (DR23) were used as model dyes. The effects of operational parameters on dye removal such as dendrimer concentration, dye concentration, salt (inorganic anions), and pH have been studied at 25°C. The Langmuir and Freundlich isotherm models were investigated. In addition, dye desorption of dendrimer was studied. The results indicated that acidic pH supported the adsorption of dyes by dendrimer. Furthermore studies of dye concentration and salt effects exhibited that dye removal percentage by dendrimer was decreased. It was found that the isotherm data of DR80, AG25, and DR23 followed Langmuir isotherm and isotherm data of AB7 followed Freundlich isotherm models. Desorption tests showed that maximum dye releasing of 76.5% for DR80, 84.5% for AG25, 87% for AB7, and 93% for DR23 were achieved in aqueous solution at pH 12. Based on the data of present study, one could conclude that the dendrimer being an environmentally friendly adsorbent with relatively large adsorption capacity might be a suitable alternative for elimination of dyes from colored textile wastewater.  相似文献   

12.
The effect of varying parameters such as dye concentration, adsorbent dose, pH and temperature on the adsorption capacity of Pleurotus ostreatus is investigated. The commonly available white rot fungus Pleurotus ostreatus is investigated as a viable biomaterial for the biological treatment of synthetic basic methylene blue effluents. The results obtained from the batch experiments reveal the ability of the fungus to remove methylene blue. The performance is dependent on the dye concentration, pH, and fungal biomass. The equilibrium and kinetics of adsorption are investigated and the Langmuir equation is used to fit the equilibrium isotherm. The adsorption isotherm of methylene blue follows only the Langmuir model with a correlation coefficient of ca. 0.96–0.99. The maximum adsorption capacity is ca. 70 mg of dye per g of dry fungus at pH 11, 70 mg L–1 dye, and 0.1 g L–1 fungus concentration, respectively. This study demonstrates that the fungus could be used as an effective biosorbent for the treatment of dye‐containing wastewater streams.  相似文献   

13.
The Manning equation is one of the most widely used formulae for calculating the velocity of shallow overland flow in hydrological and erosion models. Precise estimation of the Manning's friction coefficient (n) is critical to determining overland flow and soil erosion processes. Few studies have been conducted to quantify the effects of sediment load on Manning's n on steep slopes. This study was conducted to investigate the potential effects of sediment load on Manning's n in a flume with a fixed bed, under wide ranges of hydraulics and sediment loads. Slope gradient varied from 8·7 to 34·2%, unit flow rate from 0·66 to 5·26 × 10?3 m2 s?1, and sediment load from 0 to 6·95 kg m?1 s?1. The Reynolds number ranged from 350 to 5899. Results showed that Manning's n varied in both sediment‐free and sediment‐laden flows ranging from 0·012 to 0·055. The apparent Manning's coefficients of sediment‐laden flow were much greater than those of sediment‐free flow. The mean Manning coefficient of sediment‐laden flow was 51·27% greater than the mean value of sediment‐free flow. For sediment‐laden flow, Manning's n could be estimated with a power function of unit flow discharge and sediment content. Further studies are needed to quantify the potential effects of sediment load on the Manning's n on erodible beds and in fields. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

14.
Laccase from the white‐rot fungus Pleurotus florida, produced under solid‐state fermentation conditions, was used for the decolorization of reactive dye Remazol Brilliant Blue R (RBBR). RBBR was decolorized up to 46% by P. florida laccase alone in 10 min. In the presence of N‐hydroxybenzotriazole (HBT), the rate of decolorization was enhanced 1.56‐fold. Central composite design of response surface methodology with four variables namely, dye, enzyme, redox mediator concentrations, and time at five levels was applied to optimize the RBBR decolorization. The predicted optimum level of variables for maximum RBBR decolorization (87%) was found to be 52.90 mg L?1 (RBBR), 1.87 U mL?1 (laccase), 0.85 mM (HBT), and 7.17 min (time), respectively. The validation results showed that the experimental value of RBBR decolorization (82%) was close to the predicted one. The disappearance of C–N and C–X groups, and a small shift in N–H groups in Fourier‐transform infra red (FTIR) spectroscopy confirms the degradation of RBBR chromophore by laccase enzyme. The phytotoxicity of RBBR was considerably reduced after the treatment with laccase. RBBR decolorization kinetics; Km and Vmax were calculated to be 145.82 mg L?1 and 24.86 mg L?1 min, respectively.  相似文献   

15.
The sorption of reactive (textile) dyes onto cucurbituril, a cyclic polymer with hydrophobic cavity, was studied. Dye sorption is strongly enhanced by Ca2+ or Sr2+ concentrations up to 100 mmol/L for all studied dyes. Mg2+ and alkaline ions had similar effects for only one dye (Reactive Red 120), and only at higher concentrations. Concentrations above 100 mmol/L – depending on cation and dye – dissolve cucurbituril and prevent dye removal. As shown in previous studies by our group loadings obtained under suitable conditions (calcium concentration between 2 and 100 mmol/L, total salt concentration not exceeding 100 mmol/L) are 1 to 1.7 mol/mol or 0.9 to 1.8 g/g. The chemical mechanism responsible for the ionic influences is still under investigation. Generally, cucurbituril is a potent sorbent for reactive dyes. However, the technical application is still limited by the lack of a support material that would allow use in fixed bed filters.  相似文献   

