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1.
Filtration systems containing metallic iron as reactive medium (Fe0 beds) have been intensively used for water treatment during the last two decades. The sustainability of Fe0 beds is severely confined by two major factors: (i) reactivity loss as result of the formation of an oxide scale on Fe0 and (ii) permeability loss due to pore filling by generated iron corrosion products. Both factors are inherent to iron corrosion at pH > 4.5 and are common during the lifespan of a Fe0 bed. It is of great practical significance to improve the performance of Fe0 beds by properly addressing these key factors. Recent studies have shown that both reactivity loss and permeability loss could be addressed by mixing Fe0 and inert materials. For a non‐porous additive like quartz, the threshold value for the Fe0 volumetric proportion is 51%. Using the Fe0/quartz system as reference, this study theoretically discusses the possibility of (i) replacing Fe0 by bimetallic systems (e.g., Fe0/Cu0), or (ii) partially replacing quartz by a reactive metal oxide (MnO2 or TiO2) to improve the efficiency of Fe0 beds. Results confirmed the suitability of both tools for sustaining Fe0 bed performance. It is shown that using a Fe0:MnO2 system with the volumetric proportion 51:49 will yield a filter with 40% residual porosity at Fe0 depletion (MnO2 porosity 62%). This study improves Fe0 bed design and can be considered as a basis for further refinement and detailed research for efficient Fe0 filters.  相似文献   

2.
Metallic iron (Fe0) is often reported as a reducing agent for environmental remediation. There is still controversy as to whether Fe0 plays any significant direct role in the process of contaminant reductive transformation. The view that Fe0 is mostly a generator of reducing agents (e.g. H, H2 and FeII) and Fe oxyhydroxides has been either severely refuted or just tolerated. The tolerance is based on the simplification that, without Fe0, no secondary reducing agents could be available. Accordingly, Fe0 serves as the original source of electron donors (including H, H2 and FeII). The objective of this communication is to refute the named simplification and establish that quantitative reduction results from secondary reducing agents. For this purpose, reports on aqueous contaminant removal by Al0, Fe0 and Zn0 are comparatively discussed. Results indicated that reduction may be quantitative in aqueous systems containing Fe0 and Zn0 while no significant reduction is observed in Al0/H2O systems. Given that Al0 is a stronger reducing agent than Fe0 and Zn0, it is concluded that contaminant reduction in Fe0/H2O systems results from synergic interactions between H/H2 and FeII within porous Fe oxyhydroxides. This conclusion corroborates the operating mode of Fe0 bimetallics as H/H2 producing systems for indirect contaminant reduction.  相似文献   

3.
Over the past 30 years the literature has burgeoned with in situ approaches for groundwater remediation. Of the methods currently available, the use of metallic iron (Fe0) in permeable reactive barrier (PRB) systems is one of the most commonly applied. Despite such interest, an increasing amount of experimental and field observations have reported inconsistent Fe0 barrier operation compared to contemporary theory. In the current work, a critical review of the physical chemistry of aqueous Fe0 corrosion in porous media is presented. Subsequent implications for the design of Fe0 filtration systems are modeled. The results suggest that: (i) for the pH range of natural waters (>4.5), the high volumetric expansion of Fe0 during oxidation and precipitation dictates that Fe0 should be mixed with a non‐expansive material; (ii) naturally occurring solute precipitates have a negligible impact on permeability loss compared to Fe0 expansive corrosion; and (iii) the proliferation of H2 metabolizing bacteria may contribute to alleviate permeability loss. As a consequence, it is suggested that more emphasis must be placed on future work with regard to considering the Fe0 PRB system as a physical (size‐exclusion) water filter device.  相似文献   

