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1.
流域尺度面源污染的监测是系统认识农业面源污染的发生、迁移及转化过程,并对其进行有效控制的重要基础.当前,田块尺度的面源污染监测方法比较成熟,而流域尺度的监测,尤其是监测断面的布设及采样频率设置等方面的研究较少.本文详细梳理了小流域采样断面布设、采样频率优化和河流断面通量估算3方面的主要进展.1)从小流域样点布设来看,包括常规监测采样设计、针对性监测采样设计和融合前两种类型的监测采样设计3种类型,点位布设方法上有遗传算法、模糊逻辑法、熵值法和模型法等,样品采集方式包括随机采样、复合采样、综合采样以及连续采样4种类型,其中复合采样应用广泛;2)从采样频率来看,1～2周一次的采样频率即可精准获取污染负荷通量,若需要进一步提高精度,可在水文/水质变异大的时期提高监测频率及在特殊断面加密布点;3)在通量估算上,当前主要的计算方法有平均法、插值法和回归/曲线法3类方法,其中流量加权的浓度估计法、插值算法和LOADEST法是简便且精确的方法,方法的选择上也可根据不同时期流域污染源特征进一步优化.  相似文献   

2.
Measurement and interpretation of mass fluxes in favor of concentrations is gaining more and more interest, especially within the framework of the characterization and management of large-scale volatile organic carbon (VOC) groundwater contamination (source zones and plumes). Traditional methods of estimating contaminant fluxes and discharges involve individual measurements/calculations of the Darcy water flux and the contaminant concentrations. However, taken into account the spatially and temporally varying hydrologic conditions in complex, heterogeneous aquifers, higher uncertainty arises from such indirect estimation of contaminant fluxes. Therefore, the potential use of passive sampling devices for the direct measurement of groundwater-related VOC mass fluxes is examined. A review of current passive samplers for the measurement of organic contaminants in water yielded the selection of 18 samplers that were screened for a number of criteria. These criteria are related to the possible application of the sampler for the measurement of VOC mass fluxes in groundwater. This screening study indicates that direct measurement of VOC mass fluxes in groundwater is possible with very few passive samplers. Currently, the passive flux meter (PFM) is the only passive sampler which has proven to effectively measure mass fluxes in near source groundwater. A passive sampler for mass flux measurement in plume zones with regard to long-term monitoring (several months to a year) still needs to be developed or optimized. A passive sampler for long-term monitoring of contaminant mass fluxes in groundwater would be of considerable value in the development of risk-based assessment and management of soil and groundwater pollutions.  相似文献   

3.
The National Research Council has estimated that over 126,000 contaminated groundwater sites are unlikely to achieve low ug/L clean‐up goals in the foreseeable future. At these sites, cost‐effective, long‐term monitoring schemes are needed in order to understand the long‐term changes in contaminant concentrations. Current monitoring optimization schemes rely on site‐specific evaluations to optimize groundwater monitoring frequency. However, when using linear regression to estimate the long‐term zero‐order or first‐order contaminant attenuation rate, the effect of monitoring frequency and monitoring duration on the accuracy and confidence for the estimated attenuation rate is not site‐specific. For a fixed number of monitoring events, doubling the time between monitoring events (e.g., changing from quarterly monitoring to semi‐annual monitoring) will double the accuracy of estimated attenuation rate. For a fixed monitoring frequency (e.g., semi‐annual monitoring), increasing the number of monitoring events by 60% will double the accuracy of the estimated attenuation rate. Combining these two factors, doubling the time between monitoring events (e.g., quarterly monitoring to semi‐annual monitoring) while decreasing the total number of monitoring events by 38% will result in no change in the accuracy of the estimated attenuation rate. However, the time required to collect this dataset will increase by 25%. Understanding that the trade‐off between monitoring frequency and monitoring duration is not site‐specific should simplify the process of optimizing groundwater monitoring frequency at contaminated groundwater sites.  相似文献   

