首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献，搜索用时 31 毫秒
1.
A soil-water flux sensor was developed, which determines the flux value from the difference between downstream and upstream temperatures at some distances from an artificial heat source. It can detect flux values ranging from several mm hr.−1 to as small as 0.01 mm hr.−1. Design and calibration of the sensor are described.

The sensor was applied to the field studies of transfer processes in a surface soil, including rainwater infiltration, upward soil-water flow during evapotranspiration, and their effects on the water table level. Cl− accumulation in the surface soil is discussed on the basis of upward water flux and Cl− content observed.  相似文献   


2.
REE diffusion in calcite   总被引：6，自引：0，他引：6  
Chemical diffusion of four rare-earth elements (La, Nd, Dy and Yb) has been measured in natural calcite under anhydrous conditions, using rare-earth carbonate powders as the source of diffusants. Experiments were run in sealed silica capsules along with finely ground calcite to ensure stability of the single-crystal samples during diffusion anneals. Rutherford backscattering spectroscopy (RBS) was used to measure diffusion profiles. The following Arrhenius relations were obtained over the temperature range 600–850°C: DLa =2.6×10−14 exp(−147±14 kJ mol−1/RT) m2 s−1, DNd =2.4×10−14 exp(−150±13 kJ mol−1/RT) m2 s−1, DDy =2.9×10−14 exp(−145±25 kJ mol−1/RT) m2 s−1, DYb =3.9×10−12 exp(−186±23 kJ mol−1/RT) m2 s−1. In contrast to previous findings for refractory silicates (e.g. zircon), differences in transport rates among the REE are not pronounced over the range of temperature conditions investigated in this study. Diffusion of the REE is significantly slower than diffusion of the divalent cations Sr and Pb and slower than transport of Ca and C at temperatures above 650°C. Fine-scale zoning and isotopic and REE chemical signatures may be retained in calcites under many conditions if diffusion is the dominant process affecting alteration.  相似文献   

3.
We report the first measurements of hydrodynamic dispersion in a microfractured granite using a combination of novel techniques. A fracture network was induced in a cylindrical plug of Ailsa Craig micro-granite by thermal stressing, to produce an isotropic network of fractures with an average aperture of  0.3 μm, a density of approximately 4 × 104 fractures/mm3 and a permeability of 5.5 × 10− 17 m2. After saturating the cores with 0.01 M NaCl solution a step in the concentration profile to 1 M was advected into the plug at flow rates of 0.07 to 2.13 cm3 h− 1. The longitudinal electrical impedance of the plug was measured continuously as the solute front advected through its length until the plug was saturated with the concentrated electrolyte. Analysis of the impedance versus time relationships allows the derivation of the longitudinal dispersion coefficient, DL, and hydrodynamic retardation, RH. The Peclet number–dispersion relationship for the micro-fracture network is very similar to that predicted for other, radically different, fracture networks. Thus dispersion may be more dependent on fracture connectivity and length than fracture density and display a relationship similar to that shown by particle beds and clastic sandstones. The high retardation values observed (2.2–4.9) reflect flow behaviour within a fracture network with a proportion of ‘blind’ sections, and demonstrates how such networks can slow the advance of conservative solute components.  相似文献   

4.
This research (1) characterized the effects of sublethal cupric ion activities on the grazing behavior of two estuarine copepods (Acartia tonsa, Acartia hudsonica) and one nearshore, neritic copepod (Temora longicornis) and (2) compared the sensitivity of short-term sublethal behavioral assays with that of longer-term acute toxicity tests. A nitrilotriacetate-trace-metal-ion buffer system at 27‰. S was used to quantify and control the free cupric ion activity. Acute toxicity tests were used to determine the mortality of A. tonsa and T. longicornis over 72 h within the approximate cupric ion activity range of 10−13 to 10−9.5 M. 24 h survival was not affected within the approximate cupric ion activity range of 10−13 to 10−9.7 M, the range used for subsequent grazing activity experiments after 24 h exposure to Cu. Grazing activity was significantly diminished at cupric ion activities of ≈ 10−10 M for A. tonsa and T. longicornis, and at ≈ 10−11 M for A. hudsonica. A hormetic pattern of response in feeding activity was observed with A. tonsa and T. longicornis. Grazing activity was found to be a sensitive measure of sublethal Cu stress compared with the acute toxicity tests. Grazing activity was affected at environmentally relevant cupric ion activities.  相似文献   

