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1.
Severe red tides due toChattonella antiqua occur sporadically during summer in the Seto Inland Sea, Japan, and cause significant damage to the fishing industry. In order to assess the chemical environment with respect to the outbreak ofC. antiqua, environmental factors that affect the growth ofC. antiqua were monitored around the Ie-shima Islands, the Seto Inland Sea, in the summer of 1986. In addition, a growth bioassay of the seawater usingC. antiqua was conducted under a semicontinuous culture system. Although temperature, salinity and light intensity were optimum for the growth ofC. antiqua, red tides by this species did not occur. Concentrations of NH 4 + , NO 3 ? and PO 4 3? were low (<0.4, <0.2, <0.06 µM, respectively) above the thermocline (8–12 m) and high below it (0.6–2, 4–8, 0.4–0.8 µM, respectively). Vitamin B12 concentrations did not change significantly between the surface (0 m) and below the thermocline (25 m) in the level of 2–4 ng·l?1. The growth bioassay revealed that in the surface waters, concentrations of N- as well as P- nutrients were too low to support a rapid growth ofC. antiqua. At the depth of 25 m, neither N, P nor B12 limited the growth rate. In order to obtain more quantitative information on the growth rate as a function of the concentrations of N- and P- nutrients,C. antiqua was grown in a semicontinuous culture system by changing nutrient concentrations systematically. The observed growth rate (μ) can be approximated as follows: $$\mu = \mu _{\max } .\frac{{S_N }}{{K_g ^N + S_N }}.\frac{{S_{PO4} }}{{K_g ^P + S_{PO4} }},$$ whereS N is the concentration of NO 3 ? plus NH 4 + (0–6 µM),S PO, the concentration of PO 4 3? (0–0.6 µM), μmax (0.97 d?1) the maximal growth rate,K 0 N (1.0 µM) andK 0 P (0.11 µM) the half saturation constants for NO 3 ? and PO 4 3? , respectively. Using the above equation with nutrient concentrations measured, the rate at which seawater supports the growth ofC. antiqua can be estimated and this can be used for the assessment of chemical environments with respect to the outbreak ofC. antiqua.  相似文献   

2.
A. V. Savenko 《Oceanology》2014,54(2):170-172
The solubility of amorphous silica was studied in mixtures of riverine and marine waters simulating the water composition at the river-sea geochemical barrier. The value of the thermodynamical equilibrium constant was determined for the reaction of silicon solubility as K r 0 = (1.71 ± 0.01) × 10?3 at 22°C. A near-linear dependence was found for the activity ratio of the H4SiO 4 0 and the salinity with the increase of this ratio from 1.00 in the riverine to 1.15 in the standard seawater.  相似文献   

3.
We consider the resemblance between the ion composition of the fraction of soluble aerosols and gaseous admixtures in the atmospheric surface layer at the high-level Mondy station (East Sayan), those in the Listvyanka settlement south of Lake Baikal, in the city of Irkutsk, and at the Primorskaya station near the city of Ussuriysk (Primorskii krai). We use measurement data on the concentrations of the following ions: HCO 3 ? , SO 4 2? , NO 3 ? , Cl?, H+, Na+, K+, Mg2+, Ca2+ in the soluble fraction of aerosols and gases HNO3, HCl, NH3, and SO2 in air samples over a 10-year period conducted in the mode of online monitoring. We found the lognormal form of distributions of concentrations of each of the abovementioned components according to the number of samples. A versatile scheme of the distribution of mean geometric concentrations of atmospheric components was proposed for all four groups.  相似文献   

