Large-strain deformation and strain partitioning in polyphase rocks: Dislocation creep of olivine–magnesiowüstite aggregates     

Misha Bystricky  Florian Heidelbach  Steve Mackwell   《Tectonophysics》2006,427(1-4):115

Aggregates composed of olivine and magnesiowüstite have been deformed to large strains at high pressure and temperature to investigate stress and strain partitioning, phase segregation and possible localization of deformation in a polyphase material. Samples with 20 vol.% of natural olivine and 80 vol.% of (Mg_0.7Fe_0.3)O were synthesized and deformed in a gas-medium torsion apparatus at temperatures of 1127 °C and 1250 °C, a confining pressure of 300 MPa and constant angular displacement rates equivalent to constant shear strain rates of 1–3.3 × 10^− 4 s^− 1. The samples deformed homogeneously to total shear strains of up to γ  15. During constant strain rate measurements the flow stress remained approximately stable at 1250 °C while it progressively decreased after the initial yield stress at the lower temperature. Mechanical data, microstructures and textures indicate that both phases were deforming in the dislocation creep regime. The weaker component, magnesiowüstite, controlled the rheological behavior of the bulk material and accommodated most of the strain. Deformation and dynamic recrystallization lead to grain refinement and to textures that were not previously observed in pure magnesiowüstite and may have developed due to the presence of the second phase. At 1127 °C, olivine grains behaved as semi-rigid inclusions rotating in a viscous matrix. At 1250 °C, some olivine grains remained largely undeformed while deformation and recrystallization of other grains oriented for a-slip on (010) resulted in a weak foliation and a texture typical for pure dry olivine aggregates. Both a-slip and c-slip on (010) were activated in olivine even though the nominal stresses were up to 2 orders of magnitude lower than those needed to activate these slip systems in pure olivine at the same conditions.  相似文献   

Fe–Mg Interdiffusion in (Mg,Fe)O     

Stephen Mackwell  Misha Bystricky  Caroline Sproni 《Physics and Chemistry of Minerals》2005,32(5-6):418-425

We have performed a series of interdiffusion experiments on magnesiowüstite samples at room pressure, temperatures from 1,320° to 1,400°C, and oxygen fugacities from 10^?1.0 Pa to 10^?4.3 Pa, using mixed CO/CO₂ or H₂/CO₂ gases. The interdiffusion couples were composed of a single-crystal of MgO lightly pressed against a single-crystal of (Mg_1-x Fe _x )_1-δO with 0.07<x<0.27. The interdiffusion coefficient was calculated using the Boltzmann–Matano analysis as a function of iron content, oxygen fugacity, temperature, and water fugacity. For the entire range of conditions tested and for compositions with 0.01<x<0.27, the interdiffusion coefficient varies as $$\tilde D\, =\,2.9\times10^{ - 6}\,f_{{\text{O}}_2 }^{0.19}\,x^{0.73}\,{\text{e}}^{ - (209,000\, -\,96,000\,x)/RT}\,\,{\text{m}}^{\text{2}} {\text{s}}^{ -1} $$ These dependencies on oxygen fugacity and composition are reasonably consistent with interdiffusion mediated by unassociated cation vacancies. For the limited range of water activity that could be investigated using mixed gases at room pressure, no effect of water on interdiffusion could be observed. The dependence of the interdiffusion coefficient on iron content decreased with increasing iron concentration at constant oxygen fugacity and temperature. There is a close agreement between our activation energy for interdiffusion extrapolated to zero iron content (x=0) and that of previous researchers who used electrical conductivity experiments to determine vacancy diffusivities in lightly doped MgO.  相似文献   

Crystal clustering in magmas: Insights from HP–HT experiments     

Laurent Arbaret  Misha Bystricky  Patrick Launeau 《Comptes Rendus Geoscience》2019,351(8):574-585

We have studied by high-resolution X-ray Computed Tomography the effect of crystal clustering on the Shape-Preferred Orientation (SPO) development in synthetic magmas experimentally deformed at 300 MPa and 475–550°C. A fully connected solid network that could potentially induce the onset of yield strength is not achieved in these suspensions containing 16 vol% of crystals. The alumina grain population exhibits a glomeroporphyritic texture made of isolated grains (59.6%) and clusters of touching grains (40.4%). The SPO of the sub-population of isolated grains exhibits foliation and lineation, which are closely parallel to the plane and direction of shear, respectively. The SPO of clustered grains has little influence overall shape fabric. The angular relationships between the average foliation and cluster elongation provide a good indicator of the shear sense. Finally, we highlight the strain partitioning between nearly non-deformed large clusters acting as rigid glomerocrysts and highly sheared zones in low concentrated suspensions.  相似文献   

