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1.
Water quality index and fractal dimension analysis of water parameters   总被引：2，自引：2，他引：0  
Statistical analysis of water quality parameters were analyzed at Harike Lake on the confluence of Beas and Sutlej rivers of Punjab (India). Mean, median, mode, standard deviation, kurtosis, skewness, coefficient of variation, regression lines, correlation coefficient, Hurst exponent, fractal dimension and predictability index were estimated for each water parameter. Monthly variation of water quality index using month-wise and parameter-wise value of quality rating and actual value present in water sample was calculated and compared with World Health Organization/Environmental Protection Agency standard value of these parameters. It was observed that Brownian time series behavior exists of potential of hydrogen with total dissolved solids, hardness, alkalinity, sulfate, chloride and conductance parameters; biochemical oxygen demand with total dissolved solids, hardness, alkalinity, sulfate, chloride, conductance and calcium parameters; dissolved oxygen with total dissolved solids, hardness, alkalinity, sulfate, chloride, conductance and calcium parameters; ferrous with total dissolved solids, hardness, alkalinity, sulfate, conductance and calcium parameters; chromium with total dissolved solids, hardness, alkalinity, sulfate, chloride, conductance and zinc parameters; zinc with total dissolved solids, hardness, sulfate, chloride, conductance and calcium parameters; fluoride with total dissolved solids, hardness, alkalinity, sulfate, chloride and conductance parameters; nitrate with total dissolved solids, sulfate and conductance parameters; nitrite with potential of hydrogen, total dissolved solids, hardness, alkalinity, sulfate, chloride, conductance and calcium parameters. Also, using water quality index, it was observed that water of the lake was severely contaminated and became unfit for drinking and industrial use.  相似文献   

2.
The accumulating volumes of data collected within environmental monitoring programs facilitate the use of exploratory statistical methods of data analysis as a supplement to traditional methods of characterizing lake water quality. When principal component analysis and multidimensional scaling are applied to a matrix containing approximately 24000 samples of lake water quality variables pH, alkalinity, conductivity, hardness, color, Secchi depth and total phosphorus concentration, it is found that the total matrix variance can be approximately reproduced in an orthogonal two-dimensional base with transformations of hardness and color as best principal component representatives. This base is suggested as an empirical lake classification standard where the variance structure of subset lake populations (such as single lakes) can be referenced to the water quality standard of the generic population. Since the principal axes of the base exclusively contain inorganic and organic related variables respectively, the combined inorganic/organic characteristics of the lake can be expressed with the hardness and color variables alone. With the data matrix being large enough to produce high significance levels, and with variable ranges wide enough to represent a majority of dimictic, glacial/boreal lakes, the analysis results should be valid in many lakes throughout the world.  相似文献   

3.
Relationships between drainage area characteristics and lake water quality   总被引：1，自引：0，他引：1  
The aim of this work is to quantify some of the complex relationships between drainage area characteristics (such as bedrocks and quaternary deposits) and lake water quality (pH, alkalinity, conductivity, and hardness). Seventysix drainage lakes, mainly oligotrophic, are described with respect to drainage area characteristics, morphometry, and water chemistry. The DAZ (drainage area zonation) method has been used to describe the drainage areas. The method utilizes a weighting system to reduce the impact of land types with increasing distance from the lake. The most significant parameter governing the water chemistry parameters seems to be the percentage of open land (cultivated land and/or meadows) in the drainage areas. High percentage leads to high pH, alkalinity, conductivity, and hardness. The correlations concerning alkalinity and pH are improved using the DAZ method. No significant relationships between bedrock geology of the drainage areas and lake water chemistry have been recorded.  相似文献   

4.
Water, soil, suspended load and biomass samples were collected from a sewage and sludge treated lake (Lake Dalavayi) around Mysore, Karnataka, India. The polluted lake water is mainly used for irrigation and domestic purposes. The samples have been analysed for heavy metals (Cu, Cr, Co, Cd, Ni, Fe, Mn, V, Zn, Sr) and cations (Ca, Na, Mg) by Inductively Coupled Plasma Emission Spectrometer (ICP) model Labtam 8500. With the exception of water, all the matrices suspended particulate matter, lake bed sediment and biomass of the lake show high concentrations of heavy metals and cations when compared to the World Health Organization (WHO) standard, indicating metal toxicity in this lake. Additional inputs of soaps and detergents carried by sewage water are causing the eutrophication of the lake. Elevated levels of heavy metal toxicity, especially Co and Cd, are indicated by the bioindicator Eichornia cressepes (water hyacinth), which, using these metals as micronutrients, has grown luxuriously over the lake water, further augmenting the death of lifeforms in the lake.  相似文献   