5.
We have observed natural remanent magnetizations (NRM), ranging from 10−3 to 10−5 Gauss cm3/g, at least two orders of magnitude greater than 10−7, the noise level of our spinner magnetometer, in the carbonaceous chondrites, Orgueil, Cold Bokkeveld, Nogoya and Mighei. Preliminary alternating field demagnetization of two samples of Orgueil showed a moderate sized stable component of 10−4 Gauss cm3/g. Microscopic study reveals that a grey spinel oxide, Ni-Fe and an Fe sulphide are the principal opaque minerals in both Cold Bokkeveld and Orgueil; the oxide phase predominates in both, while the Ni-Fe is more visible in the former. Coercive force determinations in Orgueil and Cold Bokkeveld indicate single domain particles as the NRM carrier. These meteorites are suitable for the determination of the magnetic field intensity in the primary solar nebula.  相似文献   

6.
Mechanisms of compaction of quartz sand at diagenetic conditions   总被引：5，自引：0，他引：5  
The relative contribution of cracking, grain rearrangement, and pressure solution during experimental compaction of quartz sand at diagenetic conditions was determined through electron and optical microscopy and image analysis. Aggregates of St. Peter sand (255±60 μm diameter grain size and porosity of approximately 34%) were subjected to creep compaction at effective pressures of 15, 34.5, 70, and 105 MPa, temperatures of 22 and 150°C, nominally dry or water-saturated (pore fluid pressure of 12.5 MPa) conditions, and for times up to one year. All aggregates displayed transient, decelerating creep, and volume strain rates as low as 2×10−10 s−1 were achieved. The intensity of fracturing and degree of fragmentation increase with volume strain and have the same dependence on volume strain at all conditions tested, indicating that impingement fracturing and grain rearrangement were the main mechanisms of compaction throughout the creep phase. The increase in fracture density and decrease in acoustic emission rate at long times under wet conditions reflect an increase in the contribution of subcritical cracking. No quantitative evidence of significant pressure solution was found, even for long-term creep at 150°C and water-saturated conditions. Comparison of our findings to previous work suggests that pressure solution could become significant at temperatures or times somewhat greater than investigated here.  相似文献   

7.
The impact of domestic sewage effluent (SE) on the dynamics of phytoplankton assemblages from Bedford Basin was evaluated in the laboratory. Phytoplankton production and chlorophyll a increased proportionally with SE enrichment. Phytoplankton species composition also changed. The potentially harmful diatoms, Pseudonitzschia spp., present initially in small numbers (600 cells 1−1) in Bedford Basin seawater, and became dominant (3–5×106 cells 1−1) when the seawater was enriched with 0.5–5% untreated SE. With higher proportions of SE, other harmful species such as Fragilaria spp. and Euglena spp. became dominant (7−15×106 and 2.2×104 cells 1−1, respectively). Treatment of SE with UV light or activated charcoal seems to favour growth of benign species, such as Chaetoceros socialis, Skeletonema costatum and Thalassiosira spp., but not harmful species such as Pseudonitzschia spp. Further research on UV treatment of domestic sewage is recommended.  相似文献   

8.
North-seeking bacteria (NSB) with 1 μm diameters migrate to the S pole only. They were applied to identify the S pole determination on a polished surface of magnetite-rich pyroxenite whose natural remanent magnetization (NRM) intensity was 5.64 × 10−3 Am2 kg−1. The microscopic observations were performed under dark-field illumination in a controlled magnetic field to 10 μT. The NSB formed clusters on limited areas of magnetite grains and scattered over the whole magnetite grains.

The NRM decreased to 1.02 × 10−5 Am2 kg−1 by alternating field (AF) demagnetization to 60 mT but no clusters appeared, while small populations of the NSB scattered on each grain. These scattered bacteria may gather toward the S pole resulting from magnetic domain walls.