4.
The use of metallic iron filters (Fe0 filters) has been discussed as a promising low‐cost option for safe drinking water production at household level. Filter clogging due to the volumetric expansive nature of iron corrosion has been identified as the major problem of Fe0 filters. Mixing Fe0 and sand (yielding Fe0/sand filters) has been proposed as a tool to extent filter service life. However, no systematic discussion rationalizing Fe0/sand mixtures is yet available. This communication theoretically discussed suitable Fe0/sand proportions for efficient filters. Results suggested that Fe0/sand filters should not contain more that 50 vol% Fe0 (25 wt% when Fe0 is mixed with quartz). The actual Fe0 percentage in a filter will depend on its intrinsic reactivity.  相似文献   

5.
Two groups of poorly sorted ash-rich beds, previously interpreted as rain-flushed ashes, occur in the ca. AD 180 Hatepe Plinian pumice fall deposit at Taupo volcano, New Zealand. Two ash beds with similar dispersal patterns and an aggregate thickness of up to 13 cm make up the lowermost group (A). Group A beds extend 45 km north-east of the vent and cover 290 km2. In the southern part of the group A distribution area, a coarse ash to lapilli-size Plinian pumice bed (deposit B) separates the two group A beds. The scarcity of lapilli (material seen elsewhere from the still-depositing pumice fall) in group A beds indicates that they were rapidly transported and deposited. However, this rapid transportation and deposition did not produce cross-bedding, nor did it erode the underlying deposits. It is proposed that thick (>600 m) but dilute gravity currents generated from the collapsing outer margin of the otherwise buoyant Hatepe Plinian eruption column deposited the group A beds. The upper ash beds (group C) consist of one to seven layers, attain an aggregate thickness of 35 cm, and vary considerably in thickness and number of beds with respect to distance from vent. Group C beds contain variable amounts of ash mixed with angular Plinian pumices and are genuine rain-flushed ashes. Several recent eruptions at other volcanoes (Ukinrek Maars, Vulcan, Rabaul, La Soufrère de Guadeloupe and Soufrière, St Vincent) have produced gravity currents similar in style, but much smaller than those envisaged for group A deposits. The overloaded margins of otherwise buoyant eruption plumes generated these gravity currents. Laboratory studies have produced experimental gravity current analogues. Hazards from dilute gravity currents are considerable but often overlooked, thus the recognition of gravity current deposits will contribute to more thorough volcanic hazard assessment of prehistoric eruption sequences.  相似文献   

6.
The Ottaviano eruption occurred in the late neolithic (8000 y B.P.). 2.40 km3 of phonolitic pyroclastic material (0.61 km3 DRE) were emplaced as pyroclastic flow, surge and fall deposits. The eruption began with a fall phase, with a model column height of 14 km, producing a pumice fall deposit (LA). This phase ended with short-lived weak explosive activity, giving rise to a fine-grained deposit (L1), passing to pumice fall deposits as the result of an increasing column height and mass discharge rate. The subsequent two fall phases (producing LB and LC deposits), had model column heights of 20 and 22 km with eruption rates of 2.5 × 107 and 2.81 × 107 kg/s, respectively. These phases ended with the deposition of ash layers (L2 and L3), related to a decreasing, pulsing explosive activity. The values of dynamic parameters calculated for the eruption classify it as a sub-plinian event. Each fall phase was characterized by variations in the eruptive intensity, and several pyroclastic flows were emplaced (F1 to F3). Alternating pumice and ash fall beds record the waning of the eruption. Finally, owing to the collapse of a eruptive column of low gas content, the last pyroclastic flow (F4) was emplaced.  相似文献   

7.
There are ongoing efforts to render conventional biosand filters (BSF) more efficient for safe drinking water provision. One promising option is to amend BSF with a reactive layer containing metallic iron (Fe0). The present communication presents some conceptual options for efficient Fe0‐amended BSF in its fourth generation. It is shown that a second fine‐sand layer should be placed downwards from the Fe0‐reactive layer to capture dissolved iron. This second fine‐sand layer could advantageously contain adsorbing materials (e.g. activated carbons, wooden charcoals). An approach for sizing the Fe0‐reactive layer is suggested based on 3 kg Fe0 per filter. Working with the same Fe0 load will ease comparison of results with different materials and the scaling up of household BSF to large scale community slow sand filters (SSF).  相似文献   

