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1.
Dolomite aggregates deformed by dislocation creep over a wide range of conditions (T = 700–1000 °C, effective pressure of 900 MPa, strain rates of 10−7 – 10−4/s) strain weaken by up to 75% of the peak differential stress. Microstructural study of samples shortened to different finite strains beyond the peak differential stress shows that strain becomes highly localized within shear zones by high-temperature creep processes, with no contribution of brittle cracking. At low strains (8%), dolomite deforms homogeneously by recrystallization-accommodated dislocation creep. At progressively higher sample strains, deformation is localized into narrow shear zones made up of very fine (∼3 μm) recrystallized grains and relict porphyroclasts (20–100 μm). Finely-recrystallized dolomite grains in the shear zones are largely dislocation free and localized shear is facilitated by diffusion creep. In contrast, original dolomite grains and porphyroclasts in shear zones have high dislocation densities and do not deform after shear zone formation. Calculated strain rates in the shear zones are two to three orders of magnitude faster than the imposed bulk strain rate of the samples and these strain rates are consistent with predictions of the diffusion creep flow law for fine-grained dolomite.  相似文献   

2.
We extended a previous study on the influence of Mg solute impurity on diffusion creep in calcite to include deformation under a broader range of stress conditions and over a wider range of Mg contents. Synthetic marbles were produced by hot isostatic pressing (HIP) mixtures of calcite and dolomite powders for different intervals (2–30 h) at 850°C and 300 MPa confining pressure. The HIP treatment resulted in high-magnesian calcite aggregates with Mg content ranging from 0.5 to 17 mol%. Both back-scattered electron images and chemical analysis suggested that the dolomite phase was completely dissolved, and that Mg distribution was homogeneous throughout the samples at the scale of about two micrometers. The grain size after HIP varied from 8 to 31 μm, increased with time at temperature, and decreased with increasing Mg content (>3.0 mol%). Grain size and time were consistent with a normal grain growth equation, with exponents from 2.4 to 4.7, for samples containing 0.5–17.0 mol% Mg, respectively. We deformed samples after HIP at the same confining pressure with differential stresses between 20 and 200 MPa using either constant strain rate or stepping intervals of loading at constant stresses in a Paterson gas-medium deformation apparatus. The deformation tests took place at between 700 and 800°C and at strain rates between 10−6 and 10−3 s−1. After deformation to strains of about 25%, a bimodal distribution of large protoblasts and small recrystallized neoblasts coexisted in some samples loaded at higher stresses. The deformation data indicated a transition in mechanism from diffusion creep to dislocation creep. At stresses below 40 MPa, the strength was directly proportional to grain size and decreased with increasing Mg content due to the reductions in grain size. At about 40 MPa, the sensitivity of log strain rate to log stress, (n), became greater than 1 and eventually exceeded 3 for stresses above 80 MPa. At a given strain rate and temperature, the stress at which that transition occurred was larger for samples with higher Mg content and smaller grain size. At given strain rates, constant temperature, and fixed grain size, the strength of calcite in the dislocation creep regime increased with solute content, while the strength in the diffusion creep regime was independent of Mg content. The results suggest that chemical composition will be an important element to consider when solid substitution can occur during natural deformation.  相似文献   

3.
Folding experiments have been carried out on single-layers of Carrara marble and Solnhofen limestone at a confining pressure of 275 bars, temperature of 400°C, and strain rates of 5.5×10−7 to 8.2×10−7. The marble and limestone layers were embedded in a rock-salt matrix and in a matrix of a mixture of 60% fine-grained halite and 40% fine-grained calcite, respectively, and deformed to different percentages of bulk shortening. Aspect ratios of the layers varied between 11.25 and 15. The stress-strain relationship reveals that strain increased with a very small increment in compressive stresses, once folding was initiated.With progressive deformation the bulk strain is compensated by folding along one fold hinge. The resulting folds are concentric and a combination of class 1a, 1b and 3 type. The changes in the arc length, layer thickness, limb dip and wavelength with progressive folding in marble layers, are discussed.The microstructure and texture of the folded marble and limestone layers have been investigated optically and by means of an X-ray texture goniometer. The inner fold arc exhibits a strong preferred orientation, whereas in the outer fold are the preferred orientation is poorly developed. Differences in the fabric in medium-grained marble and fine-grained limestone layers have been attributed to the difference in mechanism of deformation.  相似文献   