4.
The distribution of the fugacity of CO2 ( $ f_{{{\text{CO}}_{ 2} }} $ ) and air–sea CO2 exchange were comprehensively investigated in the outer estuary to offshore shallow water region (lying adjacent to the Sundarban mangrove forest) covering an area of ~2,000 km2 in the northern Bay of Bengal during the winter. A total of ten sampling surveys were conducted between 1 December, 2011 and 21 February, 2012. Physico-chemical variables like sea surface temperature (SST), salinity, pH, total alkalinity (TAlk), dissolved inorganic carbon (DIC) and in vivo chlorophyll-a along with atmospheric variables were measured in order to study their role in controlling the CO2 flux. Surface water $ f_{{{\text{CO}}_{ 2} }} $ ranged between 111 and 459 μatm which correlated significantly with the SST (r = 0.71, p < 0.001, n = 62). Neither DIC nor TAlk showed any linear relationship with varying salinity in the estuarine mixing zone, demonstrating the significant presence of non-carbonate alkalinity. An overall net biological control on the surface $ f_{{{\text{CO}}_{ 2} }} $ distribution was established during the study, although no significant correlation was found between chlorophyll-a and $ f_{{{\text{CO}}_{ 2} }} $ (water). The shallow water region studied was mostly under-saturated with CO2 and acted as a sink for atmospheric CO2. The difference between surface water and atmospheric $ f_{{{\text{CO}}_{ 2} }} $ ( $ \Updelta f_{{{\text{CO}}_{ 2} }} $ ) ranged from ?274 to 69 μatm, with an average seaward flux of ?10.5 ± 12.6 μmol m?2 h?1. The $ \Updelta f_{{{\text{CO}}_{ 2} }} $ and hence the air–sea CO2 exchange was primarily regulated by the variation in sea surface $ f_{{{\text{CO}}_{ 2} }} $ , since atmospheric $ f_{{{\text{CO}}_{ 2} }} $ varied over a comparatively narrow range of 361.23–399.05 μatm.  相似文献   

5.
Wind-wave spectra measured in a wind-flume are analyzed according to the hypothesis of local equilibrium. The gross relation between the wave height and the frequency is reexamined to yield the basic validity of the 3/2-power law of Toba orE～? in the range of 0.4≦?≦1, where? is the wave-wind parameter defined by?=ω p u */g; ω p denotes the peak frequency of the wind-wave spectra,u * the friction velocity andg the gravitational acceleration. Noticeable deviation is found, however, for?<0.4 or?>1. In particular, the data for large? suggest the existence of an upper limit of the wave nonlinearityE at about 5×10?2, whereE=Eω p 4 /g2 withE the total power of the wind wave spectrum. Then, the spectral form is investigated in detail. As? decreases, the normalized spectrum becomes more gradual as a whole, but its forward (low frequency) part tends to show a steeper profile. In the high frequency region ( \(\tilde \omega \) >2.6), the spectrum is found to have a functional form likeu * 2 ω ?3, which differs from the usualω-dependence asω ?5 orω ?4. It suggests weak dependence of the high-frequency spectra on the gravitational accelerationg and on the peak frequencyω p ; spectral density at high frequencies may be saturated, so that its magnitude may be dominated by the frequencyω, the friction velocityu *, the surface tension and the viscosity.  相似文献   