8.
The removal of chemical oxygen demand (COD) and phenol from olive oil mill wastewaters (OOMW) was investigated experimentally by using conventional Fenton (CFP) and Fenton type processes (FTP) with zero valent iron (ZVI). Different operational parameters such as initial pH, Fe2+, Fe0, and H2O2 concentrations were examined. Kinetic studies in terms of COD and phenol removals for both CFP and FTP were performed. The original pH value (4.6) of OOMW for CFP was found as the optimum pH. The determined optimum conditions are [Fe2+] = 1500 mg L?1, [H2O2] = 1750 mg L?1, and pH = 4.6 for CFP; [Fe0] = 2000 mg L?1, [H2O2] = 2000 mg L?1, and pH = 3 for FTP. 82.4% COD and 62% phenol removals were performed under the optimum conditions by CFP, while 82% COD and 63.4% phenol were removed by FTP. According to the results of kinetic studies, it was observed that COD and phenol were removed by FTP more rapidly, compared to CFP. Consequently, it was determined that both CFP and FTP were effective processes for the pretreatment of OOMW.  相似文献   

9.
The 79 ad Plinian eruption of Vesuvius produced first a white pumice fallout from a high steady eruptive column, and then a grey pumice fallout originating from an oscillatory eruptive column with several partial column collapse events after which there was a total column collapse. This first total collapse was followed by renewed Plinian activity and produced the last grey pumice (GP) fallout deposit of the eruption. Textural characteristics (vesicularity and microcrystallinity) of a complete sequence of the pumice fallout deposits are presented along with the major element compositions and residual volatile contents (H2O, Cl) to constrain the degassing processes and the eruptive dynamics. Large variations in residual volatile contents exist between the different eruptive units. Textural features also strongly differ between white and grey pumices, but also within the grey pumices. The degassing processes were thus highly heterogeneous. We propose a new model of the 79 ad eruption in which pre-eruptive conditions (H2O saturation, magma temperature and viscosity) are the critical controls on the diversity of the syn-eruptive degassing processes and hence the eruptive dynamics. Cl contents measured in melt inclusions show that only the white pumice and the upper part of the grey pumice magma were H2O saturated prior to eruption. The white pumice eruptive units represent a typical closed-system degassing evolution, whereas the first grey pumice one, stored under similar pre-eruptive saturation conditions, follows a particular open-system degassing evolution. We suggest that the oscillatory regime that dominated the grey pumice eruptive phase is linked to pre-eruptive water undersaturation of most of the grey magma, and the associated time delays necessary for H2O exsolution. We also suggest that the high residual H2O content of the last grey pumice, deposited after the renewal of Plinian activity following the first total column collapse event, is due to syn-eruptive saturation of GP magma and reduced H2O exsolution efficiency resulting from speciation of dissolved H2O in the melt.  相似文献   