5.
Evaluation of analyses of leachate for inorganic constituents, from selected landfills in Illinois indicates that leachate quality is variable and is strongly affected by waste type and cover material. Twenty parameters were detectable in all samples, but selenium was not detected in any of the samples analyzed. More than 98% of the mean leachate composition was comprised, in descending order, of total alkalinity (bicarbonate plus carbonate), sulfate, sodium plus potassium, calcium plus magnesium, chloride, and iron plus managese. Excluding iron, trace metals contributed less than one percent to the total; of these, copper, zinc and boron were most significant. Based on milliequivalents per liter of major constituents, approximately 73 percent of the cations and 92% of the anions fall within the concentration range of potable waters. Heavy metals, organics, suspended matter, microorganisms, odor and color are among the objectionable qualities of leachate which should not be present in potable waters. In assessing the impact of leachate on ground-water quality, use of indicator parameters in place of comprehensive analyses for routine water samples is frequently desirable in the interest of both time and economics. Availability, mobility, persistence, analyticity and contrast of concentrations in leachate and ground water are important factors to consider in selection of an indicator. Boron, iron, ammonia and total dissolved solids appear to be reliable parameters for indicating ground-water pollution by leachate. Chloride and hardness may also be useful under certain conditions. Sulfate was the least reliable parameter considered. Although many of the trace elements in leachate exceed Illinois Environmental Protection Agency Public Water Supply Standards in more than 50% of the samples, these elements are most useful as indicators when a waste rich in trace elements is deposited in a landfill of unfavorable hydrogeology.  相似文献   

6.
邓丽娟  刘亮 《地下水》2009,31(2):17-19
依据新疆某水库周边耕地地下水水样化验数据,应用灰色关联分析与相关分析相结合的方法,分析了地下水主要成分与总硬度、总碱度、电导率及矿化度4个指标之间的关系.结果表明,总硬度变化主要受Ca2+影响,水中HCO3-含量与总碱度关系密切,电导率主要受Mg2+影响,Na+、K+和与Mg2+对矿化度有较大影响.通过相关分析,发现它们之间相关性极为显著.  相似文献   

7.
Gökçekaya Dam is one of the dams located on the Sakarya River (Eski?ehir) in Turkey and is approximately 38 years old. No study regarding to the water quality of the dam lake has been hitherto made. This study aimed at determining the seasonal variations with physical, chemical, and biological parameters of the water quality of the dam lake. Depth-wise water samples were taken from five selected stations, in seasonal periods during 2005–2008, and anlayzed. The quality of water was classified in accordance with the results and taking into consideration many parameters. At the same time, number and type diversities of dissolved heavy metals and algae population were analyzed. Using principal component analysis (PCA) and classification analysis (CA) methods, differences between these parameters and samples from stations have been determined . The analysis showed that Gökçekaya dam lake, formerly an oligotrophic lake, has become a mesotrophic lake. And according to the results thereof the Lake has mezotrophic characteristics due to the sudden changes (including household waste water inflow and opening the Sar?yar dam lake shutters) in certain periods and in some stations. Hierarchical clustering analysis, revealed no significant difference between the measured parameters. And according to the Water Pollution Control Regulations in Turkey (WPCR) Gökçekaya dam lake is in the first class quality in terms of anions, cations, heavy metals, temperature, and pH values. However, the is of first class quality presence of nitrite reduces the water quality in the lake and causes this lake to be classified in the fourth class quality.  相似文献   

