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蒙脱石+伊/蒙混层+伊利石等粘土矿物混合物相X射线定量分析方法—模拟定量法 总被引：3，自引：0，他引：3
本文提出粘土矿物(特别是含伊/蒙不规则混层粘土矿物)混合物相的X射线定量分析方法——模拟定量法。着重解决在蒙脱石-不规则伊/蒙混层粘土矿物-伊利石组合中,伊/蒙混层粘土矿物的定量分析计算。模拟定量法是对以前的各种粘土矿物X射线定量分析方法的补充。用纯净的蒙脱石、伊利石、高岭石、绿泥石及各种伊/蒙混层比的伊/蒙混层粘土矿物,配制了各种不同组合的粘土矿物混合样品,制成定向薄膜片,进行了X射线分析,讨论了各种组合的粘土矿物混合物相X射线衍射图谱的特征,并在此基础上提出了粘土混合物相定量分析的方法。 相似文献
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Using the “Scenario Machine” (a computer code based on the Monte-Carlo method, developed to calculate the evolution of a large ensemble of binaries), we have carried out population-synthesis calculations for X-ray binaries for the purpose of modeling the X-ray luminosity functions in various type galaxies. These calculations were focused on the evolution of magnetized neutron stars. The X-ray luminosity function is not universal, and depends on the star formation rate in the galaxy. In theoretical models, it is very important to take into account the evolution of the binaries and their lifetimes in their X-ray stages. We calculated the cumulative and differential X-ray luminosity functions in galaxies with a constant star formation rate, the cumulative luminosity functions for various time intervals since the peak star formation, and curves describing the evolution of the X-ray luminosity after a star formation burst in the galaxy. 相似文献
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车载台式能量色散X射线荧光光谱仪在地球化学勘查现场分析中的应用 总被引：10，自引：10，他引：0
充分发挥小型实验室设备的功能以提高现场快速分析的能力。在内蒙和新疆两地覆盖区的钻探现场,采用车载化台式偏振能量色散X射线荧光光谱仪,对由轻便钻采集的覆盖层和基岩样品进行了贱金属分析。共采集、制备和分析了约400件钻探样品,采用能量色散X射线荧光光谱法、波长色散X射线荧光光谱法和电感耦合等离子体质谱法对这些样品进行比对分析。现场分析数据与实验室分析数据(各方法的平均值)的比对结果表明,K、Ca、Ti、V、Cr、Mn、Fe、Ni、Cu、Zn、Ga、As、Rb、Sr、Y、Zr、Nb、Ba、Pb、Th等20余种元素的分析数据的一致性良好;含量超过10μg/g时,除了V和Ba外,其他元素的平均相对偏差均小于25%。在现场作为质控样品分析4个地质标准物质GBW07301～GBW07304,测定结果表明,除了低含量的Cu和Ga外,上述其他18种元素均符合地质行业标准地质矿产实验室测试质量管理规范(1∶20万)规定的误差要求。应用研究表明,设计的仪器车载化方案可行,现场分析方法快速、准确,适用于野外钻探、化探等急需现场数据支持的工作。 相似文献
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原位微区X射线荧光光谱分析装置与技术研究进展 总被引：2，自引：1，他引：1
原位微区X射线荧光(Micro-XRF)光谱分析技术是X射线光谱学领域一重要分支。近年来X射线毛细管光学透镜聚焦技术不断进步,以实验室X光源为基础的原位微区X射线光谱分析装置与应用技术快速发展,已成功应用于多领域样品的原位、多维、动态和非破坏性微区分析。文章介绍了近年来X射线毛细管光学透镜技术发展和原位微区X射线光谱分析装置研制进展,对近年来micro-XRF光谱分析技术在大气气溶胶颗粒物分析与来源识别、考古样品产地和真伪鉴别、古气候古环境重建研究中沉积纹层样品元素分析,以及刑侦科学中指纹样品的鉴定等应用领域进行了系统介绍,阐述了micro-XRF光谱分析技术性能的影响因素(空间分辨率和强度增益)。micro-XRF光谱分析技术不仅可以获取样品表面的信息,还能够获取样品内部的信息,成为目前国际上一门迅速发展的竞争技术。我国在毛细管透镜制造技术与性能研究,以及micro-XRF应用领域取得了重要进展。由于X射线焦斑尺寸对能量的依赖性以及样品基质对X射线的吸收效应,在微区定量分析中易引入较大误差,利用X射线毛细管透镜获取更小光斑尺寸与高稳定性的X射线光束,提高micro-XRF分析技术的空间高分辨率性能和对基体效应进行校正实验将是今后一个重要的研究目标和分析研究难点。 相似文献
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贵州中北部燃煤型砷中毒地区煤中砷的赋存状态研究 总被引：1，自引：0，他引：1
贵州中北部存在着高砷煤并引起环境和健康问题,对这些地区的煤进行了中子活化分析(INAA)、电子探针(EMPA)、能谱扫描电子显微镜(SEM-EDX)、低温灰化(LTA)、X射线衍射(XRD)、X光吸收精细结构(XAFS)和连续淋滤实验分析,综合研究了这些煤中砷的赋存状态。结果表明不同煤中砷具有不同的赋存状态。在部分样品中砷主要以无机砷的形式存在,而在其它样品中砷主要以有机砷的形式存在。除了黄铁矿和毒砂外,SEM-EDX结合LTA和XRD发现硫酸盐、粘土也不同程度含有砷。XAFS显示煤中的砷主要以As5+的形式存在。连续淋滤实验表明在样品ZJ-1中超过50%的砷不能被淋滤出来,而在另外两个样品(ZJ-8和RH-5B)中绝大部分的砷被淋滤出来。综合分析表明一些煤中以+5价存在的砷主要与有机质结合。煤中如此高的砷及其主要与有机质结合的现象是很罕见。 相似文献
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I. V. Zimovets 《Astronomy Reports》2010,54(7):657-674
An analysis is presented for the class-M9.3 solar flare of November 6, 2004, whose decay phase displayed weakly damped harmonic
oscillations of the predominantly thermal X-ray flux detected by the RHESSI spacecraft (at energies ≲25 keV). The period of
these oscillations was ≈78 s, and their characteristic decay time ≈100 min. Similar quasi-periodic pulsations were observed
in the decimeter-centimeter radio flux (pulsations of a type-IV radio outburst), but were less pronounced in the non-thermal
hard X-ray flux (≳25 keV). The area of the quasi-stationary X-ray source, which was located primarily at the apex of a set
of flare loops (≲15 keV) that were cooled primarily via thermal conduction, was found to be in anti-phase with the oscillating
