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1.
Biosurfactants are frequently used in petroleum hydrocarbon and dense non-aqueous phase liquids (DNAPLs) remediation. The applicability of biosurfactant use in clayey soils requires an understanding and characterization of their interaction. Comprehensive effects of surfactants and electrolyte solutions on kaolinite clay soil were investigated for index properties, compaction, strength characteristics, hydraulic conductivities, and adsorption characteristics. Sodium dodecyl sulfate (SDS) and NaPO3 decreased the liquid limit and plasticity index of the test soil. Maximum dry unit weights were increased and optimum moisture contents were decreased as SDS and biosurfactant were added for the compaction tests for mixtures of 30% kaolinite and 70% sand. The addition of non-ionic surfactant, biosurfactant, and CaCl2 increased the initial elastic modulus and undrained shear strength of the kaolinite–sand mixture soils. Hydraulic conductivities were measured by fixed-wall double-ring permeameters. Results showed that the hydraulic conductivity was not significantly affected, but slightly decreased from 1×10−7 cm/s (water) to 0.3×10−7 cm/s for Triton X-100 and SDS. The adsorption characteristics of the chemicals onto kaolinite were also investigated by developing isotherm curves. SDS adsorbed onto soil particles with the strongest bonding strength of the fluids tested. Correlations among parameters were developed for surfactants, electrolyte solutions, and clayey soils.  相似文献   

2.
Effects of sheet flow rate and slope gradient on sediment load   总被引：2，自引：0，他引：2  
Sheet erosion is known as one of the most important forms of erosion, particularly in agricultural land. The purpose of this study was to investigate the effect of flow rate and slope gradient on runoff and sediment discharges in two different soils. Experiments were conducted using a tilting flume facility with the test area of 0.2?×?1.0 m. Overall, 24 experiments on two soils (clay loam and sandy clay loam textures) including six flow rates (75, 100, 125, 150, 175, and 200 ml/s) and two slope gradients (1.5 and 2 %) were performed. The selected flow rates and flume slopes were generated to simulate sheet erosion. The results showed that for both soils and slopes, unit flow discharge (q) and sediment concentration increased with increasing flow rate; however, the effect of slope gradient on flow discharge depends on soil type. In addition, sandy clay loam exhibited higher values of q and sediment concentration and consequently, it showed greater amounts of sediment load. At the start of event, sediment concentration was high but it decreased to approach a steady state. In addition, the time needed to reach a steady state condition was shorter for sandy clay loam than that for clay loam soil and in lower flow rates than higher flow rates. For each soil and slope, there was a direct relationship between sediment load and flow rate. The result implied that the effect of slope gradient on sediment load was almost greater in sandy clay loam soil than clay loam soil. Moreover, the differences between sediment loads of two soils are enlarged at slope 2 %.  相似文献   

3.
This study aimed to evaluate boron (B) adsorption and the capacity of a surface complexation model for simulating this process in calcareous soils. Ten surface soils were collected from different land use areas in Hamedan, Western Iran, to characterize B sorption by soils. The mean B adsorbed by the sample soils varied from 8.9 to 32.8 %. Two empirical models including linear and Freundlich equations fitted well to the experimental data. The linear distribution (K d) values varied from 1.32 to 6.86 L kg?1, while the parameters of Freundlich equation including n and K Fr ranged from 1.16 to 1.33 and 3.31–16.81, respectively. The comparison of two empirical models indicated that B adsorption followed a nonlinear pattern. The soil organic matter had positive correlations with Freundlich and linear distribution coefficients. However, empirical models were not suitable for explaining the mechanism of B adsorption, so a surface complexation model was used to simulate and predict the B adsorption process. B adsorption modeling was conducted using Visual MINTEQ and PHREEQC, based on the assemblage of major surface components (hydrous ferric oxides, aluminum hydroxides, calcium carbonate, and humic acids). B adsorption was successfully modeled by surface complexation. The significant contribution of organic matter to B complexes was resulted from both experimental data and mechanistic modeling.  相似文献   