6.
Weller??s allometric model assumes that the allometric relationships of mean area occupied by a tree $ \bar{s} $ , i.e., the reciprocal of population density $ \rho $ , $ \bar{s}\left( { = {1 \mathord{\left/ {\vphantom {1 {\rho = g_{\varphi } \cdot \bar{w}^{\varphi } }}} \right. \kern-0em} {\rho = g_{\varphi } \cdot \bar{w}^{\varphi } }}} \right) $ , mean tree height $ \bar{H}\left( { = g_{\theta } \cdot \bar{w}^{\theta } } \right) $ , and mean aboveground mass density $ \bar{d}\left( { = g_{\delta } \cdot \bar{w}^{\delta } } \right) $ to mean aboveground mass $ \bar{w} $ hold. Using the model, the self-thinning line $ \left( {\bar{w} = K \cdot \rho^{ - \alpha } } \right) $ of overcrowded Kandelia obovata stands in Okinawa, Japan, was studied over 8?years. Mean tree height increased with increasing $ \bar{w} $ . The values of the allometric constant $ \theta $ and the multiplying factor $ g_{\theta } $ are 0.3857 and 2.157?m?kg???, respectively. The allometric constant $ \delta $ and the multiplying factor $ g_{\delta } $ are ?0.01673 and 2.685?m?3?kg1???, respectively. The $ \delta $ value was not significantly different from zero, showing that $ \bar{d} $ remains constant regardless of any increase in $ \bar{w} $ . The average of $ \bar{d} $ , i.e., biomass density $ \left( {{{\bar{w} \cdot \rho } \mathord{\left/ {\vphantom {{\bar{w} \cdot \rho } {\bar{H}}}} \right. \kern-0em} {\bar{H}}}} \right) $ , was 2.641?±?0.022?kg?m?3, which was considerably higher than 1.3?C1.5?kg?m?3 of most terrestrial forests. The self-thinning exponent $ \alpha \left( { = {1 \mathord{\left/ {\vphantom {1 {\varphi = }}} \right. \kern-0em} {\varphi = }}{1 \mathord{\left/ {\vphantom {1 {\left\{ {1 - \left( {\theta + \delta } \right)} \right\}}}} \right. \kern-0em} {\left\{ {1 - \left( {\theta + \delta } \right)} \right\}}}} \right) $ and the multiplying factor $ K\left( { = \left( {g_{\theta } \cdot g_{\delta } } \right)^{\alpha } } \right) $ were estimated to be 1.585 and 16.18?kg?m?2??, respectively. The estimators $ \theta $ and $ \delta $ are dependent on each other. Therefore, the observed value of $ \theta + \delta $ cannot be used for the test of the hypothesis that the expectation of the estimator $ \theta + \delta $ equals 1/3, i.e., $ \alpha = {3 \mathord{\left/ {\vphantom {3 2}} \right. \kern-0em} 2} $ , or 1/4, i.e., $ \alpha = {4 \mathord{\left/ {\vphantom {4 3}} \right. \kern-0em} 3} $ . The $ \varphi $ value was 0.6310, which is the same as the reciprocal of the self-thinning exponent of 1.585, and was not significantly different from 2/3 (t?=?1.860, df?=?191, p?=?0.06429), i.e., $ \alpha = {3 \mathord{\left/ {\vphantom {3 2}} \right. \kern-0em} 2} $ . Thus the self-thinning exponent is not significantly different from 3/2 based on the simple geometric model. On the other hand, the self-thinning exponent was significantly different from 3/4 (t?=?6.213, df?=?191, p?=?3.182?×?10?9), i.e., $ \alpha = {4 \mathord{\left/ {\vphantom {4 3}} \right. \kern-0em} 3} $ . Therefore, the self-thinning exponent is significantly different from 4/3 based on the metabolic model.  相似文献   

7.
The ability to degraden-paraffin mixture of two bacterial strains,Caulobacter sp. andFlavobacterium sp., isolated from sea water of Tokyo Bay was studied experimentally in the enriched seawater (ESW) medium. These bacteria degraded actively the mixture ofn-tridecane,n-tetradecane,n-pentadecane andn-hexadecane. The maximum rate of degradation was observed after a lag period of 2 to 8 day and these bacteria were found to degrade then-paraffin mixture at rates calculated to be in a range from 3.3×10?12 to 3.4×10?11 mg-oil cell?1 h?1 at 20°C. The maximum degradation rate,r m mg-oil l?1 h?1, was correlated with the amount of the initial totaln-paraffin,S mg-oil l?1, as expressed by the following equation: $$rm = (rm)\max \left( {\frac{S}{{S + Km}}} \right)$$ where (r m )max denotes the largest value ofr m whenn-paraffin exists in large excess andK m is a constant and represents the amount ofn-paraffin at which the degradation rate,r m , reaches 1/2 of its largest value, (r m )max. The values of (r m )max andK m were calculated to be as follows: In the case ofCaulobacter sp. (strain KM-1), (r m )max=6.0 mg-oil l?1 h?1 andK m =191 mg-oillesw ?1; in the case ofFlavobacterium sp., (r m )max=5.47 mg-oil l?1 h?1 andK m =152 mg-oillesw ?1.  相似文献   