When the sample acquired saturation isothermal remanent magnetization (SIRM) to 1 T, the NSB formed dense clusters at the opposite side to the applied field direction on the many grains as expected. This evidence indicated that the NSB can be useful micro-organisms for the determination of fine magnetic structures. Some grains also had NSB clusters at the edge of the grains toward the field direction or did not exhibit any clusters. The complicated distribution of the clusters (the S poles) may be explained by shape anisotropy of the magnetic grains.  相似文献   


9.
Abstract Electron spin resonance (ESR) analyses of quartz grains in fault gouge were performed for a core sample taken from the Nojima Fault that moved during the 1995 Kobe earthquake (Hyogo-ken Nanbu earthquake). Distribution of radiation-induced defects in the gouge at a depth of 389.4 m was measured by extracting quartz grains from seven discrete positions within 30 mm of the fault plane on the granite side. The decrease in E'1 and Al centers was observed within 2 mm of the fault plane, suggesting partial annealing due to faulting. Partial annealing even at that depth suggested that conventional ESR dating, which is based on the hypothesis of complete annealing during faulting, was not applicable. Theoretical calculations of the temperature rise and of the thermal annealing of defects have been made by assuming a simple annealing model of heat generation on the fault plane. Thermal energy was calculated to have been approximately 8 MJ/m2 to explain the profile of the heat-affected region. Thermal energy was much larger than the one estimated from hydrothermal solution, and corresponded to the frictional heat calculated for a normal stress of 20 MPa, a displacement of 2 m, and a frictional coefficient of 0.2.  相似文献   

10.
To examine nitrate persistence, detailed geochemical profiling, using core-squeezed water and piezometer samples, was carried out at five sites in southern Ontario where groundwater is moving downward in silt-rich aquitard sediments at rates of 16 to more than 20 cm year−1. Elevated levels of NO3−-N (5–50 mg 1−1) that occur in the shallow groundwater as a result of agricultural activity, were found to be consistently attenuated, generally to very low levels (< 0.05 mg 1−1-N), at the ‘redoxcline’, the horizon marking the boundary between the surficial weathered (brown) sediments and the underlying unweathered (grey) sediments. Tritium dating suggests that groundwater at the redoxcline depths (3–5 m) was recharged between 1970 and 1980, thus the N03 depletion appears to result from biodegradation reactions since no major landuse changes have occurred during this period. The close association of the nitrate depletion zones with the redoxcline, where, in particular, sediment sulphur contents increase abruptly, and where also porewater SO42− levels increase, suggests that the dominant attenuation reaction is autotrophic denitrification using reduced sulphur compounds present in the unweathered sediment as the electron donor. Mass balance calculations suggest that the increase in the downward rate of migration of the redoxcline, owing to added sulphur consumption from NO3− contamination, is only about 1 mm year−1 at these sites. Review of the literature indicates that most silt- and clay-rich sediments have S contents in the same range, or higher, than those investigated here, thus, in most cases where aquifers are overlain by several metres or more of unweathered confining sediments, it is likely that a high degree of protection is afforded from surficial NO3− contamination.  相似文献   

11.
We have determined the production yields for radionuclides in Al2O3, SiO2, S, Ar, K2SO4, CaCO3, Fe, Ni and Cu targets, which were irradiated with slow negative muons at the Paul Scherrer Institute in Villigen (Switzerland). The fluences of the stopped negative muons were determined by measuring the muonic X-rays. The concentrations of the long-lived and short-lived radionuclides were measured with accelerator mass spectrometry (AMS) and γ-spectroscopy, respectively. Special emphasis was put on the radionuclides 10Be, 14C and 26Al produced in quartz targets, 26Al in Al2O3 and S targets, 36Cl in K2SO4 and CaCO3 targets, and 53Mn in Fe2O3 targets. These targets were selected because they are also the naturally occurring target minerals for cosmic ray interactions in typical rocks. We also present results of calculations for depth-dependent production rates of radionuclides produced after cosmic ray μ− capture, as well as cosmic ray-induced production rates of geologically relevant radionuclides produced by the nucleonic component, by μ− capture, by fast muons and by neutron capture.  相似文献   