4.
In this study, bentonite (Ben), compost (Com), and biochar (Bio) were used as soil amendments to enhance sandy soil physical properties. A soil column experiment was conducted in a laboratory. Application rates were 3% (weight/weight) of Bio (T1), Ben (T2), and Com (T3). Furthermore, mixtures 1.5% and 1.5% of Bio and Ben (T4), Ben and Com (T5), and Bio and Com (T6), and a mixture 1%, 1%, and 1% of Bio, Ben, and Com (T7) in addition to control treatment were adopted. The mixtures of amendments and sandy soil were concentrated at the top 10 cm of columns. Results revealed that the cumulative evaporation was reduced by 2.3% and 5.7% as a result of using T3 and T5, respectively. However, the remaining treatments enhanced the cumulative evaporation. The application of amendments increased the capacity of the soil to maintain water by 35.4%, 24.4%, 13.3%, and 10.2%, for soils treated with T5, T3, T7, and T4, respectively. The water content at field capacity had the highest increase in the top 10 cm when treatment T3 was used. Although T3 (compost) was the most efficient for enhancing soil physical properties, this study recommends T5 and T7 to improve hydraulic properties of sandy soils. This is due to the fact that biochar and bentonite remain in the soil for a longer period and resist biodegradation while compost overcomes the negative impact of soil chemical properties as a result of biochar and bentonite additions.  相似文献   

5.
1,2-二氯乙烷(1,2-DCA)和1,2-二氯丙烷(1,2-DCP)是某污染场地地下水中检出最高的挥发性有机污染物。文中采用批试验方法,研究污染场地包气带中三种不同深度土壤样品对1,2-DCA和1,2-DCP的吸附-解吸特性。结果表明:土壤中有机质决定其吸附行为,三种土壤对1,2-DCA和1,2-DCP的吸附符合Henry线性等温方程,分配系数在20.49～22.43L.kg-1,1,2-DCA和1,2-DCP在三种土壤中分别具有相似的吸附能力;同一土壤中两种目标污染物的吸附能力为Kd(1,2-DCA)>Kd(1,2-DCP),但差别不大。1,2-DCA和1,2-DCP在三种土壤中的解吸可用Freundlich等温方程拟合,解吸的难易程度与土壤中黏粒含量相关,黏粒含量越高,目标污染物的解吸越困难,第三层(地下4.9～5.1m)土壤的防污能力较强;两种污染物在三种土壤中的解吸都存在明显的滞后效应,1,2-DCP的滞后指数比1,2-DCA的大。  相似文献   

6.
Disturbances have the potential to reduce soil water and nutrient retention capacity by decreasing soil organic matter (SOM), which is particularly true for sandy soils characterized by an inherent low capacity to retain nutrients and water. To restore degraded areas, several works have shown positive effects of organic matter inputs on soil properties and plant growth. Despite these promising results, it is still unclear how organic matter inputs and plant growth modify the balance between soil nutrient and water supply. The objectives of the present work were (1) to evaluate the effects of biosolids compost and municipal compost addition on plant available water (PAW), soil moisture and soil temperature in a burned sandy soil of NW Patagonia (Argentina), and (2) to relate PAW and soil moisture with bulk density, soil organic carbon, nutrient availability (inorganic and potential mineralized nitrogen (N), extractable phosphorous) and aboveground phytomass. An experiment with excised vegetation and watering was also conducted. Compost application increased SOM, but it was insufficient to increase PAW. The increase in potential mineralized N in the amended soils indicated that during moist periods (and adequate temperatures), N uptake was increased, enhancing plant growth. As a consequence, higher plant water consumption in amended treatments resulted in lower soil moisture than in non-amended plots during the vegetative growth period that coincides with decreasing precipitation. Results indicate that a relatively high dose of compost (40 Mg ha?1) applied to a sandy soil, contributed to increase nutrient availability and consequently, aboveground phytomass and water consumption.  相似文献   

