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作者研究了南海北部表层沉积物中10个站位的海绿石。用显微镜、各种谱仪、透射电镜、扫描电镜、电子探针和化学分析等方法,对海绿石的外表特征及矿物学特性,进行了较为系统的分析;并结合海绿石的产状和分布,研究了它们的成因及沉积环境问题。本区海绿石可分为生物状海绿石、页状海绿石和颗粒状海绿石;根据X射线和红外光谱等特征,有混合层海绿石和混合物海绿石两类;根据化学成份计算黑色生物状海绿石的晶体化学 相似文献
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安徽奥陶系石灰岩中含铁非骨架核形石的成因及其聚铁作用 总被引：7，自引：0，他引：7
安徽下扬子区下奥陶统顶部到中奥陶统的灰色生物屑微晶灰岩中,产出一种含铁的非骨架核形石。它形成于宁镇-皖南碳酸盐台地两侧边缘的浅水到潮坪环境中。这种核形石是由蓝绿藻以生物碎屑为核心,围绕核心以底部滚动和悬浮方式生长成同心圆状多层包壳的椭球体,有柱核形石和层柱核形石两种类型。蓝绿藻呈核形石生长过程中,吸附铁质形成含铁核形石,并能吸附铜、铅等金属元素。 相似文献
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厄瓜多尔奥连特盆地白垩系Napo组UT段发育一套分布广泛的富含海绿石的硅质碎屑岩,针对海绿石的岩相、矿物学、地球化学及时空属性进行分析,可以揭示海绿石的组分、成熟度、形成及成因类型,结合地质约束有助于理解其形成的沉积地质意义.利用偏光显微镜、X射线衍射、电子探针及Qemscan对海绿石矿物的岩相、矿物组成和主量元素进行系统地分析.暗绿色、呈弯曲玫瑰花状的海绿石具有高的K2O含量(平均值为8%,质量百分比),是形成于海相低沉积速率环境的高演化成熟型海绿石云母矿物或狭义范畴的海绿石.化学组分和时空属性揭示研究层段的海绿石经历了一定程度风暴流和/或潮汐流作用的搬运改造,属于层内准原地海绿石.UT段海绿石含量向上的增大趋势和成熟度的变化,以及横向上从盆地东部斜坡区埋深2~3 km到西部盆缘露头区相距约120 km的海绿石在形态和化学成分上具有相似性,指示其主要是层内准原地海绿石的特点.UT段垂向上海绿石含量增大的趋势同时反映外陆棚物源区原地海绿石向岸方向的短距离迁移,反映了相对海平面持续上升的海进过程;而且同时期海绿石平面上的广泛分布指示沉积时期的环境属于构造稳定的陆表海. 相似文献
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京津地区铁岭组,景儿峪组海绿石^40Ar—39Ar年龄 总被引：10，自引：2，他引：10
利用海绿石＾４０Ａｒ－＾３９Ａｒ年龄校正公式，通过测量海绿石中的可膨胀层含量ｎ以及中子活化过程中＾３９Ａｒ的丢失率η，求出海绿石的年龄。经测定，京津地区铁岭组，景儿峪组海绿石中可膨胀层含量为５％￣６％，中子活化中＾３９Ａｒ丢失率为１７％￣１９％，由校正后的海绿石年龄推测出铁岭组年龄界限范围。 相似文献
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徐州大北望寒武系徐庄组发育不同类型海绿石，为探讨不同类型海绿石的成因，基于海绿石的矿物学、地球化学及沉积环境分析，利用偏光显微镜、X 射线衍射及电子探针等方法对各含海绿石岩层及不同类型海绿石进行系统对比研究查明海绿石的指相意义。结果表明，徐庄组发育颗粒状、碎屑假象状和胶团状三种类型海绿石，其中颗粒状海绿石具有中—高含量钾、高含量铁、砂岩中—高含量铝、石灰岩中低含量铝等特征；碎屑假象状海绿石具有变化大的钾、铁、铝，且保持着其母质形态特征；胶团状海绿石具有高钾、高铁、低铝特点。颗粒状海绿石成因符合颗粒绿化理论，砂岩中海绿石易受环境影响；碎屑假象状海绿石成因符合层状晶格理论及假象替代理论，受到交代和溶蚀作用，因受较强的水动力条件影响成分变化较大；胶团状海绿石是凝胶状海绿石通过胶结作用沉淀，形成于稳定环境中。 相似文献
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笔者发现的贵州晴隆二迭系中的海绿石矿物,经测试和鉴定,认为晴隆海绿石矿物是在滨海环境中形成。晶体结构为有序高钾云母型结构类型,矿物结构属于二八面体型类型,中等成熟度,含膨胀层小于或等于10％.从而推测与它有关的峨眉山玄武岩在该地的早期喷发环境亦应为滨海环境. 相似文献
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地球的软流层(圈)堪称全球构造、岩浆与成矿作用动力之源。以往人们虽然认识到软流层的重要作用,但其形成机制的定量研究还不够。最近20多年来,对地球半径变化的检验研究结果表明,地球膨胀已经有了较多的直接证据。而且,即使按照地球膨胀晚期0.1 mm/a的半径增长率计算,所产生的地球膨胀构造动力事件,也将是一个全球性超级构造动力事件。根据地球的非线性有限膨胀演化,所提出的软流层成因是:源于原始地球深部的膨胀内压,推挤原始地幔顶部物质做功并转化为原始岩石圈球壳围限下的地幔顶部物质的压缩能A,当压缩能的积累超过原始地幔顶部物质局部熔融所需要的热能Ω时,地幔顶部物质便开始熔融并逐渐形成地球的原始软流层。据此,按照地球非线性膨胀演化初期的半径增长率1.08 mm/a、原始地幔顶部物质以15%的局部熔融和绝热等压过程估算,地球开始膨胀后仅19.2 Ma,地球的原始软流层(圈)便可形成。 相似文献
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关于东海现代沉积物中的海绿石,前人曾有过报道,但都限于一般性的描述。近年来我们对东海表层沉积物中的海绿石进行了较为系统的研究,工作范围为东经121°-129°,北纬26°30′-32°00′,样品233个。分别进行了镜下鉴定、透射电镜和扫描电镜观察,并以多晶X-射线衍射法,化学全分析、差热分析、红外吸收光谱和电子探针等方法进行较系统的矿物学研究。本文就东海表层沉积物中海绿石的矿物学特征,产状及分布进行阐述,并对其成因作了初步的探讨。 相似文献
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在内蒙古西乌珠穆沁旗晚石炭世—早二叠世阿木山组第三段泥晶灰岩中发现有海绿石。对海绿石的微观特征分析表明,阿木山组海绿石呈团粒状结构,同时呈胶体产出于方解石周边,显示了原生海绿石的基本特点。电子探针的组分分析表明,阿木山组中的海绿石为高成熟度的海绿石。通过对不同地区和不同环境下海绿石的组分特征分析,建立了一种海绿石沉积的理想模式,同时揭示了阿木山组第三段海绿石化作用是在含氧量不够充分的弱还原状态下的正常浅海中进行的。本区阿木山组的下碎屑岩段和上灰岩段是在海水两进两退环境下的沉积,阿木山组灰岩中发现的海绿石则有可能代表了一个海进的开始。本区海绿石的发现及研究,对于进一步研究该区层序地层特征、地层格架及区域地层对比具有重要意义。 相似文献