12.
The source of the lunar magnetic anomaly associated with the Rima Sirsalis linear rille has been modelled using the vector field intensities due to arbitrary uniform magnetization in a rectangular prism. It is shown that in order to match the Apollo 16 subsatellite data, the lunar surface near the rille must have a vertical magnetization of 6–9 × 10−3 G if the anomaly is due to flux leakage from a gap in the crust with the dimensions of the rille. This is more than one order of magnitude larger than the magnetization of any lunar sample, but is comparable with the high magnetization recently deduced for the Reiner γ formation in Oceanus Procellarum. An alternative explanation is that Rima Sirsalis and its surroundings are the site of a vertical magnetization contrast of 10−5 – 10−4 G which is at least as wide as the rille and extends to a depth of tens of kilometers in the crust. A wider magnetic source reduces the required magnetization (or depth) proportionately, since to first order the field at high altitude is proportional to the magnetic dipole moment per unit length.  相似文献   

13.
Argon, krypton, chlorine, bromine, and iodine were measured in a homogeneous population of high-salinity hydrothermal fluid inclusions from the Tertiary-age Mississippi Valley-type (MVT) lead-fluorite-barite deposits at Hansonburg, New Mexico to establish new types of evidence for the history of both the fluid and the major dissolved salts. Noble gases and halogens in fluid inclusions containing 10−10–10−9 L of brine (Cl= 3 molal) were analyzed by laser microprobe noble-gas mass spectrometry (lmngms) on neutron-irradiated samples.

The concentrations of36Ar (4.7 × 10−8 molal) and84Kr1.8 × 10−9 molal) in the fluid inclusions are equal to those of fresh surface waters in equilibrium with air at approximately20 ± 5°. The mole ratios ofBr/Cl (1.2 × 10−4) andI/Cl (1–2 × 10−6) are among the lowest measured in any natural waters, similar to those of modern brines formed by dissolution of Permian NaCl-bearing evaporites in southeast New Mexico.40Ar/36Ar ratios (600) are twice that of air, and indicate that the fluid inclusions had excess radiogenic40Ar (1.4 × 10−5 molal) when trapped. The amount of excess40Ar appears to be too large to have been acquired with Cl by congruent dissolution of halite-bearing evaporites, and possibly too small to have been acquired with Pb by congruent dissolution of granitic basement rocks with Proterozoic KAr ages.

From thelmngms data, combined with published Pb and S isotope data, we infer the following sequence of events in the history of the Hansonburg MVT hydrothermal brine: (1) the brine originated as relatively dilute meteoric water, and it did not gain or lose atmospheric Ar or Kr after recharge; (2) the originally dilute fluid acquired the bulk of its Cl and sulfate in the subsurface after recharge by dissolving halite-bearing Permian? marine evaporites; (3) the high salinity brine then acquired most of its Pb and excess radiogenic40Ar from interactions with aquifer rocks other than evaporites, possibly clastic sedimentary rocks or basement rocks with Phanerozoic KAr “ages”; and (4) the brine deposited fluorite without having boiled or degassed.  相似文献   


14.
Analytical procedures in the determination of iodine-129 (half-life: 1.6×107 y) have been studied using accelerator mass spectrometry (AMS), with special references to the separation procedures of iodine from soil samples for the AMS measurement. Iodine was successfully volatilized from soil samples by pyrohydrolysis at 1000 °C and collected in a trap solution. Iodine was purified from the matrix by solvent extraction. Finally, it was precipitated as silver iodide to make a target for AMS. In order to obtain information on the 129I/127I ratio in a chemical blank (or iodine carrier), we have determined the ratios in several iodine reagents and found that the ratios fell in a narrow range around 1.7×10−13. The detection limit for soil sample (1 g material) by the present method was about 0.01 mBq/kg or 4×10−11 as the ratio of stable iodine (129I/127I ratio), i.e. these values were much better than that by neutron activation analysis (NAA) used in our previous studies. We have applied this method in the analysis of soil samples collected from different places in Japan. We could successfully determine 129I in soil samples with low 129I concentrations, which could not be detected by NAA. Sample size necessary for the soil analysis by AMS was only about 0.5 g or less, whereas about 100 g of the sample were required for NAA [Muramatsu, Y., Ohmomo, Y., 1986. Iodine-129 and iodine-127 in environmental samples collected from Tokaimura/ Ibaraki, Japan. Sci. Total Environ. 48, 33-43]. Using this method, new data were obtained for the 129I levels in 20 soil samples collected from background areas far from nuclear facilities, and the ranges were 1.4×10−5−4.5×10−3 Bq/kg as 129I concentrations and 3.9×10−11−2.2×10−8 as 129I/127I ratios. These values are useful in understanding the 129I levels in Japanese environments. Higher 129I concentrations were observed in forest soils than those in field and rice paddy soils should be related to the interception effect of atmospheric 129I due to tree canopies. Relatively high 129I/127I ratios found in rice paddy soils could be explained by their low stable iodine concentrations which were caused by the desorption of stable iodine from the rice paddies during the cultivation.  相似文献   