4.
Accurate estimation of stiffness loss is a challenging problem in structural health monitoring. In this study orthogonal wavelet decomposition is used for identifying the stiffness loss in a single degree of freedom spring-mass-damper system. The effects of excitation frequency on accuracy of damage detection is investigated. Results show that pseudo-alias effects caused by the orthogonal wavelet decomposition (OWD), affect damage detectability. It is demonstrated that theproposed approach is sunable for damage detection when the excitation frequency is relatively low. This study shows how a priori knowledge about the signal and ability to control the sampling frequency can enhance damage detectability.  相似文献   

5.
《水文科学杂志》2012,57(15):1803-1823
ABSTRACT

A new methodology is proposed for improving the accuracy of groundwater-level estimations and increasing the efficiency of groundwater-level monitoring networks. Three spatio-temporal (S-T) simulation models, numerical groundwater flow, artificial neural network and S-T kriging, are implemented to simulate water-table level variations. Individual models are combined using model fusion techniques and the more accurate of the individual and combined simulation models is selected for the estimation. Leave-one-out cross-validation shows that the estimation error of the best fusion model is significantly less than that of the three individual models. The selected fusion model is then considered for optimal S-T redesign of the groundwater monitoring network of the Dehgolan Plain (Iran). Using a Bayesian maximum entropy interpolation technique, soft data are included in the geostatistical analyses. Different scenarios are defined to incorporate economic considerations and different levels of precision in selecting the best monitoring network; a network of 37 wells is proposed as the best configuration. The mean variance estimation errors of all scenarios decrease significantly compared to that of the existing monitoring network. A reduction in equivalent uniform annual costs of different scenarios is achieved.  相似文献   

6.
The results of comprehensive field testing of on‐site vapor‐phase‐based groundwater monitoring methods are presented to demonstrate their utility as a robust and cost‐effective approach for rapidly obtaining volatile organic compounds (VOCs) concentration data from a monitoring well. These methods—which rely on sensitive, commercially available field equipment to analyze vapor in equilibrium with groundwater—proved easy to implement and can be tailored to site‐specific needs, including multilevel sampling. During field testing, low‐flow groundwater concentrations could be reasonably estimated using submerged passive vapor diffusion samplers or field equilibration of collected groundwater (R2 = 0.85 to 0.96). These two methods are not as reliant on in‐well mixing to overcome vertical stratification within wells as simpler headspace methods. The importance of well and aquifer‐specific factors on concentration data (and therefore method selection) is highlighted, including the effect of changing in‐well patterns due to seasonal temperature gradients. Results indicated that vertical stratification was relatively limited within the set of wells included in these studies, resulting in similar performance for short depth‐discrete passive vapor diffusion samplers (constructed from 40‐mL vials) and longer samplers (2.5 to 5 feet in length) designed to cover a larger portion of the screened interval. A year‐long, multi‐event evaluation demonstrated that vapor‐phase‐based monitoring methods are no more variable than conventional groundwater monitoring methods, with both types subject to similar spatial and temporal variability that can be difficult to reduce. Vapor sampling methods represent a promising approach for estimation of groundwater concentrations by reducing the cost liabilities associated with monitoring while providing a more sustainable approach.  相似文献   

7.
《Limnologica》2013,43(1):43-48
Sampling efficiency is directly linked to (faunistic) stability issues of any sampled site. It is more probable to sample a high proportion of the species occurring at a certain site, if communities remain constant in species composition with time. For this study 64 groundwater monitoring wells in Southwestern Germany were sampled six times to determine sampling efficiency. False-Negative (FN) rates and SIMPER values, two independent models expressing Faunistic values of the sampled bores, were calculated and three groups of faunistic stability could be identified based on calculated SIMPER-values. FN-rates as well as SIMPER values proved to be a valuable approach for the estimation of faunistic stability/instability, as these methods showed a highly negative correlation with each other. To collect 95% of species a number of 1.7–16.4 samples was calculated to be necessary depending on faunistic stability of the sampled habitat. On the six sampling occasions the sites harbouring a stable groundwater meiofauna resulted in 98.2% of occurring species, whereas the percentage decreased over intermediate sites (94.9%) and stressed sites (79.5%).A consequence of the data presented may be to view surveys using only two samples as campaign with orienting character, with further studies of stability issues of groundwater communities which would provide efficient and effective sampling for various kinds of sites.  相似文献   