7.
Vanadium adsorption by soils representing different soil types from Germany has been studied. For 30 soils ‘Freundlich’ type sorption isotherms have been deduced from laboratory vanadium(V) adsorption experiments. The native adsorbed vanadium quantity of a soil (S0) and the Freundlich parameters m and log k have been determined by non linear regression of the experimental data to the Freundlich model. Pronounced differences in vanadium adsorption of different soils exist and could be quantified. The vanadium adsorption data could be generalized by grouping the soils into four classes according to their vanadium adsorption properties. For each class (sandy soils, top soils, sub soils with pH < 5.5, and sub soils with pH > 5.5) mean Freundlich parameters m and log k have been calculated to be 0.59, 0.72, 0.52, 0.57 and 2.55, 2.89, 4.29, 3.41, respectively. These parameters can be used to estimate vanadium sorption properties of soils for which no vanadium sorption experiments are available. Aqua regia soluble vanadium contents of the studied soils (range 1.7–143 mg/kg; median 32 mg/kg) and leached vanadium concentrations from experiments without vanadium addition (range 0.08–37 µg/l; median 2.1 µg/l) are also given.  相似文献   

8.
This study analyses the adsorption of Pb(II) and Cr(III) in soils. These metals are commonly found together in nature in urban wastes or industrial spillages, and the theoretical approach of the work was to evaluate the response of the soil to continuous Cr and Pb spillages to soil in terms of several physicochemical parameters. The influence of an anthropogenic input of phosphorus was evaluated. Continuous flow experiments were run in duplicates in acrylic columns (25 cm × 3.2 cm). The influent Cr(III) and Pb(II) solutions of 10 mg l?1 and 25 mg l?1 at pH 5 were pumped upward through the bottom of the columns to ensure saturation flow conditions. Also, successive experiments were run with the above concentrations of Cr(III) and Pb(II) and NaH2PO4, keeping metal to phosphorus ratio of 1:0, 1:0.1 and 1:1. Modelling parameters included Freundlich and Langmuir equations, together with the Two-site adsorption model using CXTFIT code. Results obtained allowed concluding that Pb(II) adsorption presents a certain degree of irreversibility and the continued spillages over soil increment the fraction which is not easily desorbed. Cr(III) desorption was almost complete, evidencing its high mobility in nature. The presence of an anthropogenic input of phosphorus leads to a marked increase of both Pb(II) and Cr(III) adsorption in soils. Z-potential measurements allow to discard the electrostatic attraction of Cr(III) and Pb(II) with the surface charged soil as the dominant process of metal sorption. Instead, CheaqsPro simulation allows to identify PbH2PO4 +, PbHPO4 (aq) and CrHPO4 + as the dominant species which regulate Cr(III) and Pb(II) transport in soils.  相似文献   

9.
This study investigated the effect of cations and anions on the sorption and desorption of iron (Fe) and manganese (Mn) in six surface calcareous soil samples from Western Iran. Six 10 mM electrolyte background solutions were used in the study, i.e., KCl, KNO3, KH2PO4, Ca(NO3)2, NaNO3, and NH4NO3. NH4NO3 and NaNO3 increased the soil retention of Fe and Mn, whereas Ca(NO3)2 decreased the soil retention of Fe and Mn. Iron and Mn sorption was decreased by NO3 ? compared with H2PO4 ? or Cl?. The Freundlich equation adequately described Fe and Mn adsorption, with all background electrolytes. The Freundlich distribution coefficient (K F) decreased in the order H2PO4 ? > Cl? > NO3 ? for Mn and H2PO4 ? > NO3 ? > Cl? for Fe. The highest sorption reversibility was for Fe and Mn in competition with a Ca2+ background, indicating the high mobility of these two cations. A MINTEQ speciation solubility model showed that Fe and Mn speciation was considerably affected by the electrolyte background used. Saturation indices indicated that all ion background solutions were saturated with respect to siderite and vivianite at low and high Fe concentrations. All ion background solutions were saturated with respect to MnCO3(am), MnHPO4, and rhodochrosite at low and high Mn concentrations. The hysteresis indices (HI) obtained for the different ion backgrounds were regressed on soil properties indicating that silt, clay, sand, and electrical conductivity (EC) were the most important soil properties influencing Fe adsorption, while cation exchange capacity (CEC), organic matter (OM), and Mn-DTPA affected Mn adsorption in these soils.  相似文献   