15.
Noble gases were extracted in steps from grain size fractions of microdiamonds ( < 100 μm) from the Kokchetav Massif, Northern Kazakhstan, by pyrolysis and combustion. The concentration of 4He in the diamonds proper (liberated by combustion) shows a 1/r dependence on grain size. For grain diameters > 15 μm the concentration also decreases with the combustion step. Both results are clear evidence that 4He has been implanted into the diamonds from -decaying elements in the surrounding matrix. The saturation concentration of 4He(5.6 × 10−4 cm3 STP/g) is among the very highest observed in any terrestrial diamonds. Fission xenon from the spontaneous fission of 238U accompanies the radiogenic 4He; the 136Xef/4He ratio of (2.5 ± 0.3) × 10−9 agrees well with the production ratio of 2.3 × 10−9 expected in a reservoir where Th/U 3.3. Radiogenic 40Ar is predominantly ( > 90%) set free upon combustion; it also resides in the diamonds and appears to have been incorporated into the diamonds upon their formation.

3He, on the other hand is mainly released during pyrolysis and hence is apparently carried by ‘contaminants’. The concentration in the diamonds proper is of the order of 4 × 10−12 cm3 STP/g, with a 3He/4He ratio of 1 × 10−8. Excess 21Ne, similarly, appears to be present in contaminants as well as in diamonds proper. These two nuclides in the contaminants must have a nucleogenic origin, but it is difficult to explain their high concentrations.  相似文献   


16.
Isotope and hydrochemical data of the thermal water system in Cieplice laskie Zdrój (Spa) indicate the existence of two subsystems that greatly differ in volume and which meet at the fault zones of a granitic horst, where they discharge at an altitude of about 340m. One of the subsystems is very small (about 4 × 103 m3) as indicated by the tritium age of the order of 10 years and a low outflow rate. Its recharge area found from the δ18O and δD values, is about 200m above the springs, most probably on the slopes of the foothills of the Karkonosze Mountains south-southwest of the spa. The large subsystem contains water which is free of tritium and whose 14C content is from 1 to 8 pmc with δ13C = −8.0 to −9.2‰. The isotopic composition of this water reflects either the climatic effect (low-altitude recharge during a cooler pre-Holocene climate) or the altitude effect (recharge in the early Holocene period at about 1000m at the heights of the Karkonosze assuming that the 14C concentration is strongly reduced by exchange with calcite in veins). For the former hypothesis, the recharge area of this water is probably either at the foot of the southeastern slopes of the Kaczawa Mountains or/and at the foot of the Rudawy Janowickie Mountains, to the east of Cieplice. The noble gas temperatures are more consistent with the pre-Holocene recharge. Similarly, the 4He excess and 40Ar/36Ar ratio support the hypothesis of a pre-Holecene age. The constant 3He/4He ratio of 26 × 10−8 for highly different helium contents indicates crustal origin of helium. For the pre-Holocene age of water its volume is calculated at >- 109m3 (stagnant water in micropores and mobile water in fractures) and the hydraulic conductivity of the host granite massif is estimated at about 7 × 10−8 ms−1. Two outflows from this subsystem have different and variable fractions of a modern water component (bomb age), most probably originating from the bank infiltration of a nearby stream.  相似文献   