4.
Post-deformational annealing of calcite rocks   总被引：3，自引：3，他引：3  
The evolution of microstructure and crystallographic preferred orientation (CPO) during post-deformational annealing was studied on three calcite rock types differing in purity and grain size: Carrara marble (98% calcite, mean grain size of 115 μm), Solnhofen limestone (96%, 5 μm) and synthetic calcite aggregates (99%, 7 μm). Samples were first deformed in torsion at 727 °C at a shear strain rate of 3 × 10− 4 s− 1 to a shear strain of 5 and subsequently heat-treated at 727 °C for various durations between 0 and 24 h. Microstructures and CPOs were analysed by optical microscopy, image analysis and electron backscatter diffraction (EBSD).All rock types deformed in the dislocation creep field at the same applied conditions, but their microstructures and CPOs after deformation and after annealing differed depending on starting grain size and material composition. In Carrara marble and in the synthetic calcite aggregate, a strong CPO developed during deformation accompanied by dynamic recrystallisation with significant changes in grain size. During annealing, widespread grain growth and subtle changes of CPO occurred, and equilibrated foam microstructures were approached after long annealing times. The CPO is the only feature in annealed samples indicating an earlier deformation phase, although it is not always identical to the CPO formed during deformation. In the more impure Solnhofen limestone, secondary phases on grain boundaries suppressed grain boundary mobility and prevented both the formation of a recrystallisation CPO during deformation and grain size modification during deformation and annealing.  相似文献   

5.
The NE to ENE trending Mesozoic Xingcheng-Taili ductile shear zone of the northeastern North China Craton was shaped by three phases of deformation. Deformation phase D1 is characterized by a steep, generally E–W striking gneissosity. It was then overprinted by deformation phase D2 with NE-sinistral shear with K-feldspar porphyroclasts forming a subhorizontal low-angle stretching lineation on a steep foliation. During deformation phase D3, lateral motion accommodated by ENE sinistral strike-slip shear zones dominated. Associated fabrics developed at upper greenschist metamorphic facies conditions and show the deformation characteristics of middle- to shallow crustal levels. In some parts, the older structures have been in turn overprinted by late-stage sinistral D3 shearing. Finite strain and kinematic vorticity in all deformed granitic rocks indicate a prolate ellipsoid (L-S tectonites) near plane strain. Simple shear-dominated general shear during D3 deformation is probably of general significance. The quartz c-axis textures indicate prism-gliding with a dominant rhomb <a> slip and basal <a> slip system formed mainly at low-middle temperatures. Mineral deformation behavior, quartz c-axis textures, quartz grain size and the Kruhl thermometer demonstrate that the ductile shear zone developed under greenschist facies metamorphic conditions at deformation temperatures ranging from 400 to 500 °C. Dislocation creep is the main deformation mechanism at a shallow crustal level. Fractal analysis showed that the boundaries of recrystallized quartz grains had statistically self-similarities. Differential stresses deduced from dynamically recrystallized quartz grain size are at around 20–39 MPa, and strain rates in the order of 10−12 to 10−14 s−1. This indicates deformation of granitic rocks in the Xingcheng-Taili ductile shear zone at low strain rates, which is consistent with most other ductile shear zones. Hornblende-plagioclase thermometer and white mica barometer indicate metamorphic conditions of medium pressures at around ca. 3–5 kbar and temperatures of 400–500 °C within greenschist facies conditions. The main D3 deformation of the ENE-trending sinistral strike-slip ductile shearing is related to the roll-back of the subducting Pacific plate beneath the North China Craton.  相似文献   