10.
Bench-scale experiments were conducted to investigate the effect of hydraulic loadings and influent concentration on the migration and biotransformation behaviour of three groundwater pollutants: ammonium (NH4+), iron (Fe2+) and manganese (Mn2+). Columns packed with aquifer media collected from a riverbank filtration (RBF) site in Harbin City, NE China were introduced synthetic groundwater (SGW) or real groundwater (RGW) were at two different constant flow rates and initial contaminant concentrations to determine the impact of system conditions on the fate of the target pollutants biotransformation. The results showed that the biotransformation rate of Fe2+ Mn2+ and NH4+ decreased by 8%, 39% and 15% under high flow rate (50 L d−1) compared to low flow rate (25 L d−1), which was consistent with the residence-time effect. While the biotransformation rate of Fe2+ Mn2+ and NH4+ decreased by 7%, 14% and 9% under high influent concentration comparing with original groundwater. The 16S rRNA analysis of the aquifer media at different depths after experiments completion demonstrated that the relative abundance of major functional microbes iron-oxidizing bacteria and manganese-oxidizing bacteria under higher flow rate and higher influent concentration decreased 13%, 14% and 25%, 24%, respectively, whereas the ammonium-oxidizing bacteria and nitrite-oxidizing bacteria exhibited minimal change, compared to the lower flow rate. Above all results indicated that both high flow rate and high concentration inhibit the biotransformation of NH4+, Fe2+ and Mn2+. The biotransformation of Fe2+ and Mn2+ occurs primarily in the 0–40 cm and 20–60 cm depth intervals, respectively, whereas the NH4+ biotransformation appears to occur relatively uniformly throughout the whole 110 cm column. The biotransformation kinetics of NH4+ in RGW and SGW, Mn2+ in RGW at different depths accords with the first order kinetics model, while Fe2+ in RGW and SGW, Mn2+ in SGW presented more complicated biotransformation process. The results should improve understanding of the transport and fate of common groundwater pollutants in RBF and other groundwater recharge environments.  相似文献   

11.
Inorganic industrial waste landfills have the potential to contaminate subsurface groundwater supplies through migration of leachates down to the water table and into groundwater aquifers, despite the use of compacted low permeability clay or polyethene liners. This paper aims the removal of Cu2+ and Zn2+ in the leachate from an industrial waste landfill using natural materials (natural zeolite, expanded vermiculite, pumice, illite, kaolinite, and bentonite) as a liner material. Cu2+ and Zn2+ concentrations for all treatments decreased during the process. Of all the different natural materials, natural zeolite, expanded vermiculite and pumice, with bentonite, were effective in removing Cu2+ and Zn2+ present in the leachate. However, the use of illite and kaolinite with bentonite as liner materials could be of disadvantage in Cu2+ and Zn2+ removal from leachate. The adsorption kinetic models were also tested for the validity. The second order kinetics with the high correlation coefficients best described adsorption kinetic data.  相似文献   

12.
 This paper examines the cause of color variations of trachytic pumices which are essentially uniform in chemical composition and proposes a geological model for their formation. A pyroclastic sequence of distinct subunits with brown, buff, and black pumices was deposited during the 5000-B.P. eruption of a tuff ring in the central Meidob volcanic field (Sudan). Subunits of buff pumices locally contain minor amounts of streaky pumice with pale-gray and dark-gray domains. The combined evidence of petrographic studies, chemical analyses of whole pumices and groundmass separates, electron microprobe analyses, optical spectroscopy, transmission electron microscopy, and magnetic susceptibility measurements show that color variations of the pumice clasts are related to the size and distribution of Fe3+-rich oxide microcrysts. Buff pumice and light-gray domains of streaky pumice have a colorless, transparent groundmass with very few microcrysts. Dark-gray domains of streaky pumice contain abundant hematite and/or magnetite microcrysts visible in thin section within a transparent, colorless glass groundmass. The groundmass of the black pumice clasts is brown in thin section which is most likely caused by submicroscopic magnetite microcrysts. Brown pumice clasts have a mixed groundmass consisting of brown domains and domains with opaque microcrysts in transparent glass. Variations in the eruption dynamics have been inferred from lithological observations. Subunits of black pumices are related to eruption pulses with low magma discharge and high water/magma mass ratio, whereas subunits of buff pumice were deposited during eruption pulses with high magma discharge and low water/magma mass ratio. Brown pumices represent the top part of the magma body, and the initial stage of the eruption probably had a low magma discharge. Streaky pumices are interpreted as the product of syn-eruptive mixing of Fe3+-rich oxide microcryst-bearing magma and microcryst-free magma. Received: 3 February 1997 / Accepted: 28 July 1997  相似文献   