10.
The adsorption process of dimethoate and 2,4-dichloro-phenoxy acetic acid (2,4-D) on Jordan Valley soils from aqueous solution at 25 °C has been studied. The adsorption isotherms may be classified as L-type of the Giles classification. The Kads values (Freundlich equation) vary between 1.01 (JV5) and 10.36 (JV7) for dimethoate insecticide and between 4.41 (JV5) and 14.87 (JV7) for 2,4-D herbicide, depending on the soil type. The adsorption of 2,4-D herbicide on soils in the study area is about threefold higher than that of dimethoate insecticide. The adsorption process of dimethoate and 2,4-D pesticides seem to be primarily controlled by the organic matter content of the soils and the clay content (most especially montmorillonite).  相似文献   

11.
The objective of this work was to study sorption–desorption and/or precipitation–dissolution processes of Hg(II) compounds considering an eventual contact of soils with Hg-bearing wastes. In addition, this study contributes new data about Hg(II) chemistry in alkaline systems. Saline and alkaline soils with low organic matter (<1 %) and high clay content (60–70 %) were obtained near a chlor-alkali plant. Batch techniques were used to perform the experiments using 0.1 M NaNO3 solutions. Total Hg(II) concentrations ranged from 6.2 × 10?8 to 6.3 × 10?3 M. Sorption of Hg(II) was evaluated at two concentration ranges: (a) 6.2 × 10?8 to 1.1 × 10?4 M, and (b) 6.4 × 10?4 to 6.3 × 10?3 M. At low Hg(II) concentrations, adsorption occurred with a maximum sorption capacity ranging from 4 to 5 mmol/kg. At high Hg(II) concentrations, sorption–precipitation reactions occurred and maximum sorption capacity ranged from 17 to 31 mmol/kg. The distribution of Hg(II) hydrolysis products showed that Hg(OH)2 was the predominant species under soil conditions. According to sorption experiments, X-ray diffraction and chemical speciation modelling, the presence of Hg(OH)2 in the interlayer of the interstratified clay minerals can be proposed. Hg(OH)2 was partially desorbed by repeated equilibrations in 0.1 M NaNO3 solution. Desorption ranged from 0.1 to 0.9 mmol/kg for soils treated with 5.8 × 10?5 M Hg(II), whereas 2.1–3.8 mmol/kg was desorbed from soils treated with 6.3 × 10?3 M Hg(II). Formation of soluble Hg(II) complexes was limited by low organic matter content, whereas neutral Hg(OH)2 was retained by adsorption on clay mineral surfaces.  相似文献   

12.
Most of the industrial wastewaters comprise toxic, biologically non-biodegradable, and heavy metals which tend to accumulate in the biological organisms causing different diseases. There are some novel technologies and strategies to remove these pollutants. Using the magnetic nanoparticles which are cheap, recyclable, and reusable can be considered as an effective method for removing the pollutants as they do not require conservation or complicated equipments. Using this method, dangerous and rare heavy metals can be restored to the industry. In this study, magnetic nanoparticles with the size of 30 nm were prepared and used for the removal of chromium from synthetic wastewater polluted by chromium sulfate. For this purpose, removal of various concentrations of chromium(III) from wastewater was investigated. The best concentration was achieved in the removal efficiency of 99.1 %. The optimal values of pH, rotation speed of magnetic stirrer, time, temperature, and the amount of nanoparticles were determined according to the primary concentration (500 mg/L). The mechanism of chromium adsorption onto iron oxide (Fe3O4) magnetic nanoadsorbent was also investigated. The results showed both Freundlich and Longmuir isotherms to be the best fit for the chromium adsorption, with Freundlich isotherm being more suitable.  相似文献   