6.
The Anita Peridotite, in southwestern New Zealand, is a ∼1 × 20 km ultramafic massif that was rapidly extruded from beneath a Cretaceous arc within the 4 km wide mylonitic Anita Shear Zone. The peridotitic body contains a spectacular array of textures that preserve evidence for changing temperature, stress, and deformation mechanisms during the exhumation process. Olivine and orthopyroxene microstructures and lattice-preferred orientations (LPO) record a three-phase deformation history. Dislocation glide on the C- and E-type slip systems is recorded by coarse pre-mylonitised olivine grains, and occurred under hydrous conditions at T ∼650 °C, stress ∼200–700 MPa and strain rate ∼10−15 s−1, probably within hydrated sub-arc mantle lithosphere. Rare protomylonite pods record deformation by dislocation creep in porphyroclasts and dislocation-accommodated grain boundary sliding in the matrix on {0kl}[100] in olivine and (100)[001] in orthopyroxene, under conditions of T ∼730–770 °C, stress ∼52–700 MPa and strain rate ∼10−15 s−1. The massif, however, is dominated by mylonite and ultramylonite that wrap the protomylonite pods, comprising mostly fine-grained olivine neoblasts that lack internal distortions and have uniform LPOs. These textures indicate deformation occurred by grain-size sensitive (GSS) creep at T ∼650 °C, stress ∼69–137 MPa and strain rate ∼10−15 s−1, and thus during conditions of cooling and decreasing stress. GSS creep became more dominant with time, as the proportion of randomly-oriented neoblasts increased and formed interlinked networks that accommodated much of the strain. Grain boundary pinning allowed GSS creep to be maintained in polyphase regions, following mixing of olivine and orthopyroxene, which may have occurred by grain boundary transport in a fluid phase during a “creep cavitation” process. The results indicate that the Anita Peridotite recrystallised and underwent rheological weakening at a constant strain rate, with strain distributed across the entire section. This widespread deformation caused rapid exhumation of the peridotite from the lithospheric mantle into the overlying arc crust. The massif therefore records multiple overprinting phases of deformation under mantle and crustal conditions associated with the rapid exhumation of a large orogenic peridotite.  相似文献   

7.
The calcite mylonites in the Xar Moron-Changchun shear zone show a significance dextral shearing characteristics. The asymmetric(σ-structure) calcite/quartz grains or aggregates, asymmetry of calcite c-axes fabric diagrams and the oblique foliation of recrystallized calcite grains correspond to a top-to-E shearing. Mineral deformation behaviors, twin morphology, C-axis EBSD fabrics, and quartz grain size-frequency diagrams demonstrate that the ductile shear zone was developed under conditions of greenschist facies, with the range of deformation temperatures from 200 to 300°C. These subgrains of host grains and surrounding recrystallized grains, strong undulose extinction, and slightly curved grain boundaries are probably results of intracrystalline deformation and dynamic recrystallization implying that the deformation took place within the dislocation-creep regime at shallow crustal levels. The calculated paleo-strain rates are between 10~(–7.87)s~(–1) and 10~(–11.49)s~(–1) with differential stresses of 32.63–63.94 MPa lying at the higher bound of typical strain rates in shear zones at crustal levels, and may indicate a relatively rapid deformation. The S-L-calcite tectonites have undergone a component of uplift which led to subhorizontal lifting in an already non-coaxial compressional deformation regime with a bulk pure shear-dominated general shear. This E-W large-scale dextral strike-slip movement is a consequence of the eastward extrusion of the Xing'an-Mongolian Orogenic Belt, and results from far-field forces associated with Late Triassic convergence domains after the final closure of the Paleo-Asian Ocean.  相似文献   