8.
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9.
水化学分析方法在地下水异常核实中的应用   总被引：1，自引：0，他引：1  
张磊  刘耀炜  任宏微  柯云龙 《地震》2019,39(1):29-38
地震前兆识别中的异常核实工作是提高地震分析预报能力的重要环节。"四图一法"是地下水异常核实中有效的水化学分析方法,其中Piper图和Schoeller图用于判定地下水化学类型和补给关系,Gibbs图用于判定地下水化学成分来源,Giggenbach三角图用于判定地下水的水岩平衡状态和是否有深部活动信息,以及混合比例法用于计算地下水的混合程度。同时,介绍了水化学分析方法在异常核实应用中的水样采集、测试方法和基本原理。使用水化学分析方法,有助于判定异常的构造或非构造活动影响因素,提高异常判定的科学水平。  相似文献   

10.
Flood risk is generally perceived as being a consequence of surface water inundation. However, large damage is also caused by high groundwater levels. In surface hydrology, statistical frequency analysis is a standard tool to estimate discharge with a given return period or exceedance probability. First, a suitable probability distribution is fit to a series of annual maximum peaks. Second, this distribution is used to determine the discharge corresponding to the desired return period. Where only short series of recorded data are available, the estimates can often be improved by regional frequency analysis (RFA). Unfortunately, there is little information in the literature on analogous approaches for the estimation of extreme groundwater levels. In this contribution, the applicability of l ‐moments‐based RFA for the estimation of extreme groundwater levels is investigated. The main issues specific to groundwater levels are (1) appropriate transformation of the data, (2) criteria for identification of statistically homogeneous regions, (3) consideration of correlation between sites, and (4) choice of distribution function. This study is based on data from more than 1100 observation sites in four shallow Austrian Aquifers with a record length of 10 to 50 years. Results show that homogeneous regions for l ‐moments‐based RFA can be identified covering about one half of the total area of the aquifers. The confidence intervals for the 30‐ and 100‐year return levels can be significantly reduced by RFA. Out of the four investigated distribution functions, none is to be preferred generally.  相似文献   

11.
A prototype flow meter has been developed, based upon the heat perturbation principle, to monitor groundwater specific discharge in soft sediments. The device is designed for use in spatially intensive, long-term monitoring campaigns in remote or inconvenient locations, and is cheap, robust and capable of being logged automatically. The results of the laboratory tests indicate that the heat perturbation principle is suitable for determining the magnitude of specific discharge to a degree of accuracy that would be useful in practical applications in dynamic groundwater systems with rapidly changing flows of approximately 1 md−1 or more and that the groundwater flow direction can generally be determined to a high level of precision. The accuracy and reliability of the estimates of specific discharge have been shown to depend strongly upon the geometrical precision of manufacture and the quality of the temperature monitoring system. These factors become most significant in the estimation of lower flows and further investigation is required to determine the detection limit of the device. Specific discharge estimates have been shown to be insensitive to dispersivity values appropriate to the scale of the device. Unlike the majority of heat perturbation devices, calibration is unnecessary.  相似文献   

12.
A numerical experiment of flow in variably saturated porous media was performed in order to evaluate the spatial and temporal distribution of the groundwater recharge at the phreatic surface for a shallow aquifer as a function of the input rainfall process and soil heterogeneity. The study focused on the groundwater recharge which resulted from the percolation of the excess rainfall for a 90-days period of an actual precipitation record. Groundwater recharge was defined as the water flux across the moving phreatic surface. The observed spatial non-uniformity of the groundwater recharge was caused by soil heterogeneity and is particularly pronounced during the stage of recharge peak (substantial percolation stage). During that stage the recharge is associated with preferential flow paths defined as soil zones of locally higher hydraulic conductivity. For the periods of low percolation intensity the groundwater recharge was exhibiting more uniform spatial characteristics. The temporal distribution of the recharge was found to be a function of the frequency and intensity of the rainfall events. Application of sampling design demonstrates the joint influence of the spatial and temporal recharge variability on the cost-effective monitoring of groundwater potentiometric surfaces.  相似文献   