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N.V. Logvinenko 《Sedimentary Geology》1982,31(1):43-48
There are two general types of sedimentary glauconite in Recent ocean sediments: terrigenous-allogenic and authigenic glauconite. Recent sediments of the oceans contain mainly terrigenous-allogenic glauconite (shelf and continental slope) which is formed from ancient glauconite-bearing rocks on coasts, islands and the ocean floor. The age of terrigenous-allogenic glauconite ranges from 2 to 70 m.y. (8 samples from the Atlantic Ocean, 13 from the Pacific Ocean, 1 from the Indian Ocean). The area of terrigenous-allogenic glauconite distribution correlates very well with the area of distribution of glauconite-bearing rocks on land and does not correlate with the climate and bathymetry.Authigenic glauconite is seldom found in Recent ocean sediments. The sediments with authigenic glauconite form transition zones between sediments with organic carbon, H2S and sulphide near coasts and oxidized sediments of the ocean floor (red clay and others). The areas of authigenic glauconite distribution are not yet well known. The formation of authigenic glauconite occurs mainly during diagenesis of sediments by synthesis from interstitial solutions and/or alteration of clay minerals. 相似文献
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A COMPARATIVE STUDY OF GLAUCONITE AND THE ASSOCIATED CLAY FRACTION IN MODERN MARINE SEDIMENTS 总被引：1，自引：0，他引：1
The crystallinity and mineralogy of both the glauconite and the clay fraction of samples from six contemporary marine environments were investigated by X-ray diffraction. In those areas where glauconite is now forming, the mineralogy and the degree of crystallinity of both the glauconite pellets and the associated clay fraction are similar. In contrast, detrital and relic glauconites are observed to have mineralogies that are different from their clay fractions. No consistent relationship was observed between degree of crystallinity and color of the pellets. Further, only two classes of glauconite as defined by BURST (1958) were common: expandable, interlayered clays and two or more clay minerals in a mixed assemblage. Based on the clay fraction-glauconite similarities and other supporting evidence, glauconite on the Scotia Ridge is concluded to be authigenic. Glauconite from Santa Monica Bay, California and from the continental shelf off Morocco appear to be detrital. Glauconite pellets in the shelf sediments off Guinea and the southeastern Atlantic Shelf of the United States are both detrital and authigenic. The poor crystallinity exhibited by the Chatham Rise glauconite is in contrast to the well-crystallized associated clay fraction and indicates that they are not genetically related. However, the origin of this glauconite remains in doubt. 相似文献