8.
To estimate benthic denitrification in a marginal sea, we assessed the usefulness of \({\text{N}}_{2}^{*}\) , a new tracer to measure the excess nitrogen gas (N2) using dissolved N2 and argon (Ar) with N* in the intermediate layer (26.6–27.4σ θ ) of the Okhotsk Sea. The examined parameters capable of affecting \({\text{N}}_{2}^{*}\) are denitrification, air injection and rapid cooling. We investigated the relative proportions of these effects on \({\text{N}}_{2}^{*}\) using multiple linear regression analysis. The best model included two examined parameters of denitrification and air injection based on the Akaike information criterion as a measure of the model fit to data. More than 80 % of \({\text{N}}_{2}^{*}\) was derived from the denitrification, followed by air injection. Denitrification over the Okhotsk Sea shelf region was estimated to be 5.6 ± 2.4 μmol kg?1. The distribution of \({\text{N}}_{2}^{*}\) was correlated with potential temperature (θ) between 26.6 and 27.4σ θ (r = ?0.55). Therefore, we concluded that \({\text{N}}_{2}^{*}\) and N* can act complementarily as a quasi-conservative tracer of benthic denitrification in the Okhotsk Sea. Our findings suggest that \({\text{N}}_{2}^{*}\) in combination with N* is a useful chemical tracer to estimate benthic denitrification in a marginal sea.  相似文献   

9.
The suggested equation system, including 267 chemical reactions and corresponding parametrizations of disturbances of the electric field and electron temperature, describes the dynamics of the mesosphere composition under the influence of high-altitude discharges (sprites and halos). Based on this system, the ionic disturbance, neutral components, and optical emissions of the night mesosphere caused by the sprites were modeled for a height of 77–85 km. Most attention was paid to the dynamics of disturbances of concentrations of electrons and O 2 + , NO+, H3O+, H5O 2 + , and N 2 + typical of the studied heights. The major chemical reactions leading to the disturbance of ionic contents are determined and the relaxation dynamics of the chemical components is reviewed. The account of the excited atoms and molecules of nitrogen and oxygen allowed us to model the radiation of the sprite flash, calculate the volumetric velocity of the photon emission, and study the influence of the sprite on the neutral components of the mesosphere.  相似文献   

10.
Trace concentrations of labile dissolved organic phosphorus (LDOP) in oligotrophic seawater were measured by use of an enzymatic procedure and a nanomolar phosphate analytical system consisting of a gas-segmented continuous flow analyzer with a liquid waveguide capillary cell. LDOP, defined as DOP hydrolyzed by alkaline phosphatase (AP) from Escherichia coli, was quantified as the difference between the phosphate concentrations of the seawater sample with and without AP treatment. For sensitive measurement of LDOP, we found that phosphate contamination derived from commercially available AP must be corrected, and azide treatment before AP treatment proved effective in removing biological effect that occurs during DOP hydrolysis. Field observations at six stations of the western North Pacific and the East China Sea during the boreal summer revealed that, in the upper 200 m of the water column, LDOP concentrations ranged from the detection limit (3 nM) to 243 nM, and phosphate concentrations ranged from 5 to 374 nM. The spatial distribution patterns of LDOP were similar to those of phosphate. Most of the depth profiles for LDOP and phosphate showed concentrations were extremely low, <25 nM, between the surface and the deep chlorophyll maximum layer (DCML) and increased below the DCML. Strongly depleted LDOP and phosphate above the DCML suggest that LDOP is actively hydrolyzed under phosphate-depleted conditions and utilized by microbes.  相似文献   

11.
Hong Kong waters receive high nutrient loading from year-round sewage effluent and Pearl River discharge during the summer wet season. We assessed the role of physical processes in reducing eutrophication by calculating a eutrophication reduction index for four different hydrographical areas and four seasons. We used outdoor incubation experiments to assess the response of phytoplankton when physical (mixing and dilution) processes and mesozooplankton grazing were reduced. The primary regulator of phytoplankton growth in low nutrient eastern waters (reference site) shifted from nutrients in the wet season to increased vertical mixing in the dry season. In the highly flushed western waters and Victoria Harbour, the majority (>86?%) of the eutrophication impacts were reduced by strong hydrodynamic mixing (turbulence, vertical mixing, and flushing effects) all year. In southern waters, eutrophication effects were severe (chlorophyll a of up to ~73?μg?L?1) and was regulated by the ambient phosphate (PO4) concentration (~0.1?μM) during summer. In contrast, 62–96?% of the potential eutrophication impacts were reduced by physical processes during other seasons. Bioassays also revealed that the yield of chlorophyll from dissolved inorganic nitrogen (DIN) that was taken up by phytoplankton [1.1–3.3?g?Chl (mol?N)?1] was not significantly different in both N- and P-limited cases. In contrast, the uptake ratios of DIN:PO4 (26:1–105:1) and Chl:P ratios [42–150?g?Chl (mol?P)?1] in the P-limited cases were significantly (p?<?0.05, t test) higher than the N-limited cases [~16DIN:1P and 22–48?g?Chl (mol?P)?1]. The C:Chl ratios ranged from 32 to 87?g?g?1. These potential ranges in ratios need to be considered in future nutrient models.  相似文献   