Bulk modulus of Fe-rich olivines corrected for non-hydrostaticity     

Frédéric Béjina  Misha Bystricky  Nicolas Tercé  Matthew L. Whitaker  Haiyan Chen 《Comptes Rendus Geoscience》2019,351(2-3):86-94

In situ X-ray diffraction was used to measure the isothermal bulk modulus at room conditions (K_T0) of synthetic olivines with different iron contents. The chemical formulae of the olivine samples were ${({\mathrm{Fe}}_x,{\mathrm{Mg}}_{1?x})}_2\mathrm{Si}{\mathrm{O}}_4$ with x = 0.45; 0.64; 0.82; 1, with 1% standard deviation (referenced as Fa45, Fa64, Fa82 and Fa100, respectively). All experiments were performed in the multi-anvil apparatus installed at NSLS beamline X17B2, to pressures up to about 7 GPa. Unit-cell volumes under hydrostatic conditions and differential stresses present in the samples were calculated using the method developed by Singh et al. (1998), and pressures measured using NaCl as a standard were then corrected for these stresses. Using a second-order Birch–Murnaghan equation of state, we obtained the isothermal bulk modulus of each composition: $K_{T0}^{\mathrm{Fa45}}=131.4\pm 2.6$ GPa, $K_{T0}^{\mathrm{Fa64}}=132.1\pm 3.1$ GPa, $K_{T0}^{\mathrm{Fa82}}=136.3\pm 1.7$ GPa and $K_{T0}^{\mathrm{Fa100}}=134.8\pm 1.4$ GPa. These values combined with data available in the literature show that the K_T0 of Fe-rich olivines increases very slowly with the Fe content, but possibly not in a simple linear trend.  相似文献   

Investigations of subsurface flow constructed wetlands and associated geomaterial resources in the Akumal and Reforma regions,Quintana Roo,Mexico     

Mark P. S. Krekeler  Pete Probst  Misha Samsonov  Cynthia M. Tselepis  William Bates  Lance E. Kearns  J. Barry Maynard 《Environmental Geology》2007,53(4):709-726

Subsurface flow constructed wetlands in the village of Akumal, Quintana Roo, Mexico were surveyed to determine the general status of the wetland systems and provide baseline information for long term monitoring and further study. Twenty subsurface flow wetlands were surveyed and common problems observed in the systems were overloading, poor plant cover, odor, and no secondary containment. Bulk mineral composition of aggregate from two subsurface flow constructed wetlands was determined to consist solely of calcite using bulk powder X-ray diffraction. Some soil structure is developed in the aggregate and aggregate levels in wetlands drop at an estimated rate between 3 and 10 cm/year for overloaded wetlands owing to dissolution. Mineral composition from fresh aggregate samples commonly is a mixture of calcite and aragonite. Trace amounts of Pb, Zn, Co, and Cr were observed in fresh aggregate. Coefficients of permeability (k) varied from 0.006 to 0.027 cm/s with an average values being 0.016 cm/s. Grain size analysis of fresh aggregate samples indicates there are unimodal and multimodal size distributions in the samples with modes in the coarse and fine sand being common. Investigations of other geologic media from the Reforma region indicate that a dolomite with minor amounts of Fe-oxide and palygorskite is abundant and may be a better aggregate source that the current materials used. A Ca-montmorillonite bed was identified in the Reforma region as well and this unit is suitable to serve as a clay liner to prevent leaks for new and existing wetland systems. These newly discovered geologic resources should aid in the improvement of subsurface flow constructed wetlands in the region. Although problems do exist in these wetlands with respect to design, these systems represent a successful implementation of constructed wetlands at a community level in developing regions.  相似文献   

The detailed palaeoecology of a mid‐Wisconsinan interstadial (ca. 32 000 14C a BP) vegetation surface from interior Alaska     

Matthew J. Wooller  Grant D. Zazula  Misha. Blinnikov  Benjamin. V. Gaglioti  Nancy. H. Bigelow  Paul. Sanborn  Svetlana. Kuzmina  Catherine. La Farge 《第四纪科学杂志》2011,26(7):746-756

We present a multi‐proxy reconstruction from a well‐preserved vegetation surface (ca. 32 000 ¹⁴C a BP) from the Fox Permafrost tunnel near Fairbanks, Alaska. A thick litter layer of plant material on the vegetation surface is consistent with the vegetation lacking evidence of disturbance. Plant macrofossils and graminoid cuticle analysis show the presence of a graminoid assemblage consistent with phytolith data. The pollen data indicate that trees were not local to the site and that Artemisia sp. was present in the region. The insect and bryophyte reconstructions are consistent with the vascular plant reconstruction, indicating the site was at least periodically wet. δ¹³C values from the graminoids present show a large range encompassing both the wet and dry range displayed by modern graminoids in Alaska. Sequential δ¹³C analyses conducted along the length of leaves attached to the vegetation surface indicate a seasonal shift towards relatively higher water use efficiency. The lower water use efficiency earlier in the growing season may have stemmed from the use of winter season meltwater by plants at the site – a scenario consistent with the site's cryostratigraphy. Our multi‐proxy reconstruction contributes to the limited palaeoecological data available for graminoid‐dominated vegetation present in Eastern Beringia and particularly the interior of Alaska during the mid‐Wisconsinan interstadial. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