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乌拉嘎、平顶山、老柞山金矿是佳木斯地块三个重要的金矿。研究表明，石英是金矿中重要的脉石矿物，也是金的主要载体。ＳｉＯ２含量低于９８％，而∑（Ａｌ２Ｏ３＋Ｋ２Ｏ＋Ｎａ２Ｏ）含量高于１．３％的石英为含金石英；含金或富含金石英的热释发光谱以双峰或多峰为其主要特征。因此，上述石英的标型特征可作为金矿床重要的找矿标志，对佳木斯地块的矿点评价和扩大找矿远景有着重要的意义 相似文献
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Terry A. Nelsen Pat Blackwelder Terri Hood Brent McKee Nidia Romer Carlos Alvarez-Zarikian Simone Metz 《Estuaries and Coasts》1994,17(4):873-885
Hypotheses related to variability in seasonal hypoxic conditions, coastal nutrient enhancement, and off-shelf transport of carbon on the Louisiana continental shelf were tested by characterization of biogenic, lithogenic, and authigenic components from two shelf and one Mississippi Canyon sediment cores. The authigenic-phase glauconite occurs above detection limits only in the core from the hypoxic area. A major increase in glauconite concentration was coincident with the onset (≈1940) of the increased use of commercial fertilizers in the United States. In the same hypoxic-area core, benthic foraminifera species diversity decreases upcore from approximately the turn of the century to the present in a manner concurrent with glauconite and fertilizer increases. A subset of opportunistic benthic foraminifera species, known to become more prominent in stressed environments (i.e., hypoxic), increased upcore from ～52% of the total population at core bottom to ≈90% at core top. These benthic foraminifera population and diversity changes were not apparent in a “control” core outside the area of documented hypoxia. Seaward of the shelf, in the Mississippi Canyon, coincident increases in sediment accumulation rate, percentages of coarse fraction and of organic carbon at core top indicate increased offshelf transport of carbon and other components. Quartz percentages indicate that episodic down-canyon transport has been active to core bottom (prior to the mid 1800s). 相似文献
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国内难溶性钾矿资源及其开发利用 总被引：2，自引：0，他引：2
国内难溶性钾矿资源较丰富,可分为含钾岩石和含钾矿物两大类及若干亚类。含钾沉积岩有:富钾火山沉积凝灰岩(绿豆岩),含钾砂、页岩,含钾泥灰岩,含钾石膏泥,含钾磷块岩等;含钾岩浆岩有:霞石正长岩、霓辉石石英正长岩、流纹斑岩、正长斑岩、花岗伟晶岩、钾长粗面凝灰熔岩等;含钾变质岩有:钾长浅粒岩、云母片岩、钾长混合片麻岩等;可作钾矿资源的含钾矿物有:钾长石、明矾石、伊利石、白榴石、海绿石等。目前,绿豆岩,含钾砂、页岩,流纹岩,海绿石,白榴石等已可单独开采利用,制作钾肥;霞石正长岩、伊利石、钾长石、明矾石等可被综合回收利用;粗面岩、响岩、粗玄岩,含钾泥灰岩、钾长浅粒岩等尚待开发利用。 相似文献
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Shovan Lal Chattoraj Santanu Banerjee P. K. Saraswati 《Journal of the Geological Society of India》2009,73(4):567-574
Glauconitic minerals are considered as one of the valuable input parameters in sequence stratigraphic analysis of a basin.
In the present study glauconitic minerals are reported from subtidal green shale facies in the lower part of the Late Paleocene-Early
Eocene Naredi Formation of western Kutch. On the basis of the foraminiferal assemblage the glauconite bearing beds are interpreted
to have formed in a mid shelf depositional settings of an unstable marine conditions. XRD studies confirm the glauconite mineralogy