12.
Stoichiometry among bioactive trace metals in the Chukchi and Beaufort Seas   总被引：1，自引：1，他引：0  
The distribution of Al, Mn, Fe, Co, Ni, Cu, Zn, Cd and Pb in seawater was investigated in the Chukchi and Beaufort Seas of the western Arctic Ocean in September 2000. The unfiltered and filtered seawater samples were used for determination of total dissolvable metal (TDM) and dissolved metal (DM), respectively. The concentration of labile particulate metal (LPM) was estimated with the difference between that of TDM and DM. The concentrations of TDAl, TDMn, TDFe, TDCo and TDPb varied substantially in the study area. The high concentrations occurred at stations near the Bering Strait, in the Mackenzie delta, and above reductive sediments on the shelf and slope. These elements were mostly dominated by labile particulate species, such as Fe?CMn oxides and species adsorbed on terrestrial clay. DCo was correlated with DMn over the study area (r?=?0.78, n?=?135), and the slope of the regression line was 27 times higher at a pelagic station than at a shelf station. TDNi, TDCu, TDZn and TDCd showed relatively small variations and were generally dominated by dissolved species. There was a moderate correlation between DCd and phosphate for all samples (r?=?0.79), whereas there were no significant correlation between the other DMs and nutrients. TDNi and TDCu showed a remarkable linearity for most stations except those near the Bering Strait (R 2?=?0.95, n?=?126). These results suggest that biogeochemical cycling including uptake by phytoplankton and remineralization from settling particles has only minor control over the distribution of trace metals in this area. Using the present data, the annual input of bioactive trace metals form the Bering Strait and the Mackenzie River was estimated. Also, the trace metal compositions of major water masses were evaluated. The dissolved elemental ratio was P:Al:Mn:Fe:Co:Ni:Cu:Zn:Cd?=?1:1.2?×?10?2:4.4?×?10?4:1.4?×?10?3:3.7?×?10?5:3.7?×?10?3:1.4?×?10?3:4.5?×?10?3:2.2?×?10?4 for Canada Basin deep water (CBDW). This ratio was significantly different from that for Pacific deep water and Bering Sea water, suggesting substantial modification of the trace metal compositions of seawater in the study area.  相似文献   

13.
A method for the determination of barium in sea water was investigated using inductively coupled plasma emission spectrometry, and sea water samples from the Japan Sea and the Pacific Ocean were directly analyzed by this method. Artificial sea water was used to prepare matrix matched standard solutions to overcome the problem of physical interference. The detection limit (signal/noise ratio=2) for barium in deionized and distilled water was 0.08µg l?1 and in sea water, 0.12µg l?1. The reproducibilities in the purified water and in the sea water at the 10µg l?1 level were 0.7% a#FFFFFFnd 0.5%, respectively. The barium concentration in both the Japan Sea and the Pacific Ocean increased with depth and ranged between 5.5–10.0µg l?1 and 4.1–18.4µg l?1, respectively.  相似文献   

14.
The stability constants K1 and K12 of phosphoric acid were determined for artificial seawater of six different salinities (5, 10, 20, 30, 35, 40‰) and in 0.2, 0.4 and 0.7 M NaCl at three temperatures (5, 15, 25°C). The results are compared with those of Kester and Pytkowicz (1967), Atlas et al. (1976) and Dickson and Riley (1979). The ionic product of water, Kw, was determined in sodium chloride media at 5, 15 and 25°C. Complex formation among Ca2+, Mg2+, HPO42? and PO43? is discussed.  相似文献   