8.
Torsion experiments were performed on synthetic aggregates of calcite with a 50% volume of muscovite. The tests were performed at 627–727 °C with a confining pressure of 300 MPa at constant shear strain rates of 3 × 10?5–3 × 10?4 s?1 on cylindrical samples with the starting foliation parallel and perpendicular to the cylinder axis. Both the foliation parallel and the foliation perpendicular experiments show similar stress–strain patterns, with an initial hardening stage followed by significant strain weakening (>60%) before a catastrophic rupture. Microstructural analysis shows that in low-strain experiments calcite grains are intensely twinned while muscovite grains appear slightly bent and kinked. Higher strains promote a segregation of the two phases with calcite forming thin layers of fine, dynamically recrystallized grains, which act as localized shear bands, while muscovite grains keep their original size and rotate assuming a strong shape preferred orientation. This strain localization of the calcite from an initially homogeneous rock produced catastrophic failure at moderate bulk shear strains (γ ～ 3). Localization of the strain first involved ductile deformation to produce a new calcite layering with fine dynamically recrystallized grains along which cavities nucleated. The orientation and kinematics of the cavities are comparable to R1 Riedel structures. All experiments on calcite–muscovite mixtures resulted in heterogeneous strain. In these torsion experiments chemical changes and crystallization of new phases (anorthite and kalsilite) are observed at 627 °C. Whereas, samples hot pressed or deformed in compression at 670 °C did not show such reactions or any localization. The effect of stress-field geometry and pore pressure upon mineral reactions is discussed. It is concluded that deformation-induced heterogeneous phase distributions caused local strength differences initiating strain localization in the calcite–muscovite mixtures, eventually leading to plastic failure.  相似文献   

9.
A detailed structural and microstructural analysis of the Miocene Raft River detachment shear zone (NW Utah) provides insight into the thermomechanical evolution of the continental crust during extension associated with the exhumation of metamorphic core complexes. Combined microstructural, electron backscattered diffraction, strain, and vorticity analysis of the very well exposed quartzite mylonite show an increase in intensity of the rock fabrics from west to east, along the transport direction, compatible with observed finite strain markers and a model of ``necking'' of the shear zone. Microstructural evidence (quartz microstructures and deformation lamellae) suggests that the detachment shear zone evolved at its peak strength, close to the dislocation creep/exponential creep transition, where meteoric fluids played an important role on strain hardening, embrittlement, and eventually seismic failure.Empirically calibrated paleopiezometers based on quartz recrystallized grain size and deformation lamellae spacing show very similar results, indicate that the shear zone developed under stress ranging from 40 MPa to 60 MPa. Using a quartzite dislocation creep flow law we further estimate that the detachment shear zone quartzite mylonite developed at a strain rates between 10−12 and 10−14 s−1. We suggest that a compressed geothermal gradient across this detachment, which was produced by a combination of ductile shearing, heat advection, and cooling by meteoric fluids, may have triggered mechanical instabilities and strongly influenced the rheology of the detachment shear zone.  相似文献   

10.
We describe the structure, microstructures, texture and paleopiezometry of quartz-rich phyllites and marbles along N-trending Moutsounas shear zone at the eastern margin of the Naxos metamorphic core complex (MCC). Fabrics consistently indicate a top-to-the-NNE non-coaxial shear and formed during the main stage of updoming and exhumation between ca. 14 and 11 Ma of the Naxos MCC. The main stage of exhumation postdates the deposition of overlying Miocene sedimentary successions and predates the overlying Upper Miocene/Pliocene conglomerates. Detailed microstructural and textural analysis reveals that the movement along the Moutsounas shear zone is associated with a retrograde greenschist to subgreenschist facies overprint of the early higher-temperature rocks. Paleopiezometry on recrystallized quartz and calcite yields differential stresses of 20–77 MPa and a strain rate of 10−15–10−13 s−1 at 350 °C for quartz and ca. 300 °C for calcite. Chlorite geothermometry of the shear zone yields two temperature regimes, 300–360 °C, and 200–250 °C. The lower temperature group is interpreted to result from late-stage hydrothermal overprint.  相似文献   