8.
为探讨冲洪积平原地带地下水水质劣变机理及过程,开展了不同的水土样品组合的16组淋滤试验,以期揭示不同源水在土柱入渗过程阴阳离子、硬度和TDS的变化规律以及地下水类型的演化特征。试验结果表明:淋出液中,阴离子浓度的变幅由大到小依次为HCO_3~-、NO_3~-、SO_4~(2-)、Cl~-和F~-,阳离子的变幅则依次为Na~++K~+、Ca~(2+)和Mg~(2+)。淋出液的硬度、TDS和水化学类型均呈现出有规律的变化,先期主要受控于源水,尔后则主要受土柱介质的影响。除了以垃圾作为淋滤介质的试验外,其他组合的试验都出现了初期TDS和硬度升高的过程,之后与源水趋于一致,揭示了淋滤中浸泡—水岩相互作用—吸附解析—淋洗等复杂过程。  相似文献   

9.
为探究青藏高原搭格架地热区地热水、湖水、河水、冰雪融水等天然水体的水化学组成及物质来源控制因子,于2014年8月对该地区进行了考察和取样。利用紫外-可见光分光光度计和ICP-OES测定了水样中各阴、阳离子含量,利用Gas Bench连接同位素质谱仪测定了水样中溶解无机碳（DIC）同位素比值。结果表明,地热水中总溶解固体（TDS）含量为977.13~1 279.50 mg/L,阳离子以K+和Na+为主,阴离子以HCO3-和Cl-为主,湖水的TDS含量为77.81~810.94 mg/L,阳离子以Na+和Ca2+为主,阴离子以HCO3-(CO32-)和SO42-为主,地热水和湖水的水化学类型为HCO3-Na型;河水和冰雪融水的各离子含量较低,水化学类型为HCO3-Ca型;地热水的DIC浓度范围为9.2~15.4 mmol/L,δ13CDIC值为-9.09‰~-0.95‰;湖水的DIC浓度为1.1~9.7 mmol/L,δ13CDIC值为-8.84‰~-0.27‰。根据水化学Gibbs分布模式图判断出区域水化学特征主要受硅酸盐岩风化控制,以钠长石和钾长石风化为主,但是地热水的水化学组分受到硅酸盐岩和蒸发盐岩共同控制。通过碳同位素比值分析对区域主要风化过程中CO2的来源示踪表明,湖区周围的硅酸盐风化其碳源主要为土壤CO2,热泉区硅酸盐水解其碳源为地球深部CO2输入。   相似文献   

10.
Branched glycerol dialkyl glycerol tetraethers (GDGTs) are bacterial membrane lipids, ubiquitously present in soils and peat bogs, as well as in rivers, lakes and lake sediments. Their distribution in soil is controlled mainly by pH and mean annual air temperature, but the controls on their distribution in lake sediments are less well understood. Several studies have found a relationship between the distribution of branched GDGTs in lake sediments and average lake water pH, suggesting an aquatic source for them, besides that for soil transported to the lake via erosion. We sampled the surface water suspended particulate matter (SPM) from 23 lakes in Minnesota and Iowa (USA), that vary widely in pH, alkalinity and trophic state. The SPM was analyzed for the concentration and distributions of core lipid (presumed fossil origin) and intact polar lipid (IPL, presumed to derive from living cells) branched GDGTs. The presence of substantial amounts (18–48%) of IPL-derived branched GDGTs suggests that branched GDGTs are likely of autochthonous origin. Temperature estimates based on their distribution using lake-specific calibrations agree reasonably with water temperature at time of sampling and average air temperature of the season of sampling. Importantly, a strong correlation between the distribution of branched GDGTs and lake water pH was found (r2 0.72), in agreement with a predominant in situ production. An stronger correlation was found with lake water alkalinity (r2 0.83), although the underlying mechanism that controls the relationship is not understood. Our results raise the potential for reconstructing pH/alkalinity of past lake environments, which could provide important knowledge on past developments in lake water chemistry.  相似文献   