13.
To remove chromate from a wastewater, a porous permeable reactive barrier system (PRBS), using pyrite and biotite, was adapted. This study included bench‐scale column experiments to evaluate the efficiency of the PRBS and investigate the reaction process. The total chromium concentration of the effluent from the biotite and pyrite columns reached the influent concentration of 0·10 mM after passing through more than 150 pore volumes (PVs) and 27 PVs respectively, and remained constant thereafter. The CrVI concentration in the effluent from the biotite column became constant at about 0·08 mM , accounting for approximately 80% of the influent concentration, after passing through 200 PVs. Moreover, in the pyrite column, the CrVI concentration remained at about 0·01 mM , 10% of the input level, after passing through 116 PVs. This shows that both columns maintained their levels of chromate reduction once the CrVI breakthrough curves (BTCs) had reached the steady state, though the steady‐state output concentration of total chromium had reached the influent level. The variances of the iron concentration closely followed those of the chromium. The observed data for both columns were fitted to the predicted BTCs calculated by CXTFIT, a program for estimating the solute transport parameters from experimental data. The degradation coefficient µ of the total chromium BTCs for both columns was zero, suggesting the mechanisms for the removal of chromate limit the µ of the CrVI BTCs. The CrVI degradation of the pyrite column (6·60) was much greater than that of the biotite column (0·27). In addition, the CrVI retardation coefficient R of the pyrite column (253) was also larger than that of the biotite column (125). The R values for the total chromium BTCs from both columns were smaller than those of the CrVI BTC. Whereas the total chromium BTC for the pyrite column showed little retardation (1·5), the biotite column showed considerable retardation (80). The results for the 900 °C heat‐treated biotite column were analogous to those of the control column (quartz sand). This suggests that the heat‐treated biotite played no role in the retardation and removal of hexavalent chromium. The parameters of the heat‐treated biotite were calculated to an R of 1·2 and µ of 0·01, and these values confirmed quantitatively that the heated biotite had little effect on the transport of CrVI. These solute transport parameters, calculated by CXTFIT from the data obtained from the column tests, can provide quantitative information for the evaluation of bench‐ or field‐scale columns as a removal technology for CrVI in wastewater or contaminated groundwater. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

14.
X-ray computed microtomography (μCT) was applied to pumices from the largest Quaternary explosive eruption of the active South Aegean Arc (the Kos Plateau Tuff; KPT) in order to better understand magma permeability within volcanic conduits. Two different types of pumices (one with highly elongated bubbles, tube pumice; and the other with near spherical bubbles, frothy pumice) produced synchronously and with identical chemical composition were selected for μCT imaging to obtain porosity, tortuosity, bubble size and throat size distributions. Tortuosity drops on average from 2.2 in frothy pumice to 1.5 in tube pumice. Bubble size and throat size distributions provide estimates for mean bubble size (~93–98 μm) and mean throat size (~23–29 μm). Using a modified Kozeny-Carman equation, variations in porosity, tortuosity, and throat size observed in KPT pumices explain the spread found in laboratory measurements of the Darcian permeability. Measured difference in inertial permeability between tube and frothy pumices can also be partly explained by the same variables but require an additional parameter related to the internal roughness of the porous medium (friction factor f 0 ). Constitutive equations for both types of permeability allow the quantification of laminar and turbulent gas escape during ascent of rhyolitic magma in volcanic conduits.  相似文献   

15.
— The influence of differential stress on the permeability of a Lower Permian sandstone was investigated. Rock cylinders of 50 mm in diameter and 100 mm length of a fine-grained (mean grain size 0.2 mm), low-porosity (6–9%) sandstone were used to study the relation between differential stress, rock deformation, rock failure and hydraulic properties, with a focus on the changes of hydraulic properties in the pre-failure and failure region of triaxial rock deformation. The experiments were conducted at confining pressures up to 20 MPa, and axial force was controlled by lateral strain with a rate ranging from 10?6 to 10?7 sec?1. While deforming the samples, permeability was determined by steady-state technique with a pressure gradient of 1 MPa over the specimen length and a fluid pressure level between 40 and 90% of the confining pressure. The results show that permeability of low-porosity sandstones under increasing triaxial stress firstly decreases due to compaction and starts to increase after the onset of dilatancy. This kind of permeability evolution is similar to that of crystalline rocks. A significant dependence of permeability evolution on strain rate was found. Comparison of permeability to volumetric strain demonstrates that the permeability increase after the onset of dilatancy is not sufficient to regain the initial permeability up to failure of the specimen. The initial permeability, which was determined in advance of the experiments, usually was regained in the post-failure region. After the onset of dilatancy, the permeability increase displays a linear dependence on volumetric strain.  相似文献   