11.
郑重  王勤 《高校地质学报》2020,26(2):197-208
白云石CaMg(CO3)2常见于白云岩、灰岩及大理岩中,其稳定的温压范围很广,是研究俯冲隧道变形、全球碳循环和地幔交代作用的重要矿物。白云石的有序度可能与重结晶过程相关,温度是影响白云石有序度的关键因素,压力对白云石有序度的影响较弱。在1~3 GPa 下白云石完全无序的转变温度为1150~1200℃,Fe、Mn、Cd 离子含量的增高可显著降低白云石结构无序化的转变温度。天然变形的白云石常发育由底面c 滑移控制的晶格优选定向。根据白云石的流变律,在天然 应变速率下（10-15~10-12 s-1）,>400℃细粒白云石以扩散蠕变为主;而粗粒白云石以位错蠕变为主,只有在高温下（>600~700℃） 扩散蠕变才成为主控变形机制。分解反应或者动态重结晶可导致白云石流变强度的显著下降,应变集中。白云石c滑移的临界剪应力随温度升高而增大的现象可能与白云石有序度的变化有关,而围压、水逸度和成分对白云石流变的影响尚不清楚,定量研究白云石的有序度与流变学性质的相关性将为追踪碳酸盐岩和大理岩的成岩和变形历史提供新的信息。  相似文献   

12.
The rates of grain growth of stoichiometric dolomite [CaMg(CO3)2] and magnesite (MgCO3) have been measured at temperatures T of 700–800°C at a confining pressure P c of 300 MPa, and compared with growth rates of calcite (CaCO3). Dry, fine-grained aggregates of the three carbonates were synthesized from high purity powders by hot isostatic pressing (HIP); initial mean grain sizes of HIP-synthesized carbonates were 1.4, 1.1, and 17 μm, respectively, for CaMg(CO3)2, MgCO3, and CaCO3, with porosities of 2, 28, and 0.04% by volume. Grain sizes of all carbonates coarsened during subsequent isostatic annealing, with mean values reaching 3.9, 5.1, and 27 μm for CaMg(CO3)2, MgCO3, and CaCO3, respectively, in 1 week. Grain growth of dolomite is much slower than the growth rates of magnesite or calcite; assuming normal grain growth and n = 3 for all three carbonates, the rate constant K for dolomite (≃5 × 10−5 μm3/s) at T = 800°C is less than that for magnesite by a factor of ~30 and less than that for calcite by three orders of magnitude. Variations in carbonate grain growth may be affected by differences in cation composition and densities of pores at grain boundaries that decrease grain boundary mobility. However, rates of coarsening correlate best with the extent of solid solution; K is the largest for calcite with extensive Mg substitution for Ca, while K is the smallest for dolomite with negligible solid solution. Secondary phases may nucleate at advancing dolomite grain boundaries, with implications for deformation processes, rheology, and reaction kinetics of carbonates.  相似文献   

13.
Hyperfiltration is the ability of a membrane to retard the passage of a solute under a hydraulic head in excess of osmotic pressure. Disaggregated and recompacted shales, mudstones, clays and tuff have been shown to exhibit hyperfiltration-induced membrane effects in past experiments. However, limestone and dolomite have not previously been tested. Therefore, eight hyperfiltration experiments were performed on intact Burlington Limestone and Jefferson City Dolomite to assess the membrane properties of these lithologies. Four experiments were conducted on each lithology using 0.0050 and 0.0100 M Cl− solutions at heads of 0.50 and 1.00 m. Reflection coefficients, a measure of osmotic efficiency, ranged from 0.34 to 0.39 for the Burlington Limestone and 0.32 to 0.40 for the Jefferson City Dolomite. At the end of the hyperfiltration experiments, Cl− was concentrated within the cell above input concentrations by 85–95% for the Burlington Limestone and 79–105% for the Jefferson City Dolomite. An additional experiment passed 0.0020 M dissolved silica solution through the Burlington Limestone at a head of 0.965 bar (14 psi). The final concentration of silica within the cell was 0.0043 M dissolved silica at steady-state; a concentration 114% higher than the original input solution concentration. The reflection coefficient for this experiment was calculated to be 0.33. The results of these experiments suggest that membrane properties in these lithologies may be worthy of consideration in some geologic scenarios, including: (1) shallow or perched aquifers bounded by thin limestone or dolomite strata, (2) overpressured aquifers bounded by limestone or dolomite, (3) limestone or dolomite bounded aquifers with significant vertical components of flow, and (4) facies changes with significant lateral component of flow bounded by either lithology. Furthermore, the results suggest that silica cementation may be possible even under relatively low head conditions. Cementation due to hyperfiltration, even at shallow depths and low pressures should be further investigated. Similarly, other low permeability lithologies lacking a charged surface could potentially function as geologic membranes.  相似文献   