15.
Nutrient requirements of a red tide flagellate,Chattonella antiqua, were investigated in a laboratory culture experiment. Growth ofC. antiqua was supported by nitrate and ammonium, and by urea to a limited extent, but not by glycine, alanine and glutamate. Orthophosphate served as a good phosphorus source but glycerophosphate did not. Fe3+ (1µM) fully promoted the flagellate's growth in the presence of 80µM of EDTA. The addition of Mn2+ (0–20µM), Zn2+ (0–10µM) and Co2+ (0–0.4µM) did not show any effect. Among three vitamins tested, only B12 (6 ng 1?1) served as a growth factor. Glucose, acetate and glycolate did not improve growth in the light nor did they support growth in darkness. The minimum cell quotas for nitrogen, phosphorus, iron and B12 were estimated to be 11 pmoles ce?1, 1.0, ～0.09 and 1.1 fg cell?1, respectively.  相似文献   

16.
Chemical extraction techniques show that the majority of the arsenic in North Atlantic deep-sea sediments is associated with an iron phase compositionally similar to that found in deep-sea ferromanganese nodules (As/Fe ～ 11 · 10?4) and is probably of seawater origin. Some sediments also contain As associated with Fe oxides produced by continental weathering. A minority (～8%) of the arsenic is of detrital origin but is not associated with Fe or Mn oxides; it has a content (1.7 ppm) similar to the average crustal abundance. In the Eastern Mediterranean Sea, near-shore sediments contain As associated with land-derived Fe oxides (As/Fe ～ 2 · 10?4), but As/Fe ratios increase to ～ 13 · 10?4 in deep-sea sediments as the contribution of seawater derived arsenic becomes dominant. Arsenic is enriched in metalliferous sediments (As/Fe ～ 20?50 · 10?4) but As/P ratios of metalliferous sediments, deep-sea ferromanganese nodules and deep-ocean water are all similar. Although a hydrothermal contribution cannot be discounted, it is likely that the arsenic is also of seawater origin, suggesting that hydrothermal iron oxyhydroxides remove As more efficiently from seawater than do iron phases (goethite) in deep-sea sediments and nodules. Arsenic accumulates in deep-sea sediments (～ 6 μg cm?2 10?3 yr?1) at sediments (～ 120 μg cm?2 10?3 yr?1) at rate sufficient to balance river input input (～3 · 1010 g yr?1). These estimates give an oceanic residence time for arsenic of 1–2 · 105 yr.  相似文献   

17.
The relation between the nitrate and phosphate concentrations in the Sea of Okhotsk and the bordering waters of the Pacific Ocean were studied. The surveys were carried out in the autumn, spring, and summer of 2001–2002. For the deepwater part of the sea, the relation [NO? 3] = ((14.88 ± 0.07) × [PO3? 4] ? 5.46 ± 0.17) was found. The coefficients in the equation given are statistically different from those in the similar equation for the Pacific waters: [NO? 3] = (16.05 ± 0.15) × [PO3? 4]-(7.23 ± 0.36). In the northern part of the sea; on the shelf; in the slope area; and, especially, in the deep waters of the TINRO Depression, the linear dependence between the phosphate and nitrate concentrations was distorted. This feature was described in terms of nitrate deficiency. The maximum values of this deficiency were found in the near-bottom waters. The principal processes that might cause the nitrate deficiency were considered: the difference in the oxidation rates of the nitrogen and phosphorus organic compounds, the matter transfer between the continent and the sea, the different efficiency of the biogenic burial of nitrogen and phosphorus in the bottom sediments, and the denitrification in the upper layer of the bottom sediments. It was shown that the most probable cause of the nitrate deficiency was the denitrification. The loss of inorganic nitrogen owing to the supply of the waters of the Sea of Okhotsk to the Pacific Ocean was estimated as ～2.5 × 1011 mol N/year.  相似文献   