11.
The results of an international interlaboratory proficiency test for the determination of carbonic species are presented. Eight laboratories analysed twelve water samples (four synthetic waters, one lake water, four geothermal waters, one seawater and two petroleum waters) by two methods: (a) individual laboratory analytical procedure and (b) acid–base titration curves in tabular form following a standardised protocol. In case (b), the concentrations of carbonic species were calculated by the organiser using the (1) Hydrologists' method, (2) Geochemists' method and/or (3) initial pH and total alkalinity method. For synthetic waters, the averaged % trueness and precision of measurement of the two methods were (trueness = 7.6, precision = 9.4) and (9.0, 3.4) for total alkalinity, and (6.6, 31.0) and (7.8, 6.1) for carbonic alkalinity, respectively. This indicates that the total alkalinity calculation procedure is in general correct in the individual laboratory method, but the carbonic alkalinity calculation procedure has serious problems. The measurements of total alkalinity for lake and seawaters were in agreement in both the methods; however, the individual laboratory measurement method for geothermal and petroleum waters was conceptually incorrect. Thus, the analytical procedures for the determination of carbonic species were reviewed. To apply the Hydrologists' and/or Geochemists' methods, the location of NaHCO3EP and H2CO3EP is necessary, even for samples with pH lower than that of NaHCO3EP, and a backward titration curve after complete removal of CO2 must be performed. The initial pH and total alkalinity method is appropriate where a complete analysis of species that contribute to the alkalinity is known.  相似文献   

12.
Groundwater quality assessment in southern parts of Tehran plain,Iran   总被引：1，自引：1，他引：0  
The hydrochemical characteristics of groundwater in the southern parts of Tehran Province are considered. Twenty-three sampling stations were selected and major anions/cations, electrical conductivity and pH were detected. Sulfate and chloride were found as major anions, while no specific dominant cation was determined. More than half of the samples were found to be unsuitable for drinking purposes, due to high concentrations of anions/cations. Regarding agricultural use, almost all samples were classified as having high-risk levels of salinity, while for alkali hazard considerable risks were observed in most cases. Generally, an increasing trend of salinity is observed from northwest to southeast of the study area. Such increase may be justified by the adjacency of the Iran central desert and salt lake to the southern boundaries of the study area. Extended use of sulfate-containing fertilizers may also play a key role in justifying the high sulfate concentration in comparison to other anions.  相似文献   

13.
Surface water samples were collected from Langtang Lirung glacier outlet point to the Narayani river system in central Nepal in order to investigate the role of elevation in the variation of chemistry along the drainage networks. The chemistry of Langtang–Narayani river system was dominated by sulfide oxidation coupled with carbonate dissolution and weathering of silicate minerals. Calcium and magnesium concentrations were relatively higher than other cations and the sum of both species strongly correlated with alkalinity, supporting the dissolution of carbonate and dolomite as the dominant source for these ions. Aluminosilicate minerals primarily as albite and anorthite appeared as dominant silicate minerals within the drainage basin. Bisiallitization was the dominant type of weathering within the entire drainage system. Hydrogen ion concentration was lower in the low elevation sites than in high elevation sites reflecting the more consumption of carbon dioxide in the low elevation sites due to enhanced chemical weathering rates. Furthermore, major solutes like sum of base cations, silicon as well as alkalinity increased in concentration in the lower elevation sites. All regulating factors appeared to be directly related to elevation and hence elevation appeared to be the prime factor for the variation in chemical species along the Langtang–Narayani river system. Toshiyuki Masuzawa: deceased.  相似文献   

14.
A hydrogeochemical study was conducted in Thoothukudi district situated in the southeast coast of Tamil Nadu, India to identify the influence of saltwater intrusion and suitability of groundwater for domestic and agricultural purposes. Scattered studies of this coastal region have reported signs of seawater intrusion, salt pan and industrial activity together with natural weathering process. To have a holistic picture of geochemical processes in the entire district, a total of 135 groundwater samples were collected and analyzed for major cations and anions. The geochemical parameters were compared with world and Indian standards and it was found that most samples are unsuitable for drinking purpose. The geochemical facies of the groundwater showed Na–Cl as the dominant water type indicating the saline nature of the groundwater. Chadda’s plots show that most of the samples fall in the Na–Cl type of water due to seawater intrusion. The samples were classified with parameters like sodium absorption ratio, residual sodium carbonate, total hardness, chloride, index to base exchange, electrical conductivity and facies to determine their suitability for irrigation purpose. It was inferred that the samples falling along the coast are not suitable for the irrigation purpose. The seawater-mixing percentage indicates that strong mixing was observed in the near shore and at the proximity of the salt pan. The permanent hardness was predominant in all the samples compared to the carbonate hardness reducing its domestic usability.  相似文献   