14.
Evaluation of mechanical and petrophysical properties of the karst limestone became essential to avoid future risks in the construction of new urban cities built on limestones. Therefore, this study aims to evaluate the impact of karsts phenomena on engineering properties of limestone foundation bed at Ar Riyadh in Saudi Arabia. Three hundred core plugs were obtained by rotary drilling at depths ranging from the ground surface to 20 m collected from 24 boreholes in two sites: (1) karst limestone (KL) at Al Aziziyah district and (2) massive hard limestone (HL) at Hittin district in Ar Riyadh city, Saudi Arabia. Petrographic, SEM, EDX, and XRD analyses are used to identify the mineralogical composition and microstructures of limestone samples. The petrophysical properties included the ovendry density, P-wave, and porosity where the mechanical properties covered the uniaxial compressive strength (UCS), point load strength index (PLI), and rock quality designation (RQD) for the karst and hard limestone samples. KL is characterized by 17.11% total porosity, 14.71% water absorption, 32.1 MPa UCS, 1.70 g/cm3 ovendry density (γ dry), 51% weathered RQD, 5.49 MPa medium shear strength, and low modulus of deformation of the plate loading test. HL showed 11.63% total porosity, 9.45% water absorption 43.1 MPa UCS, 2.50 g/cm3 ovendry density (γ dry), 78% hard to fresh rock affinity RQD, and 9.93 MPa high strength and high modulus of deformation of the plate loading test. For the water absorption (%), KL at Al Aziziyah district showed a range of 12.85–17.80% averaged 14.71%. HL at Hittin district varied between 7.04 and 11.29% with an average of 9.45%. KL proved to be dense with ovendry density (γ dry) averaged at 1.70 g/cm3 while HL showed very dense affinity of 2.50 g/cm3. KL clarified a UCS range from 22.5 to 40.1 MPa and an average of 32.1 MPa while HL showed a range from 35.4 t o 48.1 MPa with an average of 43.1 MPa. KL is moderately weathered with RQD average of 51% while HL showed a hard to fresh rock affinity of 78%. Point load test clarified a medium shear strength with 5.49 MPa for KL and high strength of 9.93 MPa for HL. Plate loading tests indicated low and high modulus of deformation for KL and HL, respectively. Results of petrographical analyses and XED of limestone samples showed that the strength parameters of samples mostly composed of micrite (mudstone/wackestone) and dolomite in hard limestone of Hittin district. In Al Aziziyah district (KL), the samples mostly consist of foraminifera and high amount of calcite as in karst limestone (wackestone/packstone). Rock mechanical tests with combination of fabric analyses have shown that strength parameters depend not only on the amount of karst but also on the amount of allochem. Major geomechanical differences between the two types of limestone provide the proper base for prioritizing areas to alleviate future risks and sustainable urban planning for decision makers. The karstic limestone, therefore, is considered as an acceptable foundation bed for light engineering structures. However, for heavy structures and buildings, improving the foundation bed strength by grouting, cement injection, and mat foundations is necessary to avoid future failure risks.  相似文献   