16.
The origin of reverse grading in air-fall pyroclastic deposits has been ascribed to: (1) changing conditions at an erupting vent; (2) deposition in water; or (3) rolling of large clasts over smaller clasts on the surface of a steep slope. Structural features in a deposit of air-fall pumice lapilli in the Coso Range, California, indicate that reverse grading there formed by a fourth mechanism during flow of pumice. Reverse-graded beds in this deposit occur where pumice lapilli fell on slopes at or near the angle of repose and formed as parts of the blanket of accumulating pumice became unstable and flowed downslope. The process of size sorting during such flow is probably analogous to that which sorts sand grains in a reverse fashion during avalanching on the slip faces of sand dunes, attributed by Bagnold (1954a) to a grain-dispersive pressure acting on particles subjected to a shear stress. In view of the several ways in which air-fall pyroclastic debris may become reverse graded, caution is advised in interpretation of the origin of this structure both in modern and in ancient deposits.  相似文献   

17.
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18.
The study area is located in the east part of the Trans-Mexican Volcanic Belt, in the Las Cumbres Volcanic Complex (LCVC) which lies between two large stratovolcanoes: Pico de Orizaba (5700 m a.s.l.) to the south, and Cofre de Perote (4200 m a.s.l.) to the NNE. The most conspicuous structure of the LCVC is a 4-km-diameter circular crater with a dacitic dome in the center, which constitutes the remains of a destroyed stratovolcano.The Quetzalapa Pumice (QP) was produced by a plinian eruption that was dated by the 14C method at 20 000 yr. BP. The eruptive sequence consists predominantly of pumice fall deposits and scarce intra-plinian pyroclastic flow deposits, which crop out on the west flank of the LCVC. The absence of post-plinian ignimbrite deposits is striking.The deposits are well sorted, clast-supported with reverse grading at the base, with a medium to high accessory lithics content. The maximum average thickness of the deposit in the proximal areas is about 15 m and has been divided into three members: the Basal Member (BM), 2 m thick with four submembers (BMf1, BMf2, BMf3, and BMafl), the Intermediate Member (IM), 10 m thick with two submembers (IMpf and IMaf), and the Upper Member (UM), 3 m thick with four submembers (UMpl, UMsdf, UMwaf, and UMpls).The predominant component of the fall deposits is a white, highly vesiculated pumice with 71% SiO2 content. Plagioclase is the most abundant mineral followed by 1–3-mm-long biotite phenocrysts. The accessory lithics are lavas mostly of andesitic composition. Their abundance increases toward the uppermost levels of the sequence.We calculate a minimum volume of 8.4 km3 (2.22 km3 dense rock equivalent), for the entire QP deposit. Isopach and isopleth maps show that the IM deposit has an elongated distribution with a NNE–SSW direction, whereas the UM deposit has a circular distribution.We estimate a maximum eruptive column height for the IM of 20 km. Field studies and isopach and isopleth maps indicate that the eruptive column was affected by a strong wind.Previous studies located the QP source in the Las Cumbres crater. However, based on the isopach and isopleth distribution, and the lack of pumice fall deposits inside the Las Cumbres crater, we consider that the QP emission center is located on the west flank of the LCVC, and was buried by its own pumice fall deposits. It coincides with an explosion crater called La Capilla formed during the closing phase of the QP eruption.A ‘pumice fountain’ model is proposed to explain the observed sequence of deposits. According to this model, the material was emitted through a ‘hose-type’ conduit during a monogenetic eruption of rhyolitic composition. This kind of volcanic activity is not extensively reported in the literature.  相似文献   