13.
This study focuses on assessing groundwater potability in a highly complex and heterogeneous fractured bedrock aquifer having variable overburden cover. Eight monitoring wells were installed in a privately serviced lakeside village, and groundwater was routinely sampled over a 2‐year timeframe for concentration analysis of nitrate, fecal indicator bacteria, stable isotopes, and a total of 41 pharmaceutical compounds. While pollutant concentrations remained low throughout the study, the presence of fecal indicator bacteria and pharmaceuticals was noted at least once (but not always consistently) in most sampling intervals. An interpretation based on the integration of chemical, bacterial, and site characterization datasets suggests that: (1) the fracture network is complex and heterogeneous with limited vertical connectivity; (2) existing pathways are sufficient for the quick and widespread migration of surface contaminants to depth; (3) anthropogenic contaminants from both septic systems and agriculture are likely sourced in the surrounding uplands where overburden is thin; and (4) fecal contamination, as observed over the long term, is ubiquitous at the village scale. Groundwater quality is continually changing in this hydrogeologic environment and the determination of potability on the larger scale is not likely to be adequately captured with infrequent domestic well sampling (i.e., voluntary annual sampling by homeowners).  相似文献   

14.
Peter G. Cook 《水文研究》2013,27(25):3694-3707
Environmental tracer methods have been used to quantify groundwater discharge to rivers for the past few decades. A number of different tracers have been used in these studies, including individual ion concentrations, electrical conductivity, stable isotopes 2H and 18O, and the dissolved gases helium, chlorofluorocarbons and radon. This paper discusses the assumptions of the method, as well as its resolution and accuracy. The method will be most accurate when the tracer concentration in groundwater is very distinct from that in the river. On the basis of typical parameters, groundwater inflow rates as low as 5 mm/day can usually be estimated with electrical conductivity and ion tracers. A lower limit of resolution of approximately 2 mm/day is usually possible with radon, principally because the ratio of the river concentration to the groundwater concentration will be higher. However, hyporheic exchange can also contribute radon to the river. Where this process is significant, it is more difficult to estimate groundwater inflow from radon activities in the river, thus reducing the accuracy of the method. For CFCs, the lower limit of resolution is approximately 30 mm/day. Helium has not been widely used but can potentially be very accurate if the groundwater is old. The method assumes steady‐state conditions and so can only be applied when river flows are stable. Sampling resolution is also particularly important for dissolved gases, and uncertainty in where groundwater inflow occurs between sampling points can cause large uncertainty in inflow rates if the distance between sample locations is large. Poor mixing of solutes within the river can limit the method if the river is wide and shallow. When correctly applied, however, the environmental tracer method is able to provide robust estimates of groundwater discharge at a scale and accuracy that is not possible with most other methods. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

15.
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16.
Recent advancements in analytical solutions to quantify water and solute travel time distributions (TTDs) and the related StorAge Selection (SAS) functions synthesize catchment complexity into a simplified, lumped representation. Although these analytical approaches are efficient in application, they require rarely available long‐term and high‐frequency hydrochemical data for parameter estimation. Alternatively, integrated hydrologic models coupled to Lagrangian particle‐tracking approaches can directly simulate age under different catchment geometries and complexity, but at a greater computational expense. Here, we bridge the two approaches, using a physically based model to explore the uncertainty in the estimation of the SAS function shape. In particular, we study the influence of subsurface heterogeneity, interactions between distinct flow domains (i.e., the vadose zone and saturated groundwater), diversity of flow pathways, and recharge rate on the shape of TTDs and the SAS functions. We use an integrated hydrology model, ParFlow, linked with a particle‐tracking model, SLIM, to compute transient residence times (or ages) at every cell in the domain, facilitating a direct characterization of the SAS function. Steady‐state results reveal that the SAS function shape shows a wide range of variation with respect to the variability in the structure of subsurface heterogeneity. Ensembles of spatially correlated realizations of hydraulic conductivity indicate that the SAS functions in the saturated groundwater have an overall weak tendency toward sampling younger ages, whereas the vadose zone gives a strong preference for older ages. We further show that the influence of recharge rate on the TTD is tightly dependent on the variability of subsurface hydraulic conductivity.  相似文献   