15.
Four dense Scandinavian limestones were analyzed to determine their mechanical properties. The generation of dust (? 10 μm) and fines (? 90 μm) during a closed circuit vertical roller mill comminution process was correlated with the calcite crystal size distributions of each limestone. Thin sections were analyzed and by means of stereology the calcite crystal size distributions for each limestone was measured. The dust generation of limestones is governed by a surface abrasive mechanism (R2 = 0.99) and the production of fines is governed by the mechanical strength of limestones (R2 = 0.99). The overall limestone degradation mechanism is predominantly controlled by the calcite cleavage planes which reduce the power consumption during the comminution process. This study is the first step in determining the influence of limestone texture on the wear rates in heterogenous raw mixes used in closed circuit comminution equipment.  相似文献   

16.
To investigate the impacts of mineral composition on physical and mechanical properties of carbonate rocks, limestone specimens containing different contents in calcite and dolomite are selected to perform CO2-water-rock reaction experiments. The X-ray Diffraction (XRD) and Nuclear Magnetic Resonance (NMR) are carried out to examine the change characteristics of mineral dissolution and pore structure after reaction. The core flooding experiments with Fiber Bragg gratings are implemented to examine the stress sensitivity of carbonate rocks. The results show that the limestones containing pure calcite are more susceptible to acid dissolution compared to limestone containing impure dolomite. The calcite content in pure limestone decreases as the reaction undergoes. The dissolution of dolomite leads to the formation of calcite in impure limestone. Calcite dissolution leads to the formation of macropore and flow channels in pure limestone, while the effects of impure dolomite in impure limestone results in mesopore formation. When confining pressure is lower than 12 MPa, pure limestones demonstrate higher strain sensitivity coefficients compared to impure limestone containing dolomite after reaction. When confining pressure exceeds 12 MPa, the strain sensitivity coefficients of both pure and impure limestones become almost equal.  相似文献   

17.
This paper is concerned with the mechanical properties of the Great Limestone in northern England. After first outlining the geological structure of the limestone at East Layton in north Yorkshire, the problem of the basal dolomitization of the limestone is introduced and the geochemistry of the rock profile evaluated. It is shown that chemical alteration due to dolomitization is accompanied by a mechanical weakening of the rock and a reduction in the quality of the bond between a tar or bitumen coating medium and the surface of the stone. The two types of rock are compared via specific gravity, moisture absorption, unconfined compressive strength, aggregate impact and aggregate crushing tests. The results from a detailed series of shear box tests taken through from peak to residual shear strength are interpreted through the fundamental strength properties of calcite and dolomite to show that whereas in the size range 200B.S. sieve, dolomite is a little weaker than limestone due to internal weakness associated with volume change; the situation is reversed as the particles decrease in size to form an aggregate of single dolomite crystals which are inherently more resistant to shear.  相似文献   

18.
Residual strain, a self-equilibrating recoverable strain that remains in rocks even after external forces and moments are removed, is found NNW of the folded Appalachian plateau in the Devonian Onondaga limestone and the Silurian Lockport dolomite and Grimsby sandstone of western New York. This residual strain is manifest upon overcoring by a NNW directed maximum expansion of the limestone and sandstone and a random maximum expansion of the dolomite. Strains, recorded with strain gauge rosettes bonded to outcrops, are as high as 200 με (microstrain). Double overcoring of the sandstone and dolomite relieves smaller strains of the same orientation as the initial overcore. X-ray analysis of the Grimsby sandstone shows that the elastic residual strain locked in quartz grains is characterized by a NE principal extension of 60 με and a 10–30 με NW principal compression oriented 30° counterclockwise from the NNW compression indicated by overcoring. Sonic velocity tests on samples in the lab indicate that Grimsby sandstone is anisotropic with a NNW maximum P-wave velocity of 4.05 km/sec. This anisotropy correlates with the residual strain in Grimsby sandstone. Mechanical twinning of calcite within both the Onondaga limestone and Grimsby sandstone indicates that the rock contains a permanent compressive strain of less than 2% in the NNW direction. The permanent strain becomes progressively smaller in a series of samples from Syracuse to Buffalo, New York. The development of solution cleavage in Onondaga limestone also indicates a NNW compression. No evidence of permanent strain was found in the dolomite. The NNW compression of the limestone and sandstone is normal to the fold axes of the Appalachian foreland fold and thrust belt. This geometric relationship indicates that the residual strain well beyond the outermost Appalachian folds was caused by the same tectonic stresses responsible for folding, the Appalachians during the late Paleozoic. Strain within the Appalachian plateau below the Silurian salt horizon suggests either the presence of a second décollement in, perhaps, Ordovician shales or a general NNW shortening of the crust under the Appalachian plateau.  相似文献   