16.
Bacillus subtilis and its extracellular polysaccharide (EPS) were used in free form as well as immobilized form as biosorbent for the removal of an anionic dye Procion Red MX 5B. Low pH was favourable for biosorption. Immobilization resulted in reduced biosorption of the dye. The presence of functional groups responsible for the high adsorption capacity in free cells (FC) and EPS was confirmed by FTIR analysis. High Qmax and b values were noted in the case of FC and free EPS in contrast to immobilized cells and EPS. The kinetics data showed that the adsorption system followed pseudo‐first‐order reaction at low dye concentration. Desorption of the dye was found to be 100% in 1 N NaOH. In the case of immobilized biomass and EPS the alginate was found to be unstable under high alkaline conditions of NaOH.  相似文献   

17.
Batch sorption technique was carried out for the removal of anionic dye Congo red (CR) from aqueous solution using raw rectorite (R‐REC) and organified rectorite (CTA+‐REC) modified by cetyltrimethylammonium bromide (CTAB) as adsorbents. The effects of organification degree of CTA+‐REC as well as the process parameters including the pH of dye solution, sorption time, and initial dye concentration on adsorption capacity for CR were investigated and the sorption kinetics was also evaluated. The results showed that the sorption behaviors of R‐REC and CTA+‐REC for CR followed pseudo‐second‐order kinetic model and the sorption equilibrium data perfectly obeyed the Langmuir isotherm. The thermodynamic parameters including entropy of sorption (ΔS0), enthalpy of sorption (ΔH0), and Gibbs free energy of sorption (ΔG0) were obtained and analyzed. Fourier transform infrared study revealed that a chemisorption process occurred between CR and CTA+‐REC. REC modified by cationic surfactants showed the higher adsorption capacities for CR compared to R‐REC and in theory would be used as an efficient and promising adsorbent for the removal of anionic dyes in wastewater treatment.  相似文献   

18.
In this study, the adsorption of reactive red 120 (RR 120) on pistachio husk, and the modeling of the adsorption was investigated. Characterization of the pistachio husk was confirmed by Fourier transform infrared spectroscopy. The pHzpc of pistachio husk was found to be pH 8.5. Increasing the initial pH value decreased (p < 0.01) the amount of dye adsorbed. However, increasing the initial dye concentration from 50 to 900 mg/L at pH 1 increased (p < 0.01) the equilibrium dye uptake from 20.83 to 182.10 mg/g. Results indicated that this adsorbent had great potential for the removal of RR 120 dye. The logistic model was found to be the most suitable of the kinetic and equilibrium models tested to describe the adsorption of the dye. The parameters determined from the logistic model were well correlated with the initial dye concentration, and were seen to increase with the increasing initial dye concentration, but this was not observed from pseudo‐second order kinetics.  相似文献   

19.
Sorption behavior of Lanaset Red (LR) G on lentil straw (LS) was studied as a function of particle size, adsorbent dose, initial pH value, initial dye concentration, and contact time. Sorption kinetics data was well described by logistic model. Modified logistic equation can be used to explain effects of initial dye concentrations and contact time on the sorption of LR G with high R2 value. Freundlich model was found to be excellent in representing the equilibrium data. Thermodynamic parameters like free energy (ΔG0), enthalpy (ΔH0), and entropy (ΔS0) were calculated by the use of Langmuir constant. Thermodynamic data showed that the sorption processes were spontaneous and endothermic in nature. Desorption process suggested that strong binding and weak interactions could be formed between adsorbent surface and dye molecules. Results revealed that LS has a remarkable potential for the sorption of LR G.  相似文献   

20.
Purification of Wastewaters Containing Azo Dyes This study describes the degradability of the azo dye C.I. Reactive Violet 5 by a continuous flow biological treatment system consisting of three rotating disc reactors. The azo dye was first decolorized in an anaerobic reactor. Decolorization was improved by adding an auxiliary substrate (yeast extract and acetic acid). Although severe operating conditions were experienced due to failures in the temperature and pH-controllers, the reactor recovered quickly and continued to decolorize reliably. The removal of the auxiliary substrate in the anaerobic reactor was not satisfactory, probably due to the copper in the azo dye. Batch experiments showed that copper was removed from the dye molecule and precipitated during the decolorization. In the continuous flow reactor, the copper precipitate on the disc can redissolve due to a pH-gradient in the fixed biomass becoming toxic again for the bacteria. In the following two aerobic reactors, the auxiliary substrate was degraded, but mineralization of the dye metabolites was insufficient. The aromatic amines produced by the anaerobic decolorization are more toxic in the bacterial luminescence test than the azo dye. Therefore, decolorization alone cannot be used to treat colored wastewater. Since the amines can also be produced in anaerobic parts of rivers, the dyes have to be removed in a more efficient way. That is the reason why in further experiments ozonation is being tested to increase the biological degradability of the azo dye for a following aerobic stage. Either ozonation can be used after the two stage treatment of the dye in anaerobic/aerobic reactors or the dye can be oxidized directly, making the addition of auxiliary substrate unnecessary. These configurations are being tested with the goal to degrade the dye with the least ozone consumption.  相似文献   

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