15.
Geochemical analyses of groundwater and streams flowing around abandoned and active dumpsites in Lagos, Southwestern Nigeria were carried out. Results show that water samples have generally low total dissolved solids with average values of 163.75 and 153.4 for abandoned and active dumpsites, respectively. pH ranges from 3.96-8.34 while total hardness varies from 10–220 mg/L calcium carbonate (soft to slightly hard). Average concentrations of the dominant ions for abandoned and active dumpsites were 57.8 and 25.86 mg/L (Na) representing 40.7 and 46.3 % of the total cations respectively and Nitrate (av. 96.89 and 61.51 mg/L) representing 49.1 % and 40 %, respectively of the total anions. The pH, coliform count and concentrations of nitrate iron, manganese and sodium in most of the water samples were above the national drinking water standards proposed by the United States Environmental Protection Agency. Trace elements like silver, arsenic, beryllium, bismuth, cerium, cobalt, chromium, lithium selenium, tellurium, titanium, uranium, vanadium, tin and yttrium were below detection level for all the water samples while tungsten, thallium, molybdenum and lead were only present in surface and groundwater close to the dumpsites and also display values higher than recommended standards while cupper, zinc, aluminum, barium and strontium were present in most of the samples. The pollution index among all sites varied from 0.009 to 1.26 and 0.106 to 6.25 for abandoned and active dumpsites, respectively while the water around most of the dumpsite areas exceeded the acute and chronic effect levels proposed by the United States Environmental Protection Agency in 2007.  相似文献   

16.
The Varahi Irrigation project site is located at 13°39′15″N (latitude) and 74°57′E (longitude) in Hole Shankaranarayana village, approximately 6 km from Siddapura, Kundapura taluk, Udupi district. A total of 59 groundwater samples were collected from dug and tube wells in November 2008 to evaluate hydrochemistry and suitability for drinking and irrigation purposes. The physico-chemical parameters estimated include pH, electrical conductivity (EC), total dissolved solids (TDS), redox potential (Eh), total hardness (TH), total alkalinity (TA), temperature, major cations and anions, besides irrigation quality parameters like boron, sodium absorption ratio (SAR), % Na, residual sodium carbonate (RSC), residual sodium bicarbonate (RSBC), chlorinity index, soluble sodium percentage (SSP), exchangeable sodium ratio (ESR), non-carbonate hardness, potential salinity (PS), permeability index (PI), Kelly index (KI), magnesium hazard (MH), magnesium ratio (MR), index of base exchange. Chloride, sulphate and bicarbonate concentrations classified the groundwater samples into normal chloride, normal sulphate and normal bicarbonate water types, respectively. The Salinity (Class I; 98.3%), Chlorinity (Class I; 100%) and Sodicity (Class 0; 96.6%) indices suggest the suitability of groundwater for irrigation. The Wilcox diagram illustrates that 96.6% of the samples belongs to excellent to good category, while the US Salinity Laboratory (USSL) diagram indicates the low salinity/low sodium content in 86.44% of samples (C1S1). Positive index of base exchange in majority of the samples (91.52%) indicates direct base exchange reaction or chloro-alkaline equilibrium in the study area. The positive value of RSC in majority of samples signifying higher concentrations of HCO3 over alkaline earths indicates that groundwater are base exchange-softened water as there is an exchange of alkaline earths for Na+ ions. Majority of water samples fall in the precipitation dominance field based on Gibbs’ ratio.  相似文献   

17.
 Soil and groundwater samples were collected during two seasons, premonsoon (April 1990) and postmonsoon (December 1990), and analyzed for major elements (Na, Mg, Al, Si, P, K, Ca, Ti, Mn and Fe), trace elements (Ni, Pb, Co, Cr and Zn) and water parameters (pH, conductivity, acidity, alkalinity, hardness, Cl and SO4). All the data were subjected to linear discriminant analysis and partial correlation analysis in order to understand the seasonal variation in the data. It was observed from the Mahalanobis generalized distance that in both soil and groundwater samples there was a large difference in the concentration level of premonsoon and postmonsoon data. Linear discriminant functions were calculated to distinguish between premonsoon and postmonsoon samples. From the partial correlation coefficient analysis of soil samples, dominance of chemical weathering and precipitation of atmospheric fallout during monsoon were inferred. In the case of the water samples, high conductivity and high hardness in the postmonsoon samples as well as atmospheric fallout of Pb and Ni during the premonsoon period was suggested from partial correlation of water samples. Received: 19 September 1995 · Accepted: 12 December 1995  相似文献   