18.
Direct measurements using a free-falling micro-profiler were conducted on the northeast coast of Hokkaido in the summer of 2007 to clarify the mixing process in the Soya Warm Current (SWC) region in terms of microstructure. The distribution of the Turner angle (Tu) showed that these regions have a high potential for double diffusive convection, but direct measurements of the turbulent dissipation rate (ε) and dissipation of temperature variance ( $ \chi_{T} $ ) did not necessarily correspond to each other in the SWC region, especially in the offshore front of SWC and farther offshore. The mixing efficiency indicated that, even though the Turner angle (Tu) indicated a high potential for double diffusive convection, turbulent mixing was the main contributor to the mixing process in this region, and double-diffusive convection only contributed partially and sparsely, especially in the boundary off SWC water. The bottom mixed layer (BML) is known to thicken off the SWC. The vertical diffusivity coefficient was enhanced near the bottom (10?4–10?3 m2 s?1) off the SWC, and these results support that turbulence near the bottom off the SWC contributed to the thickening of the BML.  相似文献   

19.
The different mineral phases of the ferromanganese (Fe–Mn) crusts stem from the interaction of biotic and abiotic components. It is therefore vital to study the activity of these components to decipher their contribution to the enrichment/depletion of metals in the crust. Thus, the present study examined sorption and release of Co and Ni by Fe-Mn crusts with associated microbial communities in the presence and absence of the metabolic poison sodium azide (15?mM). The study was conducted in the presence (G+) and absence (G?) of added glucose (0.1%) at temperatures of 4?±?1°C and 28?±?2°C. Results showed that the microbial community had maximal sorption of Co of 66.12?µg?g?1 at 4?±?1°C in the absence of added glucose and 479.75?µg?g?1 at 28?±?2°C in the presence of added glucose. Maximum sorption of Ni in the absence of added glucose was 1.89?µg?g?1 at 4?±?1°C and release of Ni was 51.28?µg?g?1 in the presence of added glucose. Under abiotic conditions with 15?mM sodium azide as a metabolic inhibitor, significant amounts of Co and Ni were released in the G+ medium. Total cell counts on the Fe-Mn crust in the presence of added glucose increased by an order of magnitude from 106 to 107 cells g?1 and in the absence of added glucose remained within the order of 106 cells?g?1 irrespective of temperature of incubation. Microscopic observation of the samples from biotic incubations showed numerous bacterial cells, exopolysaccharides, and structures resembling secondary minerals formed by bacteria. The results indicate that bacteria promote the enrichment of Co and Ni on the hydrogenetic Fe-Mn crusts by sorption processes and release of Ni by reductive dissolution of the oxides. The higher enrichment of Co than Ni is attributed to the way in which microbes interact with the metals.  相似文献   

20.
Cadmium is a biologically important trace metal that co-varies with phosphate (PO43− or Dissolved Inorganic Phosphate, DIP) in seawater. However, the exact nature of Cd uptake mechanisms and the relationship with phosphate and other nutrients in global oceans remain elusive. Here, we present a time series study of Cd and PO43− from coastal Antarctic seawater, showing that Cd co-varies with macronutrients during times of high biological activity even under nutrient and trace metal replete conditions. Our data imply that Cd/PO43− in coastal surface Antarctic seawater is higher than open ocean areas. Furthermore, the sinking of some proportion of this high Cd/PO43− water into Antarctic Bottom Water, followed by mixing into Circumpolar Deep Water, impacts Southern Ocean preformed nutrient and trace metal composition. A simple model of endmember water mass mixing with a particle fractionation of Cd/P (αCd–P) determined by the local environment can be used to account for the Cd/PO43− relationship in different parts of the ocean. The high Cd/PO43− of the coastal water is a consequence of two factors: the high input from terrestrial and continental shelf sediments and changes in biological fractionation with respect to P during uptake of Cd in regions of high Fe and Zn. This implies that the Cd/PO43− ratio of the Southern Ocean will vary on glacial–interglacial timescales as the proportion of deep water originating on the continental shelves of the Weddell Sea is reduced during glaciations because the ice shelf is pinned at the edge of the continental shelf. There could also be variations in biological fractionation of Cd/P in the surface waters of the Southern Ocean on these timescales as a result of changes in atmospheric inputs of trace metals. Further variations in the relationship between Cd and PO43− in seawater arise from changes in population structure and community requirements for macro- and micronutrients.  相似文献   

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