of the green pellets and provide an estimation of glauconite maturity. Textural attributes of the glauconites confirm their
derivation by different degrees of alteration of precursor feldspar grains. Because of the authigenic origin and autochthonous
nature, these glauconites hold promise for understanding sequence stratigraphy of the Palaeogene succession of the western
Kutch. 相似文献
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Erzsébet Tóth Tamás G. Weiszburg Teresa Jeffries C. Terry Williams András Bartha Éva Bertalan Ildikó Cora 《Chemical Geology》2010,269(3-4):312-328
Samples of glauconite, representing different stages of glauconitisation, as well as different formation environments, were analysed for rare earth elements (REE) and other trace elements using a combination of bulk sample and spatially-resolved in situ techniques. The results indicate that the high-sensitivity, spatially-resolved technique of laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) produces values up to two orders of magnitude lower than the bulk sample analyses. This suggests that submicroscopic rare earth element-bearing phases are distributed within the glauconite aggregates comprising the bulk samples. Analytical scanning electron microscopy (ASEM) revealed the presence of micrometre-sized grains of apatite and pore filling precipitates of an unidentified (REE, Ca)-phosphate (approximate composition Ca0.3–0.4(Ce0.4La0.1–0.2Nd0.1)PO4) in some glauconite grains.The inherent REE concentrations of the glauconite aggregates (i.e., glauconite crystallites without accidental mechanical inclusions or authigenic, not layer silicate mineral precipitates) was found to be relatively low (e.g., typically less than 100 ppm), and this value decreased with increasing glauconitisation (smectite–mica transformation through a series of recrystallisation processes). These results suggest that the REEs substitute for Ca in the interlayer space of the layer silicate structure and, therefore, the REE content decreases as Ca is progressively removed from the interlayer (smectite–mica transition).LA-ICP-MS, when combined with electron probe microanalysis (EPMA) or ASEM, offers an opportunity to exclude submicroscopic accessory minerals from glauconite trace element analyses, and so produces reliable trace element data for the respective minerals which host those elements.These results illustrate that accessory minerals are difficult to eliminate from clay samples, and that care needs to be taken in the interpretation of clay mineral REE distributions, irrespective of the aggregation state of the studied clay (i.e., whether finely dispersed within the sedimentary rock, or forming millimetre-sized aggregates). Model calculations showed that authigenic apatite associated with the studied green marine clays tends to have higher REE content than “bioapatites”, the total REE content being above 10 000 ppm. 相似文献