13.
This study was carried out to determine the flux of nutrients and heavy metals from the Melai sub-catchment into Lake Chini through the process of erosion. Melai River is one of the seven feeder rivers that contributed to the present water level of Lake Chini. Three properties of soils, such as particle size, organic matter content, and soil hydraulic conductivity and three chemical soil properties, such as available nutrients, dissolved nutrients, and heavy metals, were analyzed and interpreted. Potential soil loss was estimated using the revised universal soil loss equation model. The results show that the soil textures in the study area consist of clay, silty clay, clay loam, and sandy silt loam. The organic matter content ranges from 3.40 to 9.92 %, while the hydraulic conductivity ranges from 5.2 to 25.3 cm/h. Mean values of available P, K, and Mg amount was 8.5 ± 3.7 μg/g, 24.5 ± 3.4 μg/g, and 20.7 ± 18.6 μg/g, respectively. The highest concentration of soluble nutrients was SO 4 ?2 (815.8 ± 624.1 μg/g), followed by NO3 ?-N (295.5 ± 372.7 μg/g), NH4 +-N (24.5 ± 22.1 μg/g) and PO4 3? (2.0 ± 0.8 μg/g). The rainfall erosivity value was 1658.7 MJ mm/ha/h/year. The soil erodibility and slope factor ranges from 0.06 to 0.26 ton h/MJ/mm and 7.63 to 18.33, respectively. The rate of soil loss from the Melai sub-catchment in the present condition is very low (0.0028 ton/ha/year) to low (18.93 ton/ha/year), and low level flow of nutrients and heavy metals, indicating that the Melai River was not the contaminant source of sediments, nutrients, and heavy metals to the lake.  相似文献   

14.
The adsorption of cadmium (Cd) and zinc (Zn) with similar chemical properties is examined onto three soil samples: one is alkaline and the others are acidic. The distribution coefficient (K d) and the Freundlich constant (K F) for Zn are slightly higher than those for Cd, implying that the adsorption affinity of Zn is a little greater and less mobile. However, Cd and Zn usually show comparable results in the kinetic, isotherm, and envelope experiments. The adsorption of the heavy metals is relatively rapid and the reaction is almost completed within 15 min. The kinetics for both Cd and Zn are very well explained by the parabolic diffusion model. The maximum adsorption of the heavy metals is obtained at high pH, high temperature, and low ionic strength. The adsorption capacity on the alkaline soil is more significantly affected by the temperature as compared to the acidic soil. It is found that the adsorption affinity of the two heavy metals is mainly affected by the soil properties, such as pH, pHPZC, organic matter, and total carbon. It is also confirmed that the chemical properties of the heavy metals are important factors in their adsorption onto soil. The adsorption isotherms of Cd and Zn are well described in both Freundlich and Langmuir models at the usual pH (soil pH). Under acidic and alkaline pHs, however, only the Freundlich model describes the adsorption of both heavy metals satisfactorily.  相似文献   