Strain localisation in bimineralic rocks: Experimental deformation of synthetic calcite–anhydrite aggregates     

Auke Barnhoorn  Misha Bystricky  Karsten Kunze  Luigi Burlini  Jean-Pierre Burg 《Earth and Planetary Science Letters》2005,240(3-4):748-763

Deformation of synthetic calcite–anhydrite aggregates to large shear strains (up to γ = 12.4 at 600 °C, 300 MPa confining pressure and a constant angular displacement rate corresponding to a shear strain rate of 10^− 3 s^− 1) resulted in the first experimental observation of strain localisation from initially homogeneous rocks. In contrast to experiments on pure calcite and anhydrite, which deformed homogeneously to large strains (γ ≥ 5), all experiments on calcite–anhydrite mixtures resulted in heterogeneous deformation at γ > 1 and the formation of narrow localised bands in the microstructures at γ > 4. In these bands, the amount of strain is at least twice as large as in the rest of the sample and individual grains of the same phase cluster and align, thereby forming microstructural layering similar to planar fabrics in natural mylonites. A switch in deformation mechanism in anhydrite from dislocation creep to diffusion creep and/or grain boundary sliding occurs simultaneously with strain localisation. It is concluded that deformation-induced heterogeneous phase distributions cause local strength differences initiating strain localisation in the calcite–anhydrite mixtures. The study suggests that the presence of two phases in combination with a change in deformation mechanism may be responsible for strain localisation in natural poly-mineralic mylonites.  相似文献   

Post-deformational annealing of calcite rocks   总被引：3，自引：3，他引：3  

Auke Barnhoorn  Misha Bystricky  Luigi Burlini  Karsten Kunze 《Tectonophysics》2005,403(1-4):167-191

The evolution of microstructure and crystallographic preferred orientation (CPO) during post-deformational annealing was studied on three calcite rock types differing in purity and grain size: Carrara marble (98% calcite, mean grain size of 115 μm), Solnhofen limestone (96%, 5 μm) and synthetic calcite aggregates (99%, 7 μm). Samples were first deformed in torsion at 727 °C at a shear strain rate of 3 × 10^{− 4} s^{− 1} to a shear strain of 5 and subsequently heat-treated at 727 °C for various durations between 0 and 24 h. Microstructures and CPOs were analysed by optical microscopy, image analysis and electron backscatter diffraction (EBSD).All rock types deformed in the dislocation creep field at the same applied conditions, but their microstructures and CPOs after deformation and after annealing differed depending on starting grain size and material composition. In Carrara marble and in the synthetic calcite aggregate, a strong CPO developed during deformation accompanied by dynamic recrystallisation with significant changes in grain size. During annealing, widespread grain growth and subtle changes of CPO occurred, and equilibrated foam microstructures were approached after long annealing times. The CPO is the only feature in annealed samples indicating an earlier deformation phase, although it is not always identical to the CPO formed during deformation. In the more impure Solnhofen limestone, secondary phases on grain boundaries suppressed grain boundary mobility and prevented both the formation of a recrystallisation CPO during deformation and grain size modification during deformation and annealing.  相似文献   

Radial mixing in the outer Milky Way disc caused by an orbiting satellite     

A. C. Quillen  Ivan Minchev  Joss Bland-Hawthorn  Misha Haywood 《Monthly notices of the Royal Astronomical Society》2009,397(3):1599-1606

The turbulent diffusion tensor describing the evolution of the mean concentration of a passive scalar is investigated for non-helically forced turbulence in the presence of rotation or a magnetic field. With rotation, the Coriolis force causes a sideways deflection of the flux of mean concentration. Within the magnetohydrodynamics approximation there is no analogous effect from the magnetic field because the effects on the flow do not depend on the sign of the field. Both rotation and magnetic fields tend to suppress turbulent transport, but this suppression is weaker in the direction along the magnetic field. Turbulent transport along the rotation axis is not strongly affected by rotation, except on shorter length-scales, i.e. when the scale of the variation of the mean field becomes comparable with the scale of the energy-carrying eddies. These results are discussed in the context of anisotropic convective energy transport in the Sun.  相似文献