19.
The October, 1902, eruption of Santa Maria Volcano, Guatemala, was one of the largest this century. It was preceded by a great earthquake on April 19 centered at the volcano, as well as numerous other major earthquakes. The 18–20 hour-long plinian eruption on October 25 produced a column at least 28 km high, reaching well into the stratosphere.The airfall pumice deposit covered more than 1.2 million km2 with a trace of ash and was only two meters thick at the vent. White dacitic pumice, dark gray scoriaceous basalt (with physically and chemically mixed intermediate pumice) and loose crystals of plagioclase, hornblende, hypersthene, biotite and magnetite make up the juvenile components of the deposit. Lithic fragments are of volcanic, plutonic, and metamorphic origin. The plinian deposit is a fine-grained, crystal-rich, single pumice fall unit and shows inverse grading. Mapping of the deposit gives a volume of 8.3 km3 within the one mm isopach. Crystal concentration studies show that the true volume erupted was at least 20 km3 (equivalent to 8.5 km3 of dense dacite) and that 90% of the ejecta was less than 2 mm in diameter.The plinian volume eruption rate averaged 1.2 × 105 m3s−1 and the average gas muzzle velocity of the column exceeded 270 ms−1. A total of 8.3 × 1018 J of energy were released by the eruption. A knowledge of both theoretically derived eruption parameters and contemporary information allows a detailed analysis of eruption mechanisms.This eruption was the major stratospheric aerosol injection in the 1902–1903 period. However, mid- to low- latitude northern hemisphere temperature deviation data for the years following the eruption show no significant temperature decrease. This may be explained by the sulfur-poor nature of dacite magmas, suggesting that volatile composition, rather than mass of volatiles, is the controlling parameter in climatic response to explosive eruptions.  相似文献   

20.
The 274 ka “Basalt-Trachytic Tuff of Tuoripunzoli” (TBTT) from Roccamonfina volcano (Roman Region, Italy) consists of a basaltic scoria lapilli fall (Unit A) overlain by a trachytic sequence formed by a surge (Unit B), repetitive pumice lapilli and ash-rich layers both of fallout origin (Unit C) and a pyroclastic flow deposit (Unit D). The TBTT is widespread (40 km2) in the northern sector of the volcano, but limited to a small area on the southern slopes of the main cone. Interpolation between the northern deposits and the latter one yields a minimum depositional area of 123 km2, and an approximate bulk volume of 0.2-0.3 km3. Isopach and isopleth maps are consistent with a source vent within the main caldera of Roccamonfina.Unit A shows a fairly good sorting and a moderate grain size; glass fragments are cuspate and vesicular. Unit B is fine grained and poorly sorted; shards are blocky and nonvesicular. Pumice lapilli of Unit C are moderately sorted and moderately coarse grained. Glass shards are equant and vesicular. Lithic clasts are strongly comminuted to submillimetric sizes. By contrast, the ash-rich internal divisions are very fine grained and poorly sorted. They consist of a mixture of equant shards which are prevailingly blocky and poorly vesicular. Unit D is a massive, poorly sorted, moderately coarse-grained deposit. Glass fragments are nearly equant and slightly or nonvesicular.The TBTT is interpreted as due to eruption of a basaltic magma followed in rapid succession by one trachyte magma. Unit A formed by Subplinian fallout of a moderate, purely magmatic column. Interaction between a trachyte magma and water resulted in eruption of surge Unit B. A high-standing eruption column erupted alternating fallout pumice lapilli and fallout ashes. Pumice lapilli originated prevailingly from the inner part of the eruption column, whereas magma-water interaction on the external parts of the column resulted in ash fallout. The uppermost pyroclastic flow Unit D is interpreted as due to final collapse of the eruption column.  相似文献   

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