18.
Major Ion Geochemistry of Nam Co Lake and its Sources, Tibetan Plateau   总被引：4，自引：0，他引：4  
The major cations and anions from lake water samples and its sources, including glacier snow, precipitation, stream, and swamp water in the Nam Co basin, central Tibetan Plateau, were studied. The concentrations of the major ions varied significantly in the five environmental matrices. Generally, the mean concentrations of most ions are in the order of lake water > swamp water > stream water > precipitation > snow. Rock weathering is the dominant process controlling the chemical compositions of the stream and swamp waters, with carbonate weathering being the primary source of the dissolved ions. The Nam Co lake water is characterized by high Na+ concentration and extremely low Ca2+ concentration relative to other ions, resulting from evapoconcentration and chemical precipitation within the lake. Comparison with the water chemistry of other lakes over the Tibetan Plateau indicated that Nam Co is located in a transition area between non-saline lakes and highly saline lakes. The relatively low concentration of total dissolved solids is possibly due to the abundant inflow of glacial meltwater and relatively high annual precipitation.  相似文献   

19.
The Markandeya River Basin stretches geographically from 15o56′ to 16o08′ N latitude and 74o37′ to 74o58′ E longitude, positioned in the midst of Belgaum district, in the northern part of Karnataka. The groundwater quality of 54 pre-monsoon samples in the Markandeya River Basin was evaluated for its suitability for drinking and irrigation purposes by estimating pH, EC, TDS, hardness and alkalinity besides major cations (Na+, K+, Ca2+, Mg2+) and anions (HCO3–, Cl–, SO42–, PO43-, F-, NO3–), boron, SAR, % Na, RSC, RSBC, chlorinity index, SSP, non-carbonate hardness, Potential Salinity, Permeability Index, Kelley’s ratio, Magnesium hazard and Index of Base Exchange. Negative Index of Base Exchange indicates the chloro-alkaline disequilibrium in the study area and the majority of water samples fall in the rock dominance field based on Gibbs’ ratio. Permeability indices of classes I and II suggest suitability of groundwater for irrigation. Based on Cl, SO4, HCO3 concentrations, water samples can be classified as normal chloride (96.3%) and normal sulfate (94.4%) and normal bicarbonate (44.4%) water types.  相似文献   

20.
Punjab is the most cultivated state in India with the highest consumption of fertilizers. Patiala and Muktsar districts are two agricultural dominated districts of Punjab located in extreme south-east and south-west of the state. This paper highlights temporal variations of the groundwater quality and compares its suitability for irrigation and drinking purpose in these two districts. Water samples were collected in March and September 2003, representing the pre-monsoon and post-monsoon seasons, respectively. Water samples were analysed for almost all major cations, anions, dissolved heavy metals and turbidity. Parameters like sodium adsorption ratio, % sodium, residual sodium carbonate, total hardness, potential salinity, Kelley’s ratio, magnesium ratio, index of base exchange and permeability index were calculated on the basis of chemical data. A questionnaire was also used to investigate perception of villagers on taste and odour. Comparison of the concentration of the chemical constituents with WHO (world health organization) drinking water standards of 2004 and various classifications show that present status of groundwater in Patiala is better for irrigation and drinking purposes except for a few locations with a caution that it may deteriorate in near future. In Muktsar, groundwater is not suitable for drinking. Higher total hardness (TH) and total dissolved solids at numerous places indicate the unsuitability of groundwater for drinking and irrigation. Results obtained in this forms baseline data for the utility of groundwater. In terms of monsoon impact, Patiala groundwater shows dilution and flushing but Muktsar samples show excessive leaching of different chemical components into the groundwater leading to the enrichment of different anions and cations indicating pollution from extraneous sources. No clear correlation between the quality parameters studied here and perceived quality in terms of satisfactory taste response were obtained at electrical conductivity values higher than the threshold minimum acceptable value.  相似文献   

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