X-ray flux it emitted. The observed oscillations are interpreted as harmonic modulations of the radiation flux emitted by
the heated thermal flare-loop plasma, due to the global, standing, sausage mode of fast magnetoacoustic waves excited in the
loop. 相似文献
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V. I. Silaev G. A. Karpov L. P. Anikin V. N. Filippov V. A. Petrovsky A. E. Sukharev Yu. S. Simakova 《Doklady Earth Sciences》2017,476(1):1048-1053
The results of X-ray structural, electron-microscopic, and X-ray spectral microprobe studies of Al-based metal solid solutions that underwent nuclear disintegration and that were discovered in nature for the first time are presented. Based on the similarity to technical counterparts, it is suggested to recognize the previously unknown alloys as natural duralumin. 相似文献
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Natural titanites which have incurred radiation damage from the decay, over geologic time, of U and Th incorporated in the samples have been studied by powder X-ray diffraction, differential thermal analysis and infrared spectroscopy. In agreement with previous studies of ionirradiated synthetic titanite, X-ray diffraction indicated that titanite is two to three times more sensitive than zircon to damage from α-decay processes. Differential thermal analysis of samples which were deduced to have accumulated 10–30 percent of the α-fluence required to render the structure completely X-ray amorphous gave a series of exothermic peaks in the 200–800° C range of temperature. In such samples, X-ray and density measurement showed that atomic displacement damage anneals during heating periods of the order of one h in the temperature range 500–800° C. The density of titanite rendered X-ray amorphous by irradiation was estimated to be ～8 percent lower than that of crystalline titanite. 相似文献
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通过对岩石烃类检测实验数据的对比分析,探讨了岩石样品粉碎制备和氯仿抽提等实验环节中存在的一些问题,如电动法制备岩石样品导致的 相似文献
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《Russian Geology and Geophysics》2015,56(5):782-792
The porosity and permeability of core rocks were studied by X-ray tomography. This method has a high potential for studying petrophysical properties of rocks, because it permits not only a general quantitative estimation of the void volume but also visualization of the rock texture, including pores, cavities, cracks, and zones of different densities in the matrix. X-ray tomography permits detailed studies of rock inhomogeneity, which are necessary for the elaboration of reliable porosity-permeability models for hydrocarbon pools. The investigations at Perm State National Research Polytechnic University have shown that X-ray tomography of core samples has a wide spectrum of applications in petroleum geology. Nikon Metrology XT H 225 X-ray computed tomography makes it possible to examine samples with a standard diameter (30 mm) and whole core samples (100 mm). The structure of voids in carbonate and terrigenous rocks was studied on samples with standard and full diameters; the results of hydrochloric acid treatment of carbonate reservoir rocks were visualized; and the mechanical properties of rock salts were studied. Three-dimensional models for the structure of voids and mineral matrix of the core samples have been constructed with the use of the Avizo Fire software. 相似文献
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Baiyuneboite-(Ce) occurs in the REE-Fe-Nb ore deposits at Baiyunebo, Inner Mongolia. As a new mineral—NaBaCe2[Fl(C034], it is a Na-Ba-REE(Ce-series) fluor-carbonate. The authors have conducted extensive investigations into the basic mineralogy,
mineralogical spectroscopy and X-ray crystallography of the mineral and have elaborately determined its chemical composition.