17.
Air quality assessment studies have either high sampling or analyses costs. In these studies the representation of a city by a single sampling point is still a serious problem, especially in the metropolitans of developing countries, because of the absence of equipments required for sampling at different locations. In this paper, the smoke data measurements of long years are used in the determination of the region for the representation of the city by drawing contours through the Kriging method. Then, the selection of the sampling site in this region is done on the basis of the criteria recommended by the EPA. By this way, the data taken from this sampling point are used for assessing the average city concentrations with lower sampling and analyses costs. This information is valuable for monitoring the air quality and defining environmental policies, although the local distribution and the extreme concentration values over the city are not measurable.  相似文献   

18.
Seismic events can affect the physico-chemical characteristics of groundwater. These anomalies are of a pre-seismic, co-seismic and post-seismic nature and correspond to pulse variations, sudden increases and decreases without return to initial values and upward or downward changes in trend. Continuous and in situ conductivity and temperature monitoring and periodic water sampling at a hot spring associated with neotectonic activity are of great interest for establishing predictive methods. This method is limited to the seismic activity affecting the fracturing system with which the hot spring is associated. The Region of Murcia and surroundings (southeast Spain) was selected as the study area for exploring the nature of these influences on groundwater. A hot spring in the Leana spa (Murcia) was equipped and monitored during the period 2006–2008, allowing for the in situ determination of conductivity and temperature as well as of major and minor constituents at the laboratory. Due to its proximity and related with fault network, we suggest that 86 % of earthquakes located between 0 and 10 km may affect in situ parameters of groundwater, and 75 % may affect laboratory determinations. This percentage drops in more distant zones. Of all earthquakes that seem to influence groundwater, 55 % of the in situ parameter anomalies and 53 % of laboratory were of a pre-seismic nature.  相似文献   

19.
Mapping groundwater quality in the Netherlands   总被引：4，自引：0，他引：4  
Maps of 25 groundwater quality variables were obtained by estimating 4 km × 4 km block median concentrations. Estimates were presented as approximate 95% confidence intervals related to four concentration levels mostly obtained from critical levels for human consumption. These maps were based on measurements from 425 monitoring sites of national and provincial groundwater quality monitoring networks. The estimation procedure was based on a stratification by soil type and land use. Within each soil-land use category, measurements were interpolated. Spatial dependence between measurements and regional differences in mean level were taken into account. Stratification turned out to be essential: no or partial stratification (using either soil type or land use) results in essentially different maps. The effect of monitoring network density was studied by leaving out the 173 monitoring sites of the provincial monitoring networks. Important changes in resulting maps were assigned to loss of information on short-distance variation, as well as loss of location-specific information. For 12 variables, maps of changes in groundwater quality were made by spatial interpolation of short-term predictions calculated for each well screen from time series of yearly measurements over 5–7 years, using a simple regression model for variation over time and taking location-specific time-prediction uncertainties into account.

From a policy point of view, the resulting maps can be used either for quantifying diffuse groundwater contamination and location-specific background concentrations (in order to assist local contamination assessment) or for input and validation of policy supporting regional or national groundwater quality models. The maps can be considered as a translation of point information obtained from the monitoring networks into information on spatial units, the size of which is used in regional groundwater models. The maps enable location-specific network optimization. In general, the maps give little reason for reducing the monitoring network density (wide confidence intervals).  相似文献   


20.
Gas‐saturated groundwater forms bubbles when brought to atmospheric pressure, preventing precise determination of its in situ dissolved gas concentrations. To overcome this problem, a modeling approach called the atmospheric sampling method is suggested here to recover the in situ dissolved gas concentrations of groundwater collected ex situ under atmospheric conditions at the Horonobe Underground Research Laboratory, Japan. The results from this method were compared with results measured at the same locations using two special techniques, the sealed sampler and pre‐evacuated vial methods, that have been developed to collect groundwater under its in situ conditions. In gas‐saturated groundwater cases, dissolved methane and inorganic carbon concentrations derived using the atmospheric sampling method were mostly within ±4 and ±10%, respectively, of values from the sealed sampler and pre‐evacuated vial methods. In gas‐unsaturated groundwater, however, the atmospheric sampling method overestimated the in situ dissolved methane concentrations, because the groundwater pressure at which bubbles appear (Pcritical) was overestimated. The atmospheric sampling method is recommended for use where gas‐saturated groundwater can be collected only ex situ under atmospheric conditions.  相似文献   

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