19.
Torsion experiments were performed on the Al2SiO5 polymorphs in the sillimanite stability field to determine basic rheological characteristics and the effect of deformation on polymorphic transformation. The experiments resulted in extensive transformation of andalusite and kyanite to sillimanite. No transformation occurred during the hot-press (no deformation) stage of sample preparation, which was carried out at similar P–T conditions and duration as the torsion experiments. Experiments were conducted on fine-grained (< 15 µm) aggregates of natural andalusite, kyanite and sillimanite at 1250 °C, 300 MPa, and a constant shear strain rate of 2 × 10− 4/s to a maximum shear strain of 400%. Electron back-scattered diffraction (EBSD) analysis of the experiments revealed development of lattice-preferred orientations, with alignment of sillimanite and andalusite [001] slightly oblique to the shear plane. The kyanite experiment could not be analyzed using EBSD because of near complete transformation to sillimanite. Very little strain ( 30%) is required to produce widespread transformation in kyanite and andalusite. Polymorphic transformation in andalusite and kyanite experiments occurred primarily along 500 µm wide shear bands oriented slightly oblique and antithetic to the shear plane and dominated by sub-µm (100–150 nm) fibrolitic sillimanite. Shear bands are observed across the entire strain field preserved in the torsion samples. Scanning transmission electron microscope imaging shows evidence for transformation away from shear bands; e.g. fibrolitic rims on relict andalusite or kyanite. Relict grains typically have an asymmetry that is consistent with shear direction. These experimental results show that sillimanite is by far the weakest of the polymorphs, but no distinction can yet be made on the relative strengths of kyanite and andalusite. These observations also suggest that attaining high bulk strain energy in strong materials such as the Al2SiO5 polymorphs is not necessary for triggering transformation. Strain energy is concentrated along grain boundaries, and transformation occurs by a dynamic recrystallization type process. These experiments also illustrate the importance of grain-size sensitive creep at high strains in a system with simultaneous reaction and deformation.  相似文献   

20.
We conducted axial compression and general shear experiments, at T = 900 °C and P = 1.5 GPa, on samples of banded iron formation (BIF) and synthetic aggregates of quartz, hematite and magnetite to investigate how dynamic recrystallization of quartz promotes strain localization, and the role of weak second phases (oxides) on the rheology and microstructural evolution of the aggregates. Experiments showed strain localization into oxide rich layers, and that the oxide content and oxide distribution are key factors for the strength of the aggregate. Only 2–10 wt.% hematite leads to pronounced weakening and increasing hematite content above ∼10% has only a minor additional effect. Where oxide grains are dispersed, the initial strength contrast with quartz induces stress concentrations at their tips, promoting high stress recrystallization-accommodated dislocation creep of quartz. Fine recrystallized quartz reacts with oxide, forming trails of fine reaction product (ferrosilite/fayalite) leading to the interconnection/percolation of a weaker matrix. The strength contrast between the quartz framework and these fine-grained trails promotes strain localization into micro-shear zones, inducing drastic strain weakening. Thus dynamic recrystallization of quartz promotes syn-deformational reactions leading to a microstructurally-controlled evolution of phase strength contrast. It results in a rheologic transition from load-bearing framework to a matrix-controlled rheology, with transition from S–C′ to S–C fabric with increasing strain.  相似文献   

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