15.
Deltamethrin is one of the most commonly used pyrethroid in agricultural practice in different geographic regions of the world. It is detected in many environments, especially in soil and water, and can exhibit toxic effect to human and other organisms. In this study, we describe two bacterial strains DeI-1 and DeI-2, isolated from soil, and both identified as Serratia marcescens based on profile of the fatty acid methyl esters, biochemical test, and 16S RNA gene analysis, which were shown to efficiently degrade deltamethrin. Degradation of deltamethrin in mineral salt medium (50 mg l?1) proceeded by strains DeI-1 or DeI-2 reached the values of 88.3 or 82.8 % after 10 days, and DT50 was 2.8 or 4.0 days, respectively. Bioaugmentation of deltamethrin-contaminated non-sterile soils (100 mg kg?1) with strains DeI-1 or DeI-2 (3 × 106 cells g?1 of soil) enhanced the disappearance rate of pyrethroid, and its DT50 was reduced by 44.9, 33.1, 44.4, and 58.2 days or 39.1, 25.8, 35.6, and 46.0 days in sandy, sandy loam, silty loam, and silty soils, respectively, in comparison with non-sterile soils with only indigenous microflora. The three-way ANOVA indicated that DT50 of deltamethrin was significantly (P < 0.01) affected by soil type, microflora presence, and inoculum, and the interaction between these factors. Generally, the lower content of clay and organic carbon in soil, the higher degradation rate of deltamethrin was observed. Obtained results show that both strains of S. marcescens may possess potential to be used in bioremediation of deltamethrin-contaminated soils.  相似文献   

16.
Unsafe lead (Pb) concentrations in leafy vegetables raised in urban and peri-urban agricultural production systems have been reported across cities in Northern Nigeria, even though Pb concentrations in soils are within regulatory safe levels. This study examined the soil enrichment, adsorption and chemical species of Pb in urban garden fields irrigated with untreated wastewater at three industrial locations in Kano, northern Nigeria. Total Pb in the soil profiles ranged from 9 to 91 mg kg?1 and decreased rapidly from the surface to the subsurface layer, but attaining nearly constant concentration at depth ≥1.2 m in the profiles. The potentially labile Pb maintained fairly constant concentration with depth up to 0.9 m, but decreased fairly rapidly with depth thereafter. There was a significant Pb enrichment of the soils, extending up to 30–60 cm depth in the soil profiles. The adsorption of Pb by the soils increased drastically with pH, and attained maximum adsorption at pH ≥ 7.0 in the surface layer, and at pH ≥ 6 in the subsurface layer. The surface soils adsorbed between 85 and 97 % of added Pb at pH ≤ 5. Free Pb2+ activities in soil solution accounted for between 46 and 87 % at pH 5–7 of total dissolved Pb (PbT). The quantifiable chemical species of Pb in solution consisted mainly of PbOH+, PbSO 4 · , PbCl+ and PbOH 2 · which accounted for between 0.9 and 26 % of PbT in soil solution at pH ≥ 5.0, but declining to between 0.1 and 2.1 % at pH ≥ 7.5. There was no apparent equilibrium between Pb2+ activities and known Pb-compounds in the soils. It was concluded from the data that reports of excess Pb concentrations in leafy vegetables raised in these soils are consistent with high free Pb2+ activities maintained in soil solution by these predominantly sandy-textured soils.  相似文献   

17.
Phosphate sorption and desorption experiments were conducted with four ferruginous soils (alfisols) of Eastern India, in view of the low native phosphate concentrations in tropical Indian soils. From the P-isotherm curve, standard P requirement (SPR) of the soils was determined. Phosphate sorption data were fitted to both Langmuir and Freundlich equations and mean sorption maximum values obtained for the different soil series were in the decreasing order as Matimahal > Anandapur > Mrigindih > Kashipur. The fraction of added P sorbed followed the same trend as SPR, P sorption maximum (Pmax), phosphate affinity constant (K), maximum phosphate buffering capacity (MPBC), Freundlich constant K′ and phosphate desorption values. Phosphate sorption maximum was significantly correlated with MPBC, Freundlich 1/n, SPR, clay and different forms of Fe and Al. The value of K (bonding energy) was significantly correlated with MPBC, Freundlich K′ and pyrophosphate extractable Fe and Al. The MPBC was significantly correlated with Freundlich K′, Freundlich constant 1/n, clay, oxalate and dithionite extractable, amorphous and crystalline form of Fe and Al. Freundlich K′ was significantly correlated with Freundlich 1/n, pHwater, clay, dithionite extractable and crystalline form of Fe and Al. The results suggested that the soils having higher amount of extractable and reactive Fe and Al shared higher P sorbtion capacity and such soils may need higher levels of P application  相似文献   

18.
Heavy metals are governed by parent material of soils and influenced by the soil physicochemical properties and soil and crop management practices. This paper evaluates total heavy metal concentrations in rainfed soils under diverse management practices of tropical India. Vertisols (clayey soils with high shrink/swell capacity) had the highest concentrations of heavy metals. However, chromium (Cr) content was above the threshold value in Aridisol [calcium carbonate (CaCO3)]-containing soils of the arid environments with subsurface horizon development. Concentration increased at lower depths (>30 cm). Basaltic soils showed higher concentrations of nickel (Ni), copper (Cu) and manganese (Mn). Cadmium (Cd), cobalt (Co), Cu and Mn concentrations were higher in soils cultivated to cotton, whereas Cr concentration was above the threshold level of 110 mg kg?1 in food crop cultivated soils. As the specific soil surface is closely related to clay content and clay type, soil’s ability to retain heavy metals is more closely tied to the specific surface than to the soil cation exchange capacity. Higher positive correlations were found between heavy metal concentrations and clay content [Cd(r = 0.85; p ≤ 0.01); Co (r = 0.88; p ≤ 0.05); Ni (r = 0.87; p ≤ 0.01); Co (r = 0.81; p ≤ 0.05); Zn (r = 0.49; p ≤ 0.01); Cr (r = 0.80; p ≤ 0.05); Mn (r = 0.79; p ≤ 0.01)]. The amounts of nitrogen–phosphorus–potassium applied showed a positive correlation with Co and Ni (r = 0.62; p ≤ 0.05). As several soils used for growing food crops are high in Ni, Cr and Mn, the flow of these metals in soil–plant–livestock/human chain needs further attention.  相似文献   

19.
The nonsteroidal anti-inflammatory drug “diclofenac” is the pharmaceutically active ingredient of several medicines. Since the compound is used in many of its water-soluble salt forms, it is one of the most frequently found pollutants in different parts of the water cycle. Its reaction with sodium hypochlorite was investigated in the presence of humic substances and sandy soil extract at neutral pH at 25 and 250 mg/L initial concentrations. In the lower concentration, the reaction follows a pseudo-first-order kinetics, while at the higher concentration, it is described as the sum of two first-order reactions. These kinetic results, together with the organic chlorine content of the residues, indicated that both chlorination and oxidation took place. The chlorination is significantly faster. The colloids present catalyze the reactions: The clay minerals of soil extract accelerated the chlorination, while the humic acids could work as photocatalysts in the oxidation, while these compounds themselves were chlorinated. The adsorption of diclofenac on activated carbon was enhanced by humic substances, and every isotherm had a breaking point near to 3 mg/L equilibrium concentration (c e) resulting in two steps. According to the measurements of the zeta potential, the system proved to be relatively stable at this c e value, but at higher diclofenac concentrations the stability retained only in the presence of the hydrophilic fulvic acid. The results supported the adsorption hypothesis that in the first step the charge transfer interaction while in the second step hydrogen bond formation plays the key role.  相似文献   

20.
Adsorption is one of the most significant processes in the mobility of soluble pollutants in soils. The aim of this work is to characterize and evaluate the adsorption capacity of soils from Viamão District, Brazil. The studied ions were leadtotal, coppertotal, sulfate, phosphate, and potassium. The soils were mapped by remote sensing and characterized by granulometrical and mineralogical techniques. The adsorption tests were made by the contact of soil samples with aqueous solutions. The soils adsorption capacity presented the following trend: Pbtotal>Cutotal≈PO 4 3− >K+ ≈SO 4 2+ . Adsorption in the soils is strongly influenced by clay content. The adsorption of phosphate, copper, and lead was accentuated by the presence of organic matter. Phosphate adsorption was controlled by oxides and organic matter. Both potassium and sulfate showed insignificant adsorption in the studied soils.  相似文献   

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