17.
The determination of the earthquake energy budget remains a challenging issue for Earth scientists, as understanding the partitioning of energy is a key towards the understanding the physics of earthquakes. Here we estimate the partition of the mechanical work density into heat and surface energy (energy required to create new fracture surface) during seismic slip on a location along a fault. Earthquake energy partitioning is determined from field and microstructural analyses of a fault segment decorated by pseudotachylyte (solidified friction-induced melt produced during seismic slip) exhumed from a depth of ~ 10 km—typical for earthquake hypocenters in the continental crust. Frictional heat per unit fault area estimated from the thickness of pseudotachylytes is ~ 27 MJ m− 2. Surface energy, estimated from microcrack density inside clast (i.e., cracked grains) entrapped in the pseudotachylyte and in the fault wall rock, ranges between 0.10 and 0.85 MJ m− 2. Our estimates for the studied fault segment suggest that ~ 97–99% of the energy was dissipated as heat during seismic slip. We conclude that at 10 km depth, less than 3% of the total mechanical work density is adsorbed as surface energy on the fault plane during earthquake rupture.  相似文献   

18.
A new method is described for estimating: (a) the meridional electric current density, jθ, (b) the vertical growth rate of the zonal magnetic field, ∂Bφ/∂r, or its scale-height, Bφ/∂Bφ/∂r) and (c) the vertical growth rate of the vertical current density, ∂jr/∂r, at a few isolated points on the top surface of the Earth's core from observations of the internal geomagnetic field at the Earth's surface. The theoretical technique rests on combining unaccelerated, gravitationally-driven Boussinesq fluid dynamics of the core with frozen-flux electromagnetism, the mantle being treated as a spherically symmetric insulator.

Insertion into this theory of main field models for epochs 1965, 1975 leads to preliminary values for these quantities of magnitude: (a) jθ 1 A/m2, (b) ∂Bφ/∂r 10−6 T/m or Bφ/(∂Bφ/∂r) 10 m, (c) ∂jr/∂r 10−6 A/m3. Some geophysical implications of these estimates are discussed.  相似文献   


19.
238U, 232Th, 230Th and 226Ra abundances have been measured in six samples of recent Hawaiian basalt by high precision mass spectrometry, in an attempt to compare the melting process in plumes and at spreading ridges. The data reveal a very small range in (230Th/238U) activity ratio up to a maximum value of 1.02 ± 0.01, and (226Ra/230Th) activity ratios which lie between 1.10 ± 0.015 and 1.19 ± 0.02. UTh and RaTh abundances are linearly correlated demonstrating that the disequilibria predate crystallisation and differentiation. Using recently published estimates for the bulk partition coefficients of U and Th, the results are consistent with melting rates > 10−3 kg m−3 a−1 at porosities < 10−3 for dynamic fractional melting in the garnet stability field.  相似文献   

20.
本文对龙门山断裂带金河磷矿浅钻岩芯中的三种断层泥开展了低速到高速摩擦滑动的实验研究,并对实验变形样品开展了BET比表面积研究.摩擦实验在干燥和孔隙水压条件下开展,速率范围涵盖20 μm·s-1~1.4 m·s-1.实验结果显示,三种断层泥在干燥条件下的摩擦性质差别不大,但在孔隙水压条件下,三者的中低速摩擦强度与层状硅酸盐矿物的种类而非总含量紧密相关,蒙脱石和伊利石相比绿泥石更能有效地弱化断层.三种断层泥在孔隙水压条件下存在中低速率域的速度强化,暗示着对断层的加速滑动存在一定的阻碍作用.孔隙水压下,黄绿色和灰绿色断层泥的初始动态弱化非常迅速并伴随断层泥层的瞬时扩容,凹凸体急剧加热导致的局部热压作用可能是造成这种力学行为的物理机制.在经历高速滑动之后,三种断层泥在干、湿条件下的BET比表面积都显著降低,暗示着可能发生了颗粒烧结.中低速域内,孔隙水的存在使得断层泥呈现分散式的剪切变形,BET比表面积的增加因此比干燥条件下更加明显.对表面能的估算表明,颗粒磨碎所消耗的能量至多不超过摩擦力做功的8%,暗示着断层作用中颗粒磨碎所占的能量比例较低.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号