Numerous data on mineralogical experiments and fundamental parameters with respect to its crystal structure have been obtained.
X-ray structural analyses were elaborated. In addition, high-resolution electron microscopic studies were performed and its
structural image was photographed in order to validate the results of X-ray structural analyses. The experimental data available
in conjunction with the comparison between baiyuneboite-(Ce) and its analogues are sufficiently sensitive to show that baiyuneboite-(Ce)
is a new mineral. 相似文献
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我国主要白云母的矿物学特征研究 总被引：3，自引：1，他引：3
利用X射线荧光光谱分析（XRF）、常规化学分析、X射线光电子能谱分析（XPS）和粉晶X射线衍射分析（XRD）等手段对我国主要白云母进行了系统的矿物学研究，并与印度白云母进行了详细的对比分析，探讨了我国白云母与印度白云母在表丽化学组成和化学态、体栩化学成分、晶体结构方面的差异。研究发现：印度白云母表面K更多地表现为缺失留下空位，表面O严重缺失、不足，四面体层中Si有更多的暴露，表面化学键的不饱和程度高于我国白云母，表现出更高的表面活性。我国主要白云母产地的白云母为2M；型白云母，晶胞参数a、b值随结构中铁和镁离子含遗的增加而增大。 相似文献
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Yusaku Takubo Hidenori Terasaki Tadashi Kondo Shingo Mitai Seiji Kamada Takumi Kikegawa Akihiko Machida 《Comptes Rendus Geoscience》2019,351(2-3):182-189
A technique for density measurement under high pressure and high temperature was developed using the X-ray absorption imaging method combined with an externally heated diamond anvil cell. The densities of solid and liquid In were measured in the pressure and temperature ranges of 3.2–18.6 GPa and 294–719 K. The densities obtained through the X-ray absorption imaging method were in good agreement (less than 2.0% difference) with those obtained through X-ray diffraction. Based on the measured density, the isothermal bulk modulus of solid In is determined as 48.0 ± 1.1?40.9 ± 0.8 GPa at 500 K, assuming K′ = 4 to 6. The compression curve of liquid In approaches that of solid In at higher pressures and does not cross over the solid compression curve in the measurement range. The present technique enables us to determine the densities of both solids and liquids precisely in a wide pressure and temperature range. 相似文献
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以石嘴山煤田汝箕沟矿区侏罗纪的二煤、三煤和石炭井矿区二叠纪的四煤、五煤为研究对象,采用低温灰的化学组成分析和X射线衍射分析,对煤中矿物特征做对比研究。结果表明:汝箕沟矿区样品与石炭井矿区样品在化学成分、灰成分指数、Si和Al比值上,都具有明显差异;汝箕沟矿区样品X衍射图谱的波峰最大值远远小于石炭井矿区的样品值,两者的图谱形态也存在很大差异;汝箕沟矿区样品中以高岭石、伊利石、石英为主,其它很少,高岭石约占65%;石炭井矿区样品中以高岭石占绝对优势,约占85%,其他矿物含量较少。化学组成分析的结果和X射线衍射分析的结果具有较好的对